Pre-equilibrium reactions involving pendent relays improve CO 2 reduction mediated by molecular Cr-based electrocatalysts

Moberg, Megan E.; Reid, Amelia G.; Dickie, Diane A.; Machan, Charles W.

doi:10.1039/D4DT01981D

Title: Pre-equilibrium reactions involving pendent relays improve CO ₂ reduction mediated by molecular Cr-based electrocatalysts

Journal Article · 22 October 2024 · Dalton Transactions

DOI: https://doi.org/10.1039/D4DT01981D · OSTI ID:2438126

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Department of Chemistry, University of Virginia, PO Box 400319, Charlottesville, VA 22904-4319, USA

Non-covalent interactions between reduced chromium complexes and a cationic acid during homogeneous carbon dioxide reduction introduce pre-equilibrium effects which impact the operating potential and turnover frequency of catalysis.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: NONE; SC0022219

OSTI ID:: 2438126

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 41 Vol. 53; ISSN 1477-9226; ISSN ICHBD9

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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