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Title: Structural insights to metal ion linked multilayers on metal oxide surfaces via energy transfer and polarized ATR measurements

Journal Article · · Journal of Materials Chemistry. A
DOI: https://doi.org/10.1039/D4TA05156D · OSTI ID:2459377

UV-vis polarized visible attenuated total reflectance (p-ATR) and Förster Resonance Energy Transfer (FRET) measurements are used to determine the orientation of molecules in metal ion linked multilayers.

Sponsoring Organization:
USDOE
Grant/Contract Number:
SC0001084
OSTI ID:
2459377
Journal Information:
Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 42 Vol. 12; ISSN JMCAET; ISSN 2050-7488
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (64)

Zwischenmolekulare Energiewanderung und Fluoreszenz journal January 1948
A Charge‐Separated State that Lives for Almost a Second at a Conductive Metal Oxide Interface journal November 2018
Self-Assembled Bilayer Films of Ruthenium(II)/Polypyridyl Complexes through Layer-by-Layer Deposition on Nanostructured Metal Oxides journal November 2012
Covalent Surface Modification of Oxide Surfaces journal May 2014
Dichroic Spectra of Anthracene, Acridine and Phenazine in Stretched PVA sheets journal May 1971
Near-infrared electrochromism of multilayer films of a cyclometalated diruthenium complex prepared by layer-by-layer deposition on metal oxide substrates journal November 2019
Calculation of the Förster orientation factor for donor-acceptor systems with one chromophore of threefold or higher symmetry: zinc porphyrin journal November 1994
Spectra of porphyrins journal January 1961
Towards optimisation of electron transfer processes in dye sensitised solar cells journal July 2004
Linkers for anchoring sensitizers to semiconductor nanoparticles journal July 2004
Inhibited interlayer electron transfer in metal ion linked multilayers on mesoporous metal oxide films journal March 2022
Metal ion linked multilayers on mesoporous substrates: Energy/electron transfer, photon upconversion, and more journal March 2020
Integrated optical attenuated total reflection spectrometry of aqueous superstrates using prism-coupled polymer waveguides journal October 1990
Photocatalyst–Mediator Interface Modification by Surface-Metal Cations of a Dye-Sensitized H2 Evolution Photocatalyst journal July 2022
Ultrafast Time-Resolved Emission and Absorption Spectra of meso -Pyridyl Porphyrins upon Soret Band Excitation Studied by Fluorescence Up-Conversion and Transient Absorption Spectroscopy journal August 2016
Examining the Influence of Bilayer Structure on Energy Transfer and Molecular Photon Upconversion in Metal Ion Linked Multilayers journal October 2020
Molecular Orientation of −PO3H2 and −COOH Functionalized Dyes on TiO2, Al2O3, ZrO2, and ITO: A Comparative Study journal January 2023
Differentiating Intra-Assembly and Interlayer Energy Transfer in Metal-Ion-Linked Molecular Multilayers journal August 2024
Porphyrin–Anthracene Complexes: Potential in Triplet–Triplet Annihilation Upconversion journal August 2016
Surface Modification of Indium–Tin Oxide with Functionalized Perylene Diimides: Characterization of Orientation, Electron-Transfer Kinetics and Electronic Structure journal September 2016
Elucidating the Energy- and Electron-Transfer Dynamics of Photon Upconversion in Self-Assembled Bilayers journal August 2017
Zinc Phthalocyanine–Phosphonic Acid Monolayers on ITO: Influence of Molecular Orientation, Aggregation, and Tunneling Distance on Charge-Transfer Kinetics journal February 2019
Photon Upconversion and Photocurrent Generation via Self-Assembly at Organic–Inorganic Interfaces journal October 2015
Layer-by-Layer Naphthalenediimide/Zn Phosphonate Hybrid Films Grown from Aqueous Solutions by a Simple Deposition Technique journal February 2021
Molecular Orientation and Energy Transfer Dynamics of a Metal Oxide Bound Self-Assembled Trilayer journal July 2023
PM-IRRAS Determination of Molecular Orientation of Phosphonic Acid Self-Assembled Monolayers on Indium Zinc Oxide journal May 2015
Current-Driven Supramolecular Motor with In Situ Surface Chiral Directionality Switching journal June 2015
Role of Metal Ion-Linked Multilayer Thickness and Substrate Porosity in Surface Loading, Diffusion, and Solar Energy Conversion journal July 2020
Harnessing Sunlight via Molecular Photon Upconversion journal July 2021
Inhibiting Interfacial Recombination Events in Dye-Sensitized Solar Cells using Self-Assembled Bilayers journal December 2015
Energy and Electron Transfer Cascade in Self-Assembled Bilayer Dye-Sensitized Solar Cells journal October 2016
Axially Bound Ruthenium Phthalocyanine Monolayers on Indium Tin Oxide: Structure, Energetics, and Charge Transfer Properties journal August 2017
Integrated Photon Upconversion Solar Cell via Molecular Self-Assembled Bilayers journal April 2016
Singlet Sensitization-Enhanced Upconversion Solar Cells via Self-Assembled Trilayers journal May 2019
Synthetic Routes to meso -Patterned Porphyrins journal February 2010
Visible Light-Driven Water Splitting in Photoelectrochemical Cells with Supramolecular Catalysts on Photoanodes journal May 2014
Substituent effects on the electronic structure of metalloporphyrins: a quantitative analysis in terms of four-orbital-model parameters journal October 1985
Linear dichroism spectroscopy as a tool for studying molecular orientation in model membrane systems journal November 1977
Growth and characterization of metal(II) alkanebisphosphonate multilayer thin films on gold surfaces journal December 1993
Chromophore Structure, Second Harmonic Generation, and Orientational Order in Zirconium Phosphonate/Phosphate Self-Assembled Multilayers journal July 1994
Molecular Orientation Distributions in Protein Films. 1. Cytochrome c Adsorbed to Substrates of Variable Surface Chemistry journal January 1997
Harnessing Molecular Photon Upconversion in a Solar Cell at Sub-solar Irradiance: Role of the Redox Mediator journal August 2017
Efficiencies of Electron Injection from Excited N3 Dye into Nanocrystalline Semiconductor (ZrO 2 , TiO 2 , ZnO, Nb 2 O 5 , SnO 2 , In 2 O 3 ) Films journal April 2004
Modulating Electron Transfer Dynamics at Dye–Semiconductor Interfaces via Self-Assembled Bilayers journal February 2015
Coupling of Titania Inverse Opals to Nanocrystalline Titania Layers in Dye-Sensitized Solar Cells journal November 2008
Ultrafast Photoinduced Electron Transfer in a π-Conjugated Oligomer/Porphyrin Complex journal September 2014
Mechanistic Studies of Film Growth of Zirconium Bis(phosphonate) Mono- and Multilayer Thin Films. These Things Grow Darned Flat! journal November 1995
Determining the Orientation and Molecular Packing of Organic Dyes on a TiO 2 Surface Using X-ray Reflectometry journal November 2011
Orientation of Phenylphosphonic Acid Self-Assembled Monolayers on a Transparent Conductive Oxide: A Combined NEXAFS, PM-IRRAS, and DFT Study journal February 2013
Self-assembled molecular p/n junctions for applications in dye-sensitized solar energy conversion journal June 2016
Layer-by-layer grown scalable redox-active ruthenium-based molecular multilayer thin films for electrochemical applications and beyond journal January 2015
Photoelectrochemical hydrogen production in water using a layer-by-layer assembly of a Ru dye and Ni catalyst on NiO journal January 2016
Multimolecular assemblies on high surface area metal oxides and their role in interfacial energy and electron transfer journal January 2018
Singlet and triplet energy transfer dynamics in self-assembled axial porphyrin–anthracene complexes: towards supra-molecular structures for photon upconversion journal January 2018
Examining the role of acceptor molecule structure in self-assembled bilayers: surface loading, stability, energy transfer, and upconverted emission journal January 2018
Triplet–triplet annihilation based near infrared to visible molecular photon upconversion journal January 2020
Relative Orientation of Molecules Involved in Triplet–Triplet Energy Transfer journal April 1969
Orientation Dependence in Triplet–Triplet Energy Transfer: Analysis of Magnetophotoselection Experiments journal November 1970
A Theory of Sensitized Luminescence in Solids journal May 1953
Donor—Acceptor Relative Orientation for Maximum Triplet—Triplet Energy Transfer journal June 1964
Energy transfer: a spectroscopic ruler. journal August 1967
Influence of meta- and para-phosphonated diphenylanthracene on photon upconversion in self-assembled bilayers journal November 2017
Technique for determining the angular orientation of molecules bound to the surface of an arbitrary planar optical waveguide journal January 2004
Broadband Spectroelectrochemical Attenuated Total Reflectance Instrument for Molecular Adlayer Studies journal July 2002