Metal–support interactions in metal oxide-supported atomic, cluster, and nanoparticle catalysis

Leybo, Denis; Etim, Ubong J.; Monai, Matteo; Bare, Simon R.; Zhong, Ziyi; Vogt, Charlotte

doi:10.1039/d4cs00527a

Title: Metal–support interactions in metal oxide-supported atomic, cluster, and nanoparticle catalysis

Journal Article · 01 October 2024 · Chemical Society Reviews

DOI: https://doi.org/10.1039/d4cs00527a · OSTI ID:2453939

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^[2]; Monai, Matteo ^[3];

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Technion-Israel Institute of Technology, Haifa (Israel)
Guangdong Technion Israel Institute of Technology (GTIIT), Shantou (China)
Utrecht University (Netherlands)
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource (SSRL); SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States). SUNCAT Center for Interface Science and Catalysis

Supported metal catalysts are essential to a plethora of processes in the chemical industry. The overall performance of these catalysts depends strongly on the interaction of adsorbates at the atomic level, which can be manipulated and controlled by the different constituents of the active material (i.e., support and active metal). The description of catalyst activity and the relationship between active constituent and the support, or metal–support interactions (MSI), in heterogeneous (thermo)catalysts is a complex phenomenon with multivariate (dependent and independent) contributions that are difficult to disentangle, both experimentally and theoretically. So-called “strong metal–support interactions” have been reported for several decades and summarized in excellent review articles. However, in recent years, there has been a proliferation of new findings related to atomically dispersed metal sites, metal oxide defects, and, for example, the generation and evolution of MSI under reaction conditions, which has led to the designation of (sub)classifications of MSI deserving to be critically and systematically evaluated. These include dynamic restructuring under alternating redox and reaction conditions, adsorbate-induced MSI, and evidence of strong interactions in oxide-supported metal oxide catalysts. Here, we review recent literature on MSI in oxide-supported metal particles to provide an up-to-date understanding of the underlying physicochemical principles that dominate the observed effects in supported metal atomic, cluster, and nanoparticle catalysts. Critical evaluation of different subclassifications of MSI is provided, along with discussions on the formation mechanisms, theoretical and characterization advances, and tuning strategies to manipulate catalytic reaction performance. We also provide a perspective on the future of the field, and we discuss the analysis of different MSI effects on catalysis quantitatively.

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Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 2453939

Journal Information:: Chemical Society Reviews, Journal Name: Chemical Society Reviews Journal Issue: 21 Vol. 53; ISSN 1460-4744; ISSN 0306-0012

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Effects of Mott–Schottky Frequency Selection and Other Controlling Factors on Flat-Band Potential and Band-Edge Position Determination of TiO2 Lee, Siaw Foon; Jimenez-Relinque, Eva; Martinez, Isabel Catalysts, Vol. 13, Issue 6 https://doi.org/10.3390/catal13061000	journal	June 2023
Progress in determination method for ultrathin Si-based oxide bandgaps from analysis of energy loss signals for photoelectrons Ohta, Akio; Murakami, Hideki; Makihara, Katsunori Japanese Journal of Applied Physics, Vol. 54, Issue 6S1 https://doi.org/10.7567/JJAP.54.06FH08	journal	May 2015

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