Fractional precipitation of Ni and Co double salts from lithium-ion battery leachates

Klaehn, John R.; Shi, Meng; Diaz, Luis A.; Molina, Daniel E.; Repukaiti, Reyixiati; Sani, Fazlollah Madani; Lencka, Margaret; Anderko, Andre; Arulsamy, Navamoney; Lister, Tedd E.

doi:10.1039/D4SU00303A

Title: Fractional precipitation of Ni and Co double salts from lithium-ion battery leachates

Journal Article · 31 October 2024 · RSC Sustainability

DOI: https://doi.org/10.1039/D4SU00303A · OSTI ID:2447883

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Critical Materials Innovation Hub, Idaho National Laboratory, 2525 Fremont Avenue, Idaho Falls, ID 83402, USA
Critical Materials Innovation Hub, OLI Systems Inc., 2 Gatehall Dr, Suite 1D, Parsippany, NJ 07054, USA
University of Wyoming, 1000 E. University Ave., Laramie, WY 82071, USA

The isolation of Ni/Co double salts can be recovered by fractional precipitation with ammonium sulfate. The elemental analysis of these isolated double salts shows a total metal composition of >99% of Ni, Co, and Mn with negligible impurity metals.

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Sponsoring Organization:: USDOE

OSTI ID:: 2447883

Journal Information:: RSC Sustainability, Journal Name: RSC Sustainability Journal Issue: 11 Vol. 2; ISSN 2753-8125; ISSN RSSUAN

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (38)

On the design of crystallization-based separation processes: Review and extension Cisternas, Luis A.; Vásquez, Cristian M.; Swaney, Ross E. AIChE Journal, Vol. 52, Issue 5 https://doi.org/10.1002/aic.10768	journal	January 2006
Recycling of mixed cathode lithium‐ion batteries for electric vehicles: Current status and future outlook Or, Tyler; Gourley, Storm W. D.; Kaliyappan, Karthikeyan Carbon Energy, Vol. 2, Issue 1 https://doi.org/10.1002/cey2.29	journal	March 2020
Ueber die Löslichkeit einiger schwefelsauren Salze der Magnesiareihe in Wasser Tobler, Ed. Justus Liebigs Annalen der Chemie, Vol. 95, Issue 2 https://doi.org/10.1002/jlac.18550950207	journal	January 1855
Ueber einige Salze v. Hauer, Carl Ritter Journal für Praktische Chemie, Vol. 74, Issue 1 https://doi.org/10.1002/prac.18580740162	journal	January 1858
Über die Polythermen der ternären Systeme, die neben Wasser je ein Sulfat der Alkalien und der Vitriolbildner enthalten. VI Benrath, Alfred Zeitschrift für anorganische und allgemeine Chemie, Vol. 208, Issue 2 https://doi.org/10.1002/zaac.19322080208	journal	October 1932
Phase Behavior of Aqueous Na–K–Mg–Ca–Cl–NO3 Mixtures: Isopiestic Measurements and Thermodynamic Modeling Gruszkiewicz, Mirosław S.; Palmer, Donald A.; Springer, Ronald D. Journal of Solution Chemistry, Vol. 36, Issue 6 https://doi.org/10.1007/s10953-007-9145-2	journal	May 2007
Modeling Speciation and Solubility in Aqueous Systems Containing U(IV, VI), Np(IV, V, VI), Pu(III, IV, V, VI), Am(III), and Cm(III) Wang, Peiming; Anderko, Andrzej; Kosinski, Jerzy J. Journal of Solution Chemistry, Vol. 46, Issue 3 https://doi.org/10.1007/s10953-017-0587-x	journal	February 2017
Comparison of iron(III) and aluminum in precipitation of phosphate from solution Water Research, Vol. 10, Issue 10 https://doi.org/10.1016/0043-1354(76)90026-9	journal	January 1976
A speciation-based model for mixed-solvent electrolyte systems Wang, Peiming; Anderko, Andrzej; Young, Robert D. Fluid Phase Equilibria, Vol. 203, Issue 1-2 https://doi.org/10.1016/S0378-3812(02)00178-4	journal	December 2002
Optimizing solubility: Kinetic versus thermodynamic solubility temptations and risks Saal, Christoph; Petereit, Anna Christine European Journal of Pharmaceutical Sciences, Vol. 47, Issue 3 https://doi.org/10.1016/j.ejps.2012.07.019	journal	October 2012
Rare-earth elements in aqueous chloride systems: Thermodynamic modeling of binary and multicomponent systems in wide concentration ranges Das, Gaurav; Lencka, Malgorzata M.; Eslamimanesh, Ali Fluid Phase Equilibria, Vol. 452 https://doi.org/10.1016/j.fluid.2017.08.014	journal	November 2017
Modeling chemical and phase equilibria in geochemical systems using a speciation-based model Wang, Peiming; Anderko, Andrzej; Springer, Ronald D. Journal of Geochemical Exploration, Vol. 106, Issue 1-3 https://doi.org/10.1016/j.gexplo.2009.09.003	journal	July 2010
Aqueous precipitation and crystallization for the production of particulate solids with desired properties Demopoulos, G. P. Hydrometallurgy, Vol. 96, Issue 3 https://doi.org/10.1016/j.hydromet.2008.10.004	journal	April 2009
Growth and characterization of ammonium nickel-cobalt sulfate Tutton’s salt for UV light applications Ghosh, Santunu; Oliveira, Michelle; Pacheco, Tiago S. Journal of Crystal Growth, Vol. 487 https://doi.org/10.1016/j.jcrysgro.2018.02.027	journal	April 2018
Rare earth sulfates in aqueous systems: Thermodynamic modeling of binary and multicomponent systems over wide concentration and temperature ranges Das, Gaurav; Lencka, Malgorzata M.; Eslamimanesh, Ali The Journal of Chemical Thermodynamics, Vol. 131 https://doi.org/10.1016/j.jct.2018.10.020	journal	April 2019
A review of the processes and lab-scale techniques for the treatment of spent rechargeable NiMH batteries Innocenzi, Valentina; Ippolito, Nicolò Maria; De Michelis, Ida Journal of Power Sources, Vol. 362 https://doi.org/10.1016/j.jpowsour.2017.07.034	journal	September 2017
Modeling phase equilibria and speciation in mixed-solvent electrolyte systems: II. Liquid–liquid equilibria and properties of associating electrolyte solutions Wang, P.; Anderko, A.; Springer, R. D. Journal of Molecular Liquids, Vol. 125, Issue 1 https://doi.org/10.1016/j.molliq.2005.11.030	journal	March 2006
Synthesis, characterization, thermal analysis and electrical properties of (NH4)2M(SO4)2·6H2O (M = Cu, Co, Ni) Bejaoui, Abir; Souamti, Ahmed; Kahlaoui, Massoud Materials Science and Engineering: B, Vol. 240 https://doi.org/10.1016/j.mseb.2019.01.016	journal	January 2019
A new crystal of ammonium cobalt nickel sulfate hexahydrate for UV light band-pass filter Su, Genbo; Zhuang, Xinxin; He, Youping Optical Materials, Vol. 30, Issue 6 https://doi.org/10.1016/j.optmat.2007.04.002	journal	February 2008
Electrochemical-assisted leaching of active materials from lithium ion batteries Diaz, Luis A.; Strauss, Mark L.; Adhikari, Birendra Resources, Conservation and Recycling, Vol. 161 https://doi.org/10.1016/j.resconrec.2020.104900	journal	October 2020
A Critical Review and Analysis on the Recycling of Spent Lithium-Ion Batteries Lv, Weiguang; Wang, Zhonghang; Cao, Hongbin ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 2 https://doi.org/10.1021/acssuschemeng.7b03811	journal	December 2017
Hydrometallurgical Processes for Recycling Spent Lithium-Ion Batteries: A Critical Review Yao, Yonglin; Zhu, Meiying; Zhao, Zhuo ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 11 https://doi.org/10.1021/acssuschemeng.8b03545	journal	September 2018
Process designs for fractional crystallization from solution Cisternas, Luis A.; Rudd, Dale F. Industrial & Engineering Chemistry Research, Vol. 32, Issue 9 https://doi.org/10.1021/ie00021a022	journal	September 1993
Physical Properties of the Metal Cobalt. Kalmus, Herbert T.; Harper, C. Journal of Industrial & Engineering Chemistry, Vol. 7, Issue 1 https://doi.org/10.1021/ie50073a004	journal	January 1915
Ternary Systems. XXIII. Solid Solution among the Picromerite Double Salts at 25°. The Zinc, Copper and Nickel Ammonium Sulfates Hill, Arthur E.; Taylor, William J. Journal of the American Chemical Society, Vol. 60, Issue 5 https://doi.org/10.1021/ja01272a032	journal	May 1938
Solubility in the System Aluminum Phosphate-Phosphoric Acid-Water Brosheer, J. C.; Lenfesty, F. A.; Anderson, J. F. Journal of the American Chemical Society, Vol. 76, Issue 23 https://doi.org/10.1021/ja01652a016	journal	December 1954
Diffusivity, density, viscosity, and refractive index of nickel ammonium sulfate aqueous solutions Mullin, John W.; Osman, M. M. Journal of Chemical & Engineering Data, Vol. 12, Issue 4 https://doi.org/10.1021/je60035a013	journal	October 1967
Recycling lithium-ion batteries from electric vehicles Harper, Gavin; Sommerville, Roberto; Kendrick, Emma Nature, Vol. 575, Issue 7781 https://doi.org/10.1038/s41586-019-1682-5	journal	November 2019
Recycling of spent lithium-ion batteries in view of green chemistry Li, Yukun; Lv, Weiguang; Huang, Hanlin Green Chemistry, Vol. 23, Issue 17 https://doi.org/10.1039/D1GC01639C	journal	January 2021
Technologies of lithium recycling from waste lithium ion batteries: a review Bae, Hyuntae; Kim, Youngsik Materials Advances https://doi.org/10.1039/D1MA00216C	journal	January 2021
221. Equilibria in the systems (NH₄)₂SO₄–NiSO₄–H₂O, (NH₄)₂SO₄–CoSO₄–H₂O, (NH₄)₂SO₄–ZnSO₄–H₂O, Na₂SO₄–NiSO₄–H₂O, and Na₂SO₄–CoSO₄–H₂O, at 25° Caven, Robert M.; Gardner, W. Kidston J. Chem. Soc., Vol. 0, Issue 0 https://doi.org/10.1039/JR9330000943	journal	January 1933
Ammonium nickel sulfate hexahydrate crystal: a new ultraviolet light filter Su, Genbo; Zhuang, Xinxin; He, Youping Journal of Physics D: Applied Physics, Vol. 35, Issue 20 https://doi.org/10.1088/0022-3727/35/20/327	journal	October 2002
Growth and structural analysis of ammonium nickel cobalt sulfate hexahydrate crystals de Oliveira, Michelle; Ghosh, Santunu; Pacheco, Tiago S. Materials Research Express, Vol. 4, Issue 10 https://doi.org/10.1088/2053-1591/aa9194	journal	October 2017
Crystal structure refinement with SHELXL Sheldrick, George M. Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1, p. 3-8 https://doi.org/10.1107/S2053229614024218	journal	January 2015
XX. Ueber die Löslichkeit von Mischkrystallen und die Grösse des Krystallmoleküls Fock, A. Zeitschrift für Kristallographie - Crystalline Materials, Vol. 28, Issue 1-6 https://doi.org/10.1524/zkri.1897.28.1.337	journal	December 1897
Solubility Product of Iron Phosphate1 Chang, S. C.; Jackson, M. L. Soil Science Society of America Journal, Vol. 21, Issue 3 https://doi.org/10.2136/sssaj1957.03615995002100030005x	journal	January 1957
Industrial Recycling of Lithium-Ion Batteries—A Critical Review of Metallurgical Process Routes Brückner, Lisa; Frank, Julia; Elwert, Tobias Metals, Vol. 10, Issue 8 https://doi.org/10.3390/met10081107	journal	August 2020
Evolution of Environmentally Friendly Strategies for Metal Extraction Shyam Sunder, Govind Sharma; Adhikari, Sandhya; Rohanifar, Ahmad Separations, Vol. 7, Issue 1 https://doi.org/10.3390/separations7010004	journal	January 2020

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