Unraveling electrochemo-mechanical aspects of core–shell composite cathode for sulfide based all-solid-state batteries

Han, Su Cheol; Ali, Mukarram; Kim, Yoon Jun; Park, Jun-Ho; Lee, You-Jin; Park, Jun-Woo; Park, Heetaek; Park, Gumjae; Lee, Eungje; Kim, Byung Gon; Ha, Yoon-Cheol

doi:10.1039/D4TA04063E

Title: Unraveling electrochemo-mechanical aspects of core–shell composite cathode for sulfide based all-solid-state batteries

Journal Article · 24 September 2024 · Journal of Materials Chemistry. A

DOI: https://doi.org/10.1039/D4TA04063E · OSTI ID:2440453

Han, Su Cheol ^[1];

^[2]; Kim, Yoon Jun ^[3]; Park, Jun-Ho ^[2];

^[1];

^[2];

^[1]; Park, Gumjae ^[1];

^[4];

^[5];

^[2]

Battery Research Division, Korea Electrotechnology Research Institute (KERI), Changwon 51543, Republic of Korea
Battery Research Division, Korea Electrotechnology Research Institute (KERI), Changwon 51543, Republic of Korea, Department of Electric Energy Materials Engineering, University of Science and Technology (UST), Changwon 51543, Republic of Korea
Battery Research Division, Korea Electrotechnology Research Institute (KERI), Changwon 51543, Republic of Korea, School of Materials Science and Engineering, Pusan National University, Busan 46241, Republic of Korea
Chemical Sciences and Engineering Division, Argonne National Laboratory (ANL), Lemont, IL 60439, USA
Department of Applied Chemistry, College of Applied Sciences, Kyung Hee University, Yongin 17104, Republic of Korea

Multi-core–shell Li ₆ PS ₅ Cl@LiNbO ₃ @LiNi _0.8 Mn _0.1 Co _0.1 O ₂ composite cathode can achieve high capacity, high rate, and long cycle-life sulfide based all-solid-state lithium batteries (ASSLBs).

View Journal Article

Cite

Export

Save

Sponsoring Organization:: USDOE

OSTI ID:: 2440453

Journal Information:: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 37 Vol. 12; ISSN JMCAET; ISSN 2050-7488

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (42)

High‐Performance All‐Solid‐State Batteries Enabled by Intimate Interfacial Contact Between the Cathode and Sulfide‐Based Solid Electrolytes Kim, Jeongheon; Kim, Min Ji; Kim, Jaeik Advanced Functional Materials, Vol. 33, Issue 12 https://doi.org/10.1002/adfm.202211355	journal	January 2023
Sulfide Solid Electrolytes for Lithium Battery Applications Lau, Jonathan; DeBlock, Ryan H.; Butts, Danielle M. Advanced Energy Materials, Vol. 8, Issue 27 https://doi.org/10.1002/aenm.201800933	journal	August 2018
Commercialization of Lithium Battery Technologies for Electric Vehicles Zeng, Xiaoqiao; Li, Matthew; Abd El‐Hady, Deia Advanced Energy Materials, Vol. 9, Issue 27 https://doi.org/10.1002/aenm.201900161	journal	June 2019
On the Functionality of Coatings for Cathode Active Materials in Thiophosphate‐Based All‐Solid‐State Batteries Culver, Sean P.; Koerver, Raimund; Zeier, Wolfgang G. Advanced Energy Materials, Vol. 9, Issue 24 https://doi.org/10.1002/aenm.201900626	journal	May 2019
High Active Material Loading in All‐Solid‐State Battery Electrode via Particle Size Optimization Shi, Tan; Tu, Qingsong; Tian, Yaosen Advanced Energy Materials, Vol. 10, Issue 1 https://doi.org/10.1002/aenm.201902881	journal	November 2019
Toward High Rate Performance Solid‐State Batteries Lee, Dongsoo; Lee, Hyungjun; Song, Taeseup Advanced Energy Materials, Vol. 12, Issue 27 https://doi.org/10.1002/aenm.202200948	journal	June 2022
Designing Cathodes and Cathode Active Materials for Solid‐State Batteries Minnmann, Philip; Strauss, Florian; Bielefeld, Anja Advanced Energy Materials, Vol. 12, Issue 35 https://doi.org/10.1002/aenm.202201425	journal	July 2022
Electrochemo‐Mechanical Stresses and Their Measurements in Sulfide‐Based All‐Solid‐State Batteries: A Review Gu, Jiabao; Liang, Ziteng; Shi, Jingwen Advanced Energy Materials, Vol. 13, Issue 2 https://doi.org/10.1002/aenm.202203153	journal	November 2022
Current Trends in Nanoscale Interfacial Electrode Engineering for Sulfide‐Based All‐Solid‐State Li‐Ion Batteries Ali, Mukarram; Doh, Chil-Hoon; Lee, You-Jin Energy Technology, Vol. 9, Issue 5 https://doi.org/10.1002/ente.202001096	journal	March 2021
Progress in thermal stability of all‐solid‐state‐Li‐ion‐batteries Wu, Yujing; Wang, Shuo; Li, Hong InfoMat, Vol. 3, Issue 8 https://doi.org/10.1002/inf2.12224	journal	June 2021
Enhanced Electrochemical Stability and Extended Cycle Life in Sulfide‐Based All‐Solid‐State Batteries: The Role of Li₁₀SnP₂S₁₂ Coating on Ni‐Rich NCM Cathode Park, Yongsun; Chang, Joon Ha; Oh, Gwangseok Small, Vol. 20, Issue 11 https://doi.org/10.1002/smll.202305758	journal	November 2023
LiNbO3-coated LiCoO2 as cathode material for all solid-state lithium secondary batteries Ohta, Narumi; Takada, Kazunori; Sakaguchi, Isao Electrochemistry Communications, Vol. 9, Issue 7 https://doi.org/10.1016/j.elecom.2007.02.008	journal	July 2007
Insights about the irreversible capacity of LiNi0.5Mn1.5O4 cathode materials in lithium batteries Brutti, Sergio; Greco, Giorgia; Reale, Priscilla Electrochimica Acta, Vol. 106 https://doi.org/10.1016/j.electacta.2013.05.111	journal	September 2013
Synthesis, structure and electrochemical performance of the argyrodite Li 6 PS 5 Cl solid electrolyte for Li-ion solid state batteries Yu, Chuang; van Eijck, Lambert; Ganapathy, Swapna Electrochimica Acta, Vol. 215 https://doi.org/10.1016/j.electacta.2016.08.081	journal	October 2016
Excellent performance single-crystal NCM cathode under high mass loading for all-solid-state lithium batteries Li, Xuelei; Peng, Wenxiu; Tian, Rongzheng Electrochimica Acta, Vol. 363 https://doi.org/10.1016/j.electacta.2020.137185	journal	December 2020
Sulfide solid electrolytes for all-solid-state lithium batteries: Structure, conductivity, stability and application Chen, Shaojie; Xie, Dongjiu; Liu, Gaozhan Energy Storage Materials, Vol. 14 https://doi.org/10.1016/j.ensm.2018.02.020	journal	September 2018
All-solid-state lithium secondary batteries using LiCoO₂ particles with pulsed laser deposition coatings of Li₂S–P₂S₅ solid electrolytes Sakuda, Atsushi; Hayashi, Akitoshi; Ohtomo, Takamasa Journal of Power Sources, Vol. 196, Issue 16, p. 6735-6741 https://doi.org/10.1016/j.jpowsour.2010.10.103	journal	August 2011
Preparation of Li2S–P2S5 solid electrolyte from N-methylformamide solution and application for all-solid-state lithium battery Teragawa, Shingo; Aso, Keigo; Tadanaga, Kiyoharu Journal of Power Sources, Vol. 248 https://doi.org/10.1016/j.jpowsour.2013.09.117	journal	February 2014
A rocking chair type all-solid-state lithium ion battery adopting Li2O–ZrO2 coated LiNi0.8Co0.15Al0.05O2 and a sulfide based electrolyte Ito, Seitaro; Fujiki, Satoshi; Yamada, Takanobu Journal of Power Sources, Vol. 248 https://doi.org/10.1016/j.jpowsour.2013.10.005	journal	February 2014
Preparation of high lithium-ion conducting Li6PS5Cl solid electrolyte from ethanol solution for all-solid-state lithium batteries Yubuchi, So; Teragawa, Shingo; Aso, Keigo Journal of Power Sources, Vol. 293 https://doi.org/10.1016/j.jpowsour.2015.05.093	journal	October 2015
Electrochemical and structural evaluation for bulk-type all-solid-state batteries using Li4GeS4-Li3PS4 electrolyte coating on LiCoO2 particles Ito, Yusuke; Otoyama, Misae; Hayashi, Akitoshi Journal of Power Sources, Vol. 360 https://doi.org/10.1016/j.jpowsour.2017.05.112	journal	August 2017
Toward practical all-solid-state lithium-ion batteries with high energy density and safety: Comparative study for electrodes fabricated by dry- and slurry-mixing processes Nam, Young Jin; Oh, Dae Yang; Jung, Sung Hoo Journal of Power Sources, Vol. 375 https://doi.org/10.1016/j.jpowsour.2017.11.031	journal	January 2018
Progress in solid electrolytes toward realizing solid-state lithium batteries Takada, Kazunori Journal of Power Sources, Vol. 394 https://doi.org/10.1016/j.jpowsour.2018.05.003	journal	August 2018
Composite cathode prepared by argyrodite precursor solution assisted by dispersant agents for bulk-type all-solid-state batteries Rosero-Navarro, Nataly Carolina; Miura, Akira; Tadanaga, Kiyoharu Journal of Power Sources, Vol. 396 https://doi.org/10.1016/j.jpowsour.2018.06.011	journal	August 2018
The influence of void space on ion transport in a composite cathode for all-solid-state batteries Hlushkou, Dzmitry; Reising, Arved E.; Kaiser, Nico Journal of Power Sources, Vol. 396 https://doi.org/10.1016/j.jpowsour.2018.06.041	journal	August 2018
Dry coating of active material particles with sulfide solid electrolytes for an all-solid-state lithium battery Nakamura, Hideya; Kawaguchi, Takashi; Masuyama, Tomoyuki Journal of Power Sources, Vol. 448 https://doi.org/10.1016/j.jpowsour.2019.227579	journal	February 2020
Interfacial modification for high-power solid-state lithium batteries Takada, Kazunori; Ohta, Narumi; Zhang, Lianqi Solid State Ionics, Vol. 179, Issue 27-32 https://doi.org/10.1016/j.ssi.2008.02.017	journal	September 2008
Interface Stability in Solid-State Batteries Richards, William D.; Miara, Lincoln J.; Wang, Yan Chemistry of Materials, Vol. 28, Issue 1 https://doi.org/10.1021/acs.chemmater.5b04082	journal	December 2015
Between Scylla and Charybdis: Balancing Among Structural Stability and Energy Density of Layered NCM Cathode Materials for Advanced Lithium-Ion Batteries de Biasi, Lea; Kondrakov, Aleksandr O.; Geßwein, Holger The Journal of Physical Chemistry C, Vol. 121, Issue 47 https://doi.org/10.1021/acs.jpcc.7b06363	journal	November 2017
Infiltration of Solution-Processable Solid Electrolytes into Conventional Li-Ion-Battery Electrodes for All-Solid-State Li-Ion Batteries Kim, Dong Hyeon; Oh, Dae Yang; Park, Kern Ho Nano Letters, Vol. 17, Issue 5 https://doi.org/10.1021/acs.nanolett.7b00330	journal	April 2017
Quantitative Analysis of Microstructures and Reaction Interfaces on Composite Cathodes in All-Solid-State Batteries Using a Three-Dimensional Reconstruction Technique Choi, Sungjun; Jeon, Minjae; Ahn, Junsung ACS Applied Materials & Interfaces, Vol. 10, Issue 28 https://doi.org/10.1021/acsami.8b04204	journal	June 2018
High-Conductivity Argyrodite Li ₆ PS ₅ Cl Solid Electrolytes Prepared via Optimized Sintering Processes for All-Solid-State Lithium–Sulfur Batteries Wang, Shuo; Zhang, Yibo; Zhang, Xue ACS Applied Materials & Interfaces, Vol. 10, Issue 49 https://doi.org/10.1021/acsami.8b15121	journal	November 2018
Challenges and Opportunities for Fast Charging of Solid-State Lithium Metal Batteries Vishnugopi, Bairav S.; Kazyak, Eric; Lewis, John A. ACS Energy Letters, Vol. 6, Issue 10 https://doi.org/10.1021/acsenergylett.1c01352	journal	September 2021
Stack Pressure Measurements to Probe the Evolution of the Lithium–Solid-State Electrolyte Interface Lee, Chanhee; Han, Sang Yun; Lewis, John A. ACS Energy Letters, Vol. 6, Issue 9 https://doi.org/10.1021/acsenergylett.1c01395	journal	August 2021
Space–Charge Layer Effect at Interface between Oxide Cathode and Sulfide Electrolyte in All-Solid-State Lithium-Ion Battery Haruyama, Jun; Sodeyama, Keitaro; Han, Liyuan Chemistry of Materials, Vol. 26, Issue 14 https://doi.org/10.1021/cm5016959	journal	July 2014
High-energy long-cycling all-solid-state lithium metal batteries enabled by silver–carbon composite anodes Lee, Yong-Gun; Fujiki, Satoshi; Jung, Changhoon Nature Energy, Vol. 5, Issue 4 https://doi.org/10.1038/s41560-020-0575-z	journal	March 2020
New horizons for inorganic solid state ion conductors Zhang, Zhizhen; Shao, Yuanjun; Lotsch, Bettina Energy & Environmental Science, Vol. 11, Issue 8 https://doi.org/10.1039/C8EE01053F	journal	January 2018
Characterization of mechanical degradation in an all-solid-state battery cathode Shi, Tan; Zhang, Ya-Qian; Tu, Qingsong Journal of Materials Chemistry A, Vol. 8, Issue 34 https://doi.org/10.1039/D0TA06985J	journal	January 2020
Utilization Ratio of Active Materials in All-Solid-State Batteries Examined Using Electrochemical Impedance Analysis with the Transmission Line Model Togasaki, Norihiro; Nakao, Aiko; Tanaka, Takumi Journal of The Electrochemical Society, Vol. 170, Issue 5 https://doi.org/10.1149/1945-7111/acd35b	journal	May 2023
Spherically Smooth Cathode Particles by Mechanofusion Processing Zheng, Lituo; Wei, Congxiao; Garayt, M. D. L. Journal of The Electrochemical Society, Vol. 166, Issue 13 https://doi.org/10.1149/2.0681913jes	journal	January 2019
Nanoscale Interface Modification of LiCoO ₂ by Al ₂ O ₃ Atomic Layer Deposition for Solid-State Li Batteries Woo, Jae Ha; Trevey, James E.; Cavanagh, Andrew S. Journal of The Electrochemical Society, Vol. 159, Issue 7 https://doi.org/10.1149/2.085207jes	journal	January 2012
Modeling and Applications of Electrochemical Impedance Spectroscopy (EIS) for Lithium-ion Batteries Choi, Woosung; Shin, Heon-Cheol; Kim, Ji Man Journal of Electrochemical Science and Technology, Vol. 11, Issue 1 https://doi.org/10.33961/jecst.2019.00528	journal	February 2020

Similar Records

Effects of catholyte aging on high-nickel NMC cathodes in sulfide all-solid-state batteries

Journal Article · 2024 · Materials Horizons · OSTI ID:2569911

Li, Yuanshun; Cho, Yukio; Cai, Jiyu; +9 more

Highly reversible Li₂RuO₃ cathodes in sulfide-based all solid-state lithium batteries

Journal Article · 2022 · Energy & Environmental Science · OSTI ID:1963045

Wu, Yuqi; Zhou, Ke; Ren, Fucheng; +12 more

F and N Rich Solid Electrolyte for Stable All-Solid-State Battery

Journal Article · 2021 · Advanced Functional Materials · OSTI ID:1976185

Wan, Hongli L.; Zhang, Jiaxun X.; Xia, Jiale L.; +4 more

Title: Unraveling electrochemo-mechanical aspects of core–shell composite cathode for sulfide based all-solid-state batteries

Citation Formats

References (42)

Similar Records

Related Subjects