Electrochemical Imaging of Precisely‐Defined Redox and Reactive Interfaces

Edgecomb, Joseph; Nguyen, Dan Thien; Tan, Shuai; Murugesan, Vijayakumar; Johnson, Grant E.; Prabhakaran, Venkateshkumar

doi:10.1002/anie.202405846

Title: Electrochemical Imaging of Precisely‐Defined Redox and Reactive Interfaces

Journal Article · 02 August 2024 · Angewandte Chemie (International Edition)

DOI: https://doi.org/10.1002/anie.202405846 · OSTI ID:2429099

Edgecomb, Joseph ^[1]; Nguyen, Dan Thien ^[1]; Tan, Shuai ^[1]; Murugesan, Vijayakumar ^[1]; Johnson, Grant E. ^[1];

^[1]

Pacific Northwest National Laboratory Richland WA 99352 USA

Abstract Understanding the diverse electrochemical reactions occurring at electrode‐electrolyte interfaces (EEIs) is a critical challenge to developing more efficient energy conversion and storage technologies. Establishing a predictive molecular‐level understanding of solid electrolyte interphases (SEIs) is challenging due to the presence of multiple intertwined chemical and electrochemical processes occurring at battery electrodes. Similarly, chemical conversions in reactive electrochemical systems are often influenced by the heterogeneous distribution of active sites, surface defects, and catalyst particle sizes. In this mini review, we highlight an emerging field of interfacial science that isolates the impact of specific chemical species by preparing precisely‐defined EEIs and visualizing the reactivity of their individual components using single‐entity characterization techniques. We highlight the broad applicability and versatility of these methods, along with current state‐of‐the‐art instrumentation and future opportunities for these approaches to address key scientific challenges related to batteries, chemical separations, and fuel cells. We establish that controlled preparation of well‐defined electrodes combined with single entity characterization will be crucial to filling key knowledge gaps and advancing the theories used to describe and predict chemical and physical processes occurring at EEIs and accelerating new materials discovery for energy applications.

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Sponsoring Organization:: USDOE

OSTI ID:: 2429099

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 36 Vol. 63; ISSN 1433-7851

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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