Design Strategies of Spinel Oxide Frameworks Enabling Reversible Mg-Ion Intercalation

Kwon, Bob Jin; Lapidus, Saul H.; Vaughey, John T.; Ceder, Gerbrand; Cabana, Jordi; Key, Baris

doi:10.1021/acs.accounts.3c00282

Title: Design Strategies of Spinel Oxide Frameworks Enabling Reversible Mg-Ion Intercalation

Journal Article · 19 December 2023 · Accounts of Chemical Research

DOI: https://doi.org/10.1021/acs.accounts.3c00282 · OSTI ID:2375859

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Argonne National Laboratory (ANL), Argonne, IL (United States)
Univ. of California, Berkeley, CA (United States)
Univ. of Illinois, Chicago, IL (United States)

In this study, reversible Mg²⁺ intercalation in metal oxides frameworks is a key enabler for an operational Mg ion battery with high energy density needed for the next generation of energy storage technologies. While functional Mg-ion batteries have been achieved in structures with soft anions (e.g., S^2- and Se^2-), they do not meet energy density requirements to compete with the current rechargeable lithium-ion batteries due to their low insertion potentials, emphasizing the necessity of finding an oxide-based cathode that operates at high potentials. A leading hypothesis to explain the limited availability of oxide Mg-ion cathodes is the belief that Mg²⁺ has sluggish diffusion kinetics in oxides due to strong electrostatic interactions between the Mg²⁺ ions and oxide anions in the lattice. From this assessment, it can be hypothesized that such rate limiting kinetic shortcomings can be mitigated by tailoring an oxide framework through creating less stable Mg²⁺ - O^2- coordination.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Joint Center for Energy Storage Research (JCESR)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 2375859

Journal Information:: Accounts of Chemical Research, Journal Name: Accounts of Chemical Research Journal Issue: 1 Vol. 57; ISSN 0001-4842

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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