Resilience of the Aurivillius structure upon La and Cr doping in a Bi5Ti3FeO15 multiferroic

Salas, Omar Alejandro; Getahun, Yohannes W.; Mandujano, H. Cein; Manciu, Felicia; Castellanos, Mariana; Lopez, Jorge; Garza Hernández, Raquel; Buturlim, Volodymir B.; Gofryk, Krzysztof; Bairwa, Dhanpal; Elizabeth, Suja; Nair, Harikrishnan S.

doi:10.1039/d4dt00159a

Title: Resilience of the Aurivillius structure upon La and Cr doping in a Bi₅Ti₃FeO₁₅ multiferroic

Journal Article · 05 March 2024 · Dalton Transactions

DOI: https://doi.org/10.1039/d4dt00159a · OSTI ID:2371626

Salas, Omar Alejandro ^[1]; Getahun, Yohannes W. ^[1];

^[2];

^[1]; Castellanos, Mariana ^[1];

^[1];

^[3]; Buturlim, Volodymir B. ^[4];

^[4];

^[5];

^[1]

Univ. of Texas at El Paso, TX (United States)
Univ. of Maryland, College Park, MD (United States)
Centro de Investigaciones en Óptica A.C., León (Mexico)
Idaho National Laboratory (INL), Idaho Falls, ID (United States)
India Institute of Science, Bangalore (India)

Here, combining the experimental techniques of high-resolution X-ray diffraction, magnetometry, specific heat measurement, and X-ray photoelectron, Raman and dielectric spectroscopy techniques, we have studied the influence of La and Cr doping on the crystal structure and magnetism of the room temperature Aurivillius multiferroic Bi₅Ti₃FeO₁₅ by investigating the physical properties of (Bi₄La)Ti₃FeO₁₅ and Bi₅Ti₃ (Fe_0.5Cr_0.5)O₁₅. The parent (Bi₅Ti₃FeO₁₅) and the doped ((Bi₄La)Ti₃FeO₁₅ and Bi₅Ti₃(Fe_0.5Cr_0.5)O₁₅) compounds crystallize in the A2₁am space group, which is confirmed through our analysis of high-resolution synchrotron X-ray diffraction data obtained on phase-pure polycrystalline powders. We determined the oxidation states of the metal atoms in the studied compounds as Fe³⁺, Ti⁴⁺, Cr³⁺, and La³⁺ through the analysis of X-ray photoelectron spectroscopy data. The magnetic susceptibilities of the three compounds are marked by the absence of a long-range ordered ground state, but dominated by superparamagnetic clusters with dominant antiferromagnetic interactions. This signature of short-range magnetism is also seen in specific heat as a low temperature enhancement which is suppressed upon the application of external magnetic fields up to 8 T. Our dielectric spectroscopy experiments showed that the three studied compounds display similar features in the dielectric constant measured as a function of frequency. However, upon doping La at the Bi site, the width of the ferroelectric hysteresis loop increases for (Bi₄La)Ti₃FeO₁₅ compared to that of the parent compound Bi₅Ti₃FeO₁₅, and with Cr doping, Bi₅Ti₃(Fe_0.5Cr_0.5)O₁₅ becomes a leaky dielectric. The resilience of the Aurivillius crystal structure towards doping of La at the Bi site and Cr at the Fe site is clearly seen in the bulk properties of magnetic susceptibility, specific heat and the average crystal structure. The relevance of changes in the local structure is evident from our Raman spectroscopy and X-ray pair distribution function studies.

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Research Organization:: Idaho National Laboratory (INL), Idaho Falls, ID (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE); USDOE Laboratory Directed Research and Development (LDRD) Program

Grant/Contract Number:: AC07-05ID14517

OSTI ID:: 2371626

Report Number(s):: INL/JOU--24-78057-Rev000

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 14 Vol. 53; ISSN 1477-9226

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (74)

Fatigue‐Free Aurivillius Phase Ferroelectric Thin Films with Ultrahigh Energy Storage Performance Pan, Zhongbin; Wang, Peng; Hou, Xu Advanced Energy Materials https://doi.org/10.1002/aenm.202001536	journal	June 2020
Near‐Room‐Temperature Large Electrocaloric Effect in Barium Titanate Single Crystal Based on the Electric Field–Temperature Phase Diagram Li, Junjie; Li, Zhonghua; He, Jingjin physica status solidi (RRL) – Rapid Research Letters, Vol. 15, Issue 8 https://doi.org/10.1002/pssr.202100251	journal	July 2021
Structural Behavior of the Four-Layer Aurivillius-Phase Ferroelectrics SrBi4Ti4O15 and Bi5Ti3FeO15 Hervoches, Charles H.; Snedden, Alan; Riggs, Richard Journal of Solid State Chemistry, Vol. 164, Issue 2 https://doi.org/10.1006/jssc.2001.9473	journal	March 2002
Influence of different synthesizing steps on the multiferroic properties of Bi5Fe1Ti3O15 and Bi5Fe0.5Co0.5Ti3O15 ceramics Mao, Xiangyu; Wang, Wei; Sun, Hui Journal of Materials Science, Vol. 47, Issue 6 https://doi.org/10.1007/s10853-011-6129-9	journal	November 2011
Crystallisation process of Bi5Ti3FeO15 multiferroic nanoparticles synthesised by a sol–gel method Zhang, Hongjun; Ke, Hua; Ying, Pengzhan Journal of Sol-Gel Science and Technology, Vol. 85, Issue 1 https://doi.org/10.1007/s10971-017-4530-9	journal	October 2017
Raman spectra of titanium dioxide Balachandran, U.; Eror, N. G. Journal of Solid State Chemistry, Vol. 42, Issue 3 https://doi.org/10.1016/0022-4596(82)90006-8	journal	May 1982
Dielectric and magnetoelectric properties of Bi5FeTi3O15 Singh, R. S.; Bhimasankaram, T.; Kumar, G. S. Solid State Communications, Vol. 91, Issue 7 https://doi.org/10.1016/0038-1098(94)90376-X	journal	August 1994
Vibrational spectra of crystals with the A-type rare earth oxide structure—I. La2O3 and Nd2O3 Boldish, Steven I.; White, William B. Spectrochimica Acta Part A: Molecular Spectroscopy, Vol. 35, Issue 11 https://doi.org/10.1016/0584-8539(79)80204-4	journal	January 1979
Investigation of dielectric and magnetic nature of Bi7Fe3Ti3O21 Srinivas, A.; Kumar, M. Mahesh; Suryanarayana, S. V. Materials Research Bulletin, Vol. 34, Issue 6 https://doi.org/10.1016/S0025-5408(99)00093-8	journal	April 1999
Electrocaloric effect in lead-free Aurivillius relaxor ferroelectric ceramics Axelsson, Anna-Karin; Le Goupil, Florian; Valant, Matjaz Acta Materialia, Vol. 124 https://doi.org/10.1016/j.actamat.2016.11.001	journal	February 2017
Magnetic, dielectric and optical properties of five-layered Aurivillius phase Bi6Fe2Ti3O18-based ceramics Zuo, Xuzhong; He, Enjie; Bai, Jin Current Applied Physics, Vol. 19, Issue 12 https://doi.org/10.1016/j.cap.2019.09.007	journal	December 2019
Room temperature multiferroic properties of Ni-doped Aurivillus phase Bi5Ti3FeO15 Chen, Xiaoqin; Xiao, Jun; Xue, Yun Ceramics International, Vol. 40, Issue 2 https://doi.org/10.1016/j.ceramint.2013.10.063	journal	March 2014
Magnetic properties and magnetoelectric coupling enhancement in Bi5Ti3FeO15 ceramics Pikula, T.; Dzik, J.; Guzdek, P. Ceramics International, Vol. 43, Issue 14 https://doi.org/10.1016/j.ceramint.2017.06.008	journal	October 2017
Enhancement of multiferroic properties of Aurivillius Bi5Ti3FeO15 ceramics by Co doping Yu, Zhonghui; Yu, Boyuan; Liu, Ying Ceramics International, Vol. 43, Issue 17 https://doi.org/10.1016/j.ceramint.2017.08.022	journal	December 2017
Enhanced multiferroicity and narrow band gap in B-site Co-doped Aurivillius Bi5FeTi3O15 Zuo, Xuzhong; Zhu, Shunjin; Bai, Jin Ceramics International, Vol. 45, Issue 1 https://doi.org/10.1016/j.ceramint.2018.09.144	journal	January 2019
Enhanced piezoelectricity and excellent thermal stabilities in Nb–Mg co-doped CaBi4Ti4O15 Aurivillius high Curie temperature ceramics Li, Lili; Yuan, Hongbin; Huang, Peiming Ceramics International, Vol. 46, Issue 2 https://doi.org/10.1016/j.ceramint.2019.09.202	journal	February 2020
Pressure-induced structural phase transitions in the multiferroic four-layer Aurivillius ceramic Bi5FeTi3O15 Ferreira, Wellington Castro; Rodrigues, Gelson Luiz Clemente; Araújo, Bruno Sousa Ceramics International, Vol. 46, Issue 11 https://doi.org/10.1016/j.ceramint.2020.04.122	journal	August 2020
Lead-free and flexible piezoelectric nanogenerator based on CaBi4Ti4O15 Aurivillius oxides/ PDMS composites for efficient biomechanical energy harvesting Hajra, Sugato; Sahu, Manisha; Oh, Dongik Ceramics International, Vol. 47, Issue 11 https://doi.org/10.1016/j.ceramint.2021.02.140	journal	June 2021
Pair distribution function analysis driven by atomistic simulations: Application to microwave radiation synthesized TiO2 and ZrO2 Zhang, Shuyan; Gong, Jie; Xiao, Daniel Z. Computational Materials Science, Vol. 218 https://doi.org/10.1016/j.commatsci.2022.111964	journal	February 2023
Room temperature multiferroic behaviour and magnetoelectric coupling in Sm/Fe modified Bi4Ti3O12 ceramics synthesized by solid state reaction method Paul, Joginder; Bhardwaj, Sumit; Sharma, K. K. Journal of Alloys and Compounds, Vol. 634 https://doi.org/10.1016/j.jallcom.2015.01.259	journal	June 2015
Ferroelectric, piezoelectric properties and magnetoelectric coupling behavior in aurivillius Bi5Ti3FeO15 multiferroic nanofibers by electrospinning Zhao, Yuwei; Fan, Huiqing; Liu, Guocai Journal of Alloys and Compounds, Vol. 675 https://doi.org/10.1016/j.jallcom.2016.03.017	journal	August 2016
Photovoltaic properties of Aurivillius Bi4NdTi3FeO15 ceramics with different orientations Cao, Lin; Ding, Zhenzhong; Liu, Xingzhong Journal of Alloys and Compounds, Vol. 800 https://doi.org/10.1016/j.jallcom.2019.05.307	journal	September 2019
Multiferroics: Different ways to combine magnetism and ferroelectricity Khomskii, D. I. Journal of Magnetism and Magnetic Materials, Vol. 306, Issue 1 https://doi.org/10.1016/j.jmmm.2006.01.238	journal	November 2006
Magnetic and optical properties of the Aurivillius phase Bi5Ti3FeO15 Wu, Maosong; Tian, Zhaoming; Yuan, Songliu Materials Letters, Vol. 68 https://doi.org/10.1016/j.matlet.2011.09.113	journal	February 2012
PDF analysis on re-crystallized structure from amorphous BiT Yoneda, Yasuhiro; Kohara, Shinji; Hamazaki, Shin’ichi Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 238, Issue 1-4 https://doi.org/10.1016/j.nimb.2005.06.037	journal	August 2005
Multiferroic bismuth ferrite-based materials for multifunctional applications: Ceramic bulks, thin films and nanostructures Wu, Jiagang; Fan, Zhen; Xiao, Dingquan Progress in Materials Science, Vol. 84 https://doi.org/10.1016/j.pmatsci.2016.09.001	journal	December 2016
Electrical and magnetic properties of Bi5FeTi3O15 compound prepared by inserting BiFeO3 into Bi4Ti3O12 Mao, X. Y.; Wang, W.; Chen, X. B. Solid State Communications, Vol. 147, Issue 5-6 https://doi.org/10.1016/j.ssc.2008.05.025	journal	August 2008
Crystal Chemistry and Magnetic Properties of Gd-Substituted Aurivillius-Type Bi ₅ FeTi ₃ O ₁₅ Ceramics Koval, Vladimir; Skorvanek, Ivan; Viola, Giuseppe The Journal of Physical Chemistry C, Vol. 122, Issue 27 https://doi.org/10.1021/acs.jpcc.8b03801	journal	June 2018
Flexible, Fatigue-Free, and Large-Scale Bi_3.25La_0.75Ti₃O₁₂ Ferroelectric Memories Su, Liushuai; Lu, Xubing; Chen, Lang ACS Applied Materials & Interfaces, Vol. 10, Issue 25 https://doi.org/10.1021/acsami.8b04781	journal	June 2018
Vibrational Spectroscopic Characterization of Hematite, Maghemite, and Magnetite Thin Films Produced by Vapor Deposition Jubb, Aaron M.; Allen, Heather C. ACS Applied Materials & Interfaces, Vol. 2, Issue 10 https://doi.org/10.1021/am1004943	journal	September 2010
Recent Developments in Oxide Ion Conductors: Aurivillius Phases Kendall, Kurt R.; Navas, Carlos; Thomas, Julie K. Chemistry of Materials, Vol. 8, Issue 3 https://doi.org/10.1021/cm9503083	journal	January 1996
Coupled pairs of chromium(III) ions in crystals of cesium trichloromagnesate, cesium tribromomagnesate, and cesium tribromocadmate. A case of charge compensation induced pair formation McPherson, Gary L.; Heung, Wai-Ming; Barraza, Jaime J. Journal of the American Chemical Society, Vol. 100, Issue 2 https://doi.org/10.1021/ja00470a017	journal	January 1978
Lanthanum-substituted bismuth titanate for use in non-volatile memories Park, B. H.; Kang, B. S.; Bu, S. D. Nature, Vol. 401, Issue 6754 https://doi.org/10.1038/44352	journal	October 1999
Multiferroics: a magnetic twist for ferroelectricity Cheong, Sang-Wook; Mostovoy, Maxim Nature Materials, Vol. 6, Issue 1 https://doi.org/10.1038/nmat1804	journal	January 2007
Advances in magnetoelectric multiferroics Spaldin, N. A.; Ramesh, R. Nature Materials, Vol. 18, Issue 3 https://doi.org/10.1038/s41563-018-0275-2	journal	February 2019
Direct atomic scale determination of magnetic ion partition in a room temperature multiferroic material Keeney, Lynette; Downing, Clive; Schmidt, Michael Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-01902-1	journal	May 2017
Large magnetoelectric coupling in magnetically short-range ordered Bi5Ti3FeO15 film Zhao, Hongyang; Kimura, Hideo; Cheng, Zhenxiang Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep05255	journal	June 2014
Effect of Nd³⁺ substitution for Bi³⁺ on the dielectric properties and conduction behavior of Aurivillius NdBi₄Ti₃FeO₁₅ ceramics Rehman, Fida; Jin, Hai-Bo; Wang, Lin RSC Advances, Vol. 6, Issue 25 https://doi.org/10.1039/C5RA27821J	journal	January 2016
Bi_3.25La_0.75Ti_2.5Nb_0.25(Fe_0.5Co_0.5)_0.25O₁₂, a single phase room temperature multiferroic Li, Zheng; Tao, Kun; Ma, Jing Journal of Materials Chemistry C, Vol. 6, Issue 11 https://doi.org/10.1039/C8TC00161H	journal	January 2018
Laser induced Fano scattering, electron–phonon coupling, bond length and phonon lifetime changes in α-Fe₂O₃ nanostructures Sunny, Anoop; Thirumurugan, Arun; Balasubramanian, Karthikeyan Physical Chemistry Chemical Physics, Vol. 22, Issue 4 https://doi.org/10.1039/C9CP04959B	journal	January 2020
A review on the development of lead-free ferroelectric energy-storage ceramics and multilayer capacitors Zhang, Haibo; Wei, Tian; Zhang, Qi Journal of Materials Chemistry C, Vol. 8, Issue 47 https://doi.org/10.1039/D0TC04381H	journal	January 2020
High temperature Aurivillius piezoelectrics: the effect of (Li, Ln) modification on the structure and properties of (Li, Ln)0.06(Na, Bi)0.44Bi2Nb2O9 (Ln = Ce, Nd, La and Y) Long, Changbai; Fan, Huiqing; Li, Mengmeng Dalton Transactions, Vol. 42, Issue 10 https://doi.org/10.1039/c2dt32564k	journal	January 2013
Multiferroic properties of layer-structured Bi5Fe0.5Co0.5Ti3O15 ceramics Mao, Xiangyu; Wang, Wei; Chen, Xiaobing Applied Physics Letters, Vol. 95, Issue 8 https://doi.org/10.1063/1.3213344	journal	August 2009
Magnetoferroelectricity in Cr ₂ BeO ₄ Newnham, R. E.; Kramer, J. J.; Schulze, W. A. Journal of Applied Physics, Vol. 49, Issue 12 https://doi.org/10.1063/1.324527	journal	December 1978
Ferroelectric transition of Aurivillius compounds Bi5Ti3FeO15 and Bi6Ti3Fe2O18 Li, J. -B.; Huang, Y. P.; Rao, G. H. Applied Physics Letters, Vol. 96, Issue 22 https://doi.org/10.1063/1.3447372	journal	May 2010
Electrical, magnetic, and optical properties in multiferroic Bi5Ti3FeO15 thin films prepared by a chemical solution deposition route Bai, W.; Gao, Y. Q.; Zhu, J. Y. Journal of Applied Physics, Vol. 109, Issue 6 https://doi.org/10.1063/1.3553879	journal	March 2011
Study of multiferroic properties in Bi5Fe0.5Co0.5Ti3O15 thin films Sun, Hui; Lu, Xiaomei; Xu, Tingting Journal of Applied Physics, Vol. 111, Issue 12 https://doi.org/10.1063/1.4730892	journal	June 2012
The Cr-substitution concentration dependence of the structural, electric and magnetic behaviors for Aurivillius Bi5Ti3FeO15 multiferroic ceramics Liu, Jia; Bai, Wei; Yang, Jing Journal of Applied Physics, Vol. 114, Issue 23 https://doi.org/10.1063/1.4849055	journal	December 2013
Phase transformation in multiferroic Bi5Ti3FeO15 ceramics by temperature-dependent ellipsometric and Raman spectra: An interband electronic transition evidence Jiang, P. P.; Duan, Z. H.; Xu, L. P. Journal of Applied Physics, Vol. 115, Issue 8 https://doi.org/10.1063/1.4866421	journal	February 2014
Photovoltaic properties of Aurivillius phase Bi₅FeTi₃O₁₅thin films grown by pulsed laser deposition Kooriyattil, Sudheendran; Katiyar, Rajesh K.; Pavunny, Shojan P. Applied Physics Letters, Vol. 105, Issue 7 https://doi.org/10.1063/1.4893784	journal	August 2014
Effect of Nb and more Fe ions co-doping on the microstructures, magnetic, and piezoelectric properties of Aurivillius Bi5Ti3FeO15 phases Chen, Chao; Song, Kun; Bai, Wei Journal of Applied Physics, Vol. 120, Issue 21 https://doi.org/10.1063/1.4971256	journal	December 2016
Bi3.25La0.75Ti3O12 thin film capacitors for energy storage applications Yang, B. B.; Guo, M. Y.; Song, D. P. Applied Physics Letters, Vol. 111, Issue 18 https://doi.org/10.1063/1.4997351	journal	October 2017
High energy storage performances in lead-free BaBi _3.9 Pr _0.1 Ti ₄ O ₁₅ relaxor ferroelectric films Chen, Jieyu; Tang, Zhehong; Yang, Bo Applied Physics Letters, Vol. 113, Issue 15 https://doi.org/10.1063/1.5054924	journal	October 2018
Energy storage in BaBi4Ti4O15 thin films with high efficiency Song, D. P.; Yang, J.; Yang, B. B. Journal of Applied Physics, Vol. 125, Issue 13 https://doi.org/10.1063/1.5086515	journal	April 2019
Controlling the crystallization of Nd-doped Bi4Ti3O12 thin-films for lead-free energy storage capacitors Song, D. P.; Yang, J.; Sun, J. X. Journal of Applied Physics, Vol. 127, Issue 22 https://doi.org/10.1063/5.0005775	journal	June 2020
Multiferroicity: the coupling between magnetic and polarization orders Wang, K. F.; Liu, J. -M.; Ren, Z. F. Advances in Physics, Vol. 58, Issue 4 https://doi.org/10.1080/00018730902920554	journal	July 2009
Ordering mechanism and dynamics of relaxor ferroelectrics Vikhnin, V. S.; Blinc, R.; Pirc, R. Ferroelectrics, Vol. 240, Issue 1 https://doi.org/10.1080/00150190008227990	journal	January 2000
X-ray room temperature structure from single crystal data, powder diffraction measurements and optical studies of the aurivillius phase Bi ₅ (Ti ₃ Fe)O ₁₅ Kubel, F.; Schmid, H. Ferroelectrics, Vol. 129, Issue 1 https://doi.org/10.1080/00150199208016980	journal	May 1992
Multiferroic behaviour and the magneto-dielectric effect in Bi₅FeTi₃O₁₅ thin films Sun, Hui; Lu, Xiaomei; Su, Jie Journal of Physics D: Applied Physics, Vol. 45, Issue 38 https://doi.org/10.1088/0022-3727/45/38/385001	journal	September 2012
Ferroelectric phase transitions in SrBi 2 Nb 2 O 9 and Bi 5 Ti 3 FeO 15 : A powder neutron diffraction study Snedden, Alan; Hervoches, Charles H.; Lightfoot, Philip Physical Review B, Vol. 67, Issue 9 https://doi.org/10.1103/PhysRevB.67.092102	journal	March 2003
Potentially multiferroic Aurivillius phase Bi 5 FeTi 3 O 15 : Cation site preference, electric polarization, and magnetic coupling from first principles Birenbaum, Axiel Yaël; Ederer, Claude Physical Review B, Vol. 90, Issue 21 https://doi.org/10.1103/PhysRevB.90.214109	journal	December 2014
Soft phonon mode dynamics in Aurivillius-type structures Maurya, Deepam; Charkhesht, Ali; Nayak, Sanjeev K. Physical Review B, Vol. 96, Issue 13 https://doi.org/10.1103/PhysRevB.96.134114	journal	October 2017
Theory of domain patterns in systems with long-range interactions of Coulomb type Muratov, C. B. Physical Review E, Vol. 66, Issue 6 https://doi.org/10.1103/PhysRevE.66.066108	journal	December 2002
GSAS-II : the genesis of a modern open-source all purpose crystallography software package Toby, Brian H.; Von Dreele, Robert B. Journal of Applied Crystallography, Vol. 46, Issue 2 https://doi.org/10.1107/S0021889813003531	journal	March 2013
A profile refinement method for nuclear and magnetic structures Rietveld, H. M. Journal of Applied Crystallography, Vol. 2, Issue 2, p. 65-71 https://doi.org/10.1107/S0021889869006558	journal	June 1969
Electron diffraction study of the space group of Bi₅Ti₃FeO₁₅ multiferroic ceramic Zheng, Ying; Wu, Xinyan; Zhang, Yongcheng Acta Crystallographica Section C Structural Chemistry, Vol. 76, Issue 5 https://doi.org/10.1107/S2053229620005045	journal	April 2020
Direct visualization of magnetic-field-induced magnetoelectric switching in multiferroic aurivillius phase thin films Faraz, Ahmad; Maity, Tuhin; Schmidt, Michael Journal of the American Ceramic Society, Vol. 100, Issue 3 https://doi.org/10.1111/jace.14597	journal	November 2016
Segregation‐controlled densification and grain growth in rare earth‐doped Y₂O₃ Kindelmann, Moritz; Ran, Ke; Rheinheimer, Wolfgang Journal of the American Ceramic Society, Vol. 104, Issue 10 https://doi.org/10.1111/jace.17907	journal	May 2021
MATERIALS SCIENCE: The Renaissance of Magnetoelectric Multiferroics Spaldin, N. A. Science, Vol. 309, Issue 5733 https://doi.org/10.1126/science.1113357	journal	July 2005
Properties of aurivillius phases in the Bi4Ti3O12-BiFeO3 system Lomanova, N. A.; Morozov, M. I.; Ugolkov, V. L. Inorganic Materials, Vol. 42, Issue 2 https://doi.org/10.1134/S0020168506020142	journal	February 2006
Grain Orientation and Electrical Properties of Hot-Forged Bi₄Ti₃O₁₂Ceramics Takenaka, Tadashi; Sakata, Koichiro Japanese Journal of Applied Physics, Vol. 19, Issue 1 https://doi.org/10.1143/JJAP.19.31	journal	January 1980
One-Dimensional Single-Crystalline Bismuth Oxide Micro/Nanoribbons: Morphology-Controlled Synthesis and Luminescent Properties Ling, B.; Sun, X. W.; Zhao, J. L. Journal of Nanoscience and Nanotechnology, Vol. 10, Issue 12 https://doi.org/10.1166/jnn.2010.3051	journal	December 2010
Aurivillius ceramics: Bi4Ti3O12-based piezoelectrics Jardiel, T.; Caballero, A. C.; Villegas, M. Journal of the Ceramic Society of Japan, Vol. 116, Issue 1352 https://doi.org/10.2109/jcersj2.116.511	journal	January 2008
Progress and Perspectives on Aurivillius-Type Layered Ferroelectric Oxides in Binary Bi4Ti3O12-BiFeO3 System for Multifunctional Applications Sun, Shujie; Yin, Xiaofeng Crystals, Vol. 11, Issue 1 https://doi.org/10.3390/cryst11010023	journal	December 2020

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Title: Resilience of the Aurivillius structure upon La and Cr doping in a Bi5Ti3FeO15 multiferroic

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Title: Resilience of the Aurivillius structure upon La and Cr doping in a Bi₅Ti₃FeO₁₅ multiferroic