Prospective Application, Mechanism, and Deficiency of Lithium Bis(oxalate)Borate as the Electrolyte Additive for Lithium-Batteries

Li, Jianing; Yang, Jianzhong; Ji, Zhaoqi; Su, Min; Li, Huijing; Wu, Yanchao; Su, Xin; Zhang, Zhengcheng

doi:10.1002/aenm.202301422

Title: Prospective Application, Mechanism, and Deficiency of Lithium Bis(oxalate)Borate as the Electrolyte Additive for Lithium-Batteries

Journal Article · 30 July 2023 · Advanced Energy Materials

DOI: https://doi.org/10.1002/aenm.202301422 · OSTI ID:2429450

Li, Jianing ^[1]; Yang, Jianzhong ^[2]; Ji, Zhaoqi ^[1]; Su, Min ^[3]; Li, Huijing ^[1]; Wu, Yanchao ^[1];

^[1]; Zhang, Zhengcheng ^[4]

Harbin Institute of Technology, Weihai (China)
Shenzhen ORI Technology Company Limited (China)
Wanxiang A123 Systems Corp, Hangzhou (China)
Argonne National Laboratory (ANL), Argonne, IL (United States)

Lithium bis(oxalate)borate (LiBOB) is one of the most common film-forming electrolyte additives used in lithium ion batteries (LIBs), since it can form a dense boron-containing polymer as a solid electrolyte interlayer (or cathode electrolyte interlayer) in order to isolate the electrode material from the electrolyte and prevent side reactions. LiBOB can serve as HF scavenger to maintain the structural integrity of electrodes via avoiding the transition metal dissolution caused by HF attack. Additionally, LiBOB also can react with LiPF₆ to generate lithium difluoro (oxalate)borate (LiDFOB) that can be further used as a clean-up agent for reactive oxygen radicals. This article lists the application of LiBOB in high capacity and high voltage cathode materials, and also reviews the working mechanisms of LiBOB used in these materials to improve the performance of LIBs. Finally, it presents the current shortcomings of LiBOB and strategies to overcome these. This article is expected to provide useful insights for employing LiBOB as a feasible method of dealing with the difficulty of running high capacity LIBs stably under high voltage.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: Natural Science Foundation of Shandong Province; USDOE; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO); USDOE Office of Science (SC)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 2429450

Journal Information:: Advanced Energy Materials, Journal Name: Advanced Energy Materials Journal Issue: 35 Vol. 13; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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25 ENERGY STORAGE
additives
cathode electrolyte interphases
lithium bis(oxalate)borate
lithium-ion batteries
solid electrolyte interphases

Title: Prospective Application, Mechanism, and Deficiency of Lithium Bis(oxalate)Borate as the Electrolyte Additive for Lithium-Batteries

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