Novel in-capsule synthesis of metal–organic framework for innovative carbon dioxide capture system

Yu, Wei; Gao, Ming; Rim, Guanhe; Feric, Tony G.; Rivers, Mark L.; Alahmed, Ammar; Jamal, Aqil; Alissa Park, Ah-Hyung

doi:10.1016/j.gee.2021.08.002

Title: Novel in-capsule synthesis of metal–organic framework for innovative carbon dioxide capture system

Journal Article · 24 August 2021 · Green Energy & Environment

DOI: https://doi.org/10.1016/j.gee.2021.08.002 · OSTI ID:2419434

^[1];

^[2]; Rim, Guanhe ^[2]; Feric, Tony G. ^[2]; Rivers, Mark L. ^[3]; Alahmed, Ammar ^[4]; Jamal, Aqil ^[4];

^[2]

Zhejiang Univ., Hangzhou (China); Columbia Univ., New York, NY (United States); OSTI
Columbia Univ., New York, NY (United States)
Univ. of Chicago, IL (United States)
Saudi Aramco, Dhahran (Saudi Arabia)

Metal-Organic Frameworks (MOFs) have been developed as solid sorbents for CO2 capture applications and their properties can be controlled by tuning the chemical blocks of their crystalline units. A number of MOFs (e.g., HKUST-1) have been developed but the question remains how to deploy them for gas–solid contact. Unfortunately, the direct use of MOFs as nanocrystals would lead to serious problems and risks. Here, for the first time, we report a novel MOF-based hybrid sorbent that is produced via an innovative in-situ microencapsulated synthesis. Using a custom-made double capillary microfluidic assembly, double emulsions of the MOF precursor solutions and UV-curable silicone shell fluid are produced. Subsequently, HKUST-1 MOF is successfully synthesized within the droplets enclosed in the gas permeable microcapsules. The developed MOF-bearing microcapsules uniquely allow the deployment of functional nanocrystals without the challenge of handling ultrafine particles, and further, can selectively reject undesired compounds to protect encapsulated MOFs.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); Univ. of Chicago, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC)

Grant/Contract Number:: AC02-06CH11357; FG02-94ER14466

OSTI ID:: 2419434

Journal Information:: Green Energy & Environment, Journal Name: Green Energy & Environment Journal Issue: 3 Vol. 8; ISSN 2468-0257

Publisher:: Elsevier - Institute of Process Engineering, Chinese Academy of SciencesCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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Title: Novel in-capsule synthesis of metal–organic framework for innovative carbon dioxide capture system

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