Impacts of trace level chromium on formation of superoxide within uranyl triperoxide complexes

Scherrer, Sarah K.; Rajapaksha, Harindu; Kravchuk, Dmytro V.; Mason, Sara E.; Forbes, Tori Z.

doi:10.1039/D4CC03194F

Title: Impacts of trace level chromium on formation of superoxide within uranyl triperoxide complexes

Journal Article · 20 September 2024 · ChemComm

DOI: https://doi.org/10.1039/D4CC03194F · OSTI ID:2447549

Scherrer, Sarah K. ^[1];

^[1]; Kravchuk, Dmytro V. ^[1]; Mason, Sara E. ^[2];

^[1]

Department of Chemistry, University of Iowa, Iowa City, Iowa 52242, USA
Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973, USA

U( vi ) triperoxide solids oxidize to superoxide forms in the presence of trace-level chromium. In solution, the U( vi ) superoxide grows in after 48 h and can be detected by EPR spectroscopy without the use of a spin-trap.

View Journal Article

Cite

Export

Save

Sponsoring Organization:: USDOE

Grant/Contract Number:: NONE; SC0023479; SC0012704

OSTI ID:: 2447549

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 76 Vol. 60; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (24)

Isolation and Reactivity of Uranyl Superoxide Kravchuk, Dmytro V.; Dahlen, Nicholas N.; Kruse, Samantha J. Angewandte Chemie International Edition, Vol. 60, Issue 27 https://doi.org/10.1002/anie.202103039	journal	June 2021
Superoxide Radicals in Uranyl Peroxide Solids: Lasting Signatures Identified by Electron Paramagnetic Resonance Spectroscopy Scherrer, Sarah K.; Gates, Cassandra; Rajapaksha, Harindu Angewandte Chemie International Edition, Vol. 63, Issue 21 https://doi.org/10.1002/anie.202400379	journal	March 2024
Radiation chemistry and the nuclear fuel cycle Mincher, Bruce J.; Elias, Gracy; Martin, Leigh R. Journal of Radioanalytical and Nuclear Chemistry, Vol. 282, Issue 2 https://doi.org/10.1007/s10967-009-0156-x	journal	July 2009
The effects of radiation chemistry on radiochemistry: when unpaired electrons defy great expectations Mincher, Bruce J. Journal of Radioanalytical and Nuclear Chemistry, Vol. 316, Issue 2 https://doi.org/10.1007/s10967-018-5728-1	journal	February 2018
ESR of matrix isolated alkali superoxides Lindsay, D. M.; Herschbach, D. R.; Kwiram, Alvin L. Chemical Physics Letters, Vol. 25, Issue 2 https://doi.org/10.1016/0009-2614(74)89112-8	journal	March 1974
EPR kinetic studies of superoxide radicals generated during the autoxidation of 1-methyl-4-phenyl-2,3-dihydropyridinium, a bioactivated intermediate of parkinsonian-inducing neurotoxin 1-methyl-4-phenyl-1,2,3,6-tetrahydropyridine. Zang, L. Y.; Misra, H. P. Journal of Biological Chemistry, Vol. 267, Issue 33 https://doi.org/10.1016/S0021-9258(18)35881-2	journal	November 1992
Comparative chemical and structural analyses of two uranium dioxide fuel pellets Spano, Tyler L.; Simonetti, Antonio; Corcoran, Loretta Journal of Nuclear Materials, Vol. 518 https://doi.org/10.1016/j.jnucmat.2019.02.038	journal	May 2019
Distribution of Fission Products into Tributyl Phosphate under Applied Nuclear Fuel Recycling Conditions Baldwin, Anna G.; Bridges, Nicholas J.; Braley, Jenifer C. Industrial & Engineering Chemistry Research, Vol. 55, Issue 51 https://doi.org/10.1021/acs.iecr.6b04056	journal	December 2016
Computationally-Guided Assignment of Unexpected Signals in the Raman Spectra of Uranyl Triperoxide Complexes Dembowski, Mateusz; Bernales, Varinia; Qiu, Jie Inorganic Chemistry, Vol. 56, Issue 3 https://doi.org/10.1021/acs.inorgchem.6b02666	journal	January 2017
Thermodynamics and Chemical Behavior of Uranyl Superoxide at Elevated Temperatures Kravchuk, Dmytro V.; Forbes, Tori Z. ACS Materials Au, Vol. 2, Issue 1 https://doi.org/10.1021/acsmaterialsau.1c00033	journal	August 2021
EPR Spectroscopic Studies on the Formation of Chromium(V) Peroxo Complexes in the Reaction of Chromium(VI) with Hydrogen Peroxide Zhang, Lianbo; Lay, Peter A. Inorganic Chemistry, Vol. 37, Issue 8 https://doi.org/10.1021/ic971069j	journal	April 1998
Kinetic Studies of the Reactions of Peroxy Compounds of Chromium(VI), Vanadium(V), and Titanium(IV) in Acid Media Orhanovic, Mato.; Wilkins, Ralph G. Journal of the American Chemical Society, Vol. 89, Issue 2 https://doi.org/10.1021/ja00978a019	journal	January 1967
Tetraorganylammonium Superoxide Compounds: Close to Unperturbed Superoxide Ions in the Solid State Dietzel, Pascal D. C.; Kremer, Reinhard K.; Jansen, Martin Journal of the American Chemical Society, Vol. 126, Issue 14 https://doi.org/10.1021/ja039880i	journal	April 2004
New technology for post-combustion abatement of carbon dioxide via an in situ generated superoxide anion-radical Stoin, Uri; Barnea, Zach; Sasson, Yoel RSC Adv., Vol. 4, Issue 69 https://doi.org/10.1039/C4RA03844D	journal	January 2014
Uranyl peroxide enhanced nuclear fuel corrosion in seawater Armstrong, C. R.; Nyman, M.; Shvareva, T. Proceedings of the National Academy of Sciences, Vol. 109, Issue 6 https://doi.org/10.1073/pnas.1119758109	journal	January 2012
Comparison of different methods for measuring the superoxide radical by EPR spectroscopy in buffer, cell lysates and cells Scheinok, Samantha; Leveque, Philippe; Sonveaux, Pierre Free Radical Research, Vol. 52, Issue 10 https://doi.org/10.1080/10715762.2018.1541321	journal	October 2018
Stability of Peroxide-Containing Uranyl Minerals Kubatko, K. -A. H. Science, Vol. 302, Issue 5648 https://doi.org/10.1126/science.1090259	journal	November 2003
La radiolyse de l'eau et des solutions aqueuses : historique et actualité Ferradini, Christiane; Jay-Gerin, Jean-Paul Canadian Journal of Chemistry, Vol. 77, Issue 9 https://doi.org/10.1139/v99-162	journal	September 1999
Radiation chemical effects on radiochemistry: A review of examples important to nuclear power Mincher, Bruce J.; Mezyk, Stephen P. Radiochimica Acta, Vol. 97, Issue 9 https://doi.org/10.1524/ract.2009.1646	journal	January 2009
Corrosion of commercial spent nuclear fuel. 1. Formation of studtite and metastudtite Hanson, Brady D.; McNamara, Bruce; Buck, Edgar C. Radiochimica Acta, Vol. 93, Issue 3 https://doi.org/10.1524/ract.93.3.159.61613	journal	January 2005
Secondary Uranium Minerals on the Surface of Chernobyl “Lava” Burakov, B. E.; Strykanova, E. E.; Anderson, E. B. MRS Proceedings, Vol. 465 https://doi.org/10.1557/PROC-465-1309	journal	January 1996
Observation of Studtite and Metastudtite on Spent Fuel McNamara, Bruce; Buck, Edgar; Hanson, Brady MRS Proceedings, Vol. 757 https://doi.org/10.1557/PROC-757-II9.7	journal	January 2002
New insight studies of the secondary phase formation under repository conditions Rodríguez-Villagra, N.; Bonales, L. J.; Cobos, J. MRS Advances, Vol. 5, Issue 11 https://doi.org/10.1557/adv.2020.120	journal	February 2020
Studtite, [(UO ₂ )(O ₂ )(H ₂ O) ₂ ](H ₂ O) ₂ : The first structure of a peroxide mineral Burns, Peter C.; Hughes, Karrie-Ann American Mineralogist, Vol. 88, Issue 7 https://doi.org/10.2138/am-2003-0725	journal	July 2003

Similar Records

Correction: Impacts of trace level chromium on formation of superoxide within uranyl triperoxide complexes

Journal Article · 2024 · ChemComm · OSTI ID:2479942

Scherrer, Sarah K.; Rajapaksha, Harindu; Kravchuk, Dmytro V.; +2 more

Enhanced direct air capture by uranyl superoxide: a comprehensive study of the carbonation reaction of uranyl peroxide complexes

Journal Article · 2025 · Journal of Materials Chemistry. A · OSTI ID:2565777

Scherrer, Sarah K.; Forbes, Tori Z.

Superoxide Radicals in Uranyl Peroxide Solids: Lasting Signatures Identified by Electron Paramagnetic Resonance Spectroscopy

Journal Article · 2024 · Angewandte Chemie (International Edition) · OSTI ID:2340223

Scherrer, Sarah K.; Gates, Cassandra; Rajapaksha, Harindu; +3 more

Title: Impacts of trace level chromium on formation of superoxide within uranyl triperoxide complexes

Citation Formats

References (24)

Similar Records

Related Subjects