Thermoelectric Zintl phases with ultralow thermal conductivity: synthesis, structural characterization, and transport properties of Ca 10 AlSb 9 and Ca 10 CdSb 9

Ghosh, Kowsik; Borgsmiller, Leah; Baranets, Sviatoslav; Snyder, G. Jeffrey; Bobev, Svilen

doi:10.1039/D4TA05000B

Title: Thermoelectric Zintl phases with ultralow thermal conductivity: synthesis, structural characterization, and transport properties of Ca ₁₀ AlSb ₉ and Ca ₁₀ CdSb ₉

Journal Article · 23 September 2024 · Journal of Materials Chemistry. A

DOI: https://doi.org/10.1039/D4TA05000B · OSTI ID:2439299

^[1];

^[2];

^[3];

^[2];

^[1]

Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, USA
Department of Materials Science and Engineering, Northwestern University, Evanston, IL 60208, USA
Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, USA, Department of Chemistry, Louisiana State University, Baton Rouge, Louisiana 70803, USA

Polyhedral coordination in disordered Ca10MSb9 (M = Al and Cd). The new Zintl phases are intrinsic semiconductors showing ultralow thermal conductivity and candidates for the optimization of their thermoelectric performance.

View Journal Article

Cite

Export

Save

Research Organization:: Univ. of Delaware, Newark, DE (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC)

Grant/Contract Number:: SC0008885

OSTI ID:: 2439299

Journal Information:: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 37 Vol. 12; ISSN JMCAET; ISSN 2050-7488

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (81)

Zintl Phases as Thermoelectric Materials: Tuned Transport Properties of the Compounds CaxYb1-xZn2Sb2 Gascoin, F.; Ottensmann, S.; Stark, D. Advanced Functional Materials, Vol. 15, Issue 11 https://doi.org/10.1002/adfm.200500043	journal	November 2005
Traversing the Metal-Insulator Transition in a Zintl Phase: Rational Enhancement of Thermoelectric Efficiency in Yb ₁₄ Mn _{1− x} Al _x Sb ₁₁ Toberer, Eric S.; Cox, Catherine A.; Brown, Shawna R. Advanced Functional Materials, Vol. 18, Issue 18 https://doi.org/10.1002/adfm.200800298	journal	September 2008
The Zintl Compound Ca5Al2Sb6 for Low-Cost Thermoelectric Power Generation Toberer, Eric S.; Zevalkink, Alexandra; Crisosto, Nicole Advanced Functional Materials, Vol. 20, Issue 24 https://doi.org/10.1002/adfm.201000970	journal	September 2010
Achieving zT > 1 in Inexpensive Zintl Phase Ca ₉ Zn ₄₊ _x Sb ₉ by Phase Boundary Mapping Ohno, Saneyuki; Aydemir, Umut; Amsler, Maximilian Advanced Functional Materials, Vol. 27, Issue 20 https://doi.org/10.1002/adfm.201606361	journal	March 2017
Weighted Mobility Snyder, G. Jeffrey; Snyder, Alemayouh H.; Wood, Maxwell Advanced Materials, Vol. 32, Issue 25 https://doi.org/10.1002/adma.202001537	journal	May 2020
New Zintl Phase Yb₁₀MgSb₉ with High Thermoelectric Performance Borgsmiller, Leah; Li, Qingyuan; Toriyama, Michael Y. Advanced Energy Materials, Vol. 13, Issue 19 https://doi.org/10.1002/aenm.202300393	journal	April 2023
Defect-Controlled Electronic Properties in A Zn ₂ Sb ₂ Zintl Phases Pomrehn, Gregory S.; Zevalkink, Alex; Zeier, Wolfgang G. Angewandte Chemie International Edition, Vol. 53, Issue 13 https://doi.org/10.1002/anie.201311125	journal	February 2014
Enhanced Thermoelectric Figure of Merit of Zintl Phase YbCd2-xMnxSb2 by Chemical Substitution Guo, Kai; Cao, Qi-Gao; Feng, Xian-Juan European Journal of Inorganic Chemistry, Vol. 2011, Issue 26 https://doi.org/10.1002/ejic.201100282	journal	August 2011
The Zintl-Klemm Concept - A Historical Survey: The Zintl-Klemm Concept - A Historical Survey Nesper, Reinhard Zeitschrift für anorganische und allgemeine Chemie, Vol. 640, Issue 14 https://doi.org/10.1002/zaac.201400403	journal	November 2014
Increasing the Efficiency of the Multi-mission Radioisotope Thermoelectric Generator Holgate, Tim C.; Bennett, Russell; Hammel, Tom Journal of Electronic Materials, Vol. 44, Issue 6 https://doi.org/10.1007/s11664-014-3564-9	journal	December 2014
Synthesis, structure and properties of the new rare-earth Zintl phase Yb11GaSb9 Bobev, Svilen; Fritsch, Veronika; Thompson, Joe D. Journal of Solid State Chemistry, Vol. 178, Issue 4 https://doi.org/10.1016/j.jssc.2005.01.008	journal	April 2005
Thermoelectric properties and microstructure of Mg3Sb2 Condron, Cathie L.; Kauzlarich, Susan M.; Gascoin, Franck Journal of Solid State Chemistry, Vol. 179, Issue 8 https://doi.org/10.1016/j.jssc.2006.01.034	journal	August 2006
Synthesis, crystal structures, magnetic and electric transport properties of Eu11InSb9 and Yb11InSb9 Xia, Sheng-qing; Hullmann, Jonathan; Bobev, Svilen Journal of Solid State Chemistry, Vol. 180, Issue 7 https://doi.org/10.1016/j.jssc.2007.05.010	journal	July 2007
Zintl phases with group 15 elements and the transition metals: A brief overview of pnictides with diverse and complex structures Ovchinnikov, Alexander; Bobev, Svilen Journal of Solid State Chemistry, Vol. 270 https://doi.org/10.1016/j.jssc.2018.11.029	journal	February 2019
Five new ternary indium-arsenides discovered. Synthesis and structural characterization of the Zintl phases Sr3In2As4, Ba3In2As4, Eu3In2As4, Sr5In2As6 and Eu5In2As6 Childs, Amanda B.; Baranets, Sviatoslav; Bobev, Svilen Journal of Solid State Chemistry, Vol. 278 https://doi.org/10.1016/j.jssc.2019.07.050	journal	October 2019
Synthesis and structural characterization of the new Zintl phases Ba3Cd2P4 and Ba2Cd2P3. Rare example of small gap semiconducting behavior with negative thermopower within the range 300 K–700 K Balvanz, Adam; Baranets, Sviatoslav; Bobev, Svilen Journal of Solid State Chemistry, Vol. 289 https://doi.org/10.1016/j.jssc.2020.121476	journal	September 2020
Clathrate thermoelectrics Dolyniuk, Juli-Anna; Owens-Baird, Bryan; Wang, Jian Materials Science and Engineering: R: Reports, Vol. 108 https://doi.org/10.1016/j.mser.2016.08.001	journal	October 2016
Enhanced thermoelectric performance in the zintl antimonides (Ca,RE)9Cd4Sb9 (RE = rare-earth metal). Synergy between increased structural complexity and drive towards optimized chemical bonding Ogunbunmi, M. O.; Baranets, S.; Bobev, S. Materials Today Advances, Vol. 16 https://doi.org/10.1016/j.mtadv.2022.100310	journal	December 2022
Ultralow Thermal Conductivity and High Thermopower in a New Family of Zintl Antimonides Ca ₁₀ M Sb ₉ ( M = Ga, In, Mn, Zn) with Complex Structures and Heavy Disorder Ovchinnikov, Alexander; Chanakian, Sevan; Zevalkink, Alexandra Chemistry of Materials, Vol. 33, Issue 9 https://doi.org/10.1021/acs.chemmater.0c04940	journal	April 2021
Observation of Anomalously High Seebeck Coefficients in the Family of Zintl Phase Semiconductors Ca₁₀RECdSb₉ (RE = Rare-Earth Metal) Ogunbunmi, Michael O.; Bobev, Svilen Chemistry of Materials, Vol. 34, Issue 19 https://doi.org/10.1021/acs.chemmater.2c02103	journal	September 2022
Anion Redox Balances Valence against Compositional Fluctuations in the 10-1-9 Zintl Family Borgsmiller, Leah; Toriyama, Michael Y.; Kurtz, Heather E. Chemistry of Materials, Vol. 35, Issue 23, p. 10150-10155 https://doi.org/10.1021/acs.chemmater.3c02228	journal	November 2023
Yb₁₁Sb₁₀ and Yb₁₀MnSb₉─Small Change in Structure Leads to Profound Differences in Thermoelectric Properties Investigated Using Zintl Concepts Borgsmiller, Leah; Toriyama, Michael Y.; Snyder, G. Jeffrey Chemistry of Materials, Vol. 36, Issue 11, p. 5542-5551 https://doi.org/10.1021/acs.chemmater.4c00486	journal	May 2024
Rare-Earth Metal Substitutions in Ca _{9– x} RE _x Mn ₄ Sb ₉ ( RE = La–Nd, Sm; x ≈ 1). Synthesis and Characterization of a New Series of Narrow-Gap Semiconductors Wang, Yi; Bobev, Svilen Chemistry of Materials, Vol. 30, Issue 10 https://doi.org/10.1021/acs.chemmater.8b01316	journal	April 2018
Complex Structural Disorder in the Zintl Phases Yb ₁₀ MnSb ₉ and Yb ₂₁ Mn ₄ Sb ₁₈ Baranets, Sviatoslav; Ovchinnikov, Alexander; Bobev, Svilen Inorganic Chemistry, Vol. 60, Issue 9 https://doi.org/10.1021/acs.inorgchem.1c00519	journal	April 2021
Tuning the Intermediate Valence Behavior in the Zintl Compound Yb₁₄ZnSb₁₁ by Incorporation of RE³⁺ [Yb_14–xRE_xZnSb₁₁ (0.2 ≤ x ≤ 0.7), RE = Sc, Y, La, Lu and Gd] Shang, Rongqing; He, Allan; Kunz Wille, Elizabeth L. Inorganic Chemistry, Vol. 62, Issue 6 https://doi.org/10.1021/acs.inorgchem.2c03817	journal	January 2023
Yb ₁₄ MnSb ₁₁ : New High Efficiency Thermoelectric Material for Power Generation Brown, Shawna R.; Kauzlarich, Susan M.; Gascoin, Franck Chemistry of Materials, Vol. 18, Issue 7 https://doi.org/10.1021/cm060261t	journal	April 2006
Crystal Structure, Band Structure, and Physical Properties of Ba ₈ Cu ₆ _- _x Ge ₄₀₊ _x (0 ≤ x ≤ 0.7) Johnsen, Simon; Bentien, Anders; Madsen, Georg K. H. Chemistry of Materials, Vol. 18, Issue 19 https://doi.org/10.1021/cm061195y	journal	September 2006
Influence of the Triel Elements ( M = Al, Ga, In) on the Transport Properties of Ca ₅ M ₂ Sb ₆ Zintl Compounds Zevalkink, Alex; Pomrehn, Gregory S.; Johnson, Samantha Chemistry of Materials, Vol. 24, Issue 11 https://doi.org/10.1021/cm300520w	journal	May 2012
Nonstoichiometry in the Zintl Phase Yb _1−δ Zn ₂ Sb ₂ as a Route to Thermoelectric Optimization Zevalkink, Alex; Zeier, Wolfgang G.; Cheng, Ethan Chemistry of Materials, Vol. 26, Issue 19 https://doi.org/10.1021/cm502588r	journal	September 2014
Yb ₁₄ MgSb ₁₁ and Ca ₁₄ MgSb ₁₁ —New Mg-Containing Zintl Compounds and Their Structures, Bonding, and Thermoelectric Properties Hu, Yufei; Wang, Jian; Kawamura, Airi Chemistry of Materials, Vol. 27, Issue 1 https://doi.org/10.1021/cm504059t	journal	December 2014
Improved Thermoelectric Performance in Yb ₁₄ Mn _{1− x} Zn _x Sb ₁₁ by the Reduction of Spin-Disorder Scattering Brown, Shawna R.; Toberer, Eric S.; Ikeda, Teruyuki Chemistry of Materials, Vol. 20, Issue 10 https://doi.org/10.1021/cm703616q	journal	May 2008
New bulk Materials for Thermoelectric Power Generation: Clathrates and Complex Antimonides ^† Kleinke, Holger Chemistry of Materials, Vol. 22, Issue 3 https://doi.org/10.1021/cm901591d	journal	February 2010
High-Temperature Transport Properties of the Zintl Phases Yb ₁₁ GaSb ₉ and Yb ₁₁ InSb ₉ ^† Yi, Tanghong; Cox, Catherine A.; Toberer, Eric S. Chemistry of Materials, Vol. 22, Issue 3 https://doi.org/10.1021/cm901824c	journal	February 2010
Zintl Chemistry for Designing High Efficiency Thermoelectric Materials ^† ^‡ Toberer, Eric S.; May, Andrew F.; Snyder, G. Jeffrey Chemistry of Materials, Vol. 22, Issue 3 https://doi.org/10.1021/cm901956r	journal	February 2010
New Tetragonal Structure Type for A ₂ Ca ₁₀ Sb ₉ (A = Li, Mg). Electronic Variability around a Zintl Phase Ganguli, Ashok K.; Gupta, Shalabh; Corbett, John D. Inorganic Chemistry, Vol. 45, Issue 1 https://doi.org/10.1021/ic051536u	journal	January 2006
Synthesis, Structure, and Properties of Ca₁₆Sb₁₁, a Complex Zintl Phase. Twelve Other Isotypic Compounds Formed by Divalent Metals and Pnictogens Leon-Escamilla, E. Alejandro; Hurng, Weir-Mirn; Peterson, Eric S. Inorganic Chemistry, Vol. 36, Issue 4 https://doi.org/10.1021/ic961035w	journal	February 1997
Caught in Action. The Late Rare Earths Thulium and Lutetium Substituting Aluminum Atoms in the Structure of Ca ₁₄ AlBi ₁₁ Baranets, Sviatoslav; Bobev, Svilen Journal of the American Chemical Society, Vol. 143, Issue 1 https://doi.org/10.1021/jacs.0c11026	journal	December 2020
III–V Clathrate Semiconductors with Outstanding Hole Mobility: Cs ₈ In ₂₇ Sb ₁₉ and A ₈ Ga ₂₇ Sb ₁₉ ( A = Cs, Rb) Owens-Baird, Bryan; Wang, Jian; Wang, Suyin Grass Journal of the American Chemical Society, Vol. 142, Issue 4 https://doi.org/10.1021/jacs.9b12351	journal	December 2019
Complex thermoelectric materials Snyder, G. Jeffrey; Toberer, Eric S. Nature Materials, Vol. 7, Issue 2, p. 105-114 https://doi.org/10.1038/nmat2090	journal	February 2008
In situ click chemistry generation of cyclooxygenase-2 inhibitors Bhardwaj, Atul; Kaur, Jatinder; Wuest, Melinda Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-016-0009-6	journal	February 2017
Thermoelectric properties of Eu(Zn1−xCdx)2Sb2 Zhang, Hui; Baitinger, Michael; Tang, Mei-Bo Dalton Trans., Vol. 39, Issue 4 https://doi.org/10.1039/B916346H	journal	January 2010
Ca ₃ AlSb ₃ : an inexpensive, non-toxic thermoelectric material for waste heat recovery Zevalkink, Alex; Toberer, Eric S.; Zeier, Wolfgang G. Energy Environ. Sci., Vol. 4, Issue 2 https://doi.org/10.1039/C0EE00517G	journal	January 2011
Glass-like lattice thermal conductivity and high thermoelectric efficiency in Yb ₉ Mn _4.2 Sb ₉ Bux, Sabah K.; Zevalkink, Alexandra; Janka, Oliver J. Mater. Chem. A, Vol. 2, Issue 1 https://doi.org/10.1039/C3TA14021K	journal	January 2014
Thermoelectric properties of the Zintl phases Yb ₅ M ₂ Sb ₆ (M = Al, Ga, In) Aydemir, Umut; Zevalkink, Alex; Ormeci, Alim Dalton Transactions, Vol. 44, Issue 15 https://doi.org/10.1039/C4DT03773A	journal	January 2015
Thermoelectric properties of the Yb ₉ Mn _4.2−x Zn _x Sb ₉ solid solutions Ohno, Saneyuki; Zevalkink, Alexandra; Takagiwa, Yoshiki J. Mater. Chem. A, Vol. 2, Issue 20 https://doi.org/10.1039/C4TA00539B	journal	January 2014
Skutterudites as thermoelectric materials: revisited Rull-Bravo, M.; Moure, A.; Fernández, J. F. RSC Advances, Vol. 5, Issue 52 https://doi.org/10.1039/C5RA03942H	journal	January 2015
Enhanced thermoelectric properties of Sr ₅ In ₂ Sb ₆ via Zn-doping Chanakian, Sevan; Zevalkink, Alex; Aydemir, Umut Journal of Materials Chemistry A, Vol. 3, Issue 19 https://doi.org/10.1039/C5TA01967B	journal	January 2015
Grain boundary dominated charge transport in Mg ₃ Sb ₂ -based compounds Kuo, Jimmy Jiahong; Kang, Stephen Dongmin; Imasato, Kazuki Energy & Environmental Science, Vol. 11, Issue 2 https://doi.org/10.1039/C7EE03326E	journal	January 2018
Band engineering in Mg ₃ Sb ₂ by alloying with Mg ₃ Bi ₂ for enhanced thermoelectric performance Imasato, Kazuki; Kang, Stephen Dongmin; Ohno, Saneyuki Materials Horizons, Vol. 5, Issue 1 https://doi.org/10.1039/C7MH00865A	journal	January 2018
Crystal chemistry and thermoelectric transport of layered AM ₂ X ₂ compounds Peng, Wanyue; Chanakian, Sevan; Zevalkink, Alexandra Inorganic Chemistry Frontiers, Vol. 5, Issue 8 https://doi.org/10.1039/C7QI00813A	journal	January 2018
Thermoelectric properties and low thermal conductivity of Zintl compound Yb₁₀MnSb₉ Borgsmiller, Leah; Snyder, G. Jeffrey Journal of Materials Chemistry A, Vol. 10, Issue 28 https://doi.org/10.1039/D2TA03114K	journal	January 2022
Exploiting the fraternal twin nature of thermoelectrics and topological insulators in Zintl phases as a tool for engineering new efficient thermoelectric generators Ogunbunmi, Michael O.; Bobev, Svilen Journal of Materials Chemistry C, Vol. 11, Issue 25 https://doi.org/10.1039/D3TC00556A	journal	January 2023
Zintl phases for thermoelectric devices Kauzlarich, Susan M.; Brown, Shawna R.; Jeffrey Snyder, G. Dalton Transactions, Issue 21 https://doi.org/10.1039/b702266b	journal	January 2007
Crystal structure and chemical bonding of the intermetallic Zintl phase Yb11AlSb9 Kastbjerg, Sofie; Uvarov, Catherine A.; Kauzlarich, Susan M. Dalton Transactions, Vol. 41, Issue 34 https://doi.org/10.1039/c2dt30278k	journal	January 2012
Low effective mass leading to high thermoelectric performance Pei, Yanzhong; LaLonde, Aaron D.; Wang, Heng Energy & Environmental Science, Vol. 5, Issue 7 https://doi.org/10.1039/c2ee21536e	journal	January 2012
Thermoelectric properties of Sr3GaSb3 – a chain-forming Zintl compound Zevalkink, Alex; Zeier, Wolfgang G.; Pomrehn, Gregory Energy & Environmental Science, Vol. 5, Issue 10 https://doi.org/10.1039/c2ee22378c	journal	January 2012
Thermoelectric properties of Zn-doped Ca3AlSb3 Zeier, Wolfgang G.; Zevalkink, Alex; Schechtel, Eugen Journal of Materials Chemistry, Vol. 22, Issue 19 https://doi.org/10.1039/c2jm31324c	journal	January 2012
High thermoelectric efficiency in lanthanum doped Yb14MnSb11 Toberer, Eric S.; Brown, Shawna R.; Ikeda, Teruyuki Applied Physics Letters, Vol. 93, Issue 6 https://doi.org/10.1063/1.2970089	journal	August 2008
A new type of thermoelectric material, EuZn2Sb2 Zhang, Hui; Zhao, Jing-Tai; Grin, Yu. The Journal of Chemical Physics, Vol. 129, Issue 16 https://doi.org/10.1063/1.3001608	journal	October 2008
Synthesis and high thermoelectric efficiency of Zintl phase YbCd2−xZnxSb2 Wang, Xiao-Jun; Tang, Mei-Bo; Chen, Hao-Hong Applied Physics Letters, Vol. 94, Issue 9 https://doi.org/10.1063/1.3040321	journal	March 2009
Thermoelectric properties of YbxEu1−xCd2Sb2 Zhang, H.; Fang, L.; Tang, M. -B. The Journal of Chemical Physics, Vol. 133, Issue 19 https://doi.org/10.1063/1.3501370	journal	November 2010
Rapid consolidation of powdered materials by induction hot pressing LaLonde, Aaron D.; Ikeda, Teruyuki; Snyder, G. Jeffrey Review of Scientific Instruments, Vol. 82, Issue 2 https://doi.org/10.1063/1.3534080	journal	February 2011
A high temperature apparatus for measurement of the Seebeck coefficient Iwanaga, Shiho; Toberer, Eric S.; LaLonde, Aaron Review of Scientific Instruments, Vol. 82, Issue 6 https://doi.org/10.1063/1.3601358	journal	June 2011
Improved carrier concentration control in Zn-doped Ca ₅ Al ₂ Sb ₆ Zevalkink, Alex; Toberer, Eric S.; Bleith, Tim Journal of Applied Physics, Vol. 110, Issue 1 https://doi.org/10.1063/1.3607976	journal	July 2011
Measurement of the electrical resistivity and Hall coefficient at high temperatures Borup, Kasper A.; Toberer, Eric S.; Zoltan, Leslie D. Review of Scientific Instruments, Vol. 83, Issue 12 https://doi.org/10.1063/1.4770124	journal	December 2012
Why clathrates are good thermoelectrics: A theoretical study of Sr8Ga16Ge30 Blake, Nick P.; Mo/llnitz, Lone; Kresse, Georg The Journal of Chemical Physics, Vol. 111, Issue 7 https://doi.org/10.1063/1.479615	journal	August 1999
Characterization of Lorenz number with Seebeck coefficient measurement Kim, Hyun-Sik; Gibbs, Zachary M.; Tang, Yinglu APL Materials, Vol. 3, Issue 4 https://doi.org/10.1063/1.4908244	journal	April 2015
A practical field guide to thermoelectrics: Fundamentals, synthesis, and characterization Zevalkink, Alex; Smiadak, David M.; Blackburn, Jeff L. Applied Physics Reviews, Vol. 5, Issue 2 https://doi.org/10.1063/1.5021094	journal	June 2018
A local exchange-correlation potential for the spin polarized case. i Barth, U. von; Hedin, L. Journal of Physics C: Solid State Physics, Vol. 5, Issue 13 https://doi.org/10.1088/0022-3719/5/13/012	journal	July 1972
Linear methods in band theory Andersen, O. Krogh Physical Review B, Vol. 12, Issue 8 https://doi.org/10.1103/PhysRevB.12.3060	journal	October 1975
Explicit, First-Principles Tight-Binding Theory Andersen, O. K.; Jepsen, O. Physical Review Letters, Vol. 53, Issue 27 https://doi.org/10.1103/PhysRevLett.53.2571	journal	December 1984
Phonon-glass electron-crystal thermoelectric clathrates: Experiments and theory Takabatake, Toshiro; Suekuni, Koichiro; Nakayama, Tsuneyoshi Reviews of Modern Physics, Vol. 86, Issue 2 https://doi.org/10.1103/RevModPhys.86.669	journal	June 2014
EXPGUI , a graphical user interface for GSAS Toby, Brian H. Journal of Applied Crystallography, Vol. 34, Issue 2 https://doi.org/10.1107/S0021889801002242	journal	April 2001
Crystal structure refinement with SHELXL Sheldrick, George M. Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1, p. 3-8 https://doi.org/10.1107/S2053229614024218	journal	January 2015
SHELXT – Integrated space-group and crystal-structure determination Sheldrick, George M. Acta Crystallographica Section A Foundations and Advances, Vol. 71, Issue 1, p. 3-8 https://doi.org/10.1107/S2053273314026370	journal	January 2015
Discovery of multivalley Fermi surface responsible for the high thermoelectric performance in Yb ₁₄ MnSb ₁₁ and Yb ₁₄ MgSb ₁₁ Perez, Christopher J.; Wood, Maxwell; Ricci, Francesco Science Advances, Vol. 7, Issue 4 https://doi.org/10.1126/sciadv.abe9439	journal	January 2021
Zur Kenntnis von Ca11Sb10 und Ca11Bi10 Deller, Klaus; Eisenmann, Brigitte Zeitschrift für Naturforschung B, Vol. 31, Issue 1 https://doi.org/10.1515/znb-1976-0105	journal	January 1976
Zur Kenntnis von Ca₄Sb₂O / Preparation and Crystal Structure of Ca₄Sb₂O Limartha, Hadi; Eisenmann, Brigitte; Schäfer, Herbert Zeitschrift für Naturforschung B, Vol. 35, Issue 12 https://doi.org/10.1515/znb-1980-1206	journal	December 1980
The Crystal Orbital Hamilton Population (COHP) Method as a Tool to Visualize and Analyze Chemical Bonding in Intermetallic Compounds Steinberg, Simon; Dronskowski, Richard Crystals, Vol. 8, Issue 5 https://doi.org/10.3390/cryst8050225	journal	May 2018
Exploratory Work in the Quaternary System of Ca–Eu–Cd–Sb: Synthesis, Crystal, and Electronic Structures of New Zintl Solid Solutions Ovchinnikov, Alexander; Darone, Gregory; Saparov, Bayrammurad Materials, Vol. 11, Issue 11 https://doi.org/10.3390/ma11112146	journal	October 2018
Synthesis and Crystal and Electronic Structures of the Zintl Phase Sr₂₁Cd₄Sb₁₈ Ghosh, Kowsik; Bobev, Svilen Solids, Vol. 4, Issue 4, p. 344-355 https://doi.org/10.3390/solids4040022	journal	November 2023

Similar Records

Intrinsic nanostructure induced ultralow thermal conductivity yields enhanced thermoelectric performance in Zintl phase Eu2ZnSb2

Journal Article · 2021 · Nature Communications · OSTI ID:1822971

Chen, Chen; Feng, Zhenzhen; Yao, Honghao; +6 more

New Zintl Phase Yb ₁₀ MgSb ₉ with High Thermoelectric Performance

Journal Article · 2023 · Advanced Energy Materials · OSTI ID:1968936

Borgsmiller, Leah; Li, Qingyuan; Toriyama, Michael Y.; +1 more

Single crystal growth and characterization of new Zintl phase Ca₉Zn_3.1In_0.9Sb₉

Journal Article · 2021 · Journal of Solid State Chemistry · OSTI ID:1851162

Smiadak, David M.; Baranets, Sviatoslav; Rylko, Megan; +4 more

Related Subjects

Chemistry
Energy & Fuels
Materials Science

Title: Thermoelectric Zintl phases with ultralow thermal conductivity: synthesis, structural characterization, and transport properties of Ca 10 AlSb 9 and Ca 10 CdSb 9

Citation Formats

References (81)

Similar Records

Related Subjects

Title: Thermoelectric Zintl phases with ultralow thermal conductivity: synthesis, structural characterization, and transport properties of Ca ₁₀ AlSb ₉ and Ca ₁₀ CdSb ₉