Developing non-radioactive, radical methods to screen for radiolytic stability

Wackerle, Brandon G.; Vicente, Madison R.; Zohara, Fatema Tuz; Peterman, Dean R.; Wetzler, Modi; Brumaghim, Julia L.

doi:10.1039/D4CC03762F

Title: Developing non-radioactive, radical methods to screen for radiolytic stability

Journal Article · 24 October 2024 · ChemComm

DOI: https://doi.org/10.1039/D4CC03762F · OSTI ID:2447014

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Department of Chemistry, Clemson University, Clemson, SC 29634-0973, USA
Aqueous Separations and Radiochemistry Department, Idaho National Laboratory Idaho Falls, ID, 83415-6158, USA

A non-radioactive, radical method is reported as a screening tool for radiolytic degradation. Similar degradation products and trends are observed between this newly developed, higher-throughput assay and traditional gamma radiolysis.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0014664

OSTI ID:: 2447014

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 86 Vol. 60; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (16)

Di(2-ethyl hexyl) butyramide and di(2-ethyl hexyl)isobutyramide as extractants for uranium(VI) and plutonium(IV) Prabhu, D. R.; Mahajan, G. R.; Nair, G. M. Journal of Radioanalytical and Nuclear Chemistry, Vol. 224, Issue 1-2 https://doi.org/10.1007/BF02034622	journal	October 1997
Endocrine disorders after primary gamma knife radiosurgery for pituitary adenomas: A systematic review and meta-analysis Palmisciano, Paolo; Ogasawara, Christian; Ogasawara, Maya Pituitary, Vol. 25, Issue 3 https://doi.org/10.1007/s11102-022-01219-x	journal	March 2022
Gamma Radiation-Induced Synthesis of Polyaniline-Based Nanoparticles/Nanocomposites Ahmad, Sajid; Hammad, Raheel; Rubab, Seemin Journal of Electronic Materials, Vol. 51, Issue 10 https://doi.org/10.1007/s11664-022-09823-0	journal	July 2022
A Review of the Antioxidant Mechanisms of Polyphenol Compounds Related to Iron Binding Perron, Nathan R.; Brumaghim, Julia L. Cell Biochemistry and Biophysics, Vol. 53, Issue 2 https://doi.org/10.1007/s12013-009-9043-x	journal	January 2009
Review of the effects of irradiation treatments on poly(ethylene terephthalate) Jamalzadeh, Mansoureh; Sobkowicz, Margaret J. Polymer Degradation and Stability, Vol. 206 https://doi.org/10.1016/j.polymdegradstab.2022.110191	journal	December 2022
Irradiation of pharmaceuticals: A literature review Jacobs, Geoffrey P. Radiation Physics and Chemistry, Vol. 190 https://doi.org/10.1016/j.radphyschem.2021.109795	journal	January 2022
Advances in Perovskites for Photovoltaic Applications in Space Romano, Valentino; Agresti, Antonio; Verduci, Rosaria ACS Energy Letters, Vol. 7, Issue 8 https://doi.org/10.1021/acsenergylett.2c01099	journal	July 2022
Radiolytic stability of N , N -dialkyl amide: effect on Pu( iv ) complexes in solution Drader, J. A.; Boubals, N.; Camès, B. Dalton Transactions, Vol. 47, Issue 1 https://doi.org/10.1039/C7DT03447D	journal	January 2018
Effect of chemical environment on the radiation chemistry of N , N -di-(2-ethylhexyl)butyramide (DEHBA) and plutonium retention Horne, Gregory P.; Zarzana, Christopher A.; Grimes, Travis S. Dalton Transactions, Vol. 48, Issue 38 https://doi.org/10.1039/C9DT02383F	journal	January 2019
Review Article: The Effects of Radiation Chemistry on Solvent Extraction 3: A Review of Actinide and Lanthanide Extraction Mincher, Bruce J.; Modolo, Giuseppe; Mezyk, Stephen P. Solvent Extraction and Ion Exchange, Vol. 27, Issue 5-6 https://doi.org/10.1080/07366290903114098	journal	December 2009
Radiation chemistry of the branched-chain monoamide di-2-ethylhexyl-isobutyramide Drader, J.; Saint-Louis, G.; Muller, J. M. Solvent Extraction and Ion Exchange, Vol. 35, Issue 7 https://doi.org/10.1080/07366299.2017.1379713	journal	September 2017
Extraction of Non-Ferrous Metals and Iron with Systems based on Bis(2,4,4-Trimethylpentyl)Dithiophosphinic Acid (CYANEX 301), A Review Fleitlikh, I. Yu.; Grigorieva, N. A.; Logutenko, O. A. Solvent Extraction and Ion Exchange, Vol. 36, Issue 1 https://doi.org/10.1080/07366299.2017.1411034	journal	December 2017
A Study on the Radiolytic Stability of Commercial and Purified Cyanex 301 Chen, Jing; Jiao, Rongzhou; Zhu, Yongjun Solvent Extraction and Ion Exchange, Vol. 14, Issue 4 https://doi.org/10.1080/07366299608918356	journal	July 1996
Comparing Branched versus Straight-chained Monoamide Extractants for Actinide Recovery McCann, Kevin; Drader, Jessica A.; Braley, Jenifer C. Separation & Purification Reviews, Vol. 47, Issue 1 https://doi.org/10.1080/15422119.2017.1321018	journal	May 2017
Successful Migration from Radioactive Irradiators to X-ray Irradiators in One of the Largest Medical Centers in the US Kamen, Jacob; Hsu, Wen-Ya; Boswell, Brandon Health Physics, Vol. 117, Issue 5 https://doi.org/10.1097/HP.0000000000001095	journal	January 2019
Polymerization Reactions and Modifications of Polymers by Ionizing Radiation Ashfaq, Aiysha; Clochard, Marie-Claude; Coqueret, Xavier Polymers, Vol. 12, Issue 12 https://doi.org/10.3390/polym12122877	journal	November 2020

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