Formation of Fully Stoichiometric, Oxidation-State Pure Neptunium and Plutonium Dioxides from Molecular Precursors

Peterson, Appie; Kelly, Sheridon N.; Arino, Trevor; Gunther, S. Olivia; Ouellette, Erik T.; Wacker, Jennifer N.; Woods, Joshua J.; Teat, Simon J.; Lukens, Wayne W.; Arnold, John; Abergel, Rebecca J.; Minasian, Stefan G.

doi:10.1021/acs.inorgchem.4c02099

Title: Formation of Fully Stoichiometric, Oxidation-State Pure Neptunium and Plutonium Dioxides from Molecular Precursors

Journal Article · 16 September 2024 · Inorganic Chemistry

DOI: https://doi.org/10.1021/acs.inorgchem.4c02099 · OSTI ID:2449670

Peterson, Appie ^[1]; Kelly, Sheridon N. ^[2]; Arino, Trevor ^[3]; Gunther, S. Olivia ^[1];

^[2]; Wacker, Jennifer N. ^[1];

^[1]; Teat, Simon J. ^[4];

^[1];

^[2];

^[5];

^[1]

Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States
Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States, Department of Chemistry, University of California, Berkeley, Berkeley, California 94720, United States
Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States, Department of Nuclear Engineering, University of California, Berkeley, Berkeley, California 94720, United States
Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States
Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States, Department of Chemistry, University of California, Berkeley, Berkeley, California 94720, United States, Department of Nuclear Engineering, University of California, Berkeley, Berkeley, California 94720, United States

Not Available

View Journal Article

Cite

Export

Save

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA), Office of Defense Nuclear Nonproliferation

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 2449670

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 39 Vol. 63; ISSN 0020-1669

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (91)

Synthesis of Air-Stable, Volatile Uranium(IV) and (VI) Compounds and Their Gas-Phase Conversion To Uranium Oxide Films Appel, Linus; Leduc, Jennifer; Webster, Christopher L. Angewandte Chemie International Edition, Vol. 54, Issue 7 https://doi.org/10.1002/anie.201409606	journal	December 2014
Chemical Vapor Deposition of Phase-Pure Uranium Dioxide Thin Films from Uranium(IV) Amidate Precursors Straub, Mark D.; Leduc, Jennifer; Frank, Michael Angewandte Chemie International Edition, Vol. 58, Issue 17 https://doi.org/10.1002/anie.201901924	journal	March 2019
Ultra-Small Plutonium Oxide Nanocrystals: An Innovative Material in Plutonium Science Hudry, Damien; Apostolidis, Christos; Walter, Olaf Chemistry - A European Journal, Vol. 20, Issue 33 https://doi.org/10.1002/chem.201402008	journal	July 2014
Coordination Chemistry of Homoleptic Actinide(IV)-Thiocyanate Complexes Carter, Tyler J.; Wilson, Richard E. Chemistry - A European Journal, Vol. 21, Issue 44 https://doi.org/10.1002/chem.201502770	journal	September 2015
Bonding Trends in Tetravalent Th–Pu Monosalen Complexes Radoske, Thomas; März, Juliane; Patzschke, Michael Chemistry – A European Journal, Vol. 26, Issue 70 https://doi.org/10.1002/chem.202003241	journal	November 2020
How 5 f Electron Polarisability Drives Covalency and Selectivity in Actinide N‐Donor Complexes Köhler, Luisa; Patzschke, Michael; Schmidt, Moritz Chemistry – A European Journal, Vol. 27, Issue 72 https://doi.org/10.1002/chem.202102849	journal	December 2021
Quantitative Microstructural Characterization of Plutonium Oxalate Auto‐Degradation and Evidence for PuO ₂ Nanocrystal Formation Corbey, Jordan F.; Sweet, Lucas E.; Sinkov, Sergey I. European Journal of Inorganic Chemistry, Vol. 2021, Issue 32 https://doi.org/10.1002/ejic.202100511	journal	July 2021
The electronic Raman scattering spectrum of PuO₂ Villa‐Aleman, Eliel; Dick, Don D.; Christian, Jonathan H. Journal of Raman Spectroscopy, Vol. 54, Issue 3 https://doi.org/10.1002/jrs.6477	journal	December 2022
Actinide Nanoparticle Research Kalmykov, Stepan N.; Denecke, Melissa A. Springer Berlin, Heidelberg https://doi.org/10.1007/978-3-642-11432-8	book	January 2011
Neptunium compounds under high pressure Benedict, U.; Dabos, S.; Dufour, C. Journal of the Less Common Metals, Vol. 121 https://doi.org/10.1016/0022-5088(86)90563-1	journal	July 1986
Plutonium dioxide particle properties as a function of calcination temperature Machuron-Mandard, Xavier; Madic, Charles Journal of Alloys and Compounds, Vol. 235, Issue 2 https://doi.org/10.1016/0925-8388(95)02122-1	journal	March 1996
X- and -ray emissions observed in the decay of 237Np and 233Pa DeVries, Daniel; Griffin, Henry Applied Radiation and Isotopes, Vol. 66, Issue 5 https://doi.org/10.1016/j.apradiso.2007.07.019	journal	May 2008
Covalency in f-element complexes Neidig, Michael L.; Clark, David L.; Martin, Richard L. Coordination Chemistry Reviews, Vol. 257, Issue 2 https://doi.org/10.1016/j.ccr.2012.04.029	journal	January 2013
High quality epitaxial thin films of actinide oxides, carbides, and nitrides: Advancing understanding of electronic structure of f-element materials Scott, Brian L.; Joyce, John J.; Durakiewicz, Tomasz D. Coordination Chemistry Reviews, Vol. 266-267 https://doi.org/10.1016/j.ccr.2013.09.019	journal	May 2014
Investigation of process history and underlying phenomena associated with the synthesis of plutonium oxides using Vector Quantizing Variational Autoencoder Hainje, Connor M.; Nizinski, Cody A.; Jackson, Shane W. Chemometrics and Intelligent Laboratory Systems, Vol. 240 https://doi.org/10.1016/j.chemolab.2023.104909	journal	September 2023
Electronic structure and O K-edge XAS spectroscopy of U3O8 Wen, Xiao-Dong; Löble, Matthias W.; Batista, Enrique R. Journal of Electron Spectroscopy and Related Phenomena, Vol. 194 https://doi.org/10.1016/j.elspec.2014.03.005	journal	June 2014
Reaction mechanisms of the thermal conversion of Pu(IV) oxalate into plutonium oxide Vigier, N.; Grandjean, S.; Arab-Chapelet, B. Journal of Alloys and Compounds, Vol. 444-445 https://doi.org/10.1016/j.jallcom.2007.01.057	journal	October 2007
Evaluation of thermal properties of PuO2 and α-Pu2O3 by atomic simulation Chu, Mingfu; Meng, Daqiao; Xiao, Sa Journal of Alloys and Compounds, Vol. 539 https://doi.org/10.1016/j.jallcom.2012.05.094	journal	October 2012
Energy level schemes of f N electronic configurations for the di-, tri-, and tetravalent lanthanides and actinides in a free state Ma, C. -G.; Brik, M. G.; Liu, D. -X. Journal of Luminescence, Vol. 170 https://doi.org/10.1016/j.jlumin.2015.07.053	journal	February 2016
The melting behaviour of plutonium dioxide: A laser-heating study De Bruycker, F.; Boboridis, K.; Pöml, P. Journal of Nuclear Materials, Vol. 416, Issue 1-2 https://doi.org/10.1016/j.jnucmat.2010.11.030	journal	September 2011
Raman spectroscopy of plutonium dioxide and related materials Sarsfield, Mark J.; Taylor, Robin J.; Puxley, Christopher Journal of Nuclear Materials, Vol. 427, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2012.04.034	journal	August 2012
Kinetics of the high temperature oxygen exchange reaction on 238PuO2 powder Whiting, Christofer E.; Du, Miting; Felker, L. Kevin Journal of Nuclear Materials, Vol. 467 https://doi.org/10.1016/j.jnucmat.2015.10.020	journal	December 2015
Relationships between experimental signatures and processing history for a variety of PuO2 materials Scott, Brian L.; Pugmire, Alison L.; Stritzinger, Jared T. Journal of Nuclear Materials, Vol. 521 https://doi.org/10.1016/j.jnucmat.2019.04.036	journal	August 2019
Review of multi-faceted morphologic signatures of actinide process materials for nuclear forensic science McDonald, Luther W.; Sentz, Kari; Hagen, Alex Journal of Nuclear Materials, Vol. 588 https://doi.org/10.1016/j.jnucmat.2023.154779	journal	January 2024
Search for octupolar order in NpO2 by neutron powder diffraction Frontzek, Matthias D.; Sadergaski, Luke R.; Cary, Samantha K. Journal of Solid State Chemistry, Vol. 321 https://doi.org/10.1016/j.jssc.2023.123875	journal	May 2023
X-ray and electron microscopy of actinide materials Moore, Kevin T. Micron, Vol. 41, Issue 4 https://doi.org/10.1016/j.micron.2009.12.006	journal	June 2010
Advances in containment methods and plutonium recovery strategies that led to the structural characterization of plutonium(IV) tetrachloride tris-diphenylsulfoxide, PuCl4(OSPh2)3 Cary, Samantha K.; Boland, Kevin S.; Cross, Justin N. Polyhedron, Vol. 126 https://doi.org/10.1016/j.poly.2017.01.013	journal	April 2017
Accurate labeling of the light-actinide O4,5 edges Moore, Kevin T.; van der Laan, Gerrit Ultramicroscopy, Vol. 107, Issue 12 https://doi.org/10.1016/j.ultramic.2007.01.014	journal	November 2007
Recent Advances in Nuclear Forensic Chemistry Straub, Mark D.; Arnold, John; Fessenden, Julianna Analytical Chemistry, Vol. 93, Issue 1 https://doi.org/10.1021/acs.analchem.0c03571	journal	September 2020
Perrhenate and Pertechnetate Complexes of U(IV), Np(IV), and Pu(IV) with Dimethyl Sulfoxide as an O-Donor Ligand Andreev, Grigory; Budantseva, Nina; Sokolova, Marina Inorganic Chemistry, Vol. 59, Issue 16 https://doi.org/10.1021/acs.inorgchem.0c01036	journal	July 2020
Exploring the Oxidation States of Neptunium with Schiff Base Coordination Complexes Klamm, Bonnie E.; Windorff, Cory J.; Celis-Barros, Cristian Inorganic Chemistry, Vol. 59, Issue 24 https://doi.org/10.1021/acs.inorgchem.0c02455	journal	November 2020
Comprehensive Bonding Analysis of Tetravalent f-Element Complexes of the Type [M(salen) ₂ ] Kloditz, Roger; Radoske, Thomas; Schmidt, Moritz Inorganic Chemistry, Vol. 60, Issue 4 https://doi.org/10.1021/acs.inorgchem.0c03424	journal	February 2021
Comparative Analysis of Mononuclear 1:1 and 2:1 Tetravalent Actinide (U, Th, Np) Complexes: Crystal Structure, Spectroscopy, and Electrochemistry Bansal, Deepak; Kaden, Peter; Patzschke, Michael Inorganic Chemistry, Vol. 61, Issue 27 https://doi.org/10.1021/acs.inorgchem.2c01405	journal	June 2022
Structural and Bonding Analysis in Monomeric Actinide(IV) Oxalate from Th(IV) to Pu(IV): Comparison with the An(IV) Nitrate Series Tamain, Christelle; Autillo, Matthieu; Guillaumont, Dominique Inorganic Chemistry, Vol. 61, Issue 31 https://doi.org/10.1021/acs.inorgchem.2c01674	journal	July 2022
Paramagnetic Properties of [An^IV(NO₃)₆]²⁻ Complexes (An = U, Np, Pu) Probed by NMR Spectroscopy and Quantum Chemical Calculations Autillo, Matthieu; Illy, Marie-Claire; Briscese, Luca Inorganic Chemistry, Vol. 63, Issue 28 https://doi.org/10.1021/acs.inorgchem.4c01694	journal	July 2024
Coordination Modes of Americium in the Am ₂ (C ₂ O ₄ ) ₃ (H ₂ O) ₆ ·4H ₂ O Oxalate: Synthesis, Crystal Structure, Spectroscopic Characterizations and Comparison in the M ₂ (C ₂ O ₄ ) ₃ (H ₂ O) ₆ · n H ₂ O (M = Ln, An) Series Tamain, C.; Arab-Chapelet, B.; Rivenet, M. Inorganic Chemistry, Vol. 55, Issue 1 https://doi.org/10.1021/acs.inorgchem.5b01781	journal	December 2015
Nuclear Magnetic Resonance Measurements and Electronic Structure of Pu(IV) in [(Me) ₄ N] ₂ PuCl ₆ Mounce, Andrew M.; Yasuoka, Hiroshi; Koutroulakis, Georgios Inorganic Chemistry, Vol. 55, Issue 17 https://doi.org/10.1021/acs.inorgchem.6b00735	journal	August 2016
Synthesis and Crystal Structures of Volatile Neptunium(IV) β-Diketonates Johnson, Aaron T.; Parker, T. Gannon; Dickens, Sara M. Inorganic Chemistry, Vol. 56, Issue 21 https://doi.org/10.1021/acs.inorgchem.7b02290	journal	October 2017
Advancing Understanding of the +4 Metal Extractant Thenoyltrifluoroacetonate (TTA ^– ); Synthesis and Structure of M ^IV TTA ₄ (M ^IV = Zr, Hf, Ce, Th, U, Np, Pu) and M ^III (TTA) ₄ ^– (M ^III = Ce, Nd, Sm, Yb) Cary, Samantha K.; Livshits, Maksim; Cross, Justin N. Inorganic Chemistry, Vol. 57, Issue 7 https://doi.org/10.1021/acs.inorgchem.7b03089	journal	December 2017
From Thorium to Plutonium: Trends in Actinide(IV) Chloride Structural Chemistry Wacker, Jennifer N.; Han, Sae Young; Murray, Aphra V. Inorganic Chemistry, Vol. 58, Issue 16 https://doi.org/10.1021/acs.inorgchem.9b01279	journal	June 2019
Structural and Optical Properties of Phase-Pure UO ₂ , α-U ₃ O ₈ , and α-UO ₃ Epitaxial Thin Films Grown by Pulsed Laser Deposition Enriquez, Erik; Wang, Gaoxue; Sharma, Yogesh ACS Applied Materials & Interfaces, Vol. 12, Issue 31 https://doi.org/10.1021/acsami.0c08635	journal	July 2020
Evaluation of Homoleptic Guanidinate and Amidinate Complexes of Gadolinium and Dysprosium for MOCVD of Rare-Earth Nitride Thin Films Thiede, Tobias B.; Krasnopolski, Michael; Milanov, Andrian P. Chemistry of Materials, Vol. 23, Issue 6 https://doi.org/10.1021/cm102840v	journal	March 2011
Recent Developments in Synthesis and Structural Chemistry of Nonaqueous Actinide Complexes Jones, Matthew B.; Gaunt, Andrew J. Chemical Reviews, Vol. 113, Issue 2 https://doi.org/10.1021/cr300198m	journal	October 2012
Actinide Colloids and Particles of Environmental Concern Walther, Clemens; Denecke, Melissa A. Chemical Reviews, Vol. 113, Issue 2 https://doi.org/10.1021/cr300343c	journal	October 2012
Multiscale Speciation of U and Pu at Chernobyl, Hanford, Los Alamos, McGuire AFB, Mayak, and Rocky Flats Batuk, Olga N.; Conradson, Steven D.; Aleksandrova, Olga N. Environmental Science & Technology, Vol. 49, Issue 11 https://doi.org/10.1021/es506145b	journal	April 2015
Speciation and Unusual Reactivity in PuO ₂₊ _x Conradson, Steven D.; Begg, Bruce D.; Clark, David L. Inorganic Chemistry, Vol. 42, Issue 12 https://doi.org/10.1021/ic026044l	journal	June 2003
Polymeric Structure of Oxalato-Bridged Complexes of Tetravalent Actinides Th, U, Np and Pu Andreev, Grigory; Budantseva, Nina; Fedoseev, Aleksander Inorganic Chemistry, Vol. 50, Issue 22 https://doi.org/10.1021/ic201313g	journal	November 2011
Bonding Trends Traversing the Tetravalent Actinide Series: Synthesis, Structural, and Computational Analysis of An ^IV ( ^Ar acnac) ₄ Complexes (An = Th, U, Np, Pu; ^Ar acnac = Ar N C(Ph)CHC(Ph) O ; Ar = 3,5- ^t Bu ₂ C ₆ H ₃ ) Schnaars, David D.; Gaunt, Andrew J.; Hayton, Trevor W. Inorganic Chemistry, Vol. 51, Issue 15 https://doi.org/10.1021/ic301109f	journal	July 2012
Directed Synthesis of Crystalline Plutonium(III) and (IV) Oxalates: Accessing Redox-Controlled Separations in Acidic Solutions Runde, Wolfgang; Brodnax, Lia F.; Goff, George Inorganic Chemistry, Vol. 48, Issue 13 https://doi.org/10.1021/ic900344u	journal	July 2009
Local and Nanoscale Structure and Speciation in the PuO ₂₊ _x _- _y (OH) ₂ _y · z H ₂ O System Conradson, Steven D.; Begg, Bruce D.; Clark, David L. Journal of the American Chemical Society, Vol. 126, Issue 41 https://doi.org/10.1021/ja049192e	journal	October 2004
A Uranium(II) Arene Complex That Acts as a Uranium(I) Synthon Straub, Mark D.; Ouellette, Erik T.; Boreen, Michael A. Journal of the American Chemical Society, Vol. 143, Issue 47 https://doi.org/10.1021/jacs.1c07854	journal	November 2021
[AnI ₃ (THF) ₄ ] (An = Np, Pu) Preparation Bypassing An ⁰ Metal Precursors: Access to Np ³⁺ /Pu ³⁺ Nonaqueous and Organometallic Complexes Goodwin, Conrad A. P.; Janicke, Michael T.; Scott, Brian L. Journal of the American Chemical Society, Vol. 143, Issue 49 https://doi.org/10.1021/jacs.1c07967	journal	December 2021
Synthesis and Characterization of Tris-chelate Complexes for Understanding f -Orbital Bonding in Later Actinides Galley, Shane S.; Pattenaude, Scott A.; Gaggioli, Carlo Alberto Journal of the American Chemical Society, Vol. 141, Issue 6 https://doi.org/10.1021/jacs.8b10251	journal	January 2019
In-Plane Thorium(IV), Uranium(IV), and Neptunium(IV) Expanded Porphyrin Complexes Brewster, James T.; Mangel, Daniel N.; Gaunt, Andrew J. Journal of the American Chemical Society, Vol. 141, Issue 44 https://doi.org/10.1021/jacs.9b09123	journal	October 2019
New Insights into the Formation of Hyperstoichiometric Plutonium Oxides Ao, Bingyun; Qiu, Ruizhi; Lu, Haiyan The Journal of Physical Chemistry C, Vol. 119, Issue 1 https://doi.org/10.1021/jp5097794	journal	December 2014
The Scherrer equation versus the 'Debye-Scherrer equation' Holzwarth, Uwe; Gibson, Neil Nature Nanotechnology, Vol. 6, Issue 9 https://doi.org/10.1038/nnano.2011.145	journal	August 2011
Open questions in transplutonium coordination chemistry Carter, Korey P.; Pallares, Roger M.; Abergel, Rebecca J. Communications Chemistry, Vol. 3, Issue 1 https://doi.org/10.1038/s42004-020-00338-5	journal	August 2020
Synthesis and characterization of NpCl ₄ (DME) ₂ and PuCl ₄ (DME) ₂ neutral transuranic An( iv ) starting materials Reilly, Sean D.; Brown, Jessie L.; Scott, Brian L. Dalton Trans., Vol. 43, Issue 4 https://doi.org/10.1039/C3DT53058B	journal	January 2014
Bonding trends across the series of tricarbonato-actinyl anions [(AnO ₂ )(CO ₃ ) ₃ ] ⁴⁻ (An = U–Cm): the plutonium turn Liu, Jian-Biao; Chen, Guo P.; Huang, Wei Dalton Transactions, Vol. 46, Issue 8 https://doi.org/10.1039/C6DT03953G	journal	January 2017
Homoleptic zirconium amidates: single source precursors for the aerosol-assisted chemical vapour deposition of ZrO ₂ Catherall, Amanda L.; Hill, Michael S.; Johnson, Andrew L. Journal of Materials Chemistry C, Vol. 4, Issue 45 https://doi.org/10.1039/C6TC03631G	journal	January 2016
Homoleptic U( iii ) and U( iv ) amidate complexes Straub, M. D.; Hohloch, S.; Minasian, S. G. Dalton Transactions, Vol. 47, Issue 6 https://doi.org/10.1039/C7DT04813K	journal	January 2018
Plutonium chlorido nitrato complexes: ligand competition and computational metrics for assembly and bonding Surbella, Robert G.; Ducati, Lucas C.; Autschbach, Jochen Chemical Communications, Vol. 54, Issue 85 https://doi.org/10.1039/C8CC05578E	journal	January 2018
Complexation-assisted reduction: complexes of glutaroimide-dioxime with tetravalent actinides (Np( iv ) and Th( iv )) Zhang, Zhicheng; Parker, Bernard F.; Lohrey, Trevor D. Dalton Transactions, Vol. 47, Issue 24 https://doi.org/10.1039/C8DT01191E	journal	January 2018
The defect chemistry of non-stoichiometric PuO _2±x Neilson, William D.; Pegg, James T.; Steele, Helen Physical Chemistry Chemical Physics, Vol. 23, Issue 8 https://doi.org/10.1039/D0CP06497A	journal	January 2021
Systematic comparison of the structure of homoleptic tetradentate N ₂ O ₂ -type Schiff base complexes of tetravalent f-elements (M( iv ) = Ce, Th, U, Np, and Pu) in solid state and in solution Radoske, Thomas; Kloditz, Roger; Fichter, Sebastian Dalton Transactions, Vol. 49, Issue 48 https://doi.org/10.1039/D0DT03405C	journal	January 2020
Effect of calcination temperature on neptunium dioxide microstructure and dissolution Peruski, Kathryn M.; Powell, Brian A. Environmental Science: Nano, Vol. 7, Issue 12 https://doi.org/10.1039/D0EN00689K	journal	January 2020
Thorium amidates function as single-source molecular precursors for thorium dioxide Straub, Mark D.; Ouellette, Erik T.; Boreen, Michael A. Chemical Communications, Vol. 57, Issue 40 https://doi.org/10.1039/D1CC00867F	journal	January 2021
Synthesis and multi-scale properties of PuO₂ nanoparticles: recent advances and open questions Virot, Matthieu; Dumas, Thomas; Cot-Auriol, Manon Nanoscale Advances, Vol. 4, Issue 23 https://doi.org/10.1039/D2NA00306F	journal	January 2022
Actinide structural studies. Part 8. Some new oxygen-donor complexes of trichloro(cyclopentadienyl)neptunium( IV ); the crystal structure of trichloro(η ⁵ -cyclopentadienyl)bis(methyldiphenylphosphine oxide)neptunium( IV ) Bagnall, Kenneth W.; Payne, Gerard F.; Alcock, Nathaniel W. J. Chem. Soc., Dalton Trans., Issue 4 https://doi.org/10.1039/DT9860000783	journal	January 1986
Amidate complexes of titanium and zirconium: a new class of tunable precatalysts for the hydroamination of alkynesElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b3/b304176j/ Li, Chunyu; Thomson, Robert K.; Gillon, Bronwyn Chemical Communications, Issue 19 https://doi.org/10.1039/b304176j	journal	January 2003
Lanthanide amidinates and guanidinates in catalysis and materials science: a continuing success story Edelmann, Frank T. Chemical Society Reviews, Vol. 41, Issue 23 https://doi.org/10.1039/c2cs35180c	journal	January 2012
Complexation and redox chemistry of neptunium, plutonium and americium with a hydroxylaminato ligand Su, Jing; Cheisson, Thibault; McSkimming, Alex Chemical Science, Vol. 12, Issue 40 https://doi.org/10.1039/d1sc03905a	journal	January 2021
Electronic Spectra of the 5f3 Actinides: U ³⁺ , Np ⁴⁺ , Pu ⁵⁺ , and AmO ₂ ⁺⁺ . The f3 Intermediate Coupling Diagram Varga, L. P.; Reisfeld, M. J.; Asprey, L. B. The Journal of Chemical Physics, Vol. 53, Issue 1 https://doi.org/10.1063/1.1673772	journal	July 1970
Science-based cleanup of Rocky Flats Clark, David L.; Janecky, David R.; Lane, Leonard J. Physics Today, Vol. 59, Issue 9 https://doi.org/10.1063/1.2364243	journal	September 2006
Optical band gap of NpO ₂ and PuO ₂ from optical absorbance of epitaxial films Mark McCleskey, T.; Bauer, Eve; Jia, Quanxi Journal of Applied Physics, Vol. 113, Issue 1 https://doi.org/10.1063/1.4772595	journal	January 2013
Behavior of plutonium in the environment Romanchuk, A. Yu; Kalmykov, S. N.; Kersting, A. B. Russian Chemical Reviews, Vol. 85, Issue 9 https://doi.org/10.1070/RCR4602	journal	September 2016
A review of uranium-based thin films Springell, R.; Lawrence Bright, E.; Chaney, D. A. Advances in Physics, Vol. 71, Issue 3-4 https://doi.org/10.1080/00018732.2023.2230292	journal	October 2022
Eight and Nine-Coordinate Plutonium (IV) Complexes of the f-Element Extractant 2,5-Bis(diphenylphosphinomethyl)benzene P,P'-dioxide Including Structural Characterization of a Plutonium (IV) Alkoxide Matonic, John H.; Enriquez, Alejandro E.; Scott, Brian L. Journal of Nuclear Science and Technology, Vol. 39, Issue sup3 https://doi.org/10.1080/00223131.2002.10875492	journal	November 2002
5 f -Shell correlation effects in dioxides of light actinides studied by O 1 s x-ray absorption and emission spectroscopies and first-principles calculations Modin, A.; Suzuki, M-T; Vegelius, J. Journal of Physics: Condensed Matter, Vol. 27, Issue 31 https://doi.org/10.1088/0953-8984/27/31/315503	journal	July 2015
Advances in actinide thin films: synthesis, properties, and future directions Vallejo, Kevin D.; Kabir, Firoza; Poudel, Narayan Reports on Progress in Physics, Vol. 85, Issue 12 https://doi.org/10.1088/1361-6633/ac968e	journal	October 2022
Synchrotron radiation techniques and their application to actinide materials Caciuffo, R.; Lander, G. H.; van der Laan, G. Reviews of Modern Physics, Vol. 95, Issue 1 https://doi.org/10.1103/RevModPhys.95.015001	journal	March 2023
Single-crystal structure validation with the program PLATON Spek, A. L. Journal of Applied Crystallography, Vol. 36, Issue 1, p. 7-13 https://doi.org/10.1107/S0021889802022112	journal	January 2003
OLEX2 : a complete structure solution, refinement and analysis program Dolomanov, Oleg V.; Bourhis, Luc J.; Gildea, Richard J. Journal of Applied Crystallography, Vol. 42, Issue 2 https://doi.org/10.1107/S0021889808042726	journal	January 2009
A short history of SHELX Sheldrick, George M. Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122 https://doi.org/10.1107/S0108767307043930	journal	December 2007
Lithium(I) hexaamminecobalt(III) tetrakis(malonato-κ²O,O′′)plutonate(IV) pentahydrate Grigoriev, Mikhail S.; Krot, Nikolai N.; Bessonov, Alexei A. Acta Crystallographica Section E Structure Reports Online, Vol. 62, Issue 11 https://doi.org/10.1107/S1600536806041328	journal	October 2006
SHELXT – Integrated space-group and crystal-structure determination Sheldrick, George M. Acta Crystallographica Section A Foundations and Advances, Vol. 71, Issue 1, p. 3-8 https://doi.org/10.1107/S2053273314026370	journal	January 2015
Reaction of Plutonium Dioxide with Water: Formation and Properties of PuO2+x Haschke, J. M. Science, Vol. 287, Issue 5451 https://doi.org/10.1126/science.287.5451.285	journal	January 2000
Cation-cation interaction in mixed-valent An(IV)/Np(V) tribromoacetates [An(NpO2)(H2O)3(CBr3COO)5]·CBr3COOH·nH2O, An = Th(IV), Np(IV) Charushnikova, I. A.; Krot, N. N.; Grigor’ev, M. S. Radiochemistry, Vol. 56, Issue 5 https://doi.org/10.1134/S1066362214050026	journal	September 2014
Exploring the Frontiers of Nuclear and Radiochemistry Hoffman, Darleane C. Journal of Nuclear and Radiochemical Sciences, Vol. 8, Issue 2 https://doi.org/10.14494/jnrs2000.8.35	journal	January 2007
A Novel Technique for Raman Analysis of Highly Radioactive Samples Using Any Standard Micro-Raman Spectrometer Colle, Jean-Yves; Naji, Mohamed; Sierig, Mark Journal of Visualized Experiments, Issue 122 https://doi.org/10.3791/54889	journal	April 2017
The Crystal Structure of beta-Tetrakis (acetylacetonato)neptunium(IV). Allard, Bert; Dhabanandana, S.; Krogh-Moe, J. Acta Chemica Scandinavica, Vol. 26 https://doi.org/10.3891/acta.chem.scand.26-3492	journal	January 1972

Similar Records

ENTHALPY OF FORMATION OF NEPTUNIUM DIOXIDE.

Journal Article · 1968 · J. Chem. Eng. Data, 13: 545-6(Oct. 1968). · OSTI ID:4839812

Huber, Jr, E J; Holley, Jr, C E

HEPTAVALENT STATE OF NEPTUNIUM AND PLUTONIUM.

Journal Article · 1970 · Vestn. Akad. Nauk SSSR No. 3, 57-61(Mar 1970). · OSTI ID:4748230

Krot, N N; Gel'man, A D; Mefod'eva, M P

HEPTAVALENT STATE OF NEPTUNIUM AND PLUTONIUM.

Journal Article · 1969 · J. Inorg. Nucl. Chem., 31: 2733-45(Sept. 1969). · OSTI ID:4748422

Spitsyn, V I; Gelman, A D; Krot, N N; +5 more

Title: Formation of Fully Stoichiometric, Oxidation-State Pure Neptunium and Plutonium Dioxides from Molecular Precursors

Citation Formats

References (91)

Similar Records

Related Subjects