Emergence of Ruddlesden–Popper phases and other pitfalls for moderate temperature solution deposited chalcogenide perovskites

Pradhan, Apurva A.; Agarwal, Shubhanshu; Vincent, Kiruba Catherine; Hayes, Daniel C.; Peterson, Jonas M.; Turnley, Jonathan W.; Spilker, Robert M.; Uible, Madeleine C.; Bart, Suzanne C.; Huang, Libai; Kisslinger, Kim; Agrawal, Rakesh

doi:10.1039/D4QM00441H

Title: Emergence of Ruddlesden–Popper phases and other pitfalls for moderate temperature solution deposited chalcogenide perovskites

Journal Article · 07 October 2024 · Materials Chemistry Frontiers

DOI: https://doi.org/10.1039/D4QM00441H · OSTI ID:2438096

^[1];

^[1]; Peterson, Jonas M. ^[2];

^[1]; Spilker, Robert M. ^[1];

^[2];

^[2]; Kisslinger, Kim ^[3];

^[1]

Davidson School of Chemical Engineering, Purdue University, West Lafayette, IN 47907, USA
H.C. Brown Laboratory, Department of Chemistry, Purdue University, West Lafayette, IN 47907, USA
Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, NY 11973, USA

This work highlights the challenges of weak photoluminescence, the limited choice of substrates, unwanted impurity phases, and Ruddlesden–Popper phases in the moderate-temperature synthesized chalcogenide perovskites.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0012704

OSTI ID:: 2438096

Journal Information:: Materials Chemistry Frontiers, Journal Name: Materials Chemistry Frontiers Journal Issue: 20 Vol. 8; ISSN 2052-1537; ISSN MCFAC5

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (52)

An Environmentally Stable and Lead‐Free Chalcogenide Perovskite Gupta, Tushar; Ghoshal, Debjit; Yoshimura, Anthony Advanced Functional Materials, Vol. 30, Issue 23 https://doi.org/10.1002/adfm.202001387	journal	April 2020
Making BaZrS ₃ Chalcogenide Perovskite Thin Films by Molecular Beam Epitaxy Sadeghi, Ida; Ye, Kevin; Xu, Michael Advanced Functional Materials, Vol. 31, Issue 45 https://doi.org/10.1002/adfm.202105563	journal	August 2021
A High-Efficiency Solution-Deposited Thin-Film Photovoltaic Device Mitzi, David B.; Yuan, Min; Liu, Wei Advanced Materials, Vol. 20, Issue 19 https://doi.org/10.1002/adma.200800555	journal	October 2008
High Efficiency Cu ₂ ZnSn(S,Se) ₄ Solar Cells by Applying a Double In ₂ S ₃ /CdS Emitter Kim, Jeehwan; Hiroi, Homare; Todorov, Teodor K. Advanced Materials, Vol. 26, Issue 44 https://doi.org/10.1002/adma.201402373	journal	August 2014
Bandgap Control via Structural and Chemical Tuning of Transition Metal Perovskite Chalcogenides Niu, Shanyuan; Huyan, Huaixun; Liu, Yang Advanced Materials, Vol. 29, Issue 9 https://doi.org/10.1002/adma.201604733	journal	December 2016
Chalcogenide Perovskites: Tantalizing Prospects, Challenging Materials Sopiha, Kostiantyn V.; Comparotto, Corrado; Márquez, José A. Advanced Optical Materials, Vol. 10, Issue 3 https://doi.org/10.1002/adom.202101704	journal	December 2021
Earth-Abundant Element Photovoltaics Directly from Soluble Precursors with High Yield Using a Non-Toxic Solvent Ki, Wooseok; Hillhouse, Hugh W. Advanced Energy Materials, Vol. 1, Issue 5 https://doi.org/10.1002/aenm.201100140	journal	August 2011
Identifying the Real Minority Carrier Lifetime in Nonideal Semiconductors: A Case Study of Kesterite Materials Hages, Charles J.; Redinger, Alex; Levcenko, Sergiu Advanced Energy Materials, Vol. 7, Issue 18 https://doi.org/10.1002/aenm.201700167	journal	May 2017
Present Status of Solution‐Processing Routes for Cu(In,Ga)(S,Se) ₂ Solar Cell Absorbers Suresh, Sunil; Uhl, Alexander R. Advanced Energy Materials, Vol. 11, Issue 14 https://doi.org/10.1002/aenm.202003743	journal	February 2021
Synthesis of BaZrS₃ and BaHfS₃ Chalcogenide Perovskite Films Using Single‐Phase Molecular Precursors at Moderate Temperatures Pradhan, Apurva A.; Uible, Madeleine C.; Agarwal, Shubhanshu Angewandte Chemie International Edition, Vol. 62, Issue 15 https://doi.org/10.1002/anie.202301049	journal	March 2023
Recent Progress in Solution‐Processed Copper‐Chalcogenide Thin‐Film Solar Cells Li, Wenjie; Tan, Joel Ming Rui; Leow, Shin Woei Energy Technology, Vol. 6, Issue 1 https://doi.org/10.1002/ente.201700734	journal	December 2017
Extraordinary Strong Band‐Edge Absorption in Distorted Chalcogenide Perovskites Nishigaki, Yukinori; Nagai, Takayuki; Nishiwaki, Mitsutoshi Solar RRL, Vol. 4, Issue 5 https://doi.org/10.1002/solr.201900555	journal	January 2020
Defect tolerance in chalcogenide perovskite photovoltaic material BaZrS3 Wu, Xiaowei; Gao, Weiwei; Chai, Jun Science China Materials, Vol. 64, Issue 12 https://doi.org/10.1007/s40843-021-1683-0	journal	June 2021
Photoluminescence of CaS: Zr phosphors Rawat, B. L.; Ranade, J. D. Journal of Luminescence, Vol. 14, Issue 5-6 https://doi.org/10.1016/0022-2313(76)90010-7	journal	October 1976
Thermodynamics of sulphur vapour Rau, Hans; Kutty, T. R. N.; Guedes De Carvalho, J. R. F. The Journal of Chemical Thermodynamics, Vol. 5, Issue 6 https://doi.org/10.1016/S0021-9614(73)80045-X	journal	November 1973
Ce3+ energy levels relative to the band structure in CaS: evidence from photoionization and electron trapping Jia, D.; Meltzer, R. S.; Yen, W. M. Journal of Luminescence, Vol. 99, Issue 1 https://doi.org/10.1016/S0022-2313(02)00326-5	journal	August 2002
Crystal field and molecular orbital calculation of the optical transitions in Ce doped alkaline earth sulfide (MgS, CaS, SrS, and BaS) phosphors O'Brien, Ted A.; Rack, Philip D.; H. Holloway, Paul Journal of Luminescence, Vol. 78, Issue 4 https://doi.org/10.1016/S0022-2313(98)00011-8	journal	June 1998
Synthesis of BaZrS3 by short time reaction at lower temperatures Wang, Yarong; Sato, Nobuaki; Fujino, Takeo Journal of Alloys and Compounds, Vol. 327, Issue 1-2 https://doi.org/10.1016/S0925-8388(01)01553-5	journal	August 2001
P-type conductive BaZrS₃ thin film and its band gap tunning via Ruddlesden-Popper Ba₃Zr₂S₇ and titanium alloying Han, Yanbing; Xu, Jie; Liang, Yurun Chemical Engineering Journal, Vol. 473 https://doi.org/10.1016/j.cej.2023.145351 145351	journal	October 2023
Enhancing the optical absorption of chalcogenide perovskite BaZrS3 by optimizing the synthesis and post-processing conditions Xu, Jie; Fan, Yuchao; Tian, Weimin Journal of Solid State Chemistry, Vol. 307 https://doi.org/10.1016/j.jssc.2021.122872	journal	March 2022
Chalcogenide perovskites – an emerging class of ionic semiconductors Perera, Samanthe; Hui, Haolei; Zhao, Chuan Nano Energy, Vol. 22 https://doi.org/10.1016/j.nanoen.2016.02.020	journal	April 2016
Realization of BaZrS3 chalcogenide perovskite thin films for optoelectronics Wei, Xiucheng; Hui, Haolei; Zhao, Chuan Nano Energy, Vol. 68 https://doi.org/10.1016/j.nanoen.2019.104317	journal	February 2020
Incorporation of alkali metals in chalcogenide solar cells Salomé, P. M. P.; Rodriguez-Alvarez, H.; Sadewasser, S. Solar Energy Materials and Solar Cells, Vol. 143 https://doi.org/10.1016/j.solmat.2015.06.011	journal	December 2015
Shape-Controlled Synthesis of Colloidal Nanorods and Nanoparticles of Barium Titanium Sulfide Zilevu, Daniel; Creutz, Sidney E. Chemistry of Materials, Vol. 33, Issue 13 https://doi.org/10.1021/acs.chemmater.1c01193	journal	June 2021
On the Phase Stability of Chalcogenide Perovskites Jess, Alexander; Yang, Ruiquan; Hages, Charles J. Chemistry of Materials, Vol. 34, Issue 15, p. 6894-6901 https://doi.org/10.1021/acs.chemmater.2c01289	journal	July 2022
Alloying and Defect Control within Chalcogenide Perovskites for Optimized Photovoltaic Application Meng, Weiwei; Saparov, Bayrammurad; Hong, Feng Chemistry of Materials, Vol. 28, Issue 3 https://doi.org/10.1021/acs.chemmater.5b04213	journal	January 2016
Investigating Chemistry of Metal Dissolution in Amine–Thiol Mixtures and Exploiting It toward Benign Ink Formulation for Metal Chalcogenide Thin Films Zhao, Xin; Deshmukh, Swapnil D.; Rokke, David J. Chemistry of Materials, Vol. 31, Issue 15 https://doi.org/10.1021/acs.chemmater.9b01566	journal	July 2019
Versatile Colloidal Syntheses of Metal Chalcogenide Nanoparticles from Elemental Precursors Using Amine-Thiol Chemistry Deshmukh, Swapnil D.; Ellis, Ryan G.; Sutandar, Dwi S. Chemistry of Materials, Vol. 31, Issue 21 https://doi.org/10.1021/acs.chemmater.9b03401	journal	October 2019
Halide Perovskite Photovoltaics: Background, Status, and Future Prospects Jena, Ajay Kumar; Kulkarni, Ashish; Miyasaka, Tsutomu Chemical Reviews, Vol. 119, Issue 5 https://doi.org/10.1021/acs.chemrev.8b00539	journal	March 2019
Analyzing and Tuning the Chalcogen–Amine–Thiol Complexes for Tailoring of Chalcogenide Syntheses Deshmukh, Swapnil D.; Easterling, Leah F.; Manheim, Jeremy M. Inorganic Chemistry, Vol. 59, Issue 12 https://doi.org/10.1021/acs.inorgchem.0c00597	journal	May 2020
How the Temperature and Composition Govern the Structure and Band Gap of Zr-Based Chalcogenide Perovskites: Insights from ML Accelerated AIMD Jaykhedkar, Namrata; Bystrický, Roman; Sýkora, Milan Inorganic Chemistry, Vol. 62, Issue 31 https://doi.org/10.1021/acs.inorgchem.3c01696	journal	July 2023
BaZrS ₃ Chalcogenide Perovskite Thin Films by H ₂ S Sulfurization of Oxide Precursors Márquez, José A.; Rusu, Marin; Hempel, Hannes The Journal of Physical Chemistry Letters, Vol. 12, Issue 8 https://doi.org/10.1021/acs.jpclett.1c00177	journal	February 2021
Bandgap Tuning in BaZrS ₃ Perovskite Thin Films Sharma, Shyam; Ward, Zachary; Bhimani, Kevin ACS Applied Electronic Materials, Vol. 3, Issue 8 https://doi.org/10.1021/acsaelm.1c00575	journal	August 2021
Solution Processed Fabrication of Se–Te Alloy Thin Films for Application in PV Devices Deshmukh, Swapnil D.; Miskin, Caleb K.; Pradhan, Apurva A. ACS Applied Energy Materials, Vol. 5, Issue 3 https://doi.org/10.1021/acsaem.1c03896	journal	March 2022
Synthesis of BaZrS₃ Perovskite Thin Films at a Moderate Temperature on Conductive Substrates Comparotto, Corrado; Ström, Petter; Donzel-Gargand, Olivier ACS Applied Energy Materials, Vol. 5, Issue 5 https://doi.org/10.1021/acsaem.2c00704	journal	April 2022
Machine Learning-Aided Band Gap Engineering of BaZrS₃ Chalcogenide Perovskite Sharma, Shyam; Ward, Zachary D.; Bhimani, Kevin ACS Applied Materials & Interfaces, Vol. 15, Issue 15 https://doi.org/10.1021/acsami.3c00618	journal	April 2023
Ti-Alloying of BaZrS ₃ Chalcogenide Perovskite for Photovoltaics Wei, Xiucheng; Hui, Haolei; Perera, Samanthe ACS Omega, Vol. 5, Issue 30 https://doi.org/10.1021/acsomega.0c00740	journal	July 2020
Low-Temperature, Solution-Based Synthesis of Luminescent Chalcogenide Perovskite BaZrS₃ Nanoparticles Yang, Ruiquan; Jess, Alexander D.; Fai, Calvin Journal of the American Chemical Society, Vol. 144, Issue 35 https://doi.org/10.1021/jacs.2c06168	journal	August 2022
Chalcogenide Perovskites for Photovoltaics Sun, Yi-Yang; Agiorgousis, Michael L.; Zhang, Peihong Nano Letters, Vol. 15, Issue 1 https://doi.org/10.1021/nl504046x	journal	December 2014
Metal–metal chalcogenide molecular precursors to binary, ternary, and quaternary metal chalcogenide thin films for electronic devices Zhang, Ruihong; Cho, Seonghyuk; Lim, Daw Gen Chemical Communications, Vol. 52, Issue 28 https://doi.org/10.1039/C5CC09915C	journal	January 2016
Colloidal BaZrS ₃ chalcogenide perovskite nanocrystals for thin film device fabrication Ravi, Vikash Kumar; Yu, Seong Hoon; Rajput, Parikshit Kumar Nanoscale, Vol. 13, Issue 3 https://doi.org/10.1039/D0NR08078K	journal	January 2021
765. Metallo-organic compounds containing metal–nitrogen bonds. Part I. Some dialkylamino-derivatives of titanium and zirconium Bradley, D. C.; Thomas, I. M. J. Chem. Soc., Vol. 0, Issue 0 https://doi.org/10.1039/JR9600003857	journal	January 1960
Solution processing of chalcogenide materials using thiol–amine “alkahest” solvent systems McCarthy, Carrie L.; Brutchey, Richard L. Chemical Communications, Vol. 53, Issue 36 https://doi.org/10.1039/c7cc02226c	journal	January 2017
Preparation and properties of NN-dialkyldithiocarbamates of early transition elements Bradley, D. C.; Gitlitz, M. H. Journal of the Chemical Society A: Inorganic, Physical, Theoretical https://doi.org/10.1039/j19690001152	journal	January 1969
Chalcogenide perovskites for photovoltaics: current status and prospects Tiwari, Devendra; Hutter, Oliver S.; Longo, Giulia Journal of Physics: Energy, Vol. 3, Issue 3 https://doi.org/10.1088/2515-7655/abf41c	journal	May 2021
Stability and Band-Gap Tuning of the Chalcogenide Perovskite BaZrS 3 in Raman and Optical Investigations at High Pressures Gross, Nelson; Sun, Yi-Yang; Perera, Samanthe Physical Review Applied, Vol. 8, Issue 4 https://doi.org/10.1103/PhysRevApplied.8.044014	journal	October 2017
Band gap evolution in Ruddlesden-Popper phases Li, Wei; Niu, Shanyuan; Zhao, Boyang Physical Review Materials, Vol. 3, Issue 10 https://doi.org/10.1103/PhysRevMaterials.3.101601	journal	October 2019
The synthesis and crystal structures of some alkaline earth titanium and zirconium sulfides Clearfield, A. Acta Crystallographica, Vol. 16, Issue 2 https://doi.org/10.1107/S0365110X6300030X	journal	February 1963
Sulphides with the GdFeO ₃ structure Lelieveld, R.; IJdo, D. J. W. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 36, Issue 10 https://doi.org/10.1107/S056774088000845X	journal	October 1980
Raman spectroscopic properties and Raman identification of CaS-MgS-MnS-FeS-Cr₂FeS₄sulfides in meteorites and reduced sulfur-rich systems Avril, Caroline; Malavergne, Valérie; Caracas, Razvan Meteoritics & Planetary Science, Vol. 48, Issue 8 https://doi.org/10.1111/maps.12145	journal	July 2013
Fabrication of red-emitting Eu3+-induced CaS phosphors: a view of optical, in vitro, lifetime, structural and morphological studies for biomedical applications Kavitha, V.; Rani, M. Prema The European Physical Journal Plus, Vol. 137, Issue 11 https://doi.org/10.1140/epjp/s13360-022-03381-4	journal	November 2022
Thermal stability study of transition metal perovskite sulfides Niu, Shanyuan; Milam-Guerrero, JoAnna; Zhou, Yucheng Journal of Materials Research, Vol. 33, Issue 24 https://doi.org/10.1557/jmr.2018.419	journal	November 2018

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