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Title: C–H amination chemistry mediated by trinuclear Cu( i ) sites supported by a ligand scaffold featuring an arene platform and tetramethylguanidinyl residues

Journal Article · · Dalton Transactions
DOI: https://doi.org/10.1039/D4DT01670J · OSTI ID:2440916
ORCiD logo [1];  [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [1]; ORCiD logo [1]
  1. Department of Chemistry, Missouri University of Science and Technology, Rolla, MO 65409, USA
  2. Department of Chemistry, University of North Texas, Denton, TX 76203, USA
+ Show Author Affiliations

A crown-shaped Cu 3 Cl 3 fragment captured by a ligand that features tetramethylguanidinyl residues and an apically oriented arene platform gives rise to a potent benzylic and tert -C–H bond amination catalyst via a computed dicopper nitrene oxidant.

Sponsoring Organization:
USDOE
Grant/Contract Number:
FG02-03ER15387
OSTI ID:
2440916
Journal Information:
Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 38 Vol. 53; ISSN 1477-9226; ISSN ICHBD9
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

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