Electric field induced associations in the double layer of salt-in-ionic-liquid electrolytes

Markiewitz, Daniel M.; Goodwin, Zachary A. H.; McEldrew, Michael; Pedro de Souza, J.; Zhang, Xuhui; Espinosa-Marzal, Rosa M.; Bazant, Martin Z.

doi:10.1039/D4FD00021H

Title: Electric field induced associations in the double layer of salt-in-ionic-liquid electrolytes

Journal Article · 25 October 2024 · Faraday Discussions

DOI: https://doi.org/10.1039/D4FD00021H · OSTI ID:2437763

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Department of Chemical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA
John A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts 02138, USA, Department of Materials, Imperial College London, South Kensington Campus, London SW7 2AZ, UK
Department of Chemical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA, Omenn-Darling Bioengineering Institute, Princeton University, Princeton, New Jersey 08544, USA
Department of Civil and Environmental Engineering, University of Illinois at Urbana – Champaign, Urbana, IL, 61801, USA
Department of Civil and Environmental Engineering, University of Illinois at Urbana – Champaign, Urbana, IL, 61801, USA, Department of Materials Science and Engineering, University of Illinois at Urbana – Champaign, Urbana, IL, 61801, USA
Department of Chemical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA, Department of Mathematics, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA

We have developed a theory for the electrical double layer of salt-in-ionic liquids accounting for the thermoreversible association of ions into Cayley tree aggregates. We find that the solution becomes more aggregated at moderate positive voltages.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0019112

OSTI ID:: 2437763

Journal Information:: Faraday Discussions, Journal Name: Faraday Discussions Vol. 253; ISSN 1359-6640; ISSN FDISE6

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (89)

Insight into the Electrical Double Layer of Ionic Liquids Revealed through Its Temporal Evolution Han, Mengwei; Kim, Hojun; Leal, Cecilia Advanced Materials Interfaces, Vol. 7, Issue 24 https://doi.org/10.1002/admi.202001313	journal	November 2020
Ionic Liquids and Organic Ionic Plastic Crystals: Advanced Electrolytes for Safer High Performance Sodium Energy Storage Technologies Basile, Andrew; Hilder, Matthias; Makhlooghiazad, Faezeh Advanced Energy Materials, Vol. 8, Issue 17 https://doi.org/10.1002/aenm.201703491	journal	May 2018
Anion Selection Criteria for Water‐in‐Salt Electrolytes Reber, David; Grissa, Rabeb; Becker, Maximilian Advanced Energy Materials, Vol. 11, Issue 5 https://doi.org/10.1002/aenm.202002913	journal	December 2020
Ionic Liquid in Li Salt Electrolyte: Modifying the Li ⁺ Transport Mechanism by Coordination to an Asymmetric Anion Brinkkötter, Marc; Mariani, Alessandro; Jeong, Sangsik Advanced Energy and Sustainability Research, Vol. 2, Issue 2 https://doi.org/10.1002/aesr.202000078	journal	December 2020
Understanding Ionic Liquids at the Molecular Level: Facts, Problems, and Controversies Weingärtner, Hermann Angewandte Chemie International Edition, Vol. 47, Issue 4 https://doi.org/10.1002/anie.200604951	journal	January 2008
Continuum molecular electrostatics, salt effects, and counterion binding—A review of the Poisson–Boltzmann theory and its modifications Grochowski, Paweł; Trylska, Joanna Biopolymers, Vol. 89, Issue 2 https://doi.org/10.1002/bip.20877	journal	January 2008
Enforced Freedom: Electric‐Field‐Induced Declustering of Ionic‐Liquid Ions in the Electrical Double Layer Zhang, Yufan; Ye, Ting; Chen, Ming Energy & Environmental Materials, Vol. 3, Issue 3, p. 414-420 https://doi.org/10.1002/eem2.12107	journal	August 2020
Molecular distribution in condensation polymers Stockmayer, Walter H. Journal of Polymer Science, Vol. 9, Issue 1 https://doi.org/10.1002/pol.1952.120090106	journal	July 1952
Fluids with highly directional attractive forces. I. Statistical thermodynamics Wertheim, M. S. Journal of Statistical Physics, Vol. 35, Issue 1-2 https://doi.org/10.1007/BF01017362	journal	April 1984
Fluids with highly directional attractive forces. II. Thermodynamic perturbation theory and integral equations Wertheim, M. S. Journal of Statistical Physics, Vol. 35, Issue 1-2 https://doi.org/10.1007/BF01017363	journal	April 1984
Fluids with highly directional attractive forces. III. Multiple attraction sites Wertheim, M. S. Journal of Statistical Physics, Vol. 42, Issue 3-4 https://doi.org/10.1007/BF01127721	journal	February 1986
Fluids with highly directional attractive forces. IV. Equilibrium polymerization Wertheim, M. S. Journal of Statistical Physics, Vol. 42, Issue 3-4 https://doi.org/10.1007/BF01127722	journal	February 1986
The general solution of the binding mean spherical approximation for pairing ions Blum, L.; Bernard, O. Journal of Statistical Physics, Vol. 79, Issue 3-4 https://doi.org/10.1007/BF02184871	journal	May 1995
Electrostatistics of counter-ions at and between planar charged walls: From Poisson-Boltzmann to the strong-coupling theory Netz, R. R. The European Physical Journal E, Vol. 5, Issue 5 https://doi.org/10.1007/s101890170039	journal	August 2001
Interaction of charged surfaces in electrolyte solutions Kjellander, Roland; Marčelja, Stjepan Chemical Physics Letters, Vol. 127, Issue 4 https://doi.org/10.1016/0009-2614(86)80304-9	journal	June 1986
Thermoreversible gelation of associating polymers Tanaka, Fumihiko Physica A: Statistical Mechanics and its Applications, Vol. 257, Issue 1-4 https://doi.org/10.1016/S0378-4371(98)00143-5	journal	August 1998
Towards an understanding of induced-charge electrokinetics at large applied voltages in concentrated solutions Bazant, Martin Z.; Kilic, Mustafa Sabri; Storey, Brian D. Advances in Colloid and Interface Science, Vol. 152, Issue 1-2 https://doi.org/10.1016/j.cis.2009.10.001	journal	November 2009
Ionic liquids for hybrid supercapacitors Balducci, Andrea; Bardi, Ugo; Caporali, Stefano Electrochemistry Communications, Vol. 6, Issue 6 https://doi.org/10.1016/j.elecom.2004.04.005	journal	June 2004
Underscreening, overscreening and double-layer capacitance Goodwin, Zachary A. H.; Kornyshev, Alexei A. Electrochemistry Communications, Vol. 82 https://doi.org/10.1016/j.elecom.2017.07.008	journal	September 2017
Charge–discharge behavior of graphite negative electrodes in bis(fluorosulfonyl)imide-based ionic liquid and structural aspects of their electrode/electrolyte interfaces Yamagata, Masaki; Nishigaki, Nobuhide; Nishishita, Satoshi Electrochimica Acta, Vol. 110 https://doi.org/10.1016/j.electacta.2013.03.018	journal	November 2013
Mean-Field Theory of Electrical Double Layer In Ionic Liquids with Account of Short-Range Correlations Goodwin, Zachary A. H.; Feng, Guang; Kornyshev, Alexei A. Electrochimica Acta, Vol. 225 https://doi.org/10.1016/j.electacta.2016.12.092	journal	January 2017
Theory of coupled ion-electron transfer kinetics Fraggedakis, Dimitrios; McEldrew, Michael; Smith, Raymond B. Electrochimica Acta, Vol. 367 https://doi.org/10.1016/j.electacta.2020.137432	journal	January 2021
Cracking Ion Pairs in the Electrical Double Layer of Ionic Liquids Goodwin, Zachary A. H.; Kornyshev, Alexei A. Electrochimica Acta, Vol. 434 https://doi.org/10.1016/j.electacta.2022.141163 141163	journal	December 2022
On the temperature dependence of the double layer capacitance of ionic liquids Chen, Ming; Goodwin, Zachary A. H.; Feng, Guang Journal of Electroanalytical Chemistry, Vol. 819 https://doi.org/10.1016/j.jelechem.2017.11.005	journal	June 2018
Ionic liquids as electrolytes for Li-ion batteries—An overview of electrochemical studies Lewandowski, Andrzej; Świderska-Mocek, Agnieszka Journal of Power Sources, Vol. 194, Issue 2, p. 601-609 https://doi.org/10.1016/j.jpowsour.2009.06.089	journal	December 2009
Ionic liquid based electrolytes for sodium-ion batteries: Na+ solvation and ionic conductivity Monti, Damien; Jónsson, Erlendur; Palacín, M. Rosa Journal of Power Sources, Vol. 245 https://doi.org/10.1016/j.jpowsour.2013.06.153	journal	January 2014
Transport anomalies emerging from strong correlation in ionic liquid electrolytes Molinari, Nicola; Mailoa, Jonathan P.; Craig, Nathan Journal of Power Sources, Vol. 428 https://doi.org/10.1016/j.jpowsour.2019.04.085	journal	July 2019
Enhancing the performance of lithium oxygen batteries through combining redox mediating salts with a lithium protecting salt Ahmadiparidari, Alireza; Fuladi, Shadi; Majidi, Leily Journal of Power Sources, Vol. 491 https://doi.org/10.1016/j.jpowsour.2021.229506	journal	April 2021
Application of Ionic Liquids to Energy Storage and Conversion Materials and Devices Watanabe, Masayoshi; Thomas, Morgan L.; Zhang, Shiguo Chemical Reviews, Vol. 117, Issue 10 https://doi.org/10.1021/acs.chemrev.6b00504	journal	January 2017
Chelation-Induced Reversal of Negative Cation Transference Number in Ionic Liquid Electrolytes Molinari, Nicola; Kozinsky, Boris The Journal of Physical Chemistry B, Vol. 124, Issue 13 https://doi.org/10.1021/acs.jpcb.0c01089	journal	March 2020
Correlated Ion Transport and the Gel Phase in Room Temperature Ionic Liquids McEldrew, Michael; Goodwin, Zachary A. H.; Zhao, Hongbo The Journal of Physical Chemistry B, Vol. 125, Issue 10 https://doi.org/10.1021/acs.jpcb.0c09050	journal	March 2021
Salt-in-Ionic-Liquid Electrolytes: Ion Network Formation and Negative Effective Charges of Alkali Metal Cations McEldrew, Michael; Goodwin, Zachary A. H.; Molinari, Nicola The Journal of Physical Chemistry B, Vol. 125, Issue 50 https://doi.org/10.1021/acs.jpcb.1c05546	journal	December 2021
Molecular Dynamics Investigation of Correlations in Ion Transport in MeTFSI/EMIM–TFSI (Me = Li, Na) Electrolytes Kubisiak, Piotr; Wróbel, Piotr; Eilmes, Andrzej The Journal of Physical Chemistry B, Vol. 124, Issue 2 https://doi.org/10.1021/acs.jpcb.9b10391	journal	December 2019
Chelating Additives Reversing the Lithium Migration Direction in Ionic Liquid Electrolytes Ackermann, Florian; Schönhoff, Monika The Journal of Physical Chemistry C, Vol. 125, Issue 1 https://doi.org/10.1021/acs.jpcc.0c09828	journal	December 2020
Computational and Experimental Study of Li-Doped Ionic Liquids at Electrified Interfaces Haskins, Justin B.; Wu, James J.; Lawson, John W. The Journal of Physical Chemistry C, Vol. 120, Issue 22 https://doi.org/10.1021/acs.jpcc.6b02449	journal	May 2016
The Electrostatic Screening Length in Concentrated Electrolytes Increases with Concentration Smith, Alexander M.; Lee, Alpha A.; Perkin, Susan The Journal of Physical Chemistry Letters, Vol. 7, Issue 12 https://doi.org/10.1021/acs.jpclett.6b00867	journal	May 2016
General Trend of a Negative Li Effective Charge in Ionic Liquid Electrolytes Molinari, Nicola; Mailoa, Jonathan P.; Kozinsky, Boris The Journal of Physical Chemistry Letters, Vol. 10, Issue 10 https://doi.org/10.1021/acs.jpclett.9b00798	journal	April 2019
Nanoheterogeneity of LiTFSI Solutions Transitions Close to a Surface and with Concentration Han, Mengwei; Zhang, Ruixian; Gewirth, Andrew A. Nano Letters, Vol. 21, Issue 5 https://doi.org/10.1021/acs.nanolett.1c00167	journal	February 2021
Theoretical Investigation of the Na ⁺ Transport Mechanism and the Performance of Ionic Liquid-Based Electrolytes in Sodium-Ion Batteries Lourenço, Tuanan C.; Dias, Luis Gustavo; Da Silva, Juarez L. F. ACS Applied Energy Materials, Vol. 4, Issue 5 https://doi.org/10.1021/acsaem.1c00059	journal	April 2021
Beyond Local Solvation Structure: Nanometric Aggregates in Battery Electrolytes and Their Effect on Electrolyte Properties Yu, Zhou; Balsara, Nitash P.; Borodin, Oleg ACS Energy Letters, Vol. 7, Issue 1 https://doi.org/10.1021/acsenergylett.1c02391	journal	December 2021
Phase Behavior of Ionic Liquid–LiX Mixtures: Pyrrolidinium Cations and TFSI ^– Anions – Linking Structure to Transport Properties Zhou, Qian; Boyle, Paul D.; Malpezzi, Luciana Chemistry of Materials, Vol. 23, Issue 19 https://doi.org/10.1021/cm201427k	journal	September 2011
Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis. 2 Hallett, Jason P.; Welton, Tom Chemical Reviews, Vol. 111, Issue 5 https://doi.org/10.1021/cr1003248	journal	May 2011
Ionic Liquids at Electrified Interfaces Fedorov, Maxim V.; Kornyshev, Alexei A. Chemical Reviews, Vol. 114, Issue 5 https://doi.org/10.1021/cr400374x	journal	March 2014
Electrolytes and Interphases in Li-Ion Batteries and Beyond Xu, Kang Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500003w	journal	October 2014
Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis Welton, Thomas Chemical Reviews, Vol. 99, Issue 8, p. 2071-2084 https://doi.org/10.1021/cr980032t	journal	August 1999
Supramolecular Regulation of Anions Enhances Conductivity and Transference Number of Lithium in Liquid Electrolytes Qiao, Bo; Leverick, Graham M.; Zhao, Wei Journal of the American Chemical Society, Vol. 140, Issue 35 https://doi.org/10.1021/jacs.8b05915	journal	July 2018
Double-Layer in Ionic Liquids: Paradigm Change? Kornyshev, Alexei A. The Journal of Physical Chemistry B, Vol. 111, Issue 20 https://doi.org/10.1021/jp067857o	journal	May 2007
Computational and Experimental Investigation of Li-Doped Ionic Liquid Electrolytes: [pyr14][TFSI], [pyr13][FSI], and [EMIM][BF ₄ ] Haskins, Justin B.; Bennett, William R.; Wu, James J. The Journal of Physical Chemistry B, Vol. 118, Issue 38 https://doi.org/10.1021/jp5061705	journal	September 2014
Ionic Solutions in the Binding Mean Spherical Approximation: Thermodynamic Properties of Mixtures of Associating Electrolytes Simonin, Jean-Pierre; Bernard, Olivier; Blum, Lesser The Journal of Physical Chemistry B, Vol. 103, Issue 4 https://doi.org/10.1021/jp9833000	journal	January 1999
Microslips to “Avalanches” in Confined, Molecular Layers of Ionic Liquids Espinosa-Marzal, R. M.; Arcifa, A.; Rossi, A. The Journal of Physical Chemistry Letters, Vol. 5, Issue 1 https://doi.org/10.1021/jz402451v	journal	December 2013
Thermoreversible Gelation with Junctions of Variable Multiplicity Tanaka, Fumihiko; Stockmayer, Walter H. Macromolecules, Vol. 27, Issue 14 https://doi.org/10.1021/ma00092a039	journal	July 1994
Theory of thermoreversible gelation Tanaka, Fumihiko Macromolecules, Vol. 22, Issue 4 https://doi.org/10.1021/ma00194a077	journal	April 1989
Thermodynamic theory of network-forming polymer solutions. 1 Tanaka, Fumihiko Macromolecules, Vol. 23, Issue 16 https://doi.org/10.1021/ma00218a012	journal	August 1990
Theoretical Study of the Postgel Regime in Thermoreversible Gelation Ishida, Masahiko; Tanaka, Fumihiko Macromolecules, Vol. 30, Issue 13 https://doi.org/10.1021/ma960580d	journal	June 1997
Thermoreversible Gelation with Two-Component Networks Tanaka, Fumihiko; Ishida, Masahiko Macromolecules, Vol. 32, Issue 4 https://doi.org/10.1021/ma981279v	journal	January 1999
Ionic liquids and their solid-state analogues as materials for energy generation and storage MacFarlane, Douglas R.; Forsyth, Maria; Howlett, Patrick C. Nature Reviews Materials, Vol. 1, Issue 2 https://doi.org/10.1038/natrevmats.2015.5	journal	January 2016
Ionic-liquid materials for the electrochemical challenges of the future Armand, Michel; Endres, Frank; MacFarlane, Douglas R. Nature Materials, Vol. 8, Issue 8, p. 621-629 https://doi.org/10.1038/nmat2448	journal	July 2009
Energy applications of ionic liquids MacFarlane, Douglas R.; Tachikawa, Naoki; Forsyth, Maria Energy Environ. Sci., Vol. 7, Issue 1 https://doi.org/10.1039/C3EE42099J	journal	January 2014
Direct determination of ionic transference numbers in ionic liquids by electrophoretic NMR Gouverneur, Martin; Kopp, Jakob; van Wüllen, Leo Physical Chemistry Chemical Physics, Vol. 17, Issue 45 https://doi.org/10.1039/C5CP05753A	journal	January 2015
Elucidation of transport mechanism and enhanced alkali ion transference numbers in mixed alkali metal–organic ionic molten salts Chen, Fangfang; Forsyth, Maria Physical Chemistry Chemical Physics, Vol. 18, Issue 28 https://doi.org/10.1039/C6CP01411A	journal	January 2016
Negative effective Li transference numbers in Li salt/ionic liquid mixtures: does Li drift in the “Wrong” direction? Gouverneur, M.; Schmidt, F.; Schönhoff, M. Physical Chemistry Chemical Physics, Vol. 20, Issue 11 https://doi.org/10.1039/C7CP08580J	journal	January 2018
Advances in sodium secondary batteries utilizing ionic liquid electrolytes Matsumoto, Kazuhiko; Hwang, Jinkwang; Kaushik, Shubham Energy & Environmental Science, Vol. 12, Issue 11 https://doi.org/10.1039/C9EE02041A	journal	January 2019
Unified quantum theory of electrochemical kinetics by coupled ion–electron transfer Bazant, Martin Z. Faraday Discussions, Vol. 246, p. 60-124 https://doi.org/10.1039/D3FD00108C	journal	January 2023
The cluster theory for electrolyte solutions. Its extension and its limitations Laría, Daniel; Corti, Horacio R.; Fernández-Prini, Roberto J. Chem. Soc., Faraday Trans., Vol. 86, Issue 7 https://doi.org/10.1039/FT9908601051	journal	January 1990
Thermoreversible gelation of hydrated polymers Tanaka, Fumihiko; Ishida, Masahiko Journal of the Chemical Society, Faraday Transactions, Vol. 91, Issue 16 https://doi.org/10.1039/ft9959102663	journal	January 1995
Thermodynamics of High Polymer Solutions Flory, Paul J. The Journal of Chemical Physics, Vol. 10, Issue 1 https://doi.org/10.1063/1.1723621	journal	January 1942
Theory of Molecular Size Distribution and Gel Formation in Branched‐Chain Polymers Stockmayer, Walter H. The Journal of Chemical Physics, Vol. 11, Issue 2 https://doi.org/10.1063/1.1723803	journal	February 1943
Theory of Molecular Size Distribution and Gel Formation in Branched Polymers II. General Cross Linking Stockmayer, Walter H. The Journal of Chemical Physics, Vol. 12, Issue 4 https://doi.org/10.1063/1.1723922	journal	April 1944
Self-assembly of patchy particles into polymer chains: A parameter-free comparison between Wertheim theory and Monte Carlo simulation Sciortino, Francesco; Bianchi, Emanuela; Douglas, Jack F. The Journal of Chemical Physics, Vol. 126, Issue 19 https://doi.org/10.1063/1.2730797	journal	May 2007
Electrical double layer forces. A Monte Carlo study Guldbrand, Lars; Jönsson, Bo; Wennerström, Håkan The Journal of Chemical Physics, Vol. 80, Issue 5 https://doi.org/10.1063/1.446912	journal	March 1984
Theory of ion aggregation and gelation in super-concentrated electrolytes McEldrew, Michael; Goodwin, Zachary A. H.; Bi, Sheng The Journal of Chemical Physics, Vol. 152, Issue 23 https://doi.org/10.1063/5.0006197	journal	June 2020
Bayesian unsupervised learning reveals hidden structure in concentrated electrolytes Jones, Penelope; Coupette, Fabian; Härtel, Andreas The Journal of Chemical Physics, Vol. 154, Issue 13 https://doi.org/10.1063/5.0039617	journal	April 2021
Underscreening and hidden ion structures in large scale simulations of concentrated electrolytes Krucker-Velasquez, Emily; Swan, James W. The Journal of Chemical Physics, Vol. 155, Issue 13 https://doi.org/10.1063/5.0061230	journal	October 2021
Polar liquids at charged interfaces: A dipolar shell theory de Souza, J. Pedro; Kornyshev, Alexei A.; Bazant, Martin Z. The Journal of Chemical Physics, Vol. 156, Issue 24 https://doi.org/10.1063/5.0096439	journal	June 2022
Gelation, clustering, and crowding in the electrical double layer of ionic liquids Goodwin, Zachary A. H.; McEldrew, Michael; de Souza, J. Pedro The Journal of Chemical Physics, Vol. 157, Issue 9 https://doi.org/10.1063/5.0097055	journal	September 2022
Ionic liquids behave as dilute electrolyte solutions Gebbie, M. A.; Valtiner, M.; Banquy, X. Proceedings of the National Academy of Sciences, Vol. 110, Issue 24 https://doi.org/10.1073/pnas.1307871110	journal	May 2013
Long-range electrostatic screening in ionic liquids Gebbie, Matthew A.; Dobbs, Howard A.; Valtiner, Markus Proceedings of the National Academy of Sciences, Vol. 112, Issue 24 https://doi.org/10.1073/pnas.1508366112	journal	May 2015
Spatial variation of permittivity of an electrolyte solution in contact with a charged metal surface: a mini review Gongadze, E.; van Rienen, U.; Kralj-Iglič, V. Computer Methods in Biomechanics and Biomedical Engineering, Vol. 16, Issue 5 https://doi.org/10.1080/10255842.2011.624769	journal	May 2013
Theory of Cation Solvation and Ionic Association in Nonaqueous Solvent Mixtures Goodwin, Zachary A. H.; McEldrew, Michael; Kozinsky, Boris PRX Energy, Vol. 2, Issue 1 https://doi.org/10.1103/PRXEnergy.2.013007	journal	March 2023
Screening length for finite-size ions in concentrated electrolytes Adar, Ram M.; Safran, Samuel A.; Diamant, Haim Physical Review E, Vol. 100, Issue 4 https://doi.org/10.1103/PhysRevE.100.042615	journal	October 2019
Charge oscillations in ionic liquids: A microscopic cluster model Avni, Yael; Adar, Ram M.; Andelman, David Physical Review E, Vol. 101, Issue 1 https://doi.org/10.1103/PhysRevE.101.010601	journal	January 2020
Steric effects in the dynamics of electrolytes at large applied voltages. I. Double-layer charging Kilic, Mustafa Sabri; Bazant, Martin Z.; Ajdari, Armand Physical Review E, Vol. 75, Issue 2 https://doi.org/10.1103/PhysRevE.75.021502	journal	February 2007
Double Layer in Ionic Liquids: Overscreening versus Crowding Bazant, Martin Z.; Storey, Brian D.; Kornyshev, Alexei A. Physical Review Letters, Vol. 106, Issue 4 https://doi.org/10.1103/PhysRevLett.106.046102	journal	January 2011
Interfacial Layering in the Electric Double Layer of Ionic Liquids de Souza, J. Pedro; Goodwin, Zachary A. H.; McEldrew, Michael Physical Review Letters, Vol. 125, Issue 11 https://doi.org/10.1103/PhysRevLett.125.116001	journal	September 2020
Spin-glass charge ordering in ionic liquids Levy, Amir; McEldrew, Michael; Bazant, Martin Z. Physical Review Materials, Vol. 3, Issue 5 https://doi.org/10.1103/PhysRevMaterials.3.055606	journal	May 2019
Modeling of emergent memory and voltage spiking in ionic transport through angstrom-scale slits Robin, Paul; Kavokine, Nikita; Bocquet, Lydéric Science, Vol. 373, Issue 6555 https://doi.org/10.1126/science.abf7923	journal	August 2021
Ion Clusters and Networks in Water-in-Salt Electrolytes McEldrew, Michael; Goodwin, Zachary A. H.; Bi, Sheng Journal of The Electrochemical Society, Vol. 168, Issue 5 https://doi.org/10.1149/1945-7111/abf975	journal	May 2021
Solvate Ionic Liquid Electrolyte for Li–S Batteries Dokko, Kaoru; Tachikawa, Naoki; Yamauchi, Kento Journal of The Electrochemical Society, Vol. 160, Issue 8 https://doi.org/10.1149/2.111308jes	journal	January 2013
Theoretical Study of Molecular Association and Thermoreversible Gelation in Polymers Tanaka, Fumihiko Polymer Journal, Vol. 34, Issue 7 https://doi.org/10.1295/polymj.34.479	journal	July 2002

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