Layer-by-layer assembly of a [Fe-(pyrazine){Pd(CN) 4 }] spin crossover thin film

McElveen, Kayleigh A.; Hao, Guanhua; Evans, Prescott E.; Ekanayaka, Thilini K.; N’Diaye, Alpha T.; Chin, Wai Kiat; Lai, Rebecca Y.

doi:10.1088/1361-648X/ad7087

Title: Layer-by-layer assembly of a [Fe-(pyrazine){Pd(CN) ₄ }] spin crossover thin film

Journal Article · 28 August 2024 · Journal of Physics. Condensed Matter

DOI: https://doi.org/10.1088/1361-648X/ad7087 · OSTI ID:2438349

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; Evans, Prescott E.;

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Abstract [Fe-(pyrazine){Pd(CN) ₄ }] (pyrazine = pz) thin films were fabricated using a layer-by-layer assembly approach, a method known to be tunable, versatile, and scalable, since thin films are better-suited for industrial applications. In this study, [Fe-(pz){Pd(CN) ₄ }] powder was synthesized, and the results obtained from a vibrating sample magnetometer verified the presence of an abrupt hysteresis loop with widths of 45 K centered around 300 K, indicating good cooperativity. Super conducting quantum interference device magnetometry results indicated a slow spin transition with temperature but with evidence of hysteresis for thin film samples. X-ray absorption analysis provided further support of the spin crossover behavior but differs from the magnetometry because the spin state transition at the surface differs from the bulk of the thin film. X-ray photoelectron spectroscopy provided some insight into issues with the film deposition process and multiplex fitting was used to further support the claim that the surface of the film is different than the bulk of the film.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 2438349

Journal Information:: Journal of Physics. Condensed Matter, Journal Name: Journal of Physics. Condensed Matter Journal Issue: 46 Vol. 36; ISSN 0953-8984

Publisher:: IOP PublishingCopyright Statement

Country of Publication:: United Kingdom

Language:: English

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Title: Layer-by-layer assembly of a [Fe-(pyrazine){Pd(CN) ₄ }] spin crossover thin film