Selective 17O-labeling of silica

Agarwal, Amil; Mais, Marco; Perras, Frédéric A.

doi:10.1039/d4cc04584j

Title: Selective ¹⁷O-labeling of silica

Journal Article · 24 September 2024 · ChemComm

DOI: https://doi.org/10.1039/d4cc04584j · OSTI ID:2448476

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University of North Carolina at Chapel Hill, NC (United States); Ames Laboratory (AMES), Ames, IA (United States)
Ames Laboratory (AMES), Ames, IA (United States)
Ames Laboratory (AMES), Ames, IA (United States); Iowa State University, Ames, IA (United States)

The addition of ¹⁷OH₂ to silica at room temperature leads to spontaneous hydroxyl oxygen exchange and the selective isotopic enrichment of silanols, as observed using in and ex situ ¹⁷O NMR. Furthermore, the discovery that silanols are labile alters our understanding of the chemistry of silica surfaces.

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Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 2448476

Report Number(s):: IS-J--11,437

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 84 Vol. 60; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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