High–Performance NiCo2O4/Graphene Quantum Dots for Asymmetric and Symmetric Supercapacitors with Enhanced Energy Efficiency

Lakshmi‐Narayana, Ambadi; Attarzadeh, Navid; Shutthanandan, Vaithalingam; Ramana, Chintalapalle V.

doi:10.1002/adfm.202316379

Title: High–Performance NiCo₂O₄/Graphene Quantum Dots for Asymmetric and Symmetric Supercapacitors with Enhanced Energy Efficiency

Journal Article · 16 May 2024 · Advanced Functional Materials

DOI: https://doi.org/10.1002/adfm.202316379 · OSTI ID:2458227

Lakshmi‐Narayana, Ambadi ^[1]; Attarzadeh, Navid ^[1];

^[2];

^[3]

Univ. of Texas at El Paso, TX (United States)
Univ. of Texas at El Paso, TX (United States); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States). Environmental Molecular Sciences Laboratory (EMSL)
Univ. of Texas at El Paso, TX (United States); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

For the sustainable growth of future generations, energy storage technologies like supercapacitors and batteries are becoming more and more common. However, reliable and high-performance materials’ design and development is the key for the widespread adoption of batteries and supercapacitors. Quantum dots with fascinating and unusual properties are expected to revolutionize future technologies. However, while the recent discovery of quantum dots honored with a Nobel prize in Chemistry, their benefits for the tenacious problem of energy are not realized yet. In this context, herein, chemical-composition tuning enabled exceptional performance of NiCo₂O₄(NCO)/graphene quantum dots (GQDs) is reported, which outperform the existing similar materials, in supercapacitors. A comprehensive study is performed on the synthesis, characterization, and electrochemical performance evaluation of highly functional NCO/GQDs in supercapacitors delivering enhanced energy efficiency. The high-performance, functional NCO/GQDs electrode materials are synthesized by the incorporation of GQDs into NCO. The effect of variable amount of GQDs on the energy performance characteristics of NCO/GQDs in supercapacitors is studied systematically. In-depth structural and chemical bonding analyses using X-ray diffraction (XRD) and Raman spectroscopic studies indicate that all the NCO/GQDs composites crystallize in the spinel cubic phase of NiCo₂O₄ while graphene integration evident in all the NCO/GQDs. The scanning electron microscopy imaging analysis reveals homogeneously distributed spherical particles with a size distribution of 5–9 nm validating the formation of QDs. The high-resolution transmission electron microscopy analyses reveal that the NCOQDs are anchored on graphene sheets, which provide a high surface area of 42.27 m²g^–1 and high mesoporosity for the composition of NCO/GQDs-10%. In addition to establishing reliable electrical connection to graphene sheets, the NCOQDs provide reliable 3D-conductive channels for rapid transport throughout the electrode as well as synergistic effects. Chemical-composition tuning, and optimization yields NCO/GQDs-10% to deliver the best specific capacitance of 3940 Fg^–1 at 0.5 Ag^–1, where the electrodes retain ≈98% capacitance after 5000 cycles. The NCO/GQD-10%//AC asymmetric supercapacitor device demonstrates outstanding energy density and power density values of 118.04 Wh kg^–1 and 798.76 W kg^–1, respectively. The NCO/GQDs-10%//NCO/GQDs-10% symmetric supercapacitor device delivers excellent energy and power density of 24.30 Wh kg^–1 and 500 W kg^–1, respectively. These results demonstrate and conclude that NCO/GQDs are exceptional and prospective candidates for developing next-generation high-performance and sustainable energy storage devices.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: Environmental Molecular Sciences Laboratory (EMSL); National Science Foundation (NSF); USDOE Laboratory Directed Research and Development (LDRD) Program

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 2458227

Report Number(s):: PNNL-SA--197273

Journal Information:: Advanced Functional Materials, Journal Name: Advanced Functional Materials Journal Issue: 40 Vol. 34; ISSN 1616-301X

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (94)

Ultrathin Mesoporous NiCo ₂ O ₄ Nanosheets Supported on Ni Foam as Advanced Electrodes for Supercapacitors Yuan, Changzhou; Li, Jiaoyang; Hou, Linrui Advanced Functional Materials, Vol. 22, Issue 21 https://doi.org/10.1002/adfm.201200994	journal	June 2012
Tailoring Ordered Mesoporous Titania Films via Introducing Germanium Nanocrystals for Enhanced Electron Transfer Photoanodes for Photovoltaic Applications Li, Nian; Guo, Renjun; Chen, Wei Advanced Functional Materials, Vol. 31, Issue 34 https://doi.org/10.1002/adfm.202102105	journal	June 2021
ZnCo ₂ O ₄ Quantum Dots Anchored on Nitrogen-Doped Carbon Nanotubes as Reversible Oxygen Reduction/Evolution Electrocatalysts Liu, Zhao-Qing; Cheng, Hui; Li, Nan Advanced Materials, Vol. 28, Issue 19 https://doi.org/10.1002/adma.201506197	journal	March 2016
A High-Energy Density Asymmetric Supercapacitor Based on Fe ₂ O ₃ Nanoneedle Arrays and NiCo ₂ O ₄ /Ni(OH) ₂ Hybrid Nanosheet Arrays Grown on SiC Nanowire Networks as Free-Standing Advanced Electrodes Zhao, Jian; Li, Zhenjiang; Yuan, Xiangcheng Advanced Energy Materials, Vol. 8, Issue 12 https://doi.org/10.1002/aenm.201702787	journal	January 2018
Carbon Dots as New Building Blocks for Electrochemical Energy Storage and Electrocatalysis Zhai, Yunpu; Zhang, Baowei; Shi, Run Advanced Energy Materials, Vol. 12, Issue 6 https://doi.org/10.1002/aenm.202103426	journal	December 2021
Hierarchical Hybrids of Mesoporous NiCo₂O₄ Needles/Graphene/Carbon Nanotubes with High Performance for Lithium Ion Batteries and Oxygen Reduction Reactions Yan, Yan; Liu, Yuqing; Ni, Weiyan ChemNanoMat, Vol. 2, Issue 12 https://doi.org/10.1002/cnma.201600259	journal	October 2016
Effect of Urea on the Morphology of Co₃O₄ Nanostructures and Their Application for Potentiometric Glucose Biosensor Ibupoto, Zafar Hussain; Elhag, Sami; AlSalhi, M. S. Electroanalysis, Vol. 26, Issue 8 https://doi.org/10.1002/elan.201400116	journal	July 2014
Germanium‐Functionalized 3D Microporous, Nanostructured Nickel–Nickel Oxides for Application in Asymmetric Supercapacitors Kr Singh, Balwant; Das, Debabrata; Gonzalez, Cristina Energy Technology, Vol. 11, Issue 10 https://doi.org/10.1002/ente.202300360	journal	September 2023
Electrochemical storage behavior of NiCo ₂ O ₄ nanoparticles anode with structural and morphological evolution in lithium‐ion and sodium‐ion batteries Islam, Mobinul; Ali, Ghulam; Jeong, Min‐Gi International Journal of Energy Research, Vol. 45, Issue 10 https://doi.org/10.1002/er.6782	journal	April 2021
Enhanced electrochemical performance of 3‐D microporous nickel/nickel oxide nanoflakes for application in supercapacitors Singh, Balwant Kr.; Das, Debabrata; Attarzadeh, Navid Nano Select, Vol. 4, Issue 2 https://doi.org/10.1002/nano.202200180	journal	January 2023
XPS and Raman spectroscopic characterization of LiMn2O4 spinels Ramana, C. V.; Massot, M.; Julien, C. M. Surface and Interface Analysis, Vol. 37, Issue 4 https://doi.org/10.1002/sia.2022	journal	January 2005
X-ray photoelectron spectroscopic chemical state quantification of mixed nickel metal, oxide and hydroxide systems Biesinger, Mark C.; Payne, Brad P.; Lau, Leo W. M. Surface and Interface Analysis, Vol. 41, Issue 4 https://doi.org/10.1002/sia.3026	journal	April 2009
Li₂TiO₃/Graphene and Li₂TiO₃/CNT Composites as Anodes for High Power Li–Ion Batteries Lakshmi‐Narayana, Ambadi; Dhananjaya, Merum; Guru‐Prakash, Nunna ChemistrySelect, Vol. 3, Issue 31 https://doi.org/10.1002/slct.201801510	journal	August 2018
Facile Synthesis of a NiCo₂O₄ Nanoparticles Mesoporous Carbon Composite as Electrode Materials for Supercapacitor Nguyen, Nghia V.; Tran, Thu V.; Luong, Son T. ChemistrySelect, Vol. 5, Issue 23 https://doi.org/10.1002/slct.202001410	journal	June 2020
Graphene Quantum Dots Pinned on Nanosheets‐Assembled NiCo‐LDH Hollow Micro‐Tunnels: Toward High‐Performance Pouch‐Type Supercapacitor via the Regulated Electron Localization Zhao, Tingting; Liu, Cong; Meng, Tao Small, Vol. 18, Issue 20 https://doi.org/10.1002/smll.202201286	journal	April 2022
Lewis Acid Site Assisted Bifunctional Activity of Tin Doped Gallium Oxide and Its Application in Rechargeable Zn‐Air Batteries Nair, Aruna Narayanan; Sanad, Mohamed F.; Jayan, Rahul Small, Vol. 18, Issue 34 https://doi.org/10.1002/smll.202202648	journal	July 2022
Advanced Composite Solid Electrolytes for Lithium Batteries: Filler Dimensional Design and Ion Path Optimization Zheng, Feifan; Li, Chunwei; Li, Zongcheng Small, Vol. 19, Issue 21 https://doi.org/10.1002/smll.202206355	journal	February 2023
Ultrastretchable MXene Microsupercapacitors Wang, Menglu; Feng, Shuxuan; Bai, Chong Small, Vol. 19, Issue 21 https://doi.org/10.1002/smll.202300386	journal	February 2023
A Mechanistic Study on the Structure Formation of NiCo2O4 Nanofibers Decorated with In Situ Formed Graphene-Like Structures Sachin Kumar, B.; Gudla, Visweswara C.; Ambat, Rajan Journal of Inorganic and Organometallic Polymers and Materials, Vol. 28, Issue 5 https://doi.org/10.1007/s10904-018-0842-7	journal	April 2018
Fabrication of Ni-Co binary oxide/reduced graphene oxide composite with high capacitance and cyclicity as efficient electrode for supercapacitors Bai, Yang; Liu, Miaomiao; Sun, Jing Ionics, Vol. 22, Issue 4 https://doi.org/10.1007/s11581-015-1576-y	journal	October 2015
Nanocrystalline Li2TiO3 electrodes for supercapattery application Lakshmi Narayana, A.; Dhananjaya, M.; Guru Prakash, N. Ionics, Vol. 23, Issue 12 https://doi.org/10.1007/s11581-017-2147-1	journal	May 2017
Ultrahigh energy density battery-type asymmetric supercapacitors: NiMoO4 nanorod-decorated graphene and graphene/Fe2O3 quantum dots Yang, Jiao; Liu, Wei; Niu, Hao Nano Research, Vol. 11, Issue 9 https://doi.org/10.1007/s12274-018-2059-z	journal	April 2018
PEDOT Nanowires and Platinum Nanoparticles Modified Electrodes to be Assayed in Formic Acid Electro-oxidation del Valle, M. A.; Salgado, R.; Armijo, F. International Journal of Electrochemical Science, Vol. 9, Issue 3 https://doi.org/10.1016/S1452-3981(23)07813-6	journal	March 2014
Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni Biesinger, Mark C.; Payne, Brad P.; Grosvenor, Andrew P. Applied Surface Science, Vol. 257, Issue 7, p. 2717-2730 https://doi.org/10.1016/j.apsusc.2010.10.051	journal	January 2011
Graphene quantum dots encapsulated tremella-like NiCo2O4 for advanced asymmetric supercapacitors Luo, Jiahuan; Wang, Jing; Liu, Sen Carbon, Vol. 146 https://doi.org/10.1016/j.carbon.2019.01.078	journal	May 2019
NiCo2O4/graphene quantum dots (GQDs) for use in efficient electrochemical energy devices: An electrochemical and X-ray absorption spectroscopic investigation Chang, Han-Wei; Fu, Ji-Xuan; Huang, Yu-Cheng Catalysis Today, Vol. 348 https://doi.org/10.1016/j.cattod.2019.10.013	journal	May 2020
Designing flexible asymmetric supercapacitor with high energy density by electrode engineering and charge matching mechanism Qu, Guangmeng; Wang, Zonghua; Zhang, Xixi Chemical Engineering Journal, Vol. 429 https://doi.org/10.1016/j.cej.2021.132406	journal	February 2022
XPS and structural studies of high quality graphene oxide and reduced graphene oxide prepared by different chemical oxidation methods Al-Gaashani, R.; Najjar, A.; Zakaria, Y. Ceramics International, Vol. 45, Issue 11 https://doi.org/10.1016/j.ceramint.2019.04.165	journal	August 2019
Urchin-like NiCo2O4 microsphere by hydrothermal route: Structural, electrochemical, optical and magnetic properties Nayak, Priyambada; Sahoo, M.; Nayak, Saroj K. Ceramics International, Vol. 46, Issue 3 https://doi.org/10.1016/j.ceramint.2019.10.105	journal	February 2020
TiO2 thin films on Au/Ti/SiO2/textured Si substrates as high capacity anode materials for Li-ion batteries Lakshmi-Narayana, Ambadi; Zhang, Liwen; Jiao, Caiming Ceramics International, Vol. 46, Issue 8 https://doi.org/10.1016/j.ceramint.2020.01.024	journal	June 2020
Graphene-quantum-dots induced NiCo2S4 with hierarchical-like hollow nanostructure for supercapacitors with enhanced electrochemical performance Huang, Yuanyuan; Shi, Tielin; Zhong, Yan Electrochimica Acta, Vol. 269 https://doi.org/10.1016/j.electacta.2018.02.145	journal	April 2018
Facile synthesis of NiCo2O4 quantum dots for asymmetric supercapacitor Siwatch, Poonam; Sharma, Kriti; Tripathi, S. K. Electrochimica Acta, Vol. 329 https://doi.org/10.1016/j.electacta.2019.135084	journal	January 2020
Enhanced supercapacitive performance of reduced graphene oxide by incorporating NiCo2O4 quantum dots using aqueous electrolyte Siwatch, Poonam; Sharma, Kriti; Singh, Navjot Electrochimica Acta, Vol. 381 https://doi.org/10.1016/j.electacta.2021.138235	journal	June 2021
Li2TiO3/Ni foam composite as high-performance electrode for energy storage and conversion Lakshmi-Narayana, A.; Dhananjaya, M.; Guru-Prakash, N. Heliyon, Vol. 5, Issue 7 https://doi.org/10.1016/j.heliyon.2019.e02060	journal	July 2019
Urchin and sheaf-like NiCo 2 O 4 nanostructures: Synthesis and electrochemical energy storage application Umeshbabu, Ediga; Rajeshkhanna, G.; Rao, G. Ranga International Journal of Hydrogen Energy, Vol. 39, Issue 28 https://doi.org/10.1016/j.ijhydene.2014.07.168	journal	September 2014
Formation of ultrafine three-dimensional hierarchical birnessite-type MnO2 nanoflowers for supercapacitor Yan, Dongliang; Zhang, Huan; Li, Shichao Journal of Alloys and Compounds, Vol. 607 https://doi.org/10.1016/j.jallcom.2014.04.077	journal	September 2014
Graphene quantum dots decorated on spinel nickel cobaltite nanocomposites for boosting supercapacitor electrode material performance Kharangarh, Poonam R.; Ravindra, Nuggehalli M.; Rawal, Rachna Journal of Alloys and Compounds, Vol. 876 https://doi.org/10.1016/j.jallcom.2021.159990	journal	September 2021
Designing vertically aligned porous NiCo2O4@MnMoO4 Core@Shell nanostructures for high-performance asymmetric supercapacitors Singh, Arvind; Ojha, Animesh K. Journal of Colloid and Interface Science, Vol. 580 https://doi.org/10.1016/j.jcis.2020.07.062	journal	November 2020
Nitrogen-doped carbon quantum dots (N-CQDs)/Co3O4 nanocomposite for high performance supercapacitor Naushad, Mu.; Ahamad, Tansir; Ubaidullah, Mohd Journal of King Saud University - Science, Vol. 33, Issue 1 https://doi.org/10.1016/j.jksus.2020.101252	journal	January 2021
Electronic structure and chemical bonding in transition-metal-mixed gallium oxide (Ga2O3) compounds Ramana, C. V.; Roy, Swadipta; Zade, Vishal Journal of Physics and Chemistry of Solids, Vol. 157 https://doi.org/10.1016/j.jpcs.2021.110174	journal	October 2021
Enhanced activity of microwave synthesized hierarchical MnO2 for high performance supercapacitor applications Meher, Sumanta Kumar; Rao, G. Ranga Journal of Power Sources, Vol. 215 https://doi.org/10.1016/j.jpowsour.2012.04.104	journal	October 2012
Recent progress on development of electrolyte and aerogel electrodes applied in supercapacitors Xiong, Chuanyin; Zhang, Yongkang; Ni, Yonghao Journal of Power Sources, Vol. 560 https://doi.org/10.1016/j.jpowsour.2023.232698	journal	March 2023
Effects of oxygen-containing functional groups on carbon materials in supercapacitors: A review Qiu, Chunjuan; Jiang, Lili; Gao, Yige Materials & Design, Vol. 230 https://doi.org/10.1016/j.matdes.2023.111952	journal	June 2023
Preparation and performance of NiCo2O4 nanowires-loaded graphene as supercapacitor material He, Guangyu; Wang, Lin; Chen, Haiqun Materials Letters, Vol. 98 https://doi.org/10.1016/j.matlet.2013.02.035	journal	May 2013
Fabrication of hollow NiCo 2 O 4 nanoparticle/graphene composite for supercapacitor electrode Sun, Shumin; Li, Shaodan; Wang, Shen Materials Letters, Vol. 182 https://doi.org/10.1016/j.matlet.2016.06.063	journal	November 2016
Flexible all-solid-state hierarchical NiCo2O4/porous graphene paper asymmetric supercapacitors with an exceptional combination of electrochemical properties Gao, Zan; Yang, Wanlu; Wang, Jun Nano Energy, Vol. 13 https://doi.org/10.1016/j.nanoen.2015.02.036	journal	April 2015
Li2TiO3-MWCNT nanocomposite electrodes for determination of dopamine in electrochemical sensing platform Narayana, A. Lakshmi; Venkataprasad, G.; Praveen, Sekar Sensors and Actuators A: Physical, Vol. 341 https://doi.org/10.1016/j.sna.2022.113555	journal	July 2022
New interpretations of XPS spectra of nickel metal and oxides Grosvenor, Andrew P.; Biesinger, Mark C.; Smart, Roger St. C. Surface Science, Vol. 600, Issue 9 https://doi.org/10.1016/j.susc.2006.01.041	journal	May 2006
Graphene Quantum Dots Embedded in NiCo₂S₄/MWCNT Nanocomposite as a Promising Candidate for Supercapacitors and I₃^– Reduction in Dye-Sensitized Solar Cells Gayathri, V.; John Peter, I.; Ramachandran, K. Energy & Fuels, Vol. 35, Issue 16 https://doi.org/10.1021/acs.energyfuels.1c01471	journal	August 2021
Effect of Dy³⁺ and Tb³⁺ Rare-Earth Cation Co-Substitution on the Structure, Magnetic, and Magnetostrictive Properties of Ni-Co-Ferrites Gaikwad, Swati K.; Kharat, Shahaji P.; Haritha, Keerthi Inorganic Chemistry, Vol. 62, Issue 30 https://doi.org/10.1021/acs.inorgchem.3c01117	journal	July 2023
Formation, Electronic Structure, and Defects of Ni Substituted Spinel Cobalt Oxide: a DFT+U Study Shi, Xiao; Bernasek, Steven L.; Selloni, Annabella The Journal of Physical Chemistry C, Vol. 120, Issue 27 https://doi.org/10.1021/acs.jpcc.6b03096	journal	June 2016
High-Performance Supercapacitor Based on Three-Dimensional Hierarchical rGO/Nickel Cobaltite Nanostructures as Electrode Materials Foo, Chuan Yi; Lim, Hong Ngee; Mahdi, Mohd Adzir b. The Journal of Physical Chemistry C, Vol. 120, Issue 38 https://doi.org/10.1021/acs.jpcc.6b05930	journal	September 2016
Effect of High-Anisotropic Co²⁺ Substitution for Ni²⁺ on the Structural, Magnetic, and Magnetostrictive Properties of NiFe₂O₄: Implications for Sensor Applications Satish, Mudalagiriyappa; Shashanka, Hadonahalli Munegowda; Saha, Sujoy ACS Applied Materials & Interfaces, Vol. 15, Issue 12 https://doi.org/10.1021/acsami.2c23025	journal	March 2023
Enhanced Electrochemical Performance of Rare-Earth Metal-Ion-Doped Nanocrystalline Li₄Ti₅O₁₂Electrodes in High-Power Li-Ion Batteries Lakshmi-Narayana, A.; Dhananjaya, Merum; Julien, Christian M. ACS Applied Materials & Interfaces, Vol. 15, Issue 17 https://doi.org/10.1021/acsami.3c00175	journal	April 2023
Nature-Inspired Design of Nano-Architecture-Aligned Ni₅P₄-Ni₂P/NiS Arrays for Enhanced Electrocatalytic Activity of Hydrogen Evolution Reaction (HER) Attarzadeh, Navid; Das, Debabrata; Chintalapalle, Srija N. ACS Applied Materials & Interfaces, Vol. 15, Issue 18 https://doi.org/10.1021/acsami.3c00781	journal	April 2023
Three-Dimensional NiCo ₂ O ₄ @Polypyrrole Coaxial Nanowire Arrays on Carbon Textiles for High-Performance Flexible Asymmetric Solid-State Supercapacitor Kong, Dezhi; Ren, Weina; Cheng, Chuanwei ACS Applied Materials & Interfaces, Vol. 7, Issue 38 https://doi.org/10.1021/acsami.5b05908	journal	September 2015
Nickel Cobalt Hydroxide @Reduced Graphene Oxide Hybrid Nanolayers for High Performance Asymmetric Supercapacitors with Remarkable Cycling Stability Ma, Hongnan; He, Jing; Xiong, Ding-Bang ACS Applied Materials & Interfaces, Vol. 8, Issue 3 https://doi.org/10.1021/acsami.5b10280	journal	January 2016
High-Performance Supercapacitor of Graphene Quantum Dots with Uniform Sizes Zhang, Shuo; Sui, Lina; Dong, Hongzhou ACS Applied Materials & Interfaces, Vol. 10, Issue 15 https://doi.org/10.1021/acsami.8b00323	journal	March 2018
Trifunctional of Phosphorus-Doped NiCo₂O₄ Nanowire Materials for Asymmetric Supercapacitor, Oxygen Evolution Reaction, and Hydrogen Evolution Reaction Chu, Wenjing; Shi, Zijun; Hou, Yongdan ACS Applied Materials & Interfaces, Vol. 12, Issue 2 https://doi.org/10.1021/acsami.9b13182	journal	November 2019
Carbon Quantum Dots for Energy Applications: A Review Rasal, Akash S.; Yadav, Sudesh; Yadav, Anchal ACS Applied Nano Materials, Vol. 4, Issue 7 https://doi.org/10.1021/acsanm.1c01372	journal	July 2021
Rational Design of NiCo₂S₄ Nanosheet Arrays Modified by Nitrogen-Doped Graphene Quantum Dots with Enhanced Charge Storage Performance for Flexible Supercapacitors Jia, Wenhan; Wu, Hao; Liu, Ziyi ACS Applied Nano Materials, Vol. 5, Issue 12 https://doi.org/10.1021/acsanm.2c03745	journal	December 2022
Two-Dimensional Hybrid Nanosheet-Based Supercapacitors: From Building Block Architecture, Fiber Assembly, and Fabric Construction to Wearable Applications Wu, Guan; Wu, Xingjiang; Zhu, XiaoLin ACS Nano, Vol. 16, Issue 7 https://doi.org/10.1021/acsnano.2c02841	journal	July 2022
Ex Situ Characterization of 1T/2H MoS₂ and Their Carbon Composites for Energy Applications, a Review Marinov, Alexandar D.; Bravo Priegue, Laura; Shah, Ami R. ACS Nano, Vol. 17, Issue 6 https://doi.org/10.1021/acsnano.2c08913	journal	March 2023
Inspired by Wood: Thick Electrodes for Supercapacitors Wang, Feng; Lee, Jiyoung; Chen, Lian ACS Nano, Vol. 17, Issue 10 https://doi.org/10.1021/acsnano.3c01241	journal	May 2023
Fabrication of Asymmetric Supercapacitors (AC@GQDs//AC) with High Electrochemical Performance Utilizing Activated Carbon and Graphene Quantum Dots AlSalem, Huda S.; Katubi, Khadijah Mohammed Saleh; Binkadem, Mona Saad ACS Omega, Vol. 8, Issue 43 https://doi.org/10.1021/acsomega.3c05882	journal	October 2023
Facile Synthesis of Three-Dimensional Ternary ZnCo ₂ O ₄ /Reduced Graphene Oxide/NiO Composite Film on Nickel Foam for Next Generation Supercapacitor Electrodes Sahoo, Sumanta; Shim, Jae-Jin ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 1 https://doi.org/10.1021/acssuschemeng.6b01367	journal	November 2016
Examination of the Bonding in Binary Transition-Metal Monophosphides MP (M = Cr, Mn, Fe, Co) by X-Ray Photoelectron Spectroscopy Grosvenor, Andrew P.; Wik, Stephen D.; Cavell, Ronald G. Inorganic Chemistry, Vol. 44, Issue 24 https://doi.org/10.1021/ic051004d	journal	November 2005
Synthesis and Characterization of Cobalt Hydroxide, Cobalt Oxyhydroxide, and Cobalt Oxide Nanodiscs Yang, Jing; Liu, Hongwei; Martens, Wayde N. The Journal of Physical Chemistry C, Vol. 114, Issue 1 https://doi.org/10.1021/jp908548f	journal	November 2009
Integrating large specific surface area and high conductivity in hydrogenated NiCo2O4 double-shell hollow spheres to improve supercapacitors Li, Xiaoming; Jiang, Lianfu; Zhou, Cheng NPG Asia Materials, Vol. 7, Issue 3 https://doi.org/10.1038/am.2015.11	journal	March 2015
Fast and fully-scalable synthesis of reduced graphene oxide Abdolhosseinzadeh, Sina; Asgharzadeh, Hamed; Seop Kim, Hyoung Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep10160	journal	May 2015
Facile Synthesis of Carbon Nanosphere/NiCo2O4 Core-shell Sub-microspheres for High Performance Supercapacitor Li, Delong; Gong, Youning; Zhang, Yupeng Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep12903	journal	August 2015
Microwave Assisted Synthesis of Porous NiCo2O4 Microspheres: Application as High Performance Asymmetric and Symmetric Supercapacitors with Large Areal Capacitance Khalid, Syed; Cao, Chuanbao; Wang, Lin Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep22699	journal	March 2016
Facile synthesis of mesoporous spinel NiCo ₂ O ₄ nanostructures as highly efficient electrocatalysts for urea electro-oxidation Ding, Rui; Qi, Li; Jia, Mingjun Nanoscale, Vol. 6, Issue 3 https://doi.org/10.1039/C3NR05359H	journal	January 2014
NiCo ₂ O ₄ -based materials for electrochemical supercapacitors Wu, Zhibin; Zhu, Yirong; Ji, Xiaobo J. Mater. Chem. A, Vol. 2, Issue 36 https://doi.org/10.1039/C4TA02390K	journal	January 2014
Porous NiCo₂O₄spheres tuned through carbon quantum dots utilised as advanced materials for an asymmetric supercapacitor Zhu, Yirong; Wu, Zhibin; Jing, Mingjun Journal of Materials Chemistry A, Vol. 3, Issue 2 https://doi.org/10.1039/C4TA05507A	journal	January 2015
Studies on the electrochemical intercalation/de-intercalation mechanism of NiMn₂O₄ for high stable pseudocapacitor electrodes Vijaya Sankar, K.; Surendran, S.; Pandi, K. RSC Advances, Vol. 5, Issue 35 https://doi.org/10.1039/C5RA00407A	journal	January 2015
Time and temperature dependent multiple hierarchical NiCo₂O₄ for high-performance supercapacitors Wang, Shen; Sun, Shumin; Li, Shaodan Dalton Transactions, Vol. 45, Issue 17 https://doi.org/10.1039/C6DT00436A	journal	January 2016
Asymmetric supercapacitors based on a NiCo₂O₄/three dimensional graphene composite and three dimensional graphene with high energy density Sun, Shumin; Wang, Shen; Li, Shaodan Journal of Materials Chemistry A, Vol. 4, Issue 47 https://doi.org/10.1039/C6TA07746C	journal	January 2016
Flexible, sandwich-like CNTs/NiCo₂O₄ hybrid paper electrodes for all-solid state supercapacitors Zheng, Yongjia; Lin, Zhiqiang; Chen, Wenjun Journal of Materials Chemistry A, Vol. 5, Issue 12 https://doi.org/10.1039/C7TA00491E	journal	January 2017
Template-assisted synthesis of NiCoO₂ nanocages/reduced graphene oxide composites as high-performance electrodes for supercapacitors Guan, Xiao-Hui; Li, Mu; Zhang, Hai-Zhen RSC Advances, Vol. 8, Issue 30 https://doi.org/10.1039/C8RA02267D	journal	January 2018
Optimized NiCo₂O₄/rGO hybrid nanostructures on carbon fiber as an electrode for asymmetric supercapacitors Jiang, Hui; Yang, Kang; Ye, Pingwei RSC Advances, Vol. 8, Issue 65 https://doi.org/10.1039/C8RA07477A	journal	January 2018
Multilayer NiO@Co ₃ O ₄ @graphene quantum dots hollow spheres for high-performance lithium-ion batteries and supercapacitors Yin, Xiaojie; Zhi, Chuanwei; Sun, Weiwei Journal of Materials Chemistry A, Vol. 7, Issue 13 https://doi.org/10.1039/C8TA11982A	journal	January 2019
Investigation on the role of different conductive polymers in supercapacitors based on a zinc sulfide/reduced graphene oxide/conductive polymer ternary composite electrode Xu, Zichen; Zhang, Zhiqiang; Yin, Huiling RSC Advances, Vol. 10, Issue 6 https://doi.org/10.1039/C9RA07842H	journal	January 2020
Understanding the crystal structure-dependent electrochemical capacitance of spinel and rock-salt Ni–Co oxides via density function theory calculations Sun, Xuan; Sun, Jinfeng; Guo, Lingzhi RSC Advances, Vol. 10, Issue 59 https://doi.org/10.1039/D0RA05578F	journal	January 2020
Ultralow overpotentials for oxygen evolution reactions achieved by nickel cobaltite aerogels Chien, Hsing-Chi; Cheng, Wei-Yun; Wang, Yong-Hui Journal of Materials Chemistry, Vol. 21, Issue 45 https://doi.org/10.1039/c1jm14025f	journal	January 2011
Bio-inspired synthesis of NaCl-type CoxNi1−xO (0 ≤ x < 1) nanorods on reduced graphene oxide sheets and screening for asymmetric electrochemical capacitors Xiao, Junwu; Yang, Shihe Journal of Materials Chemistry, Vol. 22, Issue 24 https://doi.org/10.1039/c2jm31057k	journal	January 2012
Enhancing electrochemical reaction sites in nickel–cobalt layered double hydroxides on zinc tin oxide nanowires: a hybrid material for an asymmetric supercapacitor device Wang, Xu; Sumboja, Afriyanti; Lin, Mengfang Nanoscale, Vol. 4, Issue 22 https://doi.org/10.1039/c2nr31590d	journal	January 2012
High-performance asymmetric supercapacitor based hierarchical NiCo₂O₄@ carbon nanofibers//Activated multichannel carbon nanofibers El-Deen, Ahmed G.; Hussein El-Shafei, M.; Hessein, Amr Nanotechnology, Vol. 31, Issue 36 https://doi.org/10.1088/1361-6528/ab97d6	journal	June 2020
Hierarchical mesoporous nickel cobaltite nanoneedle/carbon cloth arrays as superior flexible electrodes for supercapacitors Zhang, Deyang; Yan, Hailong; Lu, Yang Nanoscale Research Letters, Vol. 9, Issue 1 https://doi.org/10.1186/1556-276X-9-139	journal	January 2014
Preparation and Electrochemical Properties of NiCo2O4/rGO Composites Yao, Changjuan; Su, Yu; Li, Ying International Journal of Electrochemical Science, Vol. 16, Issue 1 https://doi.org/10.20964/2021.01.25	journal	January 2021
Electrochemical Performance of Li2TiO3//LiCoO2 Li-Ion Aqueous Cell with Nanocrystalline Electrodes Lakshmi-Narayana, Ambadi; Sivajee-Ganesh, Kapu; Dhananjaya, Merum Batteries, Vol. 8, Issue 10 https://doi.org/10.3390/batteries8100149	journal	October 2022
NiCo2O4/RGO Hybrid Nanostructures on Surface-Modified Ni Core for Flexible Wire-Shaped Supercapacitor Shewale, Prashant Shivaji; Yun, Kwang-Seok Nanomaterials, Vol. 11, Issue 4 https://doi.org/10.3390/nano11040852	journal	March 2021
Graphene Quantum Dots: Novel Properties and Their Applications for Energy Storage Devices Ansari, Sajid Ali Nanomaterials, Vol. 12, Issue 21 https://doi.org/10.3390/nano12213814	journal	October 2022
Nanostructured Conducting Polymers and Their Applications in Energy Storage Devices del Valle, M. A.; Gacitúa, M. A.; Hernández, F. Polymers, Vol. 15, Issue 6 https://doi.org/10.3390/polym15061450	journal	March 2023

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Title: High–Performance NiCo₂O₄/Graphene Quantum Dots for Asymmetric and Symmetric Supercapacitors with Enhanced Energy Efficiency