Realization of Organocerium-Based Fullerene Molecular Materials Showing Mott Insulator-Type Behavior

Pandey, Pragati; Wang, Xiaoyu; Gupta, Himanshu; Smith, Patrick W.; Lapsheva, Ekaterina; Carroll, Patrick J.; Bacon, Alexandra M.; Booth, Corwin H.; Minasian, Stefan G.; Autschbach, Jochen; Zurek, Eva; Schelter, Eric J.

doi:10.1021/acsami.3c18766

Title: Realization of Organocerium-Based Fullerene Molecular Materials Showing Mott Insulator-Type Behavior

Journal Article · 27 March 2024 · ACS Applied Materials and Interfaces

DOI: https://doi.org/10.1021/acsami.3c18766 · OSTI ID:2457127

^[1];

^[2]; Gupta, Himanshu ^[3];

^[4]; Lapsheva, Ekaterina ^[5]; Carroll, Patrick J. ^[3]; Bacon, Alexandra M. ^[3]; Booth, Corwin H. ^[4];

^[4];

^[2];

^[3]

University of Pennsylvania, Philadelphia, PA (United States); École Polytechnique Fédérale de Lausanne (EPFL) (Switzerland); University of Rochester
University at Buffalo, State University of New York, NY (United States)
University of Pennsylvania, Philadelphia, PA (United States)
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
University of Pennsylvania, Philadelphia, PA (United States); Ereztech Laboratories, Sheboygan Falls, WI (United States)

Abstract Electron-rich organocerium complexes (C₅Me₄H)₃Ce and [(C₅Me₅)₂Ce(ortho-oxa)], with redox potentials E_1/2 = –0.82 V and E_1/2 = –0.86 V versus Fc/Fc⁺ respectively, were reacted with fullerene (C₆₀) in different stoichiometries to obtain molecular materials. Structurally characterized co-crystals: [(C₅Me₄H)₃Ce]₂•C₆₀ (1) and [(C₅Me₅)₂Ce(ortho-oxa)]₃•C₆₀ (2) of C₆₀ with cerium-based rare earth molecular precursors are reported for the first time. The extent of charge transfer in 1 and 2 was evaluated using a series of physical measurements: FT-IR, Raman, solidstate UV-vis-NIR spectroscopy, X-ray absorption near edge structure (XANES) spectroscopy, and magnetic susceptibility measurements. The physical measurements indicate that 1 and 2 comprise the cerium(III) oxidation state with formally neutral C₆₀ as a co-crystal in both cases. Pressure-dependent periodic density functional theory calculations were performed to study the electronic structure of 1. Inclusion of a Hubbard-U parameter removes Ce f states from the Fermi level, opens up a band gap, and stabilizes FM/AFM magnetic solutions that are isoenergetic because of the large distances between the Ce(III) cations. Furthermore, the electronic structure of this strongly correlated Mott insulator-type system is reminiscent of the well-studied Ce₂O₃.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: University of Rochester, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)

Grant/Contract Number:: SC0020340; SC0020169

OSTI ID:: 2457127

Journal Information:: ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 14 Vol. 16; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (71)

Nanoelectronics Using Metal–Insulator Transition Lee, Yoon Jung; Kim, Youngmin; Gim, Hyeongyu Advanced Materials, Vol. 36, Issue 5 https://doi.org/10.1002/adma.202305353	journal	November 2023
The Chemical Imagination at Work inVery Tight Places Grochala, Wojciech; Hoffmann, Roald; Feng, Ji Angewandte Chemie International Edition, Vol. 46, Issue 20 https://doi.org/10.1002/anie.200602485	journal	May 2007
A Two-Dimensional Organic Metal Based on Fullerene Konarev, Dmitri V.; Khasanov, Salavat S.; Otsuka, Akihiro Angewandte Chemie International Edition, Vol. 49, Issue 28 https://doi.org/10.1002/anie.201001463	journal	June 2010
Counterintuitive Anisotropy of Electron Transport Properties in KC₆₀(THF)₅⋅2 THF Fulleride Kromer, A.; Wedig, U.; Roduner, E. Angewandte Chemie International Edition, Vol. 52, Issue 48 https://doi.org/10.1002/anie.201305808	journal	October 2013
Pressure‐Tuneable Visible‐Range Band Gap in the Ionic Spinel Tin Nitride Kearney, John S. C.; Graužinytė, Miglė; Smith, Dean Angewandte Chemie International Edition, Vol. 57, Issue 36 https://doi.org/10.1002/anie.201805038	journal	September 2018
[Am(C ₅ Me ₄ H) ₃ ]: An Organometallic Americium Complex Goodwin, Conrad A. P.; Su, Jing; Albrecht-Schmitt, Thomas E. Angewandte Chemie International Edition, Vol. 58, Issue 34 https://doi.org/10.1002/anie.201905225	journal	July 2019
Manipulation of the Coordination Geometry along the C₄ Rotation Axis in a Dinuclear Tb³⁺ Triple‐Decker Complex via a Supramolecular Approach Katoh, Keiichi; Yasuda, Nobuhiro; Damjanović, Marko Chemistry – A European Journal, Vol. 26, Issue 21 https://doi.org/10.1002/chem.201905400	journal	March 2020
Probing Multiconfigurational States by Spectroscopy: The Cerium XAS L ₃ ‐edge Puzzle Sergentu, Dumitru‐Claudiu; Booth, Corwin H.; Autschbach, Jochen Chemistry – A European Journal, Vol. 27, Issue 25 https://doi.org/10.1002/chem.202101162	journal	April 2021
Synthesis and Crystal Structure of a Cocrystalline Compound of a Rare Earth Metalloporphyrin with Fullerene {[TPPYb(μ‐OH)₂Yb(THF)TPP]·C₆₀}_n Zhang, Jie; Cai, Ruifang; Chen, Minqing European Journal of Inorganic Chemistry, Vol. 2005, Issue 16 https://doi.org/10.1002/ejic.200500229	journal	August 2005
Fullerides: heterometallic superconductors with composition M2M′C60 (M = K, Rb; M′ = Yb, Lu, Sc) Bulychev, B. M.; Lunin, R. A.; Kul’bachinskii, V. A. Russian Chemical Bulletin, Vol. 53, Issue 8 https://doi.org/10.1007/s11172-005-0018-9	journal	August 2004
A review of Mott insulator in memristors: The materials, characteristics, applications for future computing systems and neuromorphic computing Ran, Yunfeng; Pei, Yifei; Zhou, Zhenyu Nano Research, Vol. 16, Issue 1 https://doi.org/10.1007/s12274-022-4773-9	journal	August 2022
Paramagnetism in organolanthanide complexes Evans, William J.; Hozbor, Maria A. Journal of Organometallic Chemistry, Vol. 326, Issue 3 https://doi.org/10.1016/0022-328X(87)87001-8	journal	June 1987
Periodicity in the band gap variation of Ln2X3 (X = O, S, Se) in the lanthanide series Prokofiev, A. V.; Shelykh, A. I.; Melekh, B. T. Journal of Alloys and Compounds, Vol. 242, Issue 1-2 https://doi.org/10.1016/0925-8388(96)02293-1	journal	September 1996
C60-fullerenides of ytterbium and lutetium Bochkarev, M. N.; Fedushkin, I. L.; Nevodchikov, V. I. Inorganica Chimica Acta, Vol. 280, Issue 1-2 https://doi.org/10.1016/S0020-1693(98)00058-9	journal	October 1998
Structures and magnetic properties of high-temperature reaction products of cerium metal and C60 solid Maruyama, Y.; Motohashi, S.; Suzuki, K. Solid State Communications, Vol. 115, Issue 9 https://doi.org/10.1016/S0038-1098(00)00232-5	journal	July 2000
Possible competition of superconductivity and ferromagnetism in Ce C60 compounds Maruyama, Y.; Motohashi, S.; Sakai, N. Solid State Communications, Vol. 123, Issue 5 https://doi.org/10.1016/S0038-1098(02)00291-0	journal	August 2002
Competition of superconductivity and ferromagnetism in CexC60 compounds Maruyama, Y.; Motohashi, S.; Sakai, N. Synthetic Metals, Vol. 135-136 https://doi.org/10.1016/S0379-6779(02)00825-1	journal	April 2003
The electrochemical behavior of cerium(III/IV) complexes: Thermodynamics, kinetics and applications in synthesis Piro, Nicholas A.; Robinson, Jerome R.; Walsh, Patrick J. Coordination Chemistry Reviews, Vol. 260 https://doi.org/10.1016/j.ccr.2013.08.034	journal	February 2014
Raman study of the pressure-induced phase transitions in the molecular donor–acceptor complex {Pt(dbdtc)2}C60 Meletov, K. P.; Konarev, D. V. Chemical Physics Letters, Vol. 553 https://doi.org/10.1016/j.cplett.2012.09.050	journal	November 2012
Superconductivity appearing from C₆₀doped with rare-earth metals Akada, Misaho; Hirai, Toshinari; Takeuchi, Junji Science and Technology of Advanced Materials, Vol. 7, Issue sup1 https://doi.org/10.1016/j.stam.2006.03.005	journal	January 2006
Pressure-Induced Donor–Acceptor Charge Transfer in a Fullerene Molecular Complex with Ferrocene Kuzmin, Alexey V.; Meletov, Konstantin P.; Khasanov, Salavat S. The Journal of Physical Chemistry C, Vol. 125, Issue 30 https://doi.org/10.1021/acs.jpcc.1c02568	journal	July 2021
Cerium Oxides without U: The Role of Many-Electron Correlation Schäfer, Tobias; Daelman, Nathan; López, Núria The Journal of Physical Chemistry Letters, Vol. 12, Issue 27 https://doi.org/10.1021/acs.jpclett.1c01589	journal	July 2021
Tuning Organocerium Electrochemical Potentials by Extending Tris(cyclopentadienyl) Scaffolds with Terminal Halogenido, Siloxy, and Alkoxy Ligands Hirneise, Lars; Langmann, Jan; Zitzer, Georg Organometallics, Vol. 40, Issue 11 https://doi.org/10.1021/acs.organomet.1c00276	journal	May 2021
Synthesis, Electrochemical, and Computational Studies of Organocerium(III) Complexes with Ce–Aryl Sigma Bonds Pandey, Pragati; Yu, Xiaojuan; Panetti, Grace B. Organometallics, Vol. 42, Issue 12 https://doi.org/10.1021/acs.organomet.2c00384	journal	November 2022
NMR Studies on Two-Dimensional Molecular Conductors and Superconductors: Mott Transition in κ-(BEDT-TTF) ₂ X Miyagawa, Kazuya; Kanoda, Kazushi; Kawamoto, Atsushi Chemical Reviews, Vol. 104, Issue 11 https://doi.org/10.1021/cr0306541	journal	October 2004
Reactions of Transition Metal Complexes with Fullerenes (C ₆₀ , C ₇₀ , etc.) and Related Materials Balch, Alan L.; Olmstead, Marilyn M. Chemical Reviews, Vol. 98, Issue 6 https://doi.org/10.1021/cr960040e	journal	August 1998
Discrete Fulleride Anions and Fullerenium Cations Reed, Christopher A.; Bolskar, Robert D. Chemical Reviews, Vol. 100, Issue 3 https://doi.org/10.1021/cr980017o	journal	March 2000
Diamagnetic Corrections and Pascal's Constants Bain, Gordon A.; Berry, John F. Journal of Chemical Education, Vol. 85, Issue 4 https://doi.org/10.1021/ed085p532	journal	April 2008
Synthesis, Structure, and ¹⁵ N NMR Studies of Paramagnetic Lanthanide Complexes Obtained by Reduction of Dinitrogen Evans, William J.; Rego, Daniel B.; Ziller, Joseph W. Inorganic Chemistry, Vol. 45, Issue 26 https://doi.org/10.1021/ic061485g	journal	December 2006
Homoleptic Cerium(III) and Cerium(IV) Nitroxide Complexes: Significant Stabilization of the 4+ Oxidation State Bogart, Justin A.; Lewis, Andrew J.; Medling, Scott A. Inorganic Chemistry, Vol. 52, Issue 19 https://doi.org/10.1021/ic401974t	journal	September 2013
Spectroelectrochemical study of the C60 and C70 fullerenes and their mono-, di-, tri- and tetraanions Dubois, Dominique; Kadish, Karl M.; Flanagan, Scott Journal of the American Chemical Society, Vol. 113, Issue 11 https://doi.org/10.1021/ja00011a069	journal	May 1991
Electrochemical detection of C606- and C706-: Enhanced stability of fullerides in solution Xie, Qingshan; Perez-Cordero, Eduardo; Echegoyen, Luis Journal of the American Chemical Society, Vol. 114, Issue 10 https://doi.org/10.1021/ja00036a056	journal	May 1992
Buckminsterfulleride(1-) salts: synthesis, EPR, and the Jahn-Teller distortion of C60- Stinchcombe, John; Penicaud, Alain; Bhyrappa, P. Journal of the American Chemical Society, Vol. 115, Issue 12 https://doi.org/10.1021/ja00065a037	journal	June 1993
Structural Evidence for the Expected Jahn-Teller Distortion in Monoanionic C60: Synthesis and X-ray Crystal Structure of Decamethylnickelocenium Buckminsterfulleride Wan, Wai Chou; Liu, Xioahua; Sweeney, Gregory M. Journal of the American Chemical Society, Vol. 117, Issue 37 https://doi.org/10.1021/ja00142a033	journal	September 1995
Syntheses and electronic structures of decamethylmetallocenes Robbins, J. L.; Edelstein, N.; Spencer, B. Journal of the American Chemical Society, Vol. 104, Issue 7 https://doi.org/10.1021/ja00371a017	journal	April 1982
Intermediate-Valence Tautomerism in Decamethylytterbocene Complexes of Methyl-Substituted Bipyridines Booth, Corwin H.; Kazhdan, Daniel; Werkema, Evan L. Journal of the American Chemical Society, Vol. 132, Issue 49 https://doi.org/10.1021/ja106902s	journal	December 2010
(Barely) Solid Li(NH ₃ ) ₄ : The Electronics of an Expanded Metal Zurek, Eva; Wen, Xiao-Dong; Hoffmann, Roald Journal of the American Chemical Society, Vol. 133, Issue 10 https://doi.org/10.1021/ja109397k	journal	March 2011
New Type of Reaction of Lanthanide Hydrido Complexes with C₆₀: Oxidative Dehydrogenation vs Addition. The Reversible σ-C₆₀−C₆₀ Bond Formation in Complex [{(Me₃Si)₂NC(NCy)₂}₂Lu(Et₂O)⁺](C₆₀^−•) Schupak, Elena A.; Lyubov, Dmitrii M.; Baranov, Evguenii V. Organometallics, Vol. 29, Issue 22 https://doi.org/10.1021/om100516s	journal	October 2010
Cerocene Revisited: The Electronic Structure of and Interconversion Between Ce ₂ (C ₈ H ₈ ) ₃ and Ce(C ₈ H ₈ ) ₂ Walter, Marc D.; Booth, Corwin H.; Lukens, Wayne W. Organometallics, Vol. 28, Issue 3 https://doi.org/10.1021/om7012327	journal	February 2009
Gigantic optical nonlinearity in one-dimensional Mott–Hubbard insulators Kishida, H.; Matsuzaki, H.; Okamoto, H. Nature, Vol. 405, Issue 6789 https://doi.org/10.1038/35016036	journal	June 2000
Origin of ferromagnetic exchange interactions in a fullerene–organic compound Narymbetov, Bakhyt; Omerzu, Ales; Kabanov, Viktor V. Nature, Vol. 407, Issue 6806 https://doi.org/10.1038/35038032	journal	October 2000
Superconductivity at 18 K in potassium-doped C60 Hebard, A. F.; Rosseinsky, M. J.; Haddon, R. C. Nature, Vol. 350, Issue 6319 https://doi.org/10.1038/350600a0	journal	April 1991
Lattice structure of the fullerene ferromagnet TDAE–C60 Stephens, Peter W.; Cox, David; Lauher, Joseph W. Nature, Vol. 355, Issue 6358 https://doi.org/10.1038/355331a0	journal	January 1992
Polymeric fullerene chains in RbC60 and KC60 Stephens, Peter W.; Bortel, G.; Faigel, G. Nature, Vol. 370, Issue 6491 https://doi.org/10.1038/370636a0	journal	August 1994
Superconductivity and cation-vacancy ordering in the rare-earth fulleride Yb2.75C60 Özdaş, E.; Kortan, A. R.; Kopylov, N. Nature, Vol. 375, Issue 6527 https://doi.org/10.1038/375126a0	journal	May 1995
Temperature-induced valence transition and associated lattice collapse in samarium fulleride Arvanitidis, J.; Papagelis, Konstantinos; Margadonna, Serena Nature, Vol. 425, Issue 6958 https://doi.org/10.1038/nature01994	journal	October 2003
Bulk superconductivity at 38 K in a molecular system Ganin, Alexey Y.; Takabayashi, Yasuhiro; Khimyak, Yaroslav Z. Nature Materials, Vol. 7, Issue 5, p. 367-371 https://doi.org/10.1038/nmat2179	journal	April 2008
Polyhydride CeH9 with an atomic-like hydrogen clathrate structure Li, Xin; Huang, Xiaoli; Duan, Defang Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-11330-6	journal	August 2019
Synthesis of clathrate cerium superhydride CeH9 at 80-100 GPa with atomic hydrogen sublattice Salke, Nilesh P.; Davari Esfahani, M. Mahdi; Zhang, Youjun Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-12326-y	journal	October 2019
Electric dipole induced bulk ferromagnetism in dimer Mott molecular compounds Yoshimoto, Ryo; Yamashita, Satoshi; Akutsu, Hiroki Scientific Reports, Vol. 11, Issue 1 https://doi.org/10.1038/s41598-020-79262-6	journal	January 2021
Probing charge transfer characteristics in a donor–acceptor metal–organic framework by Raman spectroelectrochemistry and pressure-dependence studies Usov, Pavel M.; Leong, Chanel F.; Chan, Bun Physical Chemistry Chemical Physics, Vol. 20, Issue 40 https://doi.org/10.1039/C8CP04157A	journal	January 2018
X-ray absorption spectra of f-element complexes: insight from relativistic multiconfigurational wavefunction theory Sergentu, Dumitru-Claudiu; Autschbach, Jochen Dalton Transactions, Vol. 51, Issue 5 https://doi.org/10.1039/D1DT04075H	journal	January 2022
Bis(permethylpentalene)cerium ? another ambiguity in lanthanide oxidation state Ashley, Andrew; Balazs, Gabor; Cowley, Andrew Chemical Communications, Issue 15 https://doi.org/10.1039/b700303j	journal	January 2007
Preparation and characterisation of C60(ferrocene)2 Crane, Jonathan D.; Hitchcock, Peter B.; Kroto, Harold W. Journal of the Chemical Society, Chemical Communications, Issue 24 https://doi.org/10.1039/c39920001764	journal	January 1992
Theoretical study of CeO2 and Ce2O3 using a screened hybrid density functional Hay, P. Jeffrey; Martin, Richard L.; Uddin, Jamal The Journal of Chemical Physics, Vol. 125, Issue 3 https://doi.org/10.1063/1.2206184	journal	July 2006
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu Grimme, Stefan; Antony, Jens; Ehrlich, Stephan The Journal of Chemical Physics, Vol. 132, Issue 15 https://doi.org/10.1063/1.3382344	journal	April 2010
Raman Study of the Pressure-Induced Charge Transfer Transition in the Neutral Donor-Acceptor Complexes {Ni(nPr ₂ dtc) ₂ }(C ₆₀ ) ₂ and {Cu(nPr ₂ dtc) ₂ }(C ₆₀ ) ₂ Meletov, K. P.; Konarev, D. V. Fullerenes, Nanotubes and Carbon Nanostructures, Vol. 20, Issue 4-7 https://doi.org/10.1080/1536383X.2012.655123	journal	May 2012
High-pressure behavior of the crystal structure of the fullerene molecular complex with ferrocene C₆₀·{Fe(C₅H₅)₂}₂ Kuzmin, A. V.; Khasanov, S. S.; Meletov, K. P. Fullerenes, Nanotubes and Carbon Nanostructures, Vol. 28, Issue 4 https://doi.org/10.1080/1536383X.2019.1708728	journal	December 2019
Optical and magnetic properties of the halogen-bridged metal complexes modified by hydrogen bondings: {M(1R,2R-cyclohexanediamine)2Br}Br2(M=Pt, Pd, and Ni) Okamoto, H.; Toriumi, K.; Mitani, T. Physical Review B, Vol. 42, Issue 16 https://doi.org/10.1103/PhysRevB.42.10381	journal	December 1990
Ab initiomolecular dynamics for liquid metals Kresse, G.; Hafner, J. Physical Review B, Vol. 47, Issue 1, p. 558-561 https://doi.org/10.1103/PhysRevB.47.558	journal	January 1993
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
Superconductivity at 8 K in samarium-dopedC60 Chen, X. H.; Roth, G. Physical Review B, Vol. 52, Issue 21 https://doi.org/10.1103/PhysRevB.52.15534	journal	December 1995
Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study Dudarev, S. L.; Botton, G. A.; Savrasov, S. Y. Physical Review B, Vol. 57, Issue 3, p. 1505-1509 https://doi.org/10.1103/PhysRevB.57.1505	journal	January 1998
First-principles LDA + U and GGA + U study of cerium oxides: Dependence on the effective U parameter Loschen, Christoph; Carrasco, Javier; Neyman, Konstantin M. Physical Review B, Vol. 75, Issue 3 https://doi.org/10.1103/PhysRevB.75.035115	journal	January 2007
Hybrid functionals applied to rare-earth oxides: The example of ceria Da Silva, Juarez L. F.; Ganduglia-Pirovano, M. Verónica; Sauer, Joachim Physical Review B, Vol. 75, Issue 4 https://doi.org/10.1103/PhysRevB.75.045121	journal	January 2007
Spin-gapped Mott insulator with the dimeric arrangement of twisted molecules Zn(tmdt) 2 Takagi, Rina; Gangi, Hiro; Miyagawa, Kazuya Physical Review B, Vol. 95, Issue 22 https://doi.org/10.1103/PhysRevB.95.224427	journal	June 2017
Excitation-Photon-Energy Selectivity of Photoconversions in Halogen-Bridged Pd-Chain Compounds: Mott Insulator to Metal or Charge-Density-Wave State Matsuzaki, H.; Iwata, M.; Miyamoto, T. Physical Review Letters, Vol. 113, Issue 9 https://doi.org/10.1103/PhysRevLett.113.096403	journal	August 2014
High-Temperature Superconducting Phases in Cerium Superhydride with a T c up to 115 K below a Pressure of 1 Megabar Chen, Wuhao; Semenok, Dmitrii V.; Huang, Xiaoli Physical Review Letters, Vol. 127, Issue 11 https://doi.org/10.1103/PhysRevLett.127.117001	journal	September 2021
Epitaxial growth and band structure of antiferromagnetic Mott insulator CeOI Cai, Xinqiang; Xu, Zhilin; Zhou, Hui Physical Review Materials, Vol. 4, Issue 6 https://doi.org/10.1103/PhysRevMaterials.4.064003	journal	June 2020
Mott Memory and Neuromorphic Devices Proceedings of the IEEE, Vol. 103, Issue 8 https://doi.org/10.1109/jproc.2015.2431914	journal	August 2015
Phase transitions and photoinduced transformations at high pressure in the molecular donor-acceptor fullerene complex {Cd(dedtc)2}2 · C60 Meletov, K. P.; Konarev, D. V.; Tolstikova, A. O. Journal of Experimental and Theoretical Physics, Vol. 120, Issue 6 https://doi.org/10.1134/S1063776115050167	journal	June 2015

Linked Research (3)

Similar Records

Comparison of Ce(IV)/Th(IV)-alkynyl complexes and observation of a trans-influence ligand series for Ce(IV)

Journal Article · 2025 · Chemical Science · OSTI ID:2997768

Yang, Qiaomu; Yu, Xiaojuan; Lapsheva, Ekaterina; +8 more

Chemical vapor deposition of cerium oxide using the precursors [Ce(hfac){sub 3}(glyme)]

Journal Article · 2000 · Chemistry of Materials · OSTI ID:20050864

Pollard, K D; Jenkins, H A; Puddephatt, R J

Multi‐electron Oxidation of Ce(III) Complexes Facilitated by Redox‐Active Ligands

Journal Article · 2024 · European Journal of Inorganic Chemistry · OSTI ID:2575891

Rupasinghe, D. M. Ramitha Y. P.; Lopez, Lauren M.; Poore, Andrew T.; +6 more

Related Subjects

36 MATERIALS SCIENCE
Carbon nanomaterials
Charge transfer
Density functional theory
Fulleride
Materials
Molecular materials
Mott insulator
Nanospheres
Redox reactions
Spectroscopy
Strongly correlated electrons

CCDC 2203272: Experimental Crystal Structure Determination Pragati, Pandey,; Xiaoyu, Wang,; Himanshu, Gupta, https://doi.org/10.5517/ccdc.csd.cc2cyp9b The current record is supplemented by this dataset	dataset	January 2024
CCDC 2203273: Experimental Crystal Structure Determination Pragati, Pandey,; Xiaoyu, Wang,; Himanshu, Gupta, https://doi.org/10.5517/ccdc.csd.cc2cypbc The current record is supplemented by this dataset	dataset	January 2024
CCDC 2332081: Experimental Crystal Structure Determination Pragati, Pandey,; Xiaoyu, Wang,; Himanshu, Gupta, https://doi.org/10.5517/ccdc.csd.cc2j8qfz The current record is supplemented by this dataset	dataset	January 2024

Title: Realization of Organocerium-Based Fullerene Molecular Materials Showing Mott Insulator-Type Behavior

Citation Formats

References (71)

Linked Research (3)

Similar Records

Related Subjects