The fabrication of Ti 3 C 2 and Ti 3 CN MXenes by electrochemical etching

Chan, Kai Chio; Guan, Xiang; Zhang, Teng; Lin, Kailing; Huang, Yihe; Lei, Lingshu; Georgantas, Yiannis; Gogotsi, Yury; Bissett, Mark A.; Kinloch, Ian A.

doi:10.1039/D4TA03457K

Title: The fabrication of Ti ₃ C ₂ and Ti ₃ CN MXenes by electrochemical etching

Journal Article · 24 September 2024 · Journal of Materials Chemistry. A

DOI: https://doi.org/10.1039/D4TA03457K · OSTI ID:2438123

Chan, Kai Chio ^[1]; Guan, Xiang ^[1]; Zhang, Teng ^[2]; Lin, Kailing ^[1];

^[3]; Lei, Lingshu ^[1]; Georgantas, Yiannis ^[1]; Gogotsi, Yury ^[2];

^[1];

^[1]

Advanced Nanomaterials Group, Henry Royce Institute, Department of Materials, The University of Manchester, Oxford Road, M13 9PL, UK
A. J. Drexel Nanomaterials Institute and Department of Materials Science and Engineering, Drexel University, Philadelphia, PA 19104, USA
Laser Processing Research Centre, Department of Mechanical Aerospace Civil Engineering, University of Manchester, Oxford Road, M13 9PL, UK

Ti ₃ C ₂ and Ti ₃ CN MXenes were exfoliated from their corresponding MAX phases by electrochemical etching using HBF ₄ as the electrolyte. The performance of electrochemically etched MXene as electrodes for Li-ion supercapacitors was studied.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0018618

OSTI ID:: 2438123

Journal Information:: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 37 Vol. 12; ISSN JMCAET; ISSN 2050-7488

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (51)

Synthesis and Characterization of 2D Molybdenum Carbide (MXene) Halim, Joseph; Kota, Sankalp; Lukatskaya, Maria R. Advanced Functional Materials, Vol. 26, Issue 18 https://doi.org/10.1002/adfm.201505328	journal	February 2016
How Much Oxygen Can a MXene Surface Take Before It Breaks? Persson, Ingemar; Halim, Joseph; Hansen, Thomas W. Advanced Functional Materials, Vol. 30, Issue 47 https://doi.org/10.1002/adfm.201909005	journal	February 2020
2D MXenes for Electromagnetic Shielding: A Review Iqbal, Aamir; Sambyal, Pradeep; Koo, Chong Min Advanced Functional Materials, Vol. 30, Issue 47 https://doi.org/10.1002/adfm.202000883	journal	April 2020
Two-Dimensional Nanocrystals Produced by Exfoliation of Ti₃AlC₂ Naguib, Michael; Kurtoglu, Murat; Presser, Volker Advanced Materials, Vol. 23, Issue 37, p. 4248-4253 https://doi.org/10.1002/adma.201102306	journal	August 2011
Amine-Assisted Delamination of Nb ₂ C MXene for Li-Ion Energy Storage Devices Mashtalir, Olha; Lukatskaya, Maria R.; Zhao, Meng-Qiang Advanced Materials, Vol. 27, Issue 23 https://doi.org/10.1002/adma.201500604	journal	April 2015
Fluoride‐Free 2D Niobium Carbide MXenes as Stable and Biocompatible Nanoplatforms for Electrochemical Biosensors with Ultrahigh Sensitivity Song, Menglin; Pang, Sin‐Yi; Guo, Feng Advanced Science, Vol. 7, Issue 24 https://doi.org/10.1002/advs.202001546	journal	November 2020
Enhanced Li-Ion Accessibility in MXene Titanium Carbide by Steric Chloride Termination Kajiyama, Satoshi; Szabova, Lucie; Iinuma, Hiroki Advanced Energy Materials, Vol. 7, Issue 9 https://doi.org/10.1002/aenm.201601873	journal	January 2017
Room-Temperature Carbide-Derived Carbon Synthesis by Electrochemical Etching of MAX Phases Lukatskaya, Maria R.; Halim, Joseph; Dyatkin, Boris Angewandte Chemie, Vol. 126, Issue 19 https://doi.org/10.1002/ange.201402513	journal	April 2014
Fluoride‐Free Synthesis of Two‐Dimensional Titanium Carbide (MXene) Using A Binary Aqueous System Yang, Sheng; Zhang, Panpan; Wang, Faxing Angewandte Chemie, Vol. 130, Issue 47 https://doi.org/10.1002/ange.201809662	journal	November 2018
Fluorine-Free Synthesis of High-Purity Ti ₃ C ₂ T _x (T=OH, O) via Alkali Treatment Li, Tengfei; Yao, Lulu; Liu, Qinglei Angewandte Chemie International Edition, Vol. 57, Issue 21 https://doi.org/10.1002/anie.201800887	journal	April 2018
Selective Etching of Silicon from Ti ₃ SiC ₂ (MAX) To Obtain 2D Titanium Carbide (MXene) Alhabeb, Mohamed; Maleski, Kathleen; Mathis, Tyler S. Angewandte Chemie International Edition, Vol. 57, Issue 19 https://doi.org/10.1002/anie.201802232	journal	March 2018
Ambient‐Stable Two‐Dimensional Titanium Carbide (MXene) Enabled by Iodine Etching Shi, Huanhuan; Zhang, Panpan; Liu, Zaichun Angewandte Chemie International Edition, Vol. 60, Issue 16 https://doi.org/10.1002/anie.202015627	journal	March 2021
Molten Salt Derived Nb ₂ CT _x MXene Anode for Li‐ion Batteries Dong, Hanyu; Xiao, Peng; Jin, Na ChemElectroChem, Vol. 8, Issue 5 https://doi.org/10.1002/celc.202100142	journal	March 2021
Tailoring Structure, Composition, and Energy Storage Properties of MXenes from Selective Etching of In-Plane, Chemically Ordered MAX Phases Persson, Ingemar; el Ghazaly, Ahmed; Tao, Quanzheng Small, Vol. 14, Issue 17 https://doi.org/10.1002/smll.201703676	journal	April 2018
Recent advances in MXene: Preparation, properties, and applications Lei, Jin-Cheng; Zhang, Xu; Zhou, Zhen Frontiers of Physics, Vol. 10, Issue 3 https://doi.org/10.1007/s11467-015-0493-x	journal	June 2015
X-ray photoelectron spectroscopy of select multi-layered transition metal carbides (MXenes) Halim, Joseph; Cook, Kevin M.; Naguib, Michael Applied Surface Science, Vol. 362 https://doi.org/10.1016/j.apsusc.2015.11.089	journal	January 2016
A hydrothermal etching route to synthesis of 2D MXene (Ti3C2, Nb2C): Enhanced exfoliation and improved adsorption performance Peng, Chao; Wei, Ping; Chen, Xin Ceramics International, Vol. 44, Issue 15 https://doi.org/10.1016/j.ceramint.2018.07.124	journal	October 2018
MXene: a promising transition metal carbide anode for lithium-ion batteries Naguib, Michael; Come, Jérémy; Dyatkin, Boris Electrochemistry Communications, Vol. 16, Issue 1, p. 61-64 https://doi.org/10.1016/j.elecom.2012.01.002	journal	March 2012
High mass loading, binder-free MXene anodes for high areal capacity Li-ion batteries Kim, Seon Joon; Naguib, Michael; Zhao, Mengqiang Electrochimica Acta, Vol. 163 https://doi.org/10.1016/j.electacta.2015.02.132	journal	May 2015
Acid dissolution of alumina from waste aluminium dross Dash, B.; Das, B. R.; Tripathy, B. C. Hydrometallurgy, Vol. 92, Issue 1-2 https://doi.org/10.1016/j.hydromet.2008.01.006	journal	May 2008
Scalable, Highly Conductive, and Micropatternable MXene Films for Enhanced Electromagnetic Interference Shielding Lipton, Jason; Röhr, Jason A.; Dang, Vi Matter, Vol. 3, Issue 2 https://doi.org/10.1016/j.matt.2020.05.023	journal	August 2020
Characterization of MXenes at every step, from their precursors to single flakes and assembled films Shekhirev, Mikhail; Shuck, Christopher E.; Sarycheva, Asia Progress in Materials Science, Vol. 120 https://doi.org/10.1016/j.pmatsci.2020.100757	journal	July 2021
Raman Spectroscopy Analysis of the Structure and Surface Chemistry of Ti ₃ C ₂ T _x MXene Sarycheva, Asia; Gogotsi, Yury Chemistry of Materials, Vol. 32, Issue 8 https://doi.org/10.1021/acs.chemmater.0c00359	journal	April 2020
Etching Mechanism of Monoatomic Aluminum Layers during MXene Synthesis Kim, Yong-Jae; Kim, Seon Joon; Seo, Darae Chemistry of Materials, Vol. 33, Issue 16 https://doi.org/10.1021/acs.chemmater.1c01263	journal	August 2021
The Future of MXenes Gogotsi, Yury Chemistry of Materials, Vol. 35, Issue 21 https://doi.org/10.1021/acs.chemmater.3c02491	journal	November 2023
Resolving the Structure of Ti ₃ C ₂ T _x MXenes through Multilevel Structural Modeling of the Atomic Pair Distribution Function Wang, Hsiu-Wen; Naguib, Michael; Page, Katharine Chemistry of Materials, Vol. 28, Issue 1 https://doi.org/10.1021/acs.chemmater.5b04250	journal	December 2015
Guidelines for Synthesis and Processing of Two-Dimensional Titanium Carbide (Ti ₃ C ₂ T _x MXene) Alhabeb, Mohamed; Maleski, Kathleen; Anasori, Babak Chemistry of Materials, Vol. 29, Issue 18 https://doi.org/10.1021/acs.chemmater.7b02847	journal	September 2017
Hydration of Ti ₃ C ₂ T _x MXene: An Interstratification Process with Major Implications on Physical Properties Célérier, Stéphane; Hurand, Simon; Garnero, Cyril Chemistry of Materials, Vol. 31, Issue 2 https://doi.org/10.1021/acs.chemmater.8b03976	journal	December 2018
Size-Dependent Physical and Electrochemical Properties of Two-Dimensional MXene Flakes Maleski, Kathleen; Ren, Chang E.; Zhao, Meng-Qiang ACS Applied Materials & Interfaces, Vol. 10, Issue 29 https://doi.org/10.1021/acsami.8b04662	journal	June 2018
Two-Dimensional Molybdenum Carbide (MXene) as an Efficient Electrocatalyst for Hydrogen Evolution Seh, Zhi Wei; Fredrickson, Kurt D.; Anasori, Babak ACS Energy Letters, Vol. 1, Issue 3 https://doi.org/10.1021/acsenergylett.6b00247	journal	August 2016
Halogen Etch of Ti ₃ AlC ₂ MAX Phase for MXene Fabrication Jawaid, Ali; Hassan, Asra; Neher, Gregory ACS Nano, Vol. 15, Issue 2 https://doi.org/10.1021/acsnano.0c08630	journal	January 2021
Exfoliation and Delamination of Ti₃C₂T_x MXene Prepared via Molten Salt Etching Route Liu, Liyuan; Orbay, Metin; Luo, Sha ACS Nano, Vol. 16, Issue 1 https://doi.org/10.1021/acsnano.1c08498	journal	November 2021
Ti ₃ C ₂ MXene as a High Capacity Electrode Material for Metal (Li, Na, K, Ca) Ion Batteries Er, Dequan; Li, Junwen; Naguib, Michael ACS Applied Materials & Interfaces, Vol. 6, Issue 14 https://doi.org/10.1021/am501144q	journal	June 2014
New Two-Dimensional Niobium and Vanadium Carbides as Promising Materials for Li-Ion Batteries Naguib, Michael; Halim, Joseph; Lu, Jun Journal of the American Chemical Society, Vol. 135, Issue 43 https://doi.org/10.1021/ja405735d	journal	October 2013
Exfoliation of Graphite into Graphene in Aqueous Solutions of Inorganic Salts Parvez, Khaled; Wu, Zhong-Shuai; Li, Rongjin Journal of the American Chemical Society, Vol. 136, Issue 16 https://doi.org/10.1021/ja5017156	journal	April 2014
Tailoring Electronic and Optical Properties of MXenes through Forming Solid Solutions Han, Meikang; Maleski, Kathleen; Shuck, Christopher Eugene Journal of the American Chemical Society, Vol. 142, Issue 45 https://doi.org/10.1021/jacs.0c07395	journal	October 2020
Element Replacement Approach by Reaction with Lewis Acidic Molten Salts to Synthesize Nanolaminated MAX Phases and MXenes Li, Mian; Lu, Jun; Luo, Kan Journal of the American Chemical Society, Vol. 141, Issue 11 https://doi.org/10.1021/jacs.9b00574	journal	March 2019
Universal Strategy for HF-Free Facile and Rapid Synthesis of Two-dimensional MXenes as Multifunctional Energy Materials Pang, Sin-Yi; Wong, Yuen-Ting; Yuan, Shuoguo Journal of the American Chemical Society, Vol. 141, Issue 24 https://doi.org/10.1021/jacs.9b02578	journal	April 2019
Improved Synthesis of Graphene Oxide Marcano, Daniela C.; Kosynkin, Dmitry V.; Berlin, Jacob M. ACS Nano, Vol. 4, Issue 8, p. 4806-4814 https://doi.org/10.1021/nn1006368	journal	July 2010
Prediction and Characterization of MXene Nanosheet Anodes for Non-Lithium-Ion Batteries Xie, Yu; Dall’Agnese, Yohan; Naguib, Michael ACS Nano, Vol. 8, Issue 9 https://doi.org/10.1021/nn503921j	journal	August 2014
2D metal carbides and nitrides (MXenes) for energy storage Anasori, Babak; Lukatskaya, Maria R.; Gogotsi, Yury Nature Reviews Materials, Vol. 2, Issue 2 https://doi.org/10.1038/natrevmats.2016.98	journal	January 2017
High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance Augustyn, Veronica; Come, Jérémy; Lowe, Michael A. Nature Materials, Vol. 12, Issue 6 https://doi.org/10.1038/nmat3601	journal	April 2013
How to get between the sheets: a review of recent works on the electrochemical exfoliation of graphene materials from bulk graphite Abdelkader, A. M.; Cooper, A. J.; Dryfe, R. A. W. Nanoscale, Vol. 7, Issue 16 https://doi.org/10.1039/C4NR06942K	journal	January 2015
Control of electronic properties of 2D carbides (MXenes) by manipulating their transition metal layers Anasori, Babak; Shi, Chenyang; Moon, Eun Ju Nanoscale Horizons, Vol. 1, Issue 3 https://doi.org/10.1039/C5NH00125K	journal	January 2016
Synthesis of two-dimensional titanium nitride Ti ₄ N ₃ (MXene) Urbankowski, Patrick; Anasori, Babak; Makaryan, Taron Nanoscale, Vol. 8, Issue 22 https://doi.org/10.1039/C6NR02253G	journal	January 2016
Insights into exfoliation possibility of MAX phases to MXenes Khazaei, Mohammad; Ranjbar, Ahmad; Esfarjani, Keivan Physical Chemistry Chemical Physics, Vol. 20, Issue 13 https://doi.org/10.1039/C7CP08645H	journal	January 2018
Electrochemical etching of Ti ₂ AlC to Ti ₂ CT _x (MXene) in low-concentration hydrochloric acid solution Sun, W.; Shah, S. A.; Chen, Y. J. Mater. Chem. A, Vol. 5, Issue 41 https://doi.org/10.1039/C7TA05574A	journal	January 2017
Electrochemical exfoliation of graphene-like two-dimensional nanomaterials Yang, Yingchang; Hou, Hongshuai; Zou, Guoqiang Nanoscale, Vol. 11, Issue 1 https://doi.org/10.1039/C8NR08227H	journal	January 2019
Role of acid mixtures etching on the surface chemistry and sodium ion storage in Ti ₃ C ₂ T _x MXene Anayee, Mark; Kurra, Narendra; Alhabeb, Mohamed Chemical Communications, Vol. 56, Issue 45 https://doi.org/10.1039/D0CC01042A	journal	January 2020
Cation Intercalation and High Volumetric Capacitance of Two-Dimensional Titanium Carbide Lukatskaya, M. R.; Mashtalir, O.; Ren, C. E. Science, Vol. 341, Issue 6153 https://doi.org/10.1126/science.1241488	journal	September 2013
Electromagnetic interference shielding with 2D transition metal carbides (MXenes) Shahzad, F.; Alhabeb, M.; Hatter, C. B. Science, Vol. 353, Issue 6304 https://doi.org/10.1126/science.aag2421	journal	September 2016

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Title: The fabrication of Ti ₃ C ₂ and Ti ₃ CN MXenes by electrochemical etching