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Title: Finding a natural rhythm

Journal Article · · Nature Chemical Engineering
 [1]
  1. University of Minnesota, Minneapolis, MN (United States); University of Minnnesota

Here, scaling down chemical reactors has been a century-old goal of modern catalysis. Faster reactors are smaller reactors that can be implemented in distributed applications such as the conversion of renewable power to chemical energy. Yet many important reactions have already reached their theoretical maximum speed limit, called the Sabatier limit. In the past five years, a new theory for catalytic properties oscillating with time (at sufficiently high amplitudes and frequencies) has shown that certain dynamic catalytic rates can exceed the Sabatier limit by several orders of magnitude.

Research Organization:
University of Minnesota, Minneapolis, MN (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)
Grant/Contract Number:
SC0023464
OSTI ID:
2458155
Journal Information:
Nature Chemical Engineering, Journal Name: Nature Chemical Engineering Journal Issue: 9 Vol. 1; ISSN 2948-1198
Publisher:
SpringerCopyright Statement
Country of Publication:
United States
Language:
English

References (3)

The Catalytic Mechanics of Dynamic Surfaces: Stimulating Methods for Promoting Catalytic Resonance journal September 2020
Principles of Dynamic Heterogeneous Catalysis: Surface Resonance and Turnover Frequency Response journal May 2019
Catalytic resonance theory: the catalytic mechanics of programmable ratchets journal January 2024