Isolation of a chloride-capped cerium polyoxo nanocluster built from 52 metal ions

Blanes-Díaz, Anamar; Wacker, Jennifer N.; Szymanowski, Jennifer E. S.; Bertke, Jeffery A.; Knope, Karah E.

doi:10.1039/D4CC03144J

Title: Isolation of a chloride-capped cerium polyoxo nanocluster built from 52 metal ions

Journal Article · 31 December 2023 · ChemComm

DOI: https://doi.org/10.1039/D4CC03144J · OSTI ID:2438404

Blanes-Díaz, Anamar ^[1];

^[1]; Szymanowski, Jennifer E. S. ^[2];

^[1];

^[1]

Department of Chemistry, Georgetown University, Washington, D.C. 20057, USA
Department of Civil & Environmental Engineering & Earth Sciences, University of Notre Dame, Notre Dame, IN 46556, USA

A chloride/water terminated Ce–oxo cluster built from 52 metal ions, with the longest Ce–Ce distance measuring roughly 1.6 nm, was isolated from acidic aqueous solution using pyridinium counterions.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: NONE; SC0019190

OSTI ID:: 2438404

Journal Information:: ChemComm, Journal Name: ChemComm; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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