Systematic Study of Solid-State U(VI) Photoreactivity: Long-Lived Radicalization and Electron Transfer in Uranyl Tetrachloride

Herder, Jordan A.; Kruse, Samantha J.; Nicholas, Aaron D.; Forbes, Tori Z.; Walter, Eric D.; Cho, Herman; Cahill, Christopher L.

doi:10.1021/acs.inorgchem.3c04144

Title: Systematic Study of Solid-State U(VI) Photoreactivity: Long-Lived Radicalization and Electron Transfer in Uranyl Tetrachloride

Journal Article · 03 March 2024 · Inorganic Chemistry

DOI: https://doi.org/10.1021/acs.inorgchem.3c04144 · OSTI ID:2377132

^[1]; Kruse, Samantha J. ^[2];

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George Washington Univ., Washington, DC (United States)
Univ. of Iowa, Iowa City, IA (United States)
George Washington Univ., Washington, DC (United States); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Reported are the syntheses, structural characterizations and luminescence properties of three novel [UO₂Cl₄]^2- bearing compounds containing substituted 1,1’-dialkyl-4,4’-bipyridinum dications (i.e. viologens). These compounds undergo photoinduced luminescence quenching upon exposure to UV radiation. Further, this reactivity is concurrent with two phenomena: radicalization of the uranyl tetrachloride anion and photoelectron transfer to the viologen which constitutes the formal transfer of one electron from the [UO₂Cl₄]^2- to the viologen species. This behavior is elucidated using electron paramagnetic resonance (EPR) spectroscopy and further probed through a series of characterization and computational techniques including Rehm-Weller analysis, time-dependent density functional theory (TD-DFT), and density of states (DOS). This work provides a systematic study of the photoreactivity of the uranyl unit in the solid state, an under-described aspect of fundamental uranyl chemistry.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)

Grant/Contract Number:: AC05-76RL01830; FG02-05ER15736

OSTI ID:: 2377132

Report Number(s):: PNNL-SA--192035

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 11 Vol. 63; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (69)

Photochromism of a Methyl Viologen Bismuth(III) Chloride: Structural Variation Before and After UV Irradiation Xu, Gang; Guo, Guo‐Cong; Wang, Ming‐Sheng Angewandte Chemie, Vol. 119, Issue 18 https://doi.org/10.1002/ange.200700122	journal	April 2007
The Uranyl Cation as a Visible-Light Photocatalyst for C(sp ³ )−H Fluorination West, Julian G.; Bedell, T. Aaron; Sorensen, Erik J. Angewandte Chemie, Vol. 128, Issue 31 https://doi.org/10.1002/ange.201603149	journal	June 2016
Highly Sensitive Detection of Ionizing Radiations by a Photoluminescent Uranyl Organic Framework Xie, Jian; Wang, Yaxing; Liu, Wei Angewandte Chemie, Vol. 129, Issue 26 https://doi.org/10.1002/ange.201700919	journal	May 2017
Photokatalyse der C(sp³)‐H‐Fluorierung durch Uranyl mit sichtbarem Licht: Einblicke in den Mechanismus Wu, Liangliang; Cao, Xiaoyan; Chen, Xuebo Angewandte Chemie, Vol. 130, Issue 36 https://doi.org/10.1002/ange.201806554	journal	August 2018
Emergence of Uranium as a Distinct Metal Center for Building Intrinsic X-ray Scintillators Wang, Yaxing; Yin, Xuemiao; Liu, Wei Angewandte Chemie International Edition, Vol. 57, Issue 26 https://doi.org/10.1002/anie.201802865	journal	April 2018
Novel Viologen Derivative Based Uranyl Coordination Polymers Featuring Photochromic Behaviors Hu, Kong-Qiu; Wu, Qun-Yan; Mei, Lei Chemistry - A European Journal, Vol. 23, Issue 71 https://doi.org/10.1002/chem.201704478	journal	December 2017
Atomistic‐Level Effects of Noncovalent Interactions and Crystalline Packing for Organic Material Structural Integrity upon Exposure to Gamma Radiation Kruse, Samantha J.; Rajapaksha, Harindu; MacGillivray, Leonard R. Chemistry – A European Journal, Vol. 29, Issue 64 https://doi.org/10.1002/chem.202302653	journal	October 2023
Charge-Assisted Hydrogen-Bonding and Crystallization Effects within U ^VI Glycine Compounds : Charge-Assisted Hydrogen-Bonding and Crystallization Effects within U de Groot, Joshua; Cassell, Brittany; Basile, Madeline European Journal of Inorganic Chemistry, Vol. 2017, Issue 13 https://doi.org/10.1002/ejic.201700024	journal	April 2017
Kinetics of Fluorescence Quenching by Electron and H-Atom Transfer Rehm, Dieter; Weller, Albert Israel Journal of Chemistry, Vol. 8, Issue 2 https://doi.org/10.1002/ijch.197000029	journal	January 1970
Multiwfn: A multifunctional wavefunction analyzer Lu, Tian; Chen, Feiwu Journal of Computational Chemistry, Vol. 33, Issue 5 https://doi.org/10.1002/jcc.22885	journal	December 2011
A Multi‐Responsive Cd–Viologen Complex: Photochromism, Photomodulated Fluorescence, and Luminescent Sensing Qiu, Xing‐Tai; Shi, Qing; Zhang, De‐Quan ChemistrySelect, Vol. 3, Issue 23 https://doi.org/10.1002/slct.201801005	journal	June 2018
Resonance Raman of viologen radicals Lee, P. C.; Schmidt, K.; Gordon, S. Chemical Physics Letters, Vol. 80, Issue 2 https://doi.org/10.1016/0009-2614(81)80101-7	journal	June 1981
Electron transfer mechanism in quenching of uranyl luminescence by halide ions Yokoyama, Yu; Moriyasu, Masataka; Ikeda, Shigero Journal of Inorganic and Nuclear Chemistry, Vol. 38, Issue 7 https://doi.org/10.1016/0022-1902(76)80145-5	journal	January 1976
Detection and identification of solids, surfaces, and solutions of uranium using vibrational spectroscopy Lu, Grace; Haes, Amanda J.; Forbes, Tori Z. Coordination Chemistry Reviews, Vol. 374 https://doi.org/10.1016/j.ccr.2018.07.010	journal	November 2018
Self-assembly of [UO2X4]2− (X=Cl, Br) dianions with γ substituted pyridinium cations: Structural systematics and fluorescence properties Surbella, Robert G.; Andrews, Michael B.; Cahill, Christopher L. Journal of Solid State Chemistry, Vol. 236 https://doi.org/10.1016/j.jssc.2015.09.011	journal	April 2016
Live spectroscopy to observe electrochromism in viologen based solid state device Mishra, Suryakant; Pandey, Haardik; Yogi, Priyanka Solid State Communications, Vol. 261 https://doi.org/10.1016/j.ssc.2017.05.020	journal	August 2017
Segmented contraction scheme for small-core actinide pseudopotential basis sets Cao, Xiaoyan; Dolg, Michael Journal of Molecular Structure: THEOCHEM, Vol. 673, Issue 1-3 https://doi.org/10.1016/j.theochem.2003.12.015	journal	March 2004
Spectroelectrochemical evaluation of homogeneous electron transfer involving biological molecules Ryan, Michael D.; Wilson, George S. Analytical Chemistry, Vol. 47, Issue 6 https://doi.org/10.1021/ac60356a045	journal	May 1975
Photochromic Properties of a Series of Zinc(II)–Viologen Complexes with Structural Regulation by Anions Li, Hai-Yang; Xu, Jing; Li, Lin-Ke Crystal Growth & Design, Vol. 17, Issue 12 https://doi.org/10.1021/acs.cgd.7b00995	journal	November 2017
Thermal and Photochemical Reduction and Functionalization Chemistry of the Uranyl Dication, [U ^VI O ₂ ] ²⁺ Cowie, Bradley E.; Purkis, Jamie M.; Austin, Jonathan Chemical Reviews, Vol. 119, Issue 18 https://doi.org/10.1021/acs.chemrev.9b00048	journal	August 2019
Stabilization of Photocatalytically Active Uranyl Species in a Uranyl–Organic Framework for Heterogeneous Alkane Fluorination Driven by Visible Light Zhang, Xuan; Li, Peng; Krzyaniak, Matthew Inorganic Chemistry, Vol. 59, Issue 23 https://doi.org/10.1021/acs.inorgchem.0c00850	journal	June 2020
How Does Bending the Uranyl Unit Influence Its Spectroscopy and Luminescence? Oher, Hanna; Gomes, André Severo Pereira; Wilson, Richard E. Inorganic Chemistry, Vol. 62, Issue 24 https://doi.org/10.1021/acs.inorgchem.3c00847	journal	June 2023
Photochromic Uranyl-Based Coordination Polymer for Quantitative and On-Site Detection of UV Radiation Dose Xie, Jian; Hou, Huiliang; Lu, Huangjie Inorganic Chemistry, Vol. 62, Issue 39 https://doi.org/10.1021/acs.inorgchem.3c00972	journal	September 2023
Structural Diversity of Bipyridinium-Based Uranyl Coordination Polymers: Synthesis, Characterization, and Ion-Exchange Application Zeng, Li-Wen; Hu, Kong-Qiu; Mei, Lei Inorganic Chemistry, Vol. 58, Issue 20 https://doi.org/10.1021/acs.inorgchem.9b02106	journal	October 2019
Investigation of the Luminescence of [UO ₂ X ₄ ] ^2– (X = Cl, Br) Complexes in the Organic Phase Using Time-Resolved Laser-Induced Fluorescence Spectroscopy and Quantum Chemical Simulations Oher, Hanna; Réal, Florent; Vercouter, Thomas Inorganic Chemistry, Vol. 59, Issue 9 https://doi.org/10.1021/acs.inorgchem.9b03614	journal	April 2020
Highly Sensitive Detection of UV Radiation Using a Uranium Coordination Polymer Liu, Wei; Dai, Xing; Xie, Jian ACS Applied Materials & Interfaces, Vol. 10, Issue 5 https://doi.org/10.1021/acsami.7b17954	journal	January 2018
Introducing Stable Radicals into Molecular Machines Wang, Yuping; Frasconi, Marco; Stoddart, J. Fraser ACS Central Science, Vol. 3, Issue 9 https://doi.org/10.1021/acscentsci.7b00219	journal	August 2017
Extended Structures and Physicochemical Properties of Uranyl–Organic Compounds Wang, Kai-Xue; Chen, Jie-Sheng Accounts of Chemical Research, Vol. 44, Issue 7 https://doi.org/10.1021/ar200042t	journal	July 2011
Incorporating Guest Molecules into Honeycomb Structures Constructed from Uranium(VI)-Polycarboxylates: Structural Diversities and Photocatalytic Activities for the Degradation of Organic Dye Li, Hao-Hong; Zeng, Xian-Hua; Wu, Hong-Yan Crystal Growth & Design, Vol. 15, Issue 1 https://doi.org/10.1021/cg501252x	journal	December 2014
Uranium(VI)-Catalyzed Photooxidation of Hydrocarbons with Molecular Oxygen Wang, Wei-Dong; Bakac, Andreja; Espenson, James H. Inorganic Chemistry, Vol. 34, Issue 24 https://doi.org/10.1021/ic00128a014	journal	November 1995
Mesoporous Silica-Supported Uranyl: Synthesis and Photoreactivity Nieweg, Jennifer A.; Lemma, Kelemu; Trewyn, Brian G. Inorganic Chemistry, Vol. 44, Issue 16 https://doi.org/10.1021/ic050130e	journal	August 2005
Uranyl-Promoted Peroxide Generation: Synthesis and Characterization of Three Uranyl Peroxo [(UO ₂ ) ₂ (O ₂ )] Complexes Thangavelu, Sonia G.; Cahill, Christopher L. Inorganic Chemistry, Vol. 54, Issue 9 https://doi.org/10.1021/ic502767k	journal	April 2015
Kinetics of hydrogen production from methyl viologen radicals on colloidal platinum Matheson, M. S.; Lee, P. C.; Meisel, D. The Journal of Physical Chemistry, Vol. 87, Issue 3 https://doi.org/10.1021/j100226a008	journal	February 1983
Kinetics of reduction of eight viologens by dithionite ion Tsukahara, K.; Wilkins, R. G. Journal of the American Chemical Society, Vol. 107, Issue 9 https://doi.org/10.1021/ja00295a013	journal	May 1985
The Photochemistry of Uranyl Oxalate Volman, D. H.; Seed, J. R. Journal of the American Chemical Society, Vol. 86, Issue 23 https://doi.org/10.1021/ja01077a010	journal	December 1964
Spatially Resolved Raman Spectroelectrochemistry of Solid-State Polythiophene/Viologen Memory Devices Kumar, Rajesh; Pillai, Rajesh G.; Pekas, Nikola Journal of the American Chemical Society, Vol. 134, Issue 36 https://doi.org/10.1021/ja304458s	journal	September 2012
Electronic Structure and Bonding in Actinyl Ions and their Analogs Denning, Robert G. The Journal of Physical Chemistry A, Vol. 111, Issue 20 https://doi.org/10.1021/jp071061n	journal	May 2007
Dimerized π-Complexes in Self-Assembled Monolayers Containing Viologens: An Origin of Unusual Wave Shapes in the Voltammetry of Monolayers Tang, Xiaoyan; Schneider, Thomas W.; Walker, James W. Langmuir, Vol. 12, Issue 24 https://doi.org/10.1021/la9503764	journal	January 1996
Utilizing hydrogen bonds and halogen–halogen interactions in the design of uranyl hybrid materials Andrews, Michael B.; Cahill, Christopher L. Dalton Trans., Vol. 41, Issue 14 https://doi.org/10.1039/C2DT11985D	journal	January 2012
A new methylviologen-templated zinc gallophosphate zeolite with photo-/thermochromism, fluorescent and photoelectric properties Tao, Chunyao; Wu, Junbiao; Yan, Yan Inorganic Chemistry Frontiers, Vol. 3, Issue 4 https://doi.org/10.1039/C5QI00283D	journal	January 2016
An inorganic–organic hybrid photochromic material with fast response to hard and soft X-rays at room temperature Guo, Pei-Yu; Sun, Cai; Zhang, Ning-Ning Chemical Communications, Vol. 54, Issue 36 https://doi.org/10.1039/C8CC00694F	journal	January 2018
Probing hydrogen and halogen-oxo interactions in uranyl coordination polymers: a combined crystallographic and computational study Carter, Korey P.; Kalaj, Mark; Kerridge, Andrew CrystEngComm, Vol. 20, Issue 34 https://doi.org/10.1039/C8CE00682B	journal	January 2018
Photochromic and photomodulated luminescence properties of two metal–viologen complexes constructed by a tetracarboxylate-anchored bipyridinium-based ligand Li, Lin-Ke; Li, Hai-Yang; Li, Ting CrystEngComm, Vol. 20, Issue 41 https://doi.org/10.1039/C8CE01335G	journal	January 2018
Photochromism and photomagnetism in three cyano-bridged 3d–4f heterobimetallic viologen frameworks Li, Meng-Hua; You, Ming-Hua; Lin, Mei-Jin Dalton Transactions, Vol. 50, Issue 14 https://doi.org/10.1039/D0DT04358C	journal	January 2021
Photochromic and photocontrolled luminescent rare-earth D–A hybrid crystals based on rigid viologen acceptors Wang, Yi-Wen; Li, Meng-Hua; Zhang, Shu-Quan CrystEngComm, Vol. 23, Issue 36 https://doi.org/10.1039/D1CE00789K	journal	January 2021
Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy Weigend, Florian; Ahlrichs, Reinhart Physical Chemistry Chemical Physics, Vol. 7, Issue 18, p. 3297-3305 https://doi.org/10.1039/b508541a	journal	January 2005
Lone pair–π interactions: a new supramolecular bond? Mooibroek, Tiddo J.; Gamez, Patrick; Reedijk, Jan CrystEngComm, Vol. 10, Issue 11 https://doi.org/10.1039/b812026a	journal	January 2008
The uranyl tetrachloride anion as a tecton in the assembly of U(VI) hybrid materials Deifel, Nicholas P.; Cahill, Christopher L. CrystEngComm, Vol. 11, Issue 12 https://doi.org/10.1039/b911470j	journal	January 2009
Probing the local coordination environment and nuclearity of uranyl(vi) complexes in non-aqueous media by emission spectroscopy Redmond, Michael P.; Cornet, Stephanie M.; Woodall, Sean D. Dalton Transactions, Vol. 40, Issue 15 https://doi.org/10.1039/c0dt01464h	journal	January 2011
Absorption spectrum and reaction kinetics of the photoreactive state of the uranyl ion Allen, David M.; Burrows, Hugh D.; Cox, Alan Journal of the Chemical Society, Chemical Communications, Issue 2 https://doi.org/10.1039/c39730000059	journal	January 1973
The self-assembly of a highly ordered [2]catenane Ashton, Peter R.; Brown, Christopher L.; Chrystal, Ewan J. T. Journal of the Chemical Society, Chemical Communications, Issue 9 https://doi.org/10.1039/c39910000634	journal	January 1991
Absorption spectrum, lifetime and photoreactivity towards alcohols of the excited state of the aqueous uranyl ion (UO2+2) Hill, Richard J.; Kemp, Terence J.; Allen, David M. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 70, Issue 0 https://doi.org/10.1039/f19747000847	journal	January 1974
Vibrational study of the methyl viologen dication MV2+ and radical cation MV˙+ in several salts and as an intercalate in some layered MPS3 compounds Poizat, Olivier; Sourisseau, Claude; Mathey, Yves Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 80, Issue 12 https://doi.org/10.1039/f19848003257	journal	January 1984
Valence basis sets for relativistic energy-consistent small-core actinide pseudopotentials Cao, Xiaoyan; Dolg, Michael; Stoll, Hermann The Journal of Chemical Physics, Vol. 118, Issue 2 https://doi.org/10.1063/1.1521431	journal	January 2003
Assessment and validation of a screened Coulomb hybrid density functional Heyd, Jochen; Scuseria, Gustavo E. The Journal of Chemical Physics, Vol. 120, Issue 16 https://doi.org/10.1063/1.1668634	journal	April 2004
Efficient hybrid density functional calculations in solids: Assessment of the Heyd–Scuseria–Ernzerhof screened Coulomb hybrid functional Heyd, Jochen; Scuseria, Gustavo E. The Journal of Chemical Physics, Vol. 121, Issue 3, p. 1187-1192 https://doi.org/10.1063/1.1760074	journal	July 2004
Energy band gaps and lattice parameters evaluated with the Heyd-Scuseria-Ernzerhof screened hybrid functional Heyd, Jochen; Peralta, Juan E.; Scuseria, Gustavo E. The Journal of Chemical Physics, Vol. 123, Issue 17 https://doi.org/10.1063/1.2085170	journal	November 2005
Efficient evaluation of short-range Hartree-Fock exchange in large molecules and periodic systems Izmaylov, Artur F.; Scuseria, Gustavo E.; Frisch, Michael J. The Journal of Chemical Physics, Vol. 125, Issue 10 https://doi.org/10.1063/1.2347713	journal	September 2006
Influence of the exchange screening parameter on the performance of screened hybrid functionals Krukau, Aliaksandr V.; Vydrov, Oleg A.; Izmaylov, Artur F. The Journal of Chemical Physics, Vol. 125, Issue 22 https://doi.org/10.1063/1.2404663	journal	December 2006
Can short-range hybrids describe long-range-dependent properties? Henderson, Thomas M.; Izmaylov, Artur F.; Scalmani, Giovanni The Journal of Chemical Physics, Vol. 131, Issue 4 https://doi.org/10.1063/1.3185673	journal	July 2009
Self‐consistent molecular orbital methods. XX. A basis set for correlated wave functions Krishnan, R.; Binkley, J. S.; Seeger, R. The Journal of Chemical Physics, Vol. 72, Issue 1 https://doi.org/10.1063/1.438955	journal	January 1980
Density‐functional thermochemistry. III. The role of exact exchange Becke, Axel D. The Journal of Chemical Physics, Vol. 98, Issue 7, p. 5648-5652 https://doi.org/10.1063/1.464913	journal	April 1993
Energy‐adjusted pseudopotentials for the actinides. Parameter sets and test calculations for thorium and thorium monoxide Küchle, W.; Dolg, M.; Stoll, H. The Journal of Chemical Physics, Vol. 100, Issue 10 https://doi.org/10.1063/1.466847	journal	May 1994
Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density Lee, Chengteh; Yang, Weitao; Parr, Robert G. Physical Review B, Vol. 37, Issue 2 https://doi.org/10.1103/PhysRevB.37.785	journal	January 1988
ShelXle : a Qt graphical user interface for SHELXL Hübschle, Christian B.; Sheldrick, George M.; Dittrich, Birger Journal of Applied Crystallography, Vol. 44, Issue 6 https://doi.org/10.1107/S0021889811043202	journal	November 2011
N,N'-Diethyl-4,4'-bipyridinium diiodide Eckert, N. A.; Krause Bauer, J. A.; Connick, W. B. Acta Crystallographica Section C Crystal Structure Communications, Vol. 55, Issue 9 https://doi.org/10.1107/S0108270199098844	journal	September 1999
A short history of SHELX Sheldrick, George M. Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122 https://doi.org/10.1107/S0108767307043930	journal	December 2007
Cyclic Voltammetry and In Situ Laser Raman Spectroscopy Studies of Electrogenerated Methyl Viologen Radical Cation Melendres, C. A. Journal of The Electrochemical Society, Vol. 130, Issue 7 https://doi.org/10.1149/1.2120024	journal	January 1983
Avogadro: an advanced semantic chemical editor, visualization, and analysis platform Hanwell, Marcus D.; Curtis, Donald E.; Lonie, David C. Journal of Cheminformatics, Vol. 4, Issue 1 https://doi.org/10.1186/1758-2946-4-17	journal	August 2012

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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CCDC 2118266: Experimental Crystal Structure Determination A., Herder, Jordan; J., Kruse, Samantha; D., Nicholas, Aaron https://doi.org/10.5517/ccdc.csd.cc29375v The current record is supplemented by this dataset	dataset	January 2024
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Title: Systematic Study of Solid-State U(VI) Photoreactivity: Long-Lived Radicalization and Electron Transfer in Uranyl Tetrachloride

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