Vacancy Mediated Electrooxidation of 5‐Hydroxymethyl Furfuryl Using Defect Engineered Layered Double Hydroxide Electrocatalysts

Zubair, Muhammad; Usov, Pavel M.; Ohtsu, Hiroyoshi; Yuwono, Jodie A.; Gerke, Carter S.; Foley, Gregory D. Y.; Hackbarth, Haira; Webster, Richard F.; Yang, Yuwei; Lie, William Hadinata; Ma, Zhipeng; Thomsen, Lars; Kawano, Masaki; Bedford, Nicholas M.

doi:10.1002/aenm.202400676

Title: Vacancy Mediated Electrooxidation of 5‐Hydroxymethyl Furfuryl Using Defect Engineered Layered Double Hydroxide Electrocatalysts

Journal Article · 03 June 2024 · Advanced Energy Materials

DOI: https://doi.org/10.1002/aenm.202400676 · OSTI ID:2370572

Zubair, Muhammad ^[1]; Usov, Pavel M. ^[2]; Ohtsu, Hiroyoshi ^[2]; Yuwono, Jodie A. ^[3]; Gerke, Carter S. ^[4]; Foley, Gregory D. Y. ^[4]; Hackbarth, Haira ^[1]; Webster, Richard F. ^[5]; Yang, Yuwei ^[1]; Lie, William Hadinata ^[1]; Ma, Zhipeng ^[1]; Thomsen, Lars ^[6]; Kawano, Masaki ^[2];

^[1]

School of Chemical Engineering The University of New South Wales Sydney NSW 2052 Australia
Department of Chemistry School of Science Tokyo Institute of Technology 2‐12‐1 Ookayama Meguro‐ku Tokyo 152‐8550 Japan
School of Chemical Engineering The University of Adelaide Adelaide SA 5005 Australia
Department of Chemistry Johns Hopkins University Baltimore MD 21218 USA
Mark Wainwright Analytical Centre, Electron Microscope Unit The University of New South Wales Sydney NSW 2052 Australia
Australian Synchrotron ANSTO 800 Blackburn Road Clayton VIC 3168 Australia

Abstract Electrochemical biomass oxidation coupled with hydrogen evolution offers a promising route to generate value‐added chemicals and clean energy. The complex adsorption behavior of 5‐hydroxymethyl furfural (HMF) and hydroxyl ions (OH ⁻ ) on the electrocatalyst surface during HMF electrooxidation reaction (HMFOR) necessitates an in‐depth understanding of active sites available for adsorption. Herein, oxygen vacancy (V _O ) defects are introduced in NiFe layered double hydroxide (LDH) using Ce dopants to manipulate electronic structure. Synchrotron‐based HE‐XRD and XAS indicate negligible V _O in La‐doped NiFe while Ce doping leads to V _O defects due to flexible Ce redox (Ce ³⁺ ↔ Ce ⁴⁺ ). The V _O ‐rich Ce‐NiFe exhibits higher Faradic efficiency of ≈90% to produce 2,5‐furan dicarboxylic acid (FDCA), far greater than ≈60% for NiFe V _O in Ce‐NiFe act as alternative active sites for OH ⁻ adsorption, hence reducing adsorption competition for the same metal sites. DFT calculation results corroborate experimental findings by showcasing that the presence of V _O in Ce‐NiFe manipulates the adsorption energies and facilitates the chemical adsorption OH ⁻ in V _O to improve HMFOR. In situ HE‐XRD derived pair distribution function coupled to RMC simulations confirm OH ⁻ trapping in V _O and HMF adsorption on metal centers as evident by interlayer distance evolution. Taken together, this work showcases routes for dual‐site electrocatalyst design for improved biomass electrooxidation.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: NONE; AC02-06CH11357

OSTI ID:: 2370572

Alternate ID(s):: OSTI ID: 2370574

Journal Information:: Advanced Energy Materials, Journal Name: Advanced Energy Materials Journal Issue: 35 Vol. 14; ISSN 1614-6832

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (76)

Progress and Perspectives in Photo‐ and Electrochemical‐Oxidation of Biomass for Sustainable Chemicals and Hydrogen Production Luo, Hui; Barrio, Jesús; Sunny, Nixon Advanced Energy Materials, Vol. 11, Issue 43 https://doi.org/10.1002/aenm.202101180	journal	June 2021
Modification of NiFe layered double hydroxide by lanthanum doping for boosting water splitting Yu, Jie; Lu, Ke; Wang, Chenxu Electrochimica Acta, Vol. 390 https://doi.org/10.1016/j.electacta.2021.138824	journal	September 2021
The Effect of Iron Impurities on Transition Metal Catalysts for the Oxygen Evolution Reaction in Alkaline Environment: Activity Mediators or Active Sites? Spanos, Ioannis; Masa, Justus; Zeradjanin, Aleksandar Catalysis Letters, Vol. 151, Issue 7 https://doi.org/10.1007/s10562-020-03478-4	journal	December 2020
Nanostructure by high-energy X-ray diffraction Petkov, Valeri Materials Today, Vol. 11, Issue 11 https://doi.org/10.1016/S1369-7021(08)70236-0	journal	November 2008
Electrocatalytic oxidation of 5‐hydroxymethylfurfural for sustainable 2,5‐furandicarboxylic acid production—From mechanism to catalysts design Jiang, Xiaoli; Li, Wei; Liu, Yanxia SusMat, Vol. 3, Issue 1 https://doi.org/10.1002/sus2.109	journal	January 2023
Oxygen 1 s x-ray-absorption edges of transition-metal oxides de Groot, F. M. F.; Grioni, M.; Fuggle, J. C. Physical Review B, Vol. 40, Issue 8 https://doi.org/10.1103/PhysRevB.40.5715	journal	September 1989
Lignocellulosic biomass: a sustainable platform for the production of bio-based chemicals and polymers Isikgor, Furkan H.; Becer, C. Remzi Polymer Chemistry, Vol. 6, Issue 25 https://doi.org/10.1039/C5PY00263J	journal	January 2015
Ultrathin polycrystalline Co3O4 nanosheets with enriched oxygen vacancies for efficient electrochemical oxygen evolution and 5-hydroxymethylfurfural oxidation Zhong, Ruyi; Wang, Qi; Du, Lei Applied Surface Science, Vol. 584 https://doi.org/10.1016/j.apsusc.2022.152553	journal	May 2022
Tailoring the electron structure and substrate adsorption energy of Ni hydroxide via Co doping to enhance the electrooxidation of biomass-derived chemicals Lu, Luying; Wen, Chengyan; Wang, Haiyong Journal of Catalysis, Vol. 424 https://doi.org/10.1016/j.jcat.2023.05.001	journal	August 2023
Integrated Catalytic Sites for Highly Efficient Electrochemical Oxidation of the Aldehyde and Hydroxyl Groups in 5-Hydroxymethylfurfural Lu, Yuxuan; Liu, Tianyang; Huang, Yu-Cheng ACS Catalysis, Vol. 12, Issue 7 https://doi.org/10.1021/acscatal.2c00174	journal	March 2022
In-situ structure and catalytic mechanism of NiFe and CoFe layered double hydroxides during oxygen evolution Dionigi, Fabio; Zeng, Zhenhua; Sinev, Ilya Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-16237-1	journal	May 2020
Hydrothermal Synthesis of Lanthanum-Doped MgAl-Layered Double Hydroxide/Graphene Oxide Hybrid and Its Application as Flame Retardant for Thermoplastic Polyurethane Qian, Yi; Qiao, Peng; Li, Long Advances in Polymer Technology, Vol. 2020 https://doi.org/10.1155/2020/1018093	journal	February 2020
“The Fe Effect”: A review unveiling the critical roles of Fe in enhancing OER activity of Ni and Co based catalysts Anantharaj, Sengeni; Kundu, Subrata; Noda, Suguru Nano Energy, Vol. 80 https://doi.org/10.1016/j.nanoen.2020.105514	journal	February 2021
An X- and Q-band Fe3+ EPR study of nanoparticles of magnetic semiconductor Zn1−Fe O Misra, Sushil K.; Andronenko, S. I.; Thurber, A. Journal of Magnetism and Magnetic Materials, Vol. 363 https://doi.org/10.1016/j.jmmm.2014.03.031	journal	August 2014
Resolving Potential-Dependent Degradation of Electrodeposited Ni(OH)2 Catalysts in Alkaline Oxygen Evolution Reaction (OER): In Situ XANES Studies Lee, Sang-Yeon; Kim, Ik-Sun; Cho, Hyun-Seok Applied Catalysis B: Environmental, Vol. 284 https://doi.org/10.1016/j.apcatb.2020.119729	journal	May 2021
Structural and paramagnetic resonance properties correlation in lanthanum ion doped nickel ferrite nanoparticles Gaba, Sonia; Rana, Pawan S.; Kumar, Ashok Journal of Magnetism and Magnetic Materials, Vol. 508 https://doi.org/10.1016/j.jmmm.2020.166866	journal	August 2020
One-pot preparation of La(OH)3 nanoparticles and NiMn LDH nanosheets with mutual support structure as cathode for high-performance aqueous zinc-ion batteries Zou, Yining; Guo, Zuoxing; Zhou, Juan Journal of Alloys and Compounds, Vol. 918 https://doi.org/10.1016/j.jallcom.2022.165547	journal	October 2022
Generation of oxygen vacancies in NiFe LDH electrocatalysts by ultrasound for enhancing the activity toward oxygen evolution reaction Li, Xiumin; Hu, Qianyu; Xu, Yazhou Carbon Resources Conversion, Vol. 4 https://doi.org/10.1016/j.crcon.2020.12.007	journal	January 2021
Electronic Structure Modulation of Non‐Noble‐Metal‐Based Catalysts for Biomass Electrooxidation Reactions Yang, Ganceng; Jiao, Yanqing; Yan, Haijing Small Structures, Vol. 2, Issue 10 https://doi.org/10.1002/sstr.202100095	journal	September 2021
Vacancy Promotion in Layered Double Hydroxide Electrocatalysts for Improved Oxygen Evolution Reaction Performance Zubair, Muhammad; Kumar, Priyank; Klingenhof, Malte ACS Catalysis, Vol. 13, Issue 7 https://doi.org/10.1021/acscatal.2c05863	journal	March 2023
Nickel(ii)-modified covalent-organic framework film for electrocatalytic oxidation of 5-hydroxymethylfurfural (HMF) Cai, Meng; Ding, Sha; Gibbons, Bradley Chemical Communications, Vol. 56, Issue 92 https://doi.org/10.1039/D0CC02206C	journal	January 2020
Perovskites in catalysis and electrocatalysis Hwang, Jonathan; Rao, Reshma R.; Giordano, Livia Science, Vol. 358, Issue 6364 https://doi.org/10.1126/science.aam7092	journal	November 2017
Excited-state structural dynamics of nickel complexes probed by optical and X-ray transient absorption spectroscopies: insights and implications Phelan, Brian T.; Mara, Michael W.; Chen, Lin X. Chemical Communications, Vol. 57, Issue 90 https://doi.org/10.1039/D1CC03875C	journal	January 2021
Defect‐Promoted Ni‐Based Layer Double Hydroxides with Enhanced Deprotonation Capability for Efficient Biomass Electrooxidation Yang, Yuwei; Lie, William Hadinata; Unocic, Raymond R. Advanced Materials, Vol. 35, Issue 48 https://doi.org/10.1002/adma.202305573	journal	October 2023
Hydroxymethylfurfural oxidation over unsupported Pd-Au alloy catalysts prepared by pulsed laser ablation: Synergistic and compositional effects Timofeev, Konstantin L.; Kharlamova, Tamara S.; Ezhov, Dmitry M. Applied Catalysis A: General, Vol. 656 https://doi.org/10.1016/j.apcata.2023.119121	journal	April 2023
Ultrathin layered double hydroxides nanosheets array towards efficient electrooxidation of 5-hydroxymethylfurfural coupled with hydrogen generation Song, Yingjie; Li, Zhenhua; Fan, Kui Applied Catalysis B: Environmental, Vol. 299 https://doi.org/10.1016/j.apcatb.2021.120669	journal	December 2021
Conversion of biomass to selected chemical products Gallezot, Pierre Chem. Soc. Rev., Vol. 41, Issue 4 https://doi.org/10.1039/C1CS15147A	journal	January 2012
An Overall Reaction Integrated with Highly Selective Oxidation of 5‐Hydroxymethylfurfural and Efficient Hydrogen Evolution Xie, Yanan; Zhou, Zhaoyu; Yang, Nianjun Advanced Functional Materials, Vol. 31, Issue 34 https://doi.org/10.1002/adfm.202102886	journal	May 2021
Efficient electrolysis of 5-hydroxymethylfurfural to the biopolymer-precursor furandicarboxylic acid in a zero-gap MEA-type electrolyzer Hauke, Philipp; Klingenhof, Malte; Wang, Xingli Cell Reports Physical Science, Vol. 2, Issue 12 https://doi.org/10.1016/j.xcrp.2021.100650	journal	December 2021
Accelerating the Electrocatalytic Performance of NiFe–LDH via Sn Doping toward the Water Oxidation Reaction under Alkaline Condition Bera, Krishnendu; Madhu, Ragunath; Dhandapani, Hariharan N. Inorganic Chemistry, Vol. 61, Issue 42 https://doi.org/10.1021/acs.inorgchem.2c02947	journal	October 2022
Periodicity and Atomic Ordering in Nanosized Particles of Crystals Petkov, Valeri; Bedford, Nick; Knecht, Marc R. The Journal of Physical Chemistry C, Vol. 112, Issue 24 https://doi.org/10.1021/jp801195c	journal	May 2008
2,5-Furandicarboxylic Acid: An Intriguing Precursor for Monomer and Polymer Synthesis Marshall, Adam; Jiang, Bo; Gauvin, Régis M. Molecules, Vol. 27, Issue 13 https://doi.org/10.3390/molecules27134071	journal	June 2022
Effect of Rare-Earth Element Doping on NiFe-Layered Double Hydroxides for Water Oxidation at Ultrahigh Current Densities Dang Van, Cu; Kim, Sanghoon; Kim, Minho ACS Sustainable Chemistry & Engineering, Vol. 11, Issue 4 https://doi.org/10.1021/acssuschemeng.2c05060	journal	January 2023
Biorefinery roadmap based on catalytic production and upgrading 5-hydroxymethylfurfural Hou, Qidong; Qi, Xinhua; Zhen, Meinan Green Chemistry, Vol. 23, Issue 1 https://doi.org/10.1039/D0GC02770G	journal	January 2021
Stochastic atomic modeling and optimization with fullrmc Aoun, Bachir Journal of Applied Crystallography, Vol. 55, Issue 6 https://doi.org/10.1107/S1600576722008536	journal	October 2022
Self-Supported Nickel Iron Layered Double Hydroxide-Nickel Selenide Electrocatalyst for Superior Water Splitting Activity Dutta, Soumen; Indra, Arindam; Feng, Yi ACS Applied Materials & Interfaces, Vol. 9, Issue 39 https://doi.org/10.1021/acsami.7b07984	journal	April 2017
Electrochemical oxidation of biomass derived 5-hydroxymethylfurfural (HMF): pathway, mechanism, catalysts and coupling reactions Yang, Yuechao; Mu, Tiancheng Green Chemistry, Vol. 23, Issue 12 https://doi.org/10.1039/D1GC00914A	journal	January 2021
Synthesis of calcined La-doped layered double hydroxides and application on simultaneously removal of arsenate and fluoride Luo, Si; Guo, Yaqi; Yang, Yang Journal of Solid State Chemistry, Vol. 275 https://doi.org/10.1016/j.jssc.2019.04.017	journal	July 2019
Identification of catalytic activity descriptors for selective 5-hydroxymethyl furfural electrooxidation to 2,5-furandicarboxylic acid Lie, William Hadinata; Yang, Yuwei; Yuwono, Jodie A. Journal of Materials Chemistry A, Vol. 11, Issue 11 https://doi.org/10.1039/D2TA08306J	journal	January 2023
Oxygen vacancy defects modulated electrocatalytic activity of iron-nickel layered double hydroxide on Ni foam as highly active electrodes for oxygen evolution reaction Li, Jingwei; Lian, Ruqian; Wang, Jinyao Electrochimica Acta, Vol. 331 https://doi.org/10.1016/j.electacta.2019.135395	journal	January 2020
Uncovering The Role of Oxygen in Ni-Fe(OxHy) Electrocatalysts using In situ Soft X-ray Absorption Spectroscopy during the Oxygen Evolution Reaction Drevon, Dorian; Görlin, Mikaela; Chernev, Petko Scientific Reports, Vol. 9, Issue 1 https://doi.org/10.1038/s41598-018-37307-x	journal	February 2019
Electrochemical Oxidation of 5-Hydroxymethylfurfural with NiFe Layered Double Hydroxide (LDH) Nanosheet Catalysts Liu, Wu-Jun; Dang, Lianna; Xu, Zhuoran ACS Catalysis, Vol. 8, Issue 6 https://doi.org/10.1021/acscatal.8b01017	journal	May 2018
Boosting the valorization of biomass and green electrons to chemical building blocks: A study on the kinetics and mass transfer during the electrochemical conversion of HMF to FDCA in a microreactor Delparish, Amin; Uslu, Alperen; Cao, Yiran Chemical Engineering Journal, Vol. 438 https://doi.org/10.1016/j.cej.2022.135393	journal	June 2022
Nickel–Iron Oxyhydroxide Oxygen-Evolution Electrocatalysts: The Role of Intentional and Incidental Iron Incorporation Trotochaud, Lena; Young, Samantha L.; Ranney, James K. Journal of the American Chemical Society, Vol. 136, Issue 18 https://doi.org/10.1021/ja502379c	journal	April 2014
Recent advances in catalytic oxidation of 5-hydroxymethylfurfural Zhao, Deyang; Su, Ting; Wang, Yantao Molecular Catalysis, Vol. 495 https://doi.org/10.1016/j.mcat.2020.111133	journal	November 2020
Electrochemical Oxidation of 5‐Hydroxymethylfurfural on Nickel Nitride/Carbon Nanosheets: Reaction Pathway Determined by In Situ Sum Frequency Generation Vibrational Spectroscopy Zhang, Nana; Zou, Yuqin; Tao, Li Angewandte Chemie International Edition, Vol. 58, Issue 44 https://doi.org/10.1002/anie.201908722	journal	October 2019
Activity Origins and Design Principles of Nickel-Based Catalysts for Nucleophile Electrooxidation Chen, Wei; Xie, Chao; Wang, Yanyong Chem, Vol. 6, Issue 11 https://doi.org/10.1016/j.chempr.2020.07.022	journal	November 2020
Ce-Doped NiFe-Layered Double Hydroxide Ultrathin Nanosheets/Nanocarbon Hierarchical Nanocomposite as an Efficient Oxygen Evolution Catalyst Xu, Huajie; Wang, Bingkai; Shan, Changfu ACS Applied Materials & Interfaces, Vol. 10, Issue 7 https://doi.org/10.1021/acsami.7b17939	journal	February 2018
Nature of GaO_x Shells Grown on Silica by Atomic Layer Deposition Chen, Zixuan; Zimmerli, Nora K.; Zubair, Muhammad Chemistry of Materials, Vol. 35, Issue 18 https://doi.org/10.1021/acs.chemmater.3c00923	journal	August 2023
A Comparative Study of Nickel, Cobalt, and Iron Oxyhydroxide Anodes for the Electrochemical Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid Taitt, Brandon J.; Nam, Do-Hwan; Choi, Kyoung-Shin ACS Catalysis, Vol. 9, Issue 1 https://doi.org/10.1021/acscatal.8b04003	journal	November 2018
Trimetallic NiCoFe-Layered Double Hydroxides Nanosheets Efficient for Oxygen Evolution and Highly Selective Oxidation of Biomass-Derived 5-Hydroxymethylfurfural Zhang, Man; Liu, Yuqian; Liu, Biying ACS Catalysis, Vol. 10, Issue 9 https://doi.org/10.1021/acscatal.0c00007	journal	April 2020
High‐efficiency electrolysis of biomass and its derivatives: Advances in anodic oxidation reaction mechanism and transition metal‐based electrocatalysts Li, Ying; Dang, Zhiya; Gao, Pingqi Nano Select, Vol. 2, Issue 5 https://doi.org/10.1002/nano.202000227	journal	January 2021
Tailoring Competitive Adsorption Sites by Oxygen‐Vacancy on Cobalt Oxides to Enhance the Electrooxidation of Biomass Lu, Yuxuan; Liu, Tianyang; Dong, Chung‐Li Advanced Materials, Vol. 34, Issue 2 https://doi.org/10.1002/adma.202107185	journal	October 2021
Substrate molecule adsorption energy: An activity descriptor for electrochemical oxidation of 5-Hydroxymethylfurfural (HMF) Yang, Yuechao; Xu, Danxia; Zhang, Baolong Chemical Engineering Journal, Vol. 433 https://doi.org/10.1016/j.cej.2021.133842	journal	April 2022
Probing the Atomic-Scale Structure of Amorphous Aluminum Oxide Grown by Atomic Layer Deposition Young, Matthias J.; Bedford, Nicholas M.; Yanguas-Gil, Angel ACS Applied Materials & Interfaces, Vol. 12, Issue 20 https://doi.org/10.1021/acsami.0c01905	journal	April 2020
Reverse Monte Carlo modeling for local structures of noble metal nanoparticles using high-energy XRD and EXAFS Harada, Masafumi; Ikegami, Risa; Kumara, Loku Singgappulige Rosantha RSC Advances, Vol. 9, Issue 51 https://doi.org/10.1039/C9RA06519A	journal	January 2019
Nickel oxide nanoparticles with oxygen vacancies for boosting biomass-upgrading Wang, Honglei; Zhang, Jiangwei; Tao, Shengyang Chemical Engineering Journal, Vol. 444 https://doi.org/10.1016/j.cej.2022.136693	journal	September 2022
The rise of the X-ray atomic pair distribution function method: a series of fortunate events Billinge, Simon J. L. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 377, Issue 2147 https://doi.org/10.1098/rsta.2018.0413	journal	April 2019
The impact of ultrasonic parameters on the exfoliation of NiFe LDH nanosheets as electrocatalysts for the oxygen evolution reaction in alkaline media Munonde, Tshimangadzo S.; Zheng, Haitao Ultrasonics Sonochemistry, Vol. 76 https://doi.org/10.1016/j.ultsonch.2021.105664	journal	August 2021
Unified structural motifs of the catalytically active state of Co(oxyhydr)oxides during the electrochemical oxygen evolution reaction Bergmann, Arno; Jones, Travis E.; Martinez Moreno, Elias Nature Catalysis, Vol. 1, Issue 9 https://doi.org/10.1038/s41929-018-0141-2	journal	September 2018
Electrocatalytic Oxidation of 5-(Hydroxymethyl)furfural Using High-Surface-Area Nickel Boride Barwe, Stefan; Weidner, Jonas; Cychy, Steffen Angewandte Chemie International Edition, Vol. 57, Issue 35 https://doi.org/10.1002/anie.201806298	journal	July 2018
Production of 2,5-furandicarboxylic acid (FDCA) from 5-hydroxymethylfurfural (HMF): recent progress focusing on the chemical-catalytic routes Sajid, Muhammad; Zhao, Xuebing; Liu, Dehua Green Chemistry, Vol. 20, Issue 24 https://doi.org/10.1039/C8GC02680G	journal	January 2018
Electrochemical Conversion of Biomass-Based Oxygenated Compounds Carneiro, Juliana; Nikolla, Eranda Annual Review of Chemical and Biomolecular Engineering, Vol. 10, Issue 1 https://doi.org/10.1146/annurev-chembioeng-060718-030148	journal	June 2019
Iron-related defect levels in SrTiO3 measured by photoelectron paramagnetic resonance spectroscopy Dashdorj, J.; Zvanut, M. E.; Stanley, L. J. Journal of Applied Physics, Vol. 107, Issue 8 https://doi.org/10.1063/1.3372760	journal	April 2010
Fe L-Edge X-ray Absorption Spectroscopy Determination of Differential Orbital Covalency of Siderophore Model Compounds: Electronic Structure Contributions to High Stability Constants Hocking, Rosalie K.; DeBeer George, Serena; Raymond, Kenneth N. Journal of the American Chemical Society, Vol. 132, Issue 11 https://doi.org/10.1021/ja9090098	journal	March 2010
Compositional dependence of hydrodeoxygenation pathway selectivity for Ni_2−xRh_xP nanoparticle catalysts LiBretto, Nicole J.; Tacey, Sean A.; Zubair, Muhammad Journal of Materials Chemistry A, Vol. 11, Issue 31 https://doi.org/10.1039/D3TA02071A	journal	January 2023
A Multiplet Analysis of Fe K-Edge 1s → 3d Pre-Edge Features of Iron Complexes Westre, Tami E.; Kennepohl, Pierre; DeWitt, Jane G. Journal of the American Chemical Society, Vol. 119, Issue 27 https://doi.org/10.1021/ja964352a	journal	July 1997
Engineering the Electronic Structure of NiFe Layered Double Hydroxide Nanosheet Array by Implanting Cationic Vacancies for Efficient Electrochemical Conversion of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid Qi, Yu-Feng; Wang, Kai-Yao; Sun, Yan ACS Sustainable Chemistry & Engineering, Vol. 10, Issue 1 https://doi.org/10.1021/acssuschemeng.1c07482	journal	December 2021
In situ electrochemical high-energy X-ray diffraction using a capillary working electrode cell geometry Young, Matthias J.; Bedford, Nicholas M.; Jiang, Naisheng Journal of Synchrotron Radiation, Vol. 24, Issue 4 https://doi.org/10.1107/S1600577517006282	journal	May 2017
Anionic defects engineering of NiCo2O4 for 5-hydroxymethylfurfural electrooxidation Yang, Sixian; Xiang, Xuepeng; He, Zuyun Chemical Engineering Journal, Vol. 457 https://doi.org/10.1016/j.cej.2023.141344	journal	February 2023
In Situ X-Ray Absorption Spectroscopic Studies of Nickel Oxide Electrodes Pandya, K. I. Journal of The Electrochemical Society, Vol. 137, Issue 2 https://doi.org/10.1149/1.2086450	journal	January 1990
Detailed EPR Study of Spin Crossover Dendrimeric Iron(III) Complex Domracheva, Natalia E.; Pyataev, Andrew V.; Vorobeva, Valerya E. The Journal of Physical Chemistry B, Vol. 117, Issue 25 https://doi.org/10.1021/jp403682p	journal	June 2013
Engineering active Ni-doped Co2P catalyst for efficient electrooxidation coupled with hydrogen evolution Li, Jiayi; Mao, Xin; Gong, Wanbing Nano Research, Vol. 16, Issue 5 https://doi.org/10.1007/s12274-022-5329-8	journal	December 2022
In situ immune response and mechanisms of cell damage in central nervous system of fatal cases microcephaly by Zika virus Azevedo, Raimunda S. S.; de Sousa, Jorge R.; Araujo, Marialva T. F. Scientific Reports, Vol. 8, Issue 1 https://doi.org/10.1038/s41598-017-17765-5	journal	January 2018
Oxidation of biomass derived 5-hydroxymethylfurfural using heterogeneous and electrochemical catalysis Vuyyuru, Koteswara Rao; Strasser, Peter Catalysis Today, Vol. 195, Issue 1, p. 144-154 https://doi.org/10.1016/j.cattod.2012.05.008	journal	November 2012
Novel NiFe-LDH@Ni-MOF/NF heterostructured electrocatalysts for efficient oxygen evolution Zeng, Xiaodong; Cai, Zhengyang; Zhang, Cheng Materials Research Letters, Vol. 10, Issue 2 https://doi.org/10.1080/21663831.2021.2023677	journal	January 2022

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