Kinetic H 2 S/CO 2 selectivity in an exceptionally sterically hindered amine membrane

Rao, Shraavya; Deng, Xuepeng; Zou, Changlong; Prasad, Babul; Han, Yang; Lin, Li-Chiang; Ho, W. S. Winston

doi:10.1039/D4TA04997G

Title: Kinetic H ₂ S/CO ₂ selectivity in an exceptionally sterically hindered amine membrane

Journal Article · 29 October 2024 · Journal of Materials Chemistry. A

DOI: https://doi.org/10.1039/D4TA04997G · OSTI ID:2455036

Rao, Shraavya ^[1];

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^[1]; Prasad, Babul ^[2];

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William G. Lowrie Department of Chemical and Biomolecular Engineering, The Ohio State University, 151 West Woodruff Avenue, Columbus, OH 43210-1350, USA
William G. Lowrie Department of Chemical and Biomolecular Engineering, The Ohio State University, 151 West Woodruff Avenue, Columbus, OH 43210-1350, USA, Polymer Science and Engineering Division, CSIR-National Chemical Laboratory, Dr Homi Bhabha Road, Pashan, Pune 411008, India
William G. Lowrie Department of Chemical and Biomolecular Engineering, The Ohio State University, 151 West Woodruff Avenue, Columbus, OH 43210-1350, USA, Department of Chemical Engineering, National Taiwan University, Taipei 10617, Taiwan
William G. Lowrie Department of Chemical and Biomolecular Engineering, The Ohio State University, 151 West Woodruff Avenue, Columbus, OH 43210-1350, USA, Department of Materials Science and Engineering, The Ohio State University, 2041 College Road, Columbus, OH 43210-1178, USA

Decreasing membrane thickness reduces the reaction time for the competing amine-H ₂ S and amine-CO ₂ reactions, thus enhancing the selectivity for the “faster”, kinetically favored product, i.e. , hydrosulfide.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: NONE; FE0031635

OSTI ID:: 2455036

Journal Information:: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 42 Vol. 12; ISSN JMCAET; ISSN 2050-7488

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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