Quantifying the Temperature Dependence of the Multi-Species, Multi-Reaction Model: Part II. Estimation of Entropy Coefficient for Meso-Carbon Micro-Bead Graphite

Paul, Abigail; Wolfe, Kody; Verbrugge, Mark W.; Koch, Brian J.; Lowe, Jeffrey S.; Trembly, Jason; Staser, John A.; Garrick, Taylor R.

doi:10.1149/1945-7111/ad70d9

Title: Quantifying the Temperature Dependence of the Multi-Species, Multi-Reaction Model: Part II. Estimation of Entropy Coefficient for Meso-Carbon Micro-Bead Graphite

Journal Article · 07 October 2024 · Journal of the Electrochemical Society

DOI: https://doi.org/10.1149/1945-7111/ad70d9 · OSTI ID:2459353

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; Koch, Brian J.;

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In Part 1 of this paper, the temperature impact on the Multi-Species, Multi Reaction (MSMR) model was studied. This was accomplished by acquiring data from slow rate lithiation and delithiation of a meso-carbon micro-bead (MCMB) graphite. Through this analysis, the temperature impact on the total fraction of available host sites in a particular MSMR gallery (X _j ), the impact on the reference potential ( $U_{j}^{o}$ ), and the impact on the parameter detailing the deviation from Nernstian behavior ( ω _j ) was determined. Here, the intercalation material is discussed, compared to traditional methods of acquiring the entropy coefficient, and comparison is made to previous mathematical estimates. Some of the challenges in using temperature dependent constant rate charge and discharge data as compared to the potentiodynamic entropy coefficient calculation method are also discussed, and a recommendation for future applications is proposed.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: FE0032144

OSTI ID:: 2459353

Journal Information:: Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Journal Issue: 10 Vol. 171; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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