Structure-property relationships in flexible and rigid lignin-derived polyurethane foams: A review

Sternberg, James; Sequerth, Olivia; Pilla, Srikanth

doi:10.1016/j.mtsust.2023.100643

Title: Structure-property relationships in flexible and rigid lignin-derived polyurethane foams: A review

Journal Article · 29 February 2024 · Materials Today Sustainability

DOI: https://doi.org/10.1016/j.mtsust.2023.100643 · OSTI ID:2370017

Sternberg, James; Sequerth, Olivia; Pilla, Srikanth

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Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: EE0009273; SC0021367; SC0023389

OSTI ID:: 2370017

Journal Information:: Materials Today Sustainability, Journal Name: Materials Today Sustainability Journal Issue: C Vol. 25; ISSN 2589-2347

Publisher:: ElsevierCopyright Statement

Country of Publication:: United Kingdom

Language:: English

References (135)

Polyurethanes: Versatile Materials and Sustainable Problem Solvers for Today’s Challenges Engels, Hans-Wilhelm; Pirkl, Hans-Georg; Albers, Reinhard Angewandte Chemie International Edition, Vol. 52, Issue 36 https://doi.org/10.1002/anie.201302766	journal	July 2013
Chemo‐ and Regioselective Additions of Nucleophiles to Cyclic Carbonates for the Preparation of Self‐Blowing Non‐Isocyanate Polyurethane Foams Monie, Florent; Grignard, Bruno; Thomassin, Jean‐Michel Angewandte Chemie International Edition, Vol. 59, Issue 39 https://doi.org/10.1002/anie.202006267	journal	July 2020
Water‐Induced Self‐Blown Non‐Isocyanate Polyurethane Foams Bourguignon, Maxime; Grignard, Bruno; Detrembleur, Christophe Angewandte Chemie International Edition, Vol. 61, Issue 51 https://doi.org/10.1002/anie.202213422	journal	November 2022
Lignins as macromonomers for polyurethane synthesis: A comparative study on hydroxyl group determination Cateto, Carolina Andreia; Barreiro, Maria Filomena; Rodrigues, Alírio Egídio Journal of Applied Polymer Science, Vol. 109, Issue 5 https://doi.org/10.1002/app.28393	journal	January 2008
Polyurethane foams from alkaline lignin‐based polyether polyol Li, Hong‐Qiang; Shao, Qiang; Luo, Hao Journal of Applied Polymer Science, Vol. 133, Issue 14 https://doi.org/10.1002/app.43261	journal	December 2015
Nonisocyanate thermoplastic polyurethane elastomers based on poly(ethylene glycol) prepared through the transurethanization approach Kébir, Nasreddine; Nouigues, Soumaya; Moranne, Pierre Journal of Applied Polymer Science, Vol. 134, Issue 45 https://doi.org/10.1002/app.44991	journal	March 2017
Influence of lignin's pH on polyurethane flexible foam formation and how to control it Maillard, Damien; Osso, Esthel; Faye, Adrien Journal of Applied Polymer Science, Vol. 138, Issue 18 https://doi.org/10.1002/app.50319	journal	December 2020
Renewability is not Enough: Recent Advances in the Sustainable Synthesis of Biomass-Derived Monomers and Polymers Llevot, Audrey; Dannecker, Patrick-Kurt; von Czapiewski, Marc Chemistry - A European Journal, Vol. 22, Issue 33 https://doi.org/10.1002/chem.201602068	journal	June 2016
Polyols and Polyurethanes from the Liquefaction of Lignocellulosic Biomass Hu, Shengjun; Luo, Xiaolan; Li, Yebo ChemSusChem, Vol. 7, Issue 1 https://doi.org/10.1002/cssc.201300760	journal	December 2013
From the Synthesis of Biobased Cyclic Carbonate to Polyhydroxyurethanes: A Promising Route towards Renewable Non‐Isocyanate Polyurethanes Carré, Camille; Ecochard, Yvan; Caillol, Sylvain ChemSusChem, Vol. 12, Issue 15 https://doi.org/10.1002/cssc.201900737	journal	June 2019
Heterogeneous Catalyst Design Principles for the Conversion of Lignin into High‐Value Commodity Fuels and Chemicals Gale, Mark; Cai, Charles M.; Gilliard‐Abdul‐Aziz, Kandis Leslie ChemSusChem, Vol. 13, Issue 8 https://doi.org/10.1002/cssc.202000002	journal	March 2020
Greener Routes to Biomass Waste Valorization: Lignin Transformation Through Electrocatalysis for Renewable Chemicals and Fuels Production Garedew, Mahlet; Lin, Fang; Song, Bing ChemSusChem, Vol. 13, Issue 17 https://doi.org/10.1002/cssc.202000987	journal	July 2020
Renewable Self-Blowing Non-Isocyanate Polyurethane Foams from Lysine and Sorbitol: Renewable Self-Blowing Non-Isocyanate Polyurethane Foams from Lysine and Sorbitol Clark, James H.; Farmer, Thomas J.; Ingram, Ian D. V. European Journal of Organic Chemistry, Vol. 2018, Issue 31 https://doi.org/10.1002/ejoc.201800665	journal	August 2018
A New Environmentally Friendly Approach to Lignin-Based Cyclic Carbonates Kühnel, Isabell; Saake, Bodo; Lehnen, Ralph Macromolecular Chemistry and Physics, Vol. 219, Issue 7 https://doi.org/10.1002/macp.201700613	journal	January 2018
Oxypropylation of Lignins and Preparation of Rigid Polyurethane Foams from the Ensuing Polyols Nadji, Hamid; Bruzzèse, Cécile; Belgacem, Mohamed Naceur Macromolecular Materials and Engineering, Vol. 290, Issue 10 https://doi.org/10.1002/mame.200500200	journal	October 2005
Lignin‐Based Polyurethane: Recent Advances and Future Perspectives Ma, Xiaozhen; Chen, Jing; Zhu, Jin Macromolecular Rapid Communications, Vol. 42, Issue 3 https://doi.org/10.1002/marc.202000492	journal	November 2020
Non‐isocyanate Polyurethanes from 1,1′‐Carbonyldiimidazole: A Polycondensation Approach Wolfgang, Josh D.; White, B. Tyler; Long, Timothy E. Macromolecular Rapid Communications, Vol. 42, Issue 13 https://doi.org/10.1002/marc.202100163	journal	May 2021
Environmentally Compatible Hybrid-Type Polyurethane Foams Containing Saccharide and Lignin Components Hatakeyama, Hyoe; Hatakeyama, Tatsuko Macromolecular Symposia, Vol. 224, Issue 1 https://doi.org/10.1002/masy.200550619	journal	April 2005
Non-isocyanate polyurethanes: synthesis, properties, and applications: Non-Isocyanate Polyurethanes: Synthesis, Properties, and Applications Rokicki, Gabriel; Parzuchowski, Paweł G.; Mazurek, Magdalena Polymers for Advanced Technologies, Vol. 26, Issue 7 https://doi.org/10.1002/pat.3522	journal	May 2015
Optimizing the lignin based synthesis of flexible polyurethane foams employing reactive liquefying agents: Optimizing the synthesis of polyurethane foams Bernardini, Jacopo; Anguillesi, Irene; Coltelli, Maria-Beatrice Polymer International, Vol. 64, Issue 9 https://doi.org/10.1002/pi.4905	journal	March 2015
Synthesis and properties of renewable nonisocyanate polyurethanes (NIPUs) from dimethylcarbonate Duval, Charlotte; Kébir, Nasreddine; Charvet, Agathe Journal of Polymer Science Part A: Polymer Chemistry, Vol. 53, Issue 11 https://doi.org/10.1002/pola.27568	journal	March 2015
Organocatalytic synthesis of novel renewable non-isocyanate polyhydroxyurethanes Duval, Charlotte; Kébir, Nasreddine; Jauseau, Raphaël Journal of Polymer Science Part A: Polymer Chemistry, Vol. 54, Issue 6 https://doi.org/10.1002/pola.27908	journal	September 2015
Role of Silicone Surfactant in Flexible Polyurethane Foam Zhang, X. D.; Macosko, C. W.; Davis, H. T. Journal of Colloid and Interface Science, Vol. 215, Issue 2 https://doi.org/10.1006/jcis.1999.6233	journal	July 1999
Hydroxymethylation of technical lignins obtained from different pretreatments for preparation of high-performance rigid polyurethane foam Lee, Yerin; Tran, My Ha; Lee, Eun Yeol European Journal of Wood and Wood Products, Vol. 80, Issue 5 https://doi.org/10.1007/s00107-022-01845-z	journal	June 2022
Effect of Liquefied Lignin Content on Synthesis of Bio-based Polyurethane Foam for Oil Adsorption Application Mohammadpour, Raziyeh; Mir Mohamad Sadeghi, Gity Journal of Polymers and the Environment, Vol. 28, Issue 3 https://doi.org/10.1007/s10924-019-01650-5	journal	January 2020
Effect of Brown-Rotted Spruce as Lignin-Enriched Filler on the Properties of Reinforced Polyurethane Foam Kan, Yuna; Zhai, Shengcheng; Chen, Bingwei Journal of Polymers and the Environment, Vol. 30, Issue 6 https://doi.org/10.1007/s10924-021-02347-4	journal	January 2022
Production and characterization of rigid polyurethane foam by oxypropylation of organosolv lignin extracted from exhausted olive pomace Abid, Amine; Brosse, Nicolas; Ziegler-Devin, Isabelle Journal of Polymer Research, Vol. 27, Issue 9 https://doi.org/10.1007/s10965-020-02228-9	journal	August 2020
Potential use of black liquor as lignin source for synthesis of polyurethane foam Mohammadpour, Raziye; Mir Mohamad Sadeghi, Gity Journal of Polymer Research, Vol. 27, Issue 12 https://doi.org/10.1007/s10965-020-02334-8	journal	November 2020
Effect of Kraft lignin and palm kernel oil as substitutes of petroleum-based polyols on the properties of viscoelastic polyurethane foams Flôres, Camila C.; Rufino, Thiago do C.; Oliveira, Mauricio P. Journal of Polymer Research, Vol. 28, Issue 12 https://doi.org/10.1007/s10965-021-02827-0	journal	November 2021
Thermal properties of lignin-and molasses-based polyurethane foams Hatakeyama, H.; Kosugi, R.; Hatakeyama, T. Journal of Thermal Analysis and Calorimetry, Vol. 92, Issue 2 https://doi.org/10.1007/s10973-007-8963-1	journal	May 2008
Performance characterization of rigid polyurethane foam with refined alkali lignin and modified alkali lignin Liu, Zhi-ming; Yu, Fei; Fang, Gui-zhen Journal of Forestry Research, Vol. 20, Issue 2 https://doi.org/10.1007/s11676-009-0028-9	journal	May 2009
Biological conversion of lignin and its derivatives to fuels and chemicals Dikshit, Pritam Kumar; Jun, Hang-Bae; Kim, Beom Soo Korean Journal of Chemical Engineering, Vol. 37, Issue 3 https://doi.org/10.1007/s11814-019-0458-9	journal	March 2020
Catalyzed non-isocyanate polyurethane (NIPU) coatings from bio-based poly(cyclic carbonates) Yu, Arvin Z.; Setien, Raul A.; Sahouani, Jonas M. Journal of Coatings Technology and Research, Vol. 16, Issue 1 https://doi.org/10.1007/s11998-018-0135-7	journal	September 2018
Compressive viscoelastic properties of softwood kraft lignin-based flexible polyurethane foams Jeong, Heonyoung; Park, Jongshin; Kim, Sunghoon Fibers and Polymers, Vol. 14, Issue 8 https://doi.org/10.1007/s12221-013-1301-2	journal	August 2013
Production of Bio-based Polyol from Oxypropylated Pyrolytic Lignin for Rigid Polyurethane Foam Application Saffar, Thana; Bouafif, Hassine; Braghiroli, Flavia Lega Waste and Biomass Valorization, Vol. 11, Issue 11 https://doi.org/10.1007/s12649-019-00876-7	journal	November 2019
Molecular weight determination of lignosulfonates by size-exclusion chromatography and multi-angle laser light scattering Fredheim, Guro Elise; Braaten, Svein Magne; Christensen, Bjørn E. Journal of Chromatography A, Vol. 942, Issue 1-2 https://doi.org/10.1016/S0021-9673(01)01377-2	journal	January 2002
Liquefaction of lignin by polyethyleneglycol and glycerol Jin, Yanqiao; Ruan, Xuemin; Cheng, Xiansu Bioresource Technology, Vol. 102, Issue 3 https://doi.org/10.1016/j.biortech.2010.10.050	journal	February 2011
Production and characterization of biopolyols and polyurethane foams from crude glycerol based liquefaction of soybean straw Hu, Shengjun; Wan, Caixia; Li, Yebo Bioresource Technology, Vol. 103, Issue 1 https://doi.org/10.1016/j.biortech.2011.09.125	journal	January 2012
Multi-scale modelling of heat transfer in polyurethane foams Ferkl, Pavel; Toulec, Miloš; Laurini, Erik Chemical Engineering Science, Vol. 172 https://doi.org/10.1016/j.ces.2017.06.035	journal	November 2017
Green synthesis of flexible polyurethane foams from liquefied lignin Cinelli, Patrizia; Anguillesi, Irene; Lazzeri, Andrea European Polymer Journal, Vol. 49, Issue 6 https://doi.org/10.1016/j.eurpolymj.2013.04.005	journal	June 2013
Flexible polyurethane foams green production employing lignin or oxypropylated lignin Bernardini, Jacopo; Cinelli, Patrizia; Anguillesi, Irene European Polymer Journal, Vol. 64 https://doi.org/10.1016/j.eurpolymj.2014.11.039	journal	March 2015
A new way of creating cellular polyurethane materials: NIPU foams Cornille, Adrien; Dworakowska, Sylwia; Bogdal, Dariusz European Polymer Journal, Vol. 66 https://doi.org/10.1016/j.eurpolymj.2015.01.034	journal	May 2015
Preparation of bio-based rigid polyurethane foam using hydrolytically depolymerized Kraft lignin via direct replacement or oxypropylation Mahmood, Nubla; Yuan, Zhongshun; Schmidt, John European Polymer Journal, Vol. 68 https://doi.org/10.1016/j.eurpolymj.2015.04.030	journal	July 2015
How to explain low molar masses in PolyHydroxyUrethanes (PHUs) Besse, Vincent; Camara, Fatoumata; Méchin, Francoise European Polymer Journal, Vol. 71 https://doi.org/10.1016/j.eurpolymj.2015.07.020	journal	October 2015
Production and characterization of polyurethane foams from a simple mixture of castor oil, crude glycerol and untreated lignin as bio-based polyols Carriço, Camila S.; Fraga, Thaís; Pasa, Vânya M. D. European Polymer Journal, Vol. 85 https://doi.org/10.1016/j.eurpolymj.2016.10.012	journal	December 2016
A perspective approach to sustainable routes for non-isocyanate polyurethanes Cornille, Adrien; Auvergne, Rémi; Figovsky, Oleg European Polymer Journal, Vol. 87 https://doi.org/10.1016/j.eurpolymj.2016.11.027	journal	February 2017
Synthesis of hybrid polyhydroxyurethanes by Michael addition Cornille, Adrien; Ecochard, Yvan; Blain, Marine European Polymer Journal, Vol. 96 https://doi.org/10.1016/j.eurpolymj.2017.09.028	journal	November 2017
A new synthesis route to produce isocyanate-free polyurethane foams Amezúa-Arranz, Clara; Santiago-Calvo, Mercedes; Rodríguez-Pérez, Miguel-Ángel European Polymer Journal, Vol. 197 https://doi.org/10.1016/j.eurpolymj.2023.112366	journal	October 2023
Unveiling the structure and ultrastructure of lignin carbohydrate complexes in softwoods Lawoko, Martin International Journal of Biological Macromolecules, Vol. 62 https://doi.org/10.1016/j.ijbiomac.2013.10.022	journal	November 2013
Development of high-performance biodegradable rigid polyurethane foams using all bioresource-based polyols: Lignin and soy oil-derived polyols Luo, Xiaogang; Xiao, Yuqin; Wu, Qiangxian International Journal of Biological Macromolecules, Vol. 115 https://doi.org/10.1016/j.ijbiomac.2018.04.126	journal	August 2018
Successive organic solvent fractionation and homogenization of technical lignin for polyurethane foam with high mechanical performance Guo, Weiqi; Sun, Shirong; Wang, Ping International Journal of Biological Macromolecules, Vol. 221 https://doi.org/10.1016/j.ijbiomac.2022.09.074	journal	November 2022
Review of current and future softwood kraft lignin process chemistry Chakar, Fadi S.; Ragauskas, Arthur J. Industrial Crops and Products, Vol. 20, Issue 2 https://doi.org/10.1016/j.indcrop.2004.04.016	journal	September 2004
Lignin as a reactive reinforcing filler for water-blown rigid biofoam composites from soy oil-based polyurethane Luo, Xiaogang; Mohanty, Amar; Misra, Manju Industrial Crops and Products, Vol. 47 https://doi.org/10.1016/j.indcrop.2013.01.040	journal	May 2013
Lignopolyurethanic materials based on oxypropylated sodium lignosulfonate and castor oil blends Oliveira, Fernando de; Ramires, Elaine C.; Frollini, Elisabete Industrial Crops and Products, Vol. 72 https://doi.org/10.1016/j.indcrop.2015.01.023	journal	October 2015
Properties of flexible polyurethane foams containing isocyanate functionalized kraft lignin Gómez-Fernández, Sandra; Ugarte, Lorena; Calvo-Correas, Tamara Industrial Crops and Products, Vol. 100 https://doi.org/10.1016/j.indcrop.2017.02.005	journal	June 2017
Oxyalkylation of lignin with propylene carbonate: Influence of reaction parameters on the ensuing bio-based polyols Kühnel, Isabell; Saake, Bodo; Lehnen, Ralph Industrial Crops and Products, Vol. 101 https://doi.org/10.1016/j.indcrop.2017.03.002	journal	July 2017
A simple methodology for improving the performance and sustainability of rigid polyurethane foam by incorporating industrial lignin Hayati, Amir Nemati; Evans, David Alwyn Charles; Laycock, Bronwyn Industrial Crops and Products, Vol. 117 https://doi.org/10.1016/j.indcrop.2018.03.006	journal	July 2018
Lab-scale structural insulated panels with lignin-incorporated rigid polyurethane foams as core Zhang, Xuefeng; Kim, Yunsang; Eberhardt, Thomas L. Industrial Crops and Products, Vol. 132 https://doi.org/10.1016/j.indcrop.2019.02.035	journal	June 2019
Rigid polyurethane foams containing lignin oxyalkylated with ethylene carbonate and polyethylene glycol Zhang, Xuefeng; Kim, Yunsang; Elsayed, Islam Industrial Crops and Products, Vol. 141 https://doi.org/10.1016/j.indcrop.2019.111797	journal	December 2019
Fractionation and oxypropylation of corn-stover lignin for the production of biobased rigid polyurethane foam Li, Bing; Zhou, Mingyuan; Huo, Weizhong Industrial Crops and Products, Vol. 143 https://doi.org/10.1016/j.indcrop.2019.111887	journal	January 2020
Biobased rigid polyurethane foam using gradient acid precipitated lignin from the black liquor: Revealing the relationship between lignin structural features and polyurethane performances Cao, Hui; Liu, Ruilin; Li, Bing Industrial Crops and Products, Vol. 177 https://doi.org/10.1016/j.indcrop.2021.114480	journal	March 2022
Exploring the reactivity of aliphatic and phenolic hydroxyl groups in lignin hydrogenolysis oil towards urethane bond formation Rubens, M.; Wesemael, M. Van; Feghali, E. Industrial Crops and Products, Vol. 180 https://doi.org/10.1016/j.indcrop.2022.114703	journal	June 2022
Rational analysis of dispersion and solubility of Kraft lignin in polyols for polyurethanes Haridevan, Hima; Evans, David A. C.; Martin, Darren J. Industrial Crops and Products, Vol. 185 https://doi.org/10.1016/j.indcrop.2022.115129	journal	October 2022
One-pot lignin extraction and modification in γ-valerolactone from steam explosion pre-treated lignocellulosic biomass Angelini, Stefania; Ingles, David; Gelosia, Mattia Journal of Cleaner Production, Vol. 151 https://doi.org/10.1016/j.jclepro.2017.03.062	journal	May 2017
A brief overview on lignin dissolution Melro, Elodie; Alves, Luis; Antunes, Filipe E. Journal of Molecular Liquids, Vol. 265 https://doi.org/10.1016/j.molliq.2018.06.021	journal	September 2018
Structure-properties relationships of cellular materials from biobased polyurethane foams Peyrton, Julien; Avérous, Luc Materials Science and Engineering: R: Reports, Vol. 145 https://doi.org/10.1016/j.mser.2021.100608	journal	July 2021
Chemical modification of lignins: Towards biobased polymers Laurichesse, Stéphanie; Avérous, Luc Progress in Polymer Science, Vol. 39, Issue 7, p. 1266-1290 https://doi.org/10.1016/j.progpolymsci.2013.11.004	journal	July 2014
Kinetic study of the formation of lignin-based polyurethanes in bulk Cateto, Carolina Andreia; Barreiro, Maria Filomena; Rodrigues, Alírio Egídio Reactive and Functional Polymers, Vol. 71, Issue 8 https://doi.org/10.1016/j.reactfunctpolym.2011.05.007	journal	August 2011
A review on lignin-based polymeric, micro- and nano-structured materials Duval, Antoine; Lawoko, Martin Reactive and Functional Polymers, Vol. 85 https://doi.org/10.1016/j.reactfunctpolym.2014.09.017	journal	December 2014
Comparison of different cyclic organic carbonates in the oxyalkylation of various types of lignin Kühnel, Isabell; Saake, Bodo; Lehnen, Ralph Reactive and Functional Polymers, Vol. 120 https://doi.org/10.1016/j.reactfunctpolym.2017.09.011	journal	November 2017
Catalytic Transformation of Lignin for the Production of Chemicals and Fuels Li, Changzhi; Zhao, Xiaochen; Wang, Aiqin Chemical Reviews, Vol. 115, Issue 21, p. 11559-11624 https://doi.org/10.1021/acs.chemrev.5b00155	journal	October 2015
Strategies for the Conversion of Lignin to High-Value Polymeric Materials: Review and Perspective Upton, Brianna M.; Kasko, Andrea M. Chemical Reviews, Vol. 116, Issue 4, p. 2275-2306 https://doi.org/10.1021/acs.chemrev.5b00345	journal	December 2015
Thermo-Responsive Shape-Memory Polyurethane Foams from Renewable Lignin Resources with Tunable Structures–Properties and Enhanced Temperature Resistance Liu, Li-Yang; Karaaslan, Muzaffer A.; Hua, Qi Industrial & Engineering Chemistry Research, Vol. 60, Issue 32 https://doi.org/10.1021/acs.iecr.1c01717	journal	August 2021
Highly Resilient Lignin-Containing Polyurethane Foam Wang, Shengyu; Liu, Weifeng; Yang, Dongjie Industrial & Engineering Chemistry Research, Vol. 58, Issue 1 https://doi.org/10.1021/acs.iecr.8b05072	journal	December 2018
Non-Isocyanate Polyurethanes from Carbonated Soybean Oil Using Monomeric or Oligomeric Diamines To Achieve Thermosets or Thermoplastics Poussard, L.; Mariage, J.; Grignard, B. Macromolecules, Vol. 49, Issue 6 https://doi.org/10.1021/acs.macromol.5b02467	journal	March 2016
Preparation of Mechanically Robust Bio-Based Polyurethane Foams Using Depolymerized Native Lignin Quinsaat, Jose Enrico Q.; Feghali, Elias; van de Pas, Daniel J. ACS Applied Polymer Materials, Vol. 3, Issue 11 https://doi.org/10.1021/acsapm.1c01081	journal	October 2021
Kraft Lignin with Improved Homogeneity Recovered Directly from Black Liquor and Its Application in Flexible Polyurethane Foams Quan, Peng; Kiziltas, Alper; Gondaliya, Akash ACS Omega, Vol. 7, Issue 19 https://doi.org/10.1021/acsomega.2c01206	journal	May 2022
Reductive Catalytic Fractionation of Corn Stover Lignin Anderson, Eric M.; Katahira, Rui; Reed, Michelle ACS Sustainable Chemistry & Engineering, Vol. 4, Issue 12 https://doi.org/10.1021/acssuschemeng.6b01858	journal	October 2016
Cyclic Carbonates as Safe and Versatile Etherifying Reagents for the Functionalization of Lignins and Tannins Duval, Antoine; Avérous, Luc ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 8 https://doi.org/10.1021/acssuschemeng.7b01502	journal	July 2017
Lignin-First Approach to Biorefining: Utilizing Fenton’s Reagent and Supercritical Ethanol for the Production of Phenolics and Sugars Sagues, William J.; Bao, Hanxi; Nemenyi, John L. ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 4 https://doi.org/10.1021/acssuschemeng.7b04500	journal	February 2018
Optimization Study of Lignin Oxypropylation in View of the Preparation of Polyurethane Rigid Foams Cateto, Carolina Andreia; Barreiro, Maria Filomena; Rodrigues, Alírio Egídio Industrial & Engineering Chemistry Research, Vol. 48, Issue 5 https://doi.org/10.1021/ie801251r	journal	March 2009
Aromatic Monomers by in Situ Conversion of Reactive Intermediates in the Acid-Catalyzed Depolymerization of Lignin Deuss, Peter J.; Scott, Martin; Tran, Fanny Journal of the American Chemical Society, Vol. 137, Issue 23 https://doi.org/10.1021/jacs.5b03693	journal	June 2015
Morphology of Dry Lignins and Size and Shape of Dissolved Kraft Lignin Particles by X-ray Scattering Vainio, Ulla; Maximova, Natalia; Hortling, Bo Langmuir, Vol. 20, Issue 22 https://doi.org/10.1021/la048407v	journal	October 2004
From Petrochemical Polyurethanes to Biobased Polyhydroxyurethanes Nohra, Bassam; Candy, Laure; Blanco, Jean-François Macromolecules, Vol. 46, Issue 10 https://doi.org/10.1021/ma400197c	journal	May 2013
Upgrading of lignin-derived bio-oils by catalytic hydrodeoxygenation Saidi, Majid; Samimi, Fereshteh; Karimipourfard, Dornaz Energy Environ. Sci., Vol. 7, Issue 1 https://doi.org/10.1039/C3EE43081B	journal	January 2014
Adipic acid production from lignin Vardon, Derek R.; Franden, Mary Ann; Johnson, Christopher W. Energy & Environmental Science, Vol. 8, Issue 2 https://doi.org/10.1039/C4EE03230F	journal	January 2015
Lignin solubilisation and gentle fractionation in liquid ammonia Strassberger, Zea; Prinsen, Pepijn; Klis, Frits van der Green Chemistry, Vol. 17, Issue 1 https://doi.org/10.1039/C4GC01143K	journal	January 2015
Tuning the lignin oil OH-content with Ru and Pd catalysts during lignin hydrogenolysis on birch wood Van den Bosch, S.; Schutyser, W.; Koelewijn, S. -F. Chemical Communications, Vol. 51, Issue 67 https://doi.org/10.1039/C5CC04025F	journal	January 2015
Reductive lignocellulose fractionation into soluble lignin-derived phenolic monomers and dimers and processable carbohydrate pulps Van den Bosch, S.; Schutyser, W.; Vanholme, R. Energy & Environmental Science, Vol. 8, Issue 6 https://doi.org/10.1039/C5EE00204D	journal	January 2015
Hydrolytic liquefaction of hydrolysis lignin for the preparation of bio-based rigid polyurethane foam Mahmood, Nubla; Yuan, Zhongshun; Schmidt, John Green Chemistry, Vol. 18, Issue 8 https://doi.org/10.1039/C5GC02876K	journal	January 2016
New insights into the structure and composition of technical lignins: a comparative characterisation study Constant, Sandra; Wienk, Hans L. J.; Frissen, Augustinus E. Green Chemistry, Vol. 18, Issue 9 https://doi.org/10.1039/C5GC03043A	journal	January 2016
Chemical modifications of lignin for the preparation of macromers containing cyclic carbonates Salanti, Anika; Zoia, Luca; Orlandi, Marco Green Chemistry, Vol. 18, Issue 14 https://doi.org/10.1039/C6GC01028H	journal	January 2016
From lignin association to nano-/micro-particle preparation: extracting higher value of lignin Zhao, Wenwen; Simmons, Blake; Singh, Seema Green Chemistry, Vol. 18, Issue 21 https://doi.org/10.1039/C6GC01813K	journal	January 2016
Pre-treatment of lignocellulosic feedstocks using biorenewable alcohols: towards complete biomass valorisation Lancefield, Christopher S.; Panovic, Isabella; Deuss, Peter J. Green Chemistry, Vol. 19, Issue 1 https://doi.org/10.1039/C6GC02739C	journal	January 2017
Polyurethane types, synthesis and applications – a review Akindoyo, John O.; Beg, M. D. H.; Ghazali, Suriati RSC Advances, Vol. 6, Issue 115 https://doi.org/10.1039/C6RA14525F	journal	January 2016
Chemicals from lignin: an interplay of lignocellulose fractionation, depolymerisation, and upgrading Schutyser, W.; Renders, T.; Van den Bosch, S. Chemical Society Reviews, Vol. 47, Issue 3 https://doi.org/10.1039/C7CS00566K	journal	January 2018
From lignin subunits to aggregates: insights into lignin solubilization Zhao, Wenwen; Xiao, Ling-Ping; Song, Guoyong Green Chemistry, Vol. 19, Issue 14 https://doi.org/10.1039/C7GC00944E	journal	January 2017
Lignin transformations for high value applications: towards targeted modifications using green chemistry Gillet, S.; Aguedo, M.; Petitjean, L. Green Chemistry, Vol. 19, Issue 18 https://doi.org/10.1039/C7GC01479A	journal	January 2017
On the structure of softwood kraft lignin Crestini, Claudia; Lange, Heiko; Sette, Marco Green Chemistry, Vol. 19, Issue 17 https://doi.org/10.1039/C7GC01812F	journal	January 2017
Utilization of cyclocarbonated lignin as a bio-based cross-linker for the preparation of poly(hydroxy urethane)s Salanti, Anika; Zoia, Luca; Mauri, Michele RSC Advances, Vol. 7, Issue 40 https://doi.org/10.1039/C7RA03416D	journal	January 2017
Lignin-first biorefinery: a reusable catalyst for lignin depolymerization and application of lignin oil to jet fuel aromatics and polyurethane feedstock Huang, Yong; Duan, Yijing; Qiu, Shi Sustainable Energy & Fuels, Vol. 2, Issue 3 https://doi.org/10.1039/C7SE00535K	journal	January 2018
Renewable polyols for advanced polyurethane foams from diverse biomass resources Furtwengler, Pierre; Avérous, Luc Polymer Chemistry, Vol. 9, Issue 32 https://doi.org/10.1039/C8PY00827B	journal	January 2018
Bio-based polyurethane foam preparation employing lignin from corn stalk enzymatic hydrolysis residues Zhu, Shiyun; Chen, Kefu; Xu, Jun RSC Advances, Vol. 8, Issue 28 https://doi.org/10.1039/C8RA01089G	journal	January 2018
Identification of a diagnostic structural motif reveals a new reaction intermediate and condensation pathway in kraft lignin formation Lancefield, Christopher S.; Wienk, Hans L. J.; Boelens, Rolf Chemical Science, Vol. 9, Issue 30 https://doi.org/10.1039/C8SC02000K	journal	January 2018
Materials for the biorefinery: high bio-content, shape memory Kraft lignin-derived non-isocyanate polyurethane foams using a non-toxic protocol Sternberg, James; Pilla, Srikanth Green Chemistry, Vol. 22, Issue 20 https://doi.org/10.1039/D0GC01659D	journal	January 2020
Low molecular weight and highly functional RCF lignin products as a full bisphenol a replacer in bio-based epoxy resins Van Aelst, Korneel; Van Sinay, Elien; Vangeel, Thijs Chemical Communications, Vol. 57, Issue 46 https://doi.org/10.1039/D1CC02263F	journal	January 2021
Simultaneous extraction and controlled chemical functionalization of hardwood lignin for improved phenolation Bertella, Stefania; Luterbacher, Jeremy S. Green Chemistry, Vol. 23, Issue 9 https://doi.org/10.1039/D1GC00358E	journal	January 2021
Valorisation of technical lignin in rigid polyurethane foam: a critical evaluation on trends, guidelines and future perspectives Haridevan, Hima; Evans, David A. C.; Ragauskas, Arthur J. Green Chemistry, Vol. 23, Issue 22 https://doi.org/10.1039/D1GC02744A	journal	January 2021
Lignin-derivable alternatives to petroleum-derived non-isocyanate polyurethane thermosets with enhanced toughness Mhatre, Sampanna V.; Mahajan, Jignesh S.; Epps, Thomas H. Materials Advances, Vol. 4, Issue 1 https://doi.org/10.1039/D2MA00895E	journal	January 2023
Cyclic limonene dicarbonate as a new monomer for non-isocyanate oligo- and polyurethanes (NIPU) based upon terpenes Bähr, Moritz; Bitto, Alexandro; Mülhaupt, Rolf Green Chemistry, Vol. 14, Issue 5 https://doi.org/10.1039/c2gc35099h	journal	January 2012
Non-isocyanate polyurethanes: from chemistry to applications Kathalewar, Mukesh S.; Joshi, Padmanabh B.; Sabnis, Anagha S. RSC Advances, Vol. 3, Issue 13 https://doi.org/10.1039/c2ra21938g	journal	January 2013
Kraft Lignin-Based Rigid Polyurethane Foam Li, Yang; Ragauskas, Arthur J. Journal of Wood Chemistry and Technology, Vol. 32, Issue 3 https://doi.org/10.1080/02773813.2011.652795	journal	July 2012
Renewable natural resources as green alternative substrates to obtain bio-based non-isocyanate polyurethanes-review Błażek, Kamila; Datta, Janusz Critical Reviews in Environmental Science and Technology, Vol. 49, Issue 3 https://doi.org/10.1080/10643389.2018.1537741	journal	January 2019
From Vegetable Oils to Polyurethanes: Synthetic Routes to Polyols and Main Industrial Products Desroches, Myriam; Escouvois, Maxime; Auvergne, Remi Polymer Reviews, Vol. 52, Issue 1 https://doi.org/10.1080/15583724.2011.640443	journal	January 2012
Formaldehyde stabilization facilitates lignin monomer production during biomass depolymerization Shuai, Li; Amiri, Masoud Talebi; Questell-Santiago, Ydna M. Science, Vol. 354, Issue 6310 https://doi.org/10.1126/science.aaf7810	journal	October 2016
A sustainable wood biorefinery for low–carbon footprint chemicals production Liao, Yuhe; Koelewijn, Steven-Friso; Van den Bossche, Gil Science, Vol. 367, Issue 6484 https://doi.org/10.1126/science.aau1567	journal	February 2020
Preparation of Polyurethane Foams Based on Liquefied Corn Stalk Enzymatic Hydrolysis Lignin Li, Yan; Han, Yanming; Qin, Tefu Journal of Biobased Materials and Bioenergy, Vol. 6, Issue 1 https://doi.org/10.1166/jbmb.2012.1197	journal	February 2012
Effect of replacing polyol by organosolv and kraft lignin on the property and structure of rigid polyurethane foam Pan, Xuejun; Saddler, Jack N. Biotechnology for Biofuels, Vol. 6, Issue 1 https://doi.org/10.1186/1754-6834-6-12	journal	January 2013
Wheat straw lignin as filler for rigid polyurethane foams on the basis of tall oil amide Paberza, Aiga; Cabulis, Ugis; Arshanitsa, Alexander Polimery, Vol. 59, Issue 06 https://doi.org/10.14314/polimery.2014.477	journal	June 2014
Properties of polyurethane foam with fourth-generation blowing agent Yakushin, Vladimir; Cabulis, Ugis; Fridrihsone, Velta e-Polymers, Vol. 21, Issue 1 https://doi.org/10.1515/epoly-2021-0081	journal	October 2021
Synthesis of lignin polyols via oxyalkylation with propylene carbonate Kühnel, Isabell; Podschun, Jacob; Saake, Bodo Holzforschung, Vol. 69, Issue 5 https://doi.org/10.1515/hf-2014-0068	journal	July 2015
Lignosulfonate-based polyurethane materials via cyclic carbonates: preparation and characterization Mimini, Vebi; Amer, Hassan; Hettegger, Hubert Holzforschung, Vol. 0, Issue 0 https://doi.org/10.1515/hf-2018-0298	journal	May 2019
The use of lignin as cross-linker for polyurethane foam for potential application in adsorbing materials Li, Jinpeng; Wang, Bin; Chen, Kefu BioResources, Vol. 12, Issue 4 https://doi.org/10.15376/biores.12.4.8653-8671	journal	October 2017
Synthesis of Lignin-Based Polyurethanes: A Mini-Review Gouveia, Júlia Rocha; da Costa, Cleber Lucius; Tavares, Lara Basílio Mini-Reviews in Organic Chemistry, Vol. 16, Issue 4 https://doi.org/10.2174/1570193X15666180514125817	journal	March 2019
Valorization of Lignin Side-Streams into Polyols and Rigid Polyurethane Foams—A Contribution to the Pulp and Paper Industry Biorefinery Pinto, João A.; Fernandes, Isabel P.; Pinto, Virginia D. Energies, Vol. 14, Issue 13 https://doi.org/10.3390/en14133825	journal	June 2021
Controlling the Molecular Weight of Lignosulfonates by an Alkaline Oxidative Treatment at Moderate Temperatures and Atmospheric Pressure: A Size-Exclusion and Reverse-Phase Chromatography Study Guizani, Chamseddine; Lachenal, Dominique International Journal of Molecular Sciences, Vol. 18, Issue 12 https://doi.org/10.3390/ijms18122520	journal	November 2017
Producing Lignin-Based Polyols through Microwave-Assisted Liquefaction for Rigid Polyurethane Foam Production Xue, Bai-Liang; Wen, Jia-Long; Sun, Run-Cang Materials, Vol. 8, Issue 2 https://doi.org/10.3390/ma8020586	journal	February 2015
Polyurethane Foams for Thermal Insulation Uses Produced from Castor Oil and Crude Glycerol Biopolyols Carriço, Camila; Fraga, Thaís; Carvalho, Vagner Molecules, Vol. 22, Issue 7 https://doi.org/10.3390/molecules22071091	journal	July 2017
Reactivity of Aliphatic and Phenolic Hydroxyl Groups in Kraft Lignin towards 4,4′ MDI Antonino, Leonardo Dalseno; Gouveia, Júlia Rocha; de Sousa Júnior, Rogério Ramos Molecules, Vol. 26, Issue 8 https://doi.org/10.3390/molecules26082131	journal	April 2021
Lignin as a Partial Polyol Replacement in Polyurethane Flexible Foam Gondaliya, Akash; Nejad, Mojgan Molecules, Vol. 26, Issue 8 https://doi.org/10.3390/molecules26082302	journal	April 2021
Studying the Suitability of Nineteen Lignins as Partial Polyol Replacement in Rigid Polyurethane/Polyisocyanurate Foam Henry, Christián; Gondaliya, Akash; Thies, Mark Molecules, Vol. 27, Issue 8 https://doi.org/10.3390/molecules27082535	journal	April 2022
Effects of Surface Functionalization of Lignin on Synthesis and Properties of Rigid Bio-Based Polyurethanes Foams Zhang, Xuefeng; Jeremic, Dragica; Kim, Yunsang Polymers, Vol. 10, Issue 7 https://doi.org/10.3390/polym10070706	journal	June 2018
Lignin-Based Polyurethanes: Opportunities for Bio-Based Foams, Elastomers, Coatings and Adhesives Alinejad, Mona; Henry, Christián; Nikafshar, Saeid Polymers, Vol. 11, Issue 7 https://doi.org/10.3390/polym11071202	journal	July 2019
Preparation and Evaluation of Glucose Based Non-Isocyanate Polyurethane Self-Blowing Rigid Foams Xi, Xuedong; Pizzi, Antonio; Gerardin, Christine Polymers, Vol. 11, Issue 11 https://doi.org/10.3390/polym11111802	journal	November 2019
Photodegradation of Polyurethane Foam Obtained from Renewable Resource–Pulp Production Byproducts Paberza, A.; Stiebra, L.; Cabulis, U. Journal of Renewable Materials, Vol. 3, Issue 1 https://doi.org/10.7569/JRM.2014.634138	journal	March 2015

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