Lithium-ion battery functionality over broad operating conditions via local high concentration fluorinated ester electrolytes

Quilty, Calvin D.; Marin Bernardez, Edelmy J.; Nicoll, Andrew; Hossain, MD Jamil; Kingan, Arun; Arnot, David J.; Mohamed, Hafsa A.; O'Connor, Ciara L.; Tong, Xiao; Jaye, Cherno; Fischer, Daniel A.; Wang, Lei; Qi, Yue; Takeuchi, Esther S.; Marschilok, Amy C.; Yan, Shan; Bock, David C.; Takeuchi, Kenneth J.

doi:10.1039/D3LF00259D

Title: Lithium-ion battery functionality over broad operating conditions via local high concentration fluorinated ester electrolytes

Journal Article · 09 September 2024 · RSC Applied Interfaces

DOI: https://doi.org/10.1039/D3LF00259D · OSTI ID:2368594

Quilty, Calvin D. ^[1]; Marin Bernardez, Edelmy J. ^[1]; Nicoll, Andrew ^[1];

^[2]; Kingan, Arun ^[1]; Arnot, David J. ^[3]; Mohamed, Hafsa A. ^[4]; O'Connor, Ciara L. ^[5];

^[6]; Jaye, Cherno ^[7]; Fischer, Daniel A. ^[7];

^[8];

^[2];

^[9];

^[8];

^[9]

Department of Chemistry, Stony Brook University, Stony Brook, NY, 11794, USA, Institute of Energy: Sustainability, Environment, and Equity (I:SEE), Stony Brook University, Stony Brook, NY, 11794, USA
School of Engineering, Brown University, Providence, RI, 02912, USA
Institute of Energy: Sustainability, Environment, and Equity (I:SEE), Stony Brook University, Stony Brook, NY, 11794, USA, Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, NY, 11794, USA
Science Undergraduate Laboratory Internship (SULI) Program, Brookhaven National Laboratory, Upton, NY, 11973, USA, Department of Chemistry, University of Rochester, Rochester, NY 14627, USA
Science Undergraduate Laboratory Internship (SULI) Program, Brookhaven National Laboratory, Upton, NY, 11973, USA, Department of Chemistry, The College of Wooster, Wooster, OH 44691, USA
Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, NY, 11973, USA
Material Measurement Laboratory, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, USA
Institute of Energy: Sustainability, Environment, and Equity (I:SEE), Stony Brook University, Stony Brook, NY, 11794, USA, Interdisciplinary Science Department, Brookhaven National Laboratory, Upton, NY, 11973, USA
Department of Chemistry, Stony Brook University, Stony Brook, NY, 11794, USA, Institute of Energy: Sustainability, Environment, and Equity (I:SEE), Stony Brook University, Stony Brook, NY, 11794, USA, Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, NY, 11794, USA, Interdisciplinary Science Department, Brookhaven National Laboratory, Upton, NY, 11973, USA

Delivered capacities of non-flammable LHCE vs. flammable LiPF ₆ EC:DMC electrolyte at low temperature, high voltage charge, and fast charge.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: NONE; EE0009643; SC0012673; SC0012704

OSTI ID:: 2368594

Journal Information:: RSC Applied Interfaces, Journal Name: RSC Applied Interfaces Journal Issue: 5 Vol. 1; ISSN 2755-3701; ISSN RAISCD

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (109)

Nonflammable Localized High-Concentration Electrolytes with Long-Term Cycling Stability for High-Performance Li Metal Batteries Xu, Zelin; Deng, Kuirong; Zhou, Suping ACS Applied Materials & Interfaces, Vol. 14, Issue 43 https://doi.org/10.1021/acsami.2c13922	journal	October 2022
GSAS-II : the genesis of a modern open-source all purpose crystallography software package Toby, Brian H.; Von Dreele, Robert B. Journal of Applied Crystallography, Vol. 46, Issue 2 https://doi.org/10.1107/S0021889813003531	journal	March 2013
Formation of LiF‐rich Cathode‐Electrolyte Interphase by Electrolyte Reduction Bai, Panxing; Ji, Xiao; Zhang, Jiaxun Angewandte Chemie International Edition, Vol. 61, Issue 26 https://doi.org/10.1002/anie.202202731	journal	April 2022
Study of the corrosion behavior of LiFSI based electrolyte for Li-ion cells Wu, Xianyang; Du, Zhijia Electrochemistry Communications, Vol. 129 https://doi.org/10.1016/j.elecom.2021.107088	journal	August 2021
Low-temperature performance of Li-ion cells with a LiBF4-based electrolyte Zhang, S.; Xu, K.; Jow, T. Journal of Solid State Electrochemistry, Vol. 7, Issue 3 https://doi.org/10.1007/s10008-002-0300-9	journal	March 2003
High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes Chen, Shuru; Zheng, Jianming; Mei, Donghai Advanced Materials, Vol. 30, Issue 21 https://doi.org/10.1002/adma.201706102	journal	March 2018
Battery electrolytes based on saturated ring ionic liquids: Physical and electrochemical properties Di Leo, Roberta A.; Marschilok, Amy C.; Takeuchi, Kenneth J. Electrochimica Acta, Vol. 109 https://doi.org/10.1016/j.electacta.2013.07.041	journal	October 2013
Calculation of One-Electron Redox Potentials Revisited. Is It Possible to Calculate Accurate Potentials with Density Functional Methods? Roy, Lindsay E.; Jakubikova, Elena; Guthrie, M. Graham The Journal of Physical Chemistry A, Vol. 113, Issue 24 https://doi.org/10.1021/jp811388w	journal	June 2009
Diethyl(thiophen-2-ylmethyl)phosphonate: a novel multifunctional electrolyte additive for high voltage batteries Zhu, Yunmin; Luo, Xueyi; Zhi, Huozhen Journal of Materials Chemistry A, Vol. 6, Issue 23 https://doi.org/10.1039/C8TA01236A	journal	January 2018
Understanding undesirable anode lithium plating issues in lithium-ion batteries Liu, Qianqian; Du, Chunyu; Shen, Bin RSC Advances, Vol. 6, Issue 91 https://doi.org/10.1039/C6RA19482F	journal	January 2016
Anion-Containing Solvation Structure Reconfiguration Enables Wide-Temperature Electrolyte for High-Energy-Density Lithium-Metal Batteries Kuang, Silan; Hua, Haiming; Lai, Pengbin ACS Applied Materials & Interfaces, Vol. 14, Issue 16 https://doi.org/10.1021/acsami.2c02221	journal	April 2022
Evolution and expansion of Li concentration gradient during charge–discharge cycling Chae, Byeong-Gyu; Park, Seong Yong; Song, Jay Hyok Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-24120-w	journal	June 2021
Improved Cycling of Li\|\|NMC811 Batteries under Practical Conditions by a Localized High‐Concentration Electrolyte Guo, Feng; Chen, Xi; Hou, Yuhan Small, Vol. 19, Issue 16 https://doi.org/10.1002/smll.202207290	journal	January 2023
Gas Generation in Lithium Cells with High-Nickel Cathodes and Localized High-Concentration Electrolytes Langdon, Jayse; Sim, Richard; Manthiram, Arumugam ACS Energy Letters, Vol. 7, Issue 8 https://doi.org/10.1021/acsenergylett.2c01444	journal	July 2022
Localized High-Concentration Sulfone Electrolytes for High-Efficiency Lithium-Metal Batteries Ren, Xiaodi; Chen, Shuru; Lee, Hongkyung Chem, Vol. 4, Issue 8 https://doi.org/10.1016/j.chempr.2018.05.002	journal	August 2018
Effect of stirring environment humidity on electrochemical performance of nickel-rich cathode materials as lithium ion batteries Wu, Xingyu; Ruan, Dingshan; Tan, Shenghe Ionics, Vol. 26, Issue 11 https://doi.org/10.1007/s11581-020-03708-0	journal	July 2020
Surface study of electrodes after long-term cycling in Li1.2Ni0.15Mn0.55Co0.1O2–graphite lithium-ion cells Li, Xiaobo; Xu, Mengqing; Chen, Yanjing Journal of Power Sources, Vol. 248 https://doi.org/10.1016/j.jpowsour.2013.10.044	journal	February 2014
Prediction of vapor pressure for nonaqueous electrolyte solutions using an electrolyte equation of state Zuo, You-Xiang; Fürst, Walter Fluid Phase Equilibria, Vol. 138, Issue 1-2 https://doi.org/10.1016/S0378-3812(97)00145-3	journal	November 1997
Effect of Sulfate Electrolyte Additives on LiNi _1/3 Mn _1/3 Co _1/3 O ₂ /Graphite Pouch Cell Lifetime: Correlation between XPS Surface Studies and Electrochemical Test Results Madec, Lénaïc; Xia, Jian; Petibon, Rémi The Journal of Physical Chemistry C, Vol. 118, Issue 51 https://doi.org/10.1021/jp509731y	journal	December 2014
Lithium-ion batteries for low-temperature applications: Limiting factors and solutions Belgibayeva, Ayaulym; Rakhmetova, Aiym; Rakhatkyzy, Makpal Journal of Power Sources, Vol. 557 https://doi.org/10.1016/j.jpowsour.2022.232550	journal	February 2023
Structural Changes and Thermal Stability of Charged LiNi _x Mn _y Co _z O ₂ Cathode Materials Studied by Combined In Situ Time-Resolved XRD and Mass Spectroscopy Bak, Seong-Min; Hu, Enyuan; Zhou, Yongning ACS Applied Materials & Interfaces, Vol. 6, Issue 24 https://doi.org/10.1021/am506712c	journal	December 2014
Stable Dendrite-Free Sodium–Sulfur Batteries Enabled by a Localized High-Concentration Electrolyte He, Jiarui; Bhargav, Amruth; Shin, Woochul Journal of the American Chemical Society, Vol. 143, Issue 48 https://doi.org/10.1021/jacs.1c08851	journal	November 2021
Controlling Ion Coordination Structure and Diffusion Kinetics for Optimized Electrode-Electrolyte Interphases and High-Performance Si Anodes Jia, Haiping; Gao, Peiyuan; Zou, Lianfeng Chemistry of Materials, Vol. 32, Issue 20 https://doi.org/10.1021/acs.chemmater.0c02954	journal	September 2020
Stable non-corrosive sulfonimide salt for 4-V-class lithium metal batteries Qiao, Lixin; Oteo, Uxue; Martinez-Ibañez, Maria Nature Materials, Vol. 21, Issue 4 https://doi.org/10.1038/s41563-021-01190-1	journal	February 2022
Dehydration Rather Than HF Capture Explains Performance Improvements of Li-Ion Cells by Ceramic Nanoparticles Rodrigues, Marco-Tulio F.; Liao, Chen; Kalaga, Kaushik ACS Applied Energy Materials, Vol. 2, Issue 8 https://doi.org/10.1021/acsaem.9b00976	journal	July 2019
Design aspects of electrolytes for fast charge of Li‐ion batteries Zhang, Sheng S. InfoMat, Vol. 3, Issue 1 https://doi.org/10.1002/inf2.12159	journal	October 2020
Electrolyte System for High Voltage Li-Ion Cells Petibon, Remi; Xia, Jian; Ma, Lin Journal of The Electrochemical Society, Vol. 163, Issue 13 https://doi.org/10.1149/2.0321613jes	journal	January 2016
Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries Lin, Feng; Markus, Isaac M.; Nordlund, Dennis Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4529	journal	March 2014
Editors' Choice—Hindering Rollover Failure of Li[Ni _0.5 Mn _0.3 Co _0.2 ]O ₂ /Graphite Pouch Cells during Long-Term Cycling Ma, Xiaowei; Harlow, Jessie E.; Li, Jing Journal of The Electrochemical Society, Vol. 166, Issue 4 https://doi.org/10.1149/2.0801904jes	journal	January 2019
2 p x-ray absorption of 3 d transition-metal compounds: An atomic multiplet description including the crystal field de Groot, F. M. F.; Fuggle, J. C.; Thole, B. T. Physical Review B, Vol. 42, Issue 9 https://doi.org/10.1103/PhysRevB.42.5459	journal	September 1990
Advances and issues in developing salt-concentrated battery electrolytes Yamada, Yuki; Wang, Jianhui; Ko, Seongjae Nature Energy https://doi.org/10.1038/s41560-019-0336-z	journal	March 2019
Gas Evolution during Unwanted Lithium Plating in Li-Ion Cells with EC-Based or EC-Free Electrolytes Liu, Q. Q.; Xiong, D. J.; Petibon, R. Journal of The Electrochemical Society, Vol. 163, Issue 14 https://doi.org/10.1149/2.0711614jes	journal	January 2016
Is Nonflammability of Electrolyte Overrated in the Overall Safety Performance of Lithium Ion Batteries? A Sobering Revelation from a Completely Nonflammable Electrolyte Jia, Hao; Yang, Zhijie; Xu, Yaobin Advanced Energy Materials, Vol. 13, Issue 4 https://doi.org/10.1002/aenm.202203144	journal	December 2022
Organic Batteries Operated at −70°C Dong, Xiaoli; Guo, Zhaowei; Guo, Ziyang Joule, Vol. 2, Issue 5 https://doi.org/10.1016/j.joule.2018.01.017	journal	May 2018
Nonflammable Fluorinated Ester-Based Electrolytes for Safe and High-Energy Batteries with LiCoO₂ Ugata, Yosuke; Yukishita, Kazuki; Kazahaya, Natsuho Chemistry of Materials, Vol. 35, Issue 9 https://doi.org/10.1021/acs.chemmater.3c00374	journal	April 2023
Depth-Dependent Redox Behavior of LiNi _0.6 Mn _0.2 Co _0.2 O ₂ Tian, Chixia; Nordlund, Dennis; Xin, Huolin L. Journal of The Electrochemical Society, Vol. 165, Issue 3 https://doi.org/10.1149/2.1021803jes	journal	January 2018
Rechargeable Battery Electrolytes Capable of Operating over Wide Temperature Windows and Delivering High Safety Lin, Xidong; Zhou, Guodong; Liu, Jiapeng Advanced Energy Materials, Vol. 10, Issue 43 https://doi.org/10.1002/aenm.202001235	journal	October 2020
The Relationship between Ionic Conductivity and Solvation Structures of Localized High-Concentration Fluorinated Electrolytes for Lithium-Ion Batteries Hossain, Md Jamil; Wu, Qisheng; Marin Bernardez, Edelmy J. The Journal of Physical Chemistry Letters, Vol. 14, Issue 34 https://doi.org/10.1021/acs.jpclett.3c01453	journal	August 2023
Exploiting Mechanistic Solvation Kinetics for Dual‐Graphite Batteries with High Power Output at Extremely Low Temperature Holoubek, John; Yin, Yijie; Li, Mingqian Angewandte Chemie International Edition, Vol. 58, Issue 52 https://doi.org/10.1002/anie.201912167	journal	December 2019
Bio-inspired synthesis of N,F co-doped 3D graphitized carbon foams containing manganese fluoride nanocrystals for lithium ion batteries Lu, Y.; Zhou, Y. P.; Yan, Q. Y. Journal of Materials Chemistry A, Vol. 4, Issue 7 https://doi.org/10.1039/C5TA09185C	journal	January 2016
Surface film formation on a graphite electrode in Li-ion batteries: AFM and XPS study Leroy, S.; Blanchard, F.; Dedryvère, R. Surface and Interface Analysis, Vol. 37, Issue 10 https://doi.org/10.1002/sia.2072	journal	January 2005
Highly Concentrated LiTFSI–EC Electrolytes for Lithium Metal Batteries Nilsson, Viktor; Kotronia, Antonia; Lacey, Matthew ACS Applied Energy Materials, Vol. 3, Issue 1 https://doi.org/10.1021/acsaem.9b01203	journal	December 2019
Toward Unraveling the Origin of Lithium Fluoride in the Solid Electrolyte Interphase Cao, Chuntian; Pollard, Travis P.; Borodin, Oleg Chemistry of Materials, Vol. 33, Issue 18 https://doi.org/10.1021/acs.chemmater.1c01744	journal	September 2021
Non-polar ether-based electrolyte solutions for stable high-voltage non-aqueous lithium metal batteries Li, Zheng; Rao, Harsha; Atwi, Rasha Nature Communications, Vol. 14, Issue 1 https://doi.org/10.1038/s41467-023-36647-1	journal	February 2023
Concentrated electrolytes: decrypting electrolyte properties and reassessing Al corrosion mechanisms McOwen, Dennis W.; Seo, Daniel M.; Borodin, Oleg Energy Environ. Sci., Vol. 7, Issue 1 https://doi.org/10.1039/C3EE42351D	journal	January 2014
An All-Fluorinated Ester Electrolyte for Stable High-Voltage Li Metal Batteries Capable of Ultra-Low-Temperature Operation Holoubek, John; Yu, Mingyu; Yu, Sicen ACS Energy Letters, Vol. 5, Issue 5 https://doi.org/10.1021/acsenergylett.0c00643	journal	April 2020
Achieving High Energy Density through Increasing the Output Voltage: A Highly Reversible 5.3 V Battery Chen, Long; Fan, Xiulin; Hu, Enyuan Chem, Vol. 5, Issue 4 https://doi.org/10.1016/j.chempr.2019.02.003	journal	April 2019
Decomposition of the fluoroethylene carbonate additive and the glue effect of lithium fluoride products for the solid electrolyte interphase: an ab initio study Okuno, Yukihiro; Ushirogata, Keisuke; Sodeyama, Keitaro Physical Chemistry Chemical Physics, Vol. 18, Issue 12 https://doi.org/10.1039/C5CP07583A	journal	January 2016
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
Analysis of Vinylene Carbonate (VC) as Additive in Graphite/LiNi _0.5 Mn _1.5 O ₄ Cells Pritzl, Daniel; Solchenbach, Sophie; Wetjen, Morten Journal of The Electrochemical Society, Vol. 164, Issue 12 https://doi.org/10.1149/2.1441712jes	journal	January 2017
Energy landscape of the charge transfer reaction at the complex Li/SEI/electrolyte interface Li, Yunsong; Qi, Yue Energy & Environmental Science, Vol. 12, Issue 4 https://doi.org/10.1039/C8EE03586E	journal	January 2019
Extremely Stable Sodium Metal Batteries Enabled by Localized High-Concentration Electrolytes Zheng, Jianming; Chen, Shuru; Zhao, Wengao ACS Energy Letters, Vol. 3, Issue 2 https://doi.org/10.1021/acsenergylett.7b01213	journal	January 2018
Rational Design of Fluorinated Electrolytes for Low Temperature Lithium‐Ion Batteries Yoo, Dong‐Joo; Liu, Qian; Cohen, Orion Advanced Energy Materials, Vol. 13, Issue 20 https://doi.org/10.1002/aenm.202204182	journal	April 2023
Soft X-ray Absorption Spectroscopy of Liquids and Solutions Smith, Jacob W.; Saykally, Richard J. Chemical Reviews, Vol. 117, Issue 23 https://doi.org/10.1021/acs.chemrev.7b00213	journal	June 2017
Review—Localized High-Concentration Electrolytes for Lithium Batteries Cao, Xia; Jia, Hao; Xu, Wu Journal of The Electrochemical Society, Vol. 168, Issue 1 https://doi.org/10.1149/1945-7111/abd60e	journal	January 2021
Copper Dissolution in Overdischarged Lithium-ion Cells: X-ray Photoelectron Spectroscopy and X-ray Absorption Fine Structure Analysis Hendricks, Christopher E.; Mansour, Azzam N.; Fuentevilla, Daphne A. Journal of The Electrochemical Society, Vol. 167, Issue 9 https://doi.org/10.1149/1945-7111/ab697a	journal	January 2020
Tuning Two Interfaces with Fluoroethylene Carbonate Electrolytes for High-Performance Li/LCO Batteries Lee, Jinhong; Kim, Yun-Jung; Jin, Hyun Soo ACS Omega, Vol. 4, Issue 2 https://doi.org/10.1021/acsomega.8b03022	journal	February 2019
A study of highly conductive ester co-solvents in Li[Ni0.5Mn0.3Co0.2]O2/Graphite pouch cells Ma, Xiaowei; Li, Jing; Glazier, Stephen L. Electrochimica Acta, Vol. 270 https://doi.org/10.1016/j.electacta.2018.03.006	journal	April 2018
Accessing the robustness of adventitious carbon for charge referencing (correction) purposes in XPS analysis: Insights from a multi-user facility data review Biesinger, Mark C. Applied Surface Science, Vol. 597 https://doi.org/10.1016/j.apsusc.2022.153681	journal	September 2022
High‐Performance Silicon Anodes Enabled By Nonflammable Localized High‐Concentration Electrolytes Jia, Haiping; Zou, Lianfeng; Gao, Peiyuan Advanced Energy Materials, Vol. 9, Issue 31 https://doi.org/10.1002/aenm.201900784	journal	July 2019
A Study of the Physical Properties of Li-Ion Battery Electrolytes Containing Esters Logan, E. R.; Tonita, Erin M.; Gering, K. L. Journal of The Electrochemical Society, Vol. 165, Issue 2 https://doi.org/10.1149/2.0271802jes	journal	January 2018
Electrolyte Design for Fast-Charging Li-Ion Batteries Logan, E. R.; Dahn, J. R. Trends in Chemistry, Vol. 2, Issue 4 https://doi.org/10.1016/j.trechm.2020.01.011	journal	April 2020
Recent Advance in Ionic‐Liquid‐Based Electrolytes for Rechargeable Metal‐Ion Batteries Zhou, Wenjun; Zhang, Meng; Kong, Xiangyue Advanced Science, Vol. 8, Issue 13 https://doi.org/10.1002/advs.202004490	journal	May 2021
Synthesis and Properties of Acyclic Ammonium-based Ionic Liquids with Allyl Substituents as Electrolytes Yim, Taeeun; Choi, Chang Young; Mun, Junyoung Molecules, Vol. 14, Issue 5 https://doi.org/10.3390/molecules14051840	journal	May 2009
Physical characterization of the charging process of a Li-ion battery and prediction of Li plating by electrochemical modelling Legrand, N.; Knosp, B.; Desprez, P. Journal of Power Sources, Vol. 245 https://doi.org/10.1016/j.jpowsour.2013.06.130	journal	January 2014
Rational Design of Electrolytes for Long-Term Cycling of Si Anodes over a Wide Temperature Range Chae, Sujong; Kwak, Won-Jin; Han, Kee Sung ACS Energy Letters, Vol. 6, Issue 2 https://doi.org/10.1021/acsenergylett.0c02214	journal	January 2021
Does Li-ion transport occur rapidly in localized high-concentration electrolytes? Watanabe, Yoshifumi; Ugata, Yosuke; Ueno, Kazuhide Physical Chemistry Chemical Physics, Vol. 25, Issue 4 https://doi.org/10.1039/D2CP05319E	journal	January 2023
Advanced Electrolytes for Fast‐Charging High‐Voltage Lithium‐Ion Batteries in Wide‐Temperature Range Zhang, Xianhui; Zou, Lianfeng; Xu, Yaobin Advanced Energy Materials, Vol. 10, Issue 22 https://doi.org/10.1002/aenm.202000368	journal	April 2020
Thermal Decomposition of LiPF[sub 6]-Based Electrolytes for Lithium-Ion Batteries Campion, Christopher L.; Li, Wentao; Lucht, Brett L. Journal of The Electrochemical Society, Vol. 152, Issue 12 https://doi.org/10.1149/1.2083267	journal	January 2005
Lithium Metal Battery Using LiFe_0.5Mn_0.5PO₄ Olivine Cathode and Pyrrolidinium-Based Ionic Liquid Electrolyte Di Lecce, Daniele; Hassoun, Jusef ACS Omega, Vol. 3, Issue 8 https://doi.org/10.1021/acsomega.8b01328	journal	August 2018
Enabling High-Voltage Lithium-Metal Batteries under Practical Conditions Ren, Xiaodi; Zou, Lianfeng; Cao, Xia Joule, Vol. 3, Issue 7 https://doi.org/10.1016/j.joule.2019.05.006	journal	July 2019
Universal Solvation Model Based on Solute Electron Density and on a Continuum Model of the Solvent Defined by the Bulk Dielectric Constant and Atomic Surface Tensions Marenich, Aleksandr V.; Cramer, Christopher J.; Truhlar, Donald G. The Journal of Physical Chemistry B, Vol. 113, Issue 18, p. 6378-6396 https://doi.org/10.1021/jp810292n	journal	May 2009
Lithium bis(fluorosulfonyl)imide (LiFSI) as conducting salt for nonaqueous liquid electrolytes for lithium-ion batteries: Physicochemical and electrochemical properties Han, Hong-Bo; Zhou, Si-Si; Zhang, Dai-Jun Journal of Power Sources, Vol. 196, Issue 7 https://doi.org/10.1016/j.jpowsour.2010.12.040	journal	April 2011
All-temperature batteries enabled by fluorinated electrolytes with non-polar solvents Fan, Xiulin; Ji, Xiao; Chen, Long Nature Energy, Vol. 4, Issue 10 https://doi.org/10.1038/s41560-019-0474-3	journal	October 2019
A Temperature‐Responsive Electrolyte Endowing Superior Safety Characteristic of Lithium Metal Batteries Zhou, Qian; Dong, Shanmu; Lv, Zhaolin Advanced Energy Materials, Vol. 10, Issue 6 https://doi.org/10.1002/aenm.201903441	journal	December 2019
Nonflammable Electrolytes for Lithium Ion Batteries Enabled by Ultraconformal Passivation Interphases Cao, Xia; Xu, Yaobin; Zhang, Linchao ACS Energy Letters, Vol. 4, Issue 10 https://doi.org/10.1021/acsenergylett.9b01926	journal	September 2019
High-Efficiency Lithium Metal Batteries with Fire-Retardant Electrolytes Chen, Shuru; Zheng, Jianming; Yu, Lu Joule, Vol. 2, Issue 8 https://doi.org/10.1016/j.joule.2018.05.002	journal	August 2018
Fluorinated carboxylate ester-based electrolyte for lithium ion batteries operated at low temperature Yang, Yang; Li, Panlong; Wang, Nan Chemical Communications, Vol. 56, Issue 67 https://doi.org/10.1039/D0CC04049E	journal	January 2020
Effects of Solid Electrolyte Interphase Components on the Reduction of LiFSI over Lithium Metal Kamphaus, Ethan P.; Gomez, Stefany Angarita; Qin, Xueping ChemPhysChem, Vol. 21, Issue 12 https://doi.org/10.1002/cphc.202000174	journal	May 2020
Exceptional long-life performance of lithium-ion batteries using ionic liquid-based electrolytes Elia, Giuseppe Antonio; Ulissi, Ulderico; Jeong, Sangsik Energy & Environmental Science, Vol. 9, Issue 10 https://doi.org/10.1039/C6EE01295G	journal	January 2016
Primary and secondary oxygen-induced C1s binding energy shifts in x-ray photoelectron spectroscopy of polymers Briggs, David.; Beamson, Graham. Analytical Chemistry, Vol. 64, Issue 15 https://doi.org/10.1021/ac00039a018	journal	August 1992
Lithium-ion battery fast charging: A review Tomaszewska, Anna; Chu, Zhengyu; Feng, Xuning eTransportation, Vol. 1 https://doi.org/10.1016/j.etran.2019.100011	journal	August 2019
Structural Interactions within Lithium Salt Solvates: Acyclic Carbonates and Esters Afroz, Taliman; Seo, Daniel M.; Han, Sang-Don The Journal of Physical Chemistry C, Vol. 119, Issue 13 https://doi.org/10.1021/acs.jpcc.5b00309	journal	March 2015
A new approach toward improved low temperature performance of Li-ion battery Zhang, S. S.; Xu, K.; Jow, T. R. Electrochemistry Communications, Vol. 4, Issue 11 https://doi.org/10.1016/S1388-2481(02)00490-3	journal	November 2002
A superconcentrated ether electrolyte for fast-charging Li-ion batteries Yamada, Yuki; Yaegashi, Makoto; Abe, Takeshi Chemical Communications, Vol. 49, Issue 95, p. 11194-11196 https://doi.org/10.1039/c3cc46665e	journal	January 2013
Oxidative Stability and Initial Decomposition Reactions of Carbonate, Sulfone, and Alkyl Phosphate-Based Electrolytes Borodin, Oleg; Behl, Wishvender; Jow, T. Richard The Journal of Physical Chemistry C, Vol. 117, Issue 17 https://doi.org/10.1021/jp400527c	journal	April 2013
Research progress on the surface/interface modification of high-voltage lithium oxide cathode materials Heng, Yong-Li; Gu, Zhen-Yi; Guo, Jin-Zhi Energy Materials, Vol. 2, Issue 3 https://doi.org/10.20517/energymater.2022.18	journal	January 2022
Inhibiting Solvent Co‐Intercalation in a Graphite Anode by a Localized High‐Concentration Electrolyte in Fast‐Charging Batteries Jiang, Li‐Li; Yan, Chong; Yao, Yu‐Xing Angewandte Chemie International Edition, Vol. 60, Issue 7 https://doi.org/10.1002/anie.202009738	journal	December 2020
FSI-inspired solvent and “full fluorosulfonyl” electrolyte for 4 V class lithium-metal batteries Xue, Weijiang; Shi, Zhe; Huang, Mingjun Energy & Environmental Science, Vol. 13, Issue 1 https://doi.org/10.1039/C9EE02538C	journal	January 2020
Electrolyte design for Li-ion batteries under extreme operating conditions Xu, Jijian; Zhang, Jiaxun; Pollard, Travis P. Nature, Vol. 614, Issue 7949 https://doi.org/10.1038/s41586-022-05627-8	journal	February 2023
Effect of the damping function in dispersion corrected density functional theory Grimme, Stefan; Ehrlich, Stephan; Goerigk, Lars Journal of Computational Chemistry, Vol. 32, Issue 7 https://doi.org/10.1002/jcc.21759	journal	March 2011
Fast formation cycling for lithium ion batteries An, Seong Jin; Li, Jianlin; Du, Zhijia Journal of Power Sources, Vol. 342 https://doi.org/10.1016/j.jpowsour.2017.01.011	journal	February 2017
Hexagonal Boron Nitride-Based Electrolyte Composite for Li-Ion Battery Operation from Room Temperature to 150 °C Rodrigues, Marco-Tulio F.; Kalaga, Kaushik; Gullapalli, Hemtej Advanced Energy Materials, Vol. 6, Issue 12 https://doi.org/10.1002/aenm.201600218	journal	April 2016
Highly Stable Lithium Metal Batteries Enabled by Regulating the Solvation of Lithium Ions in Nonaqueous Electrolytes Zhang, Xue-Qiang; Chen, Xiang; Cheng, Xin-Bing Angewandte Chemie, Vol. 130, Issue 19 https://doi.org/10.1002/ange.201801513	journal	March 2018
The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: two new functionals and systematic testing of four M06-class functionals and 12 other functionals Zhao, Yan; Truhlar, Donald G. Theoretical Chemistry Accounts, Vol. 120, Issue 1-3 https://doi.org/10.1007/s00214-007-0310-x	journal	July 2007
Thin Film NCM Cathodes as Model Systems to Assess the Influence of Coating Layers on the Electrochemical Performance of Lithium Ion Batteries Hemmelmann, Hendrik; Dinter, Julius K.; Elm, Matthias T. Advanced Materials Interfaces, Vol. 8, Issue 9 https://doi.org/10.1002/admi.202002074	journal	March 2021
A Guide to Ethylene Carbonate-Free Electrolyte Making for Li-Ion Cells Ma, Lin; Glazier, S. L.; Petibon, R. Journal of The Electrochemical Society, Vol. 164, Issue 1 https://doi.org/10.1149/2.0191701jes	journal	November 2016
Ester-Based Electrolytes for Fast Charging of Energy Dense Lithium-Ion Batteries Logan, E. R.; Hall, D. S.; Cormier, Marc M. E. The Journal of Physical Chemistry C, Vol. 124, Issue 23 https://doi.org/10.1021/acs.jpcc.0c02370	journal	May 2020
Quantification of Heterogeneous Degradation in Li‐Ion Batteries Yang, Yang; Xu, Rong; Zhang, Kai Advanced Energy Materials, Vol. 9, Issue 25 https://doi.org/10.1002/aenm.201900674	journal	May 2019
Effect of Ambient Storage on the Degradation of Ni-Rich Positive Electrode Materials (NMC811) for Li-Ion Batteries Jung, Roland; Morasch, Robert; Karayaylali, Pinar Journal of The Electrochemical Society, Vol. 165, Issue 2 https://doi.org/10.1149/2.0401802jes	journal	January 2018
Systematic and collaborative approach to problem solving using X-ray photoelectron spectroscopy Fairley, Neal; Fernandez, Vincent; Richard‐Plouet, Mireille Applied Surface Science Advances, Vol. 5 https://doi.org/10.1016/j.apsadv.2021.100112	journal	September 2021
Studies of the SEI layers in Li(Ni _0.5 Mn _0.3 Co _0.2 )O ₂ /Artificial Graphite Cells after Formation and after Cycling Keefe, A. S.; Weber, Rochelle; Hill, I. G. Journal of The Electrochemical Society, Vol. 167, Issue 12 https://doi.org/10.1149/1945-7111/abaa1b	journal	January 2020
Revealing electrolyte oxidation via carbonate dehydrogenation on Ni-based oxides in Li-ion batteries by in situ Fourier transform infrared spectroscopy Zhang, Yirui; Katayama, Yu; Tatara, Ryoichi Energy & Environmental Science, Vol. 13, Issue 1 https://doi.org/10.1039/C9EE02543J	journal	January 2020
Progress Towards Extended Cycle Life Si-based Anodes: Investigation of Fluorinated Local High Concentration Electrolytes Lutz, Diana M.; McCarthy, Alison H.; King, Steven T. Journal of The Electrochemical Society, Vol. 169, Issue 9 https://doi.org/10.1149/1945-7111/ac8a1e	journal	September 2022
Static Dielectric Constants of Pure Liquids and Binary Liquid Mixtures Wohlfarth, Christian; Lechner, M. D. Landolt-Börnstein - Group IV Physical Chemistry, Vol. 27 https://doi.org/10.1007/978-3-662-48168-4	book	January 2015
Anion–Diluent Pairing for Stable High-Energy Li Metal Batteries Zhu, Chunnan; Sun, Chuangchao; Li, Ruhong ACS Energy Letters, Vol. 7, Issue 4 https://doi.org/10.1021/acsenergylett.2c00232	journal	March 2022
Li-ion battery materials: present and future Nitta, Naoki; Wu, Feixiang; Lee, Jung Tae Materials Today, Vol. 18, Issue 5 https://doi.org/10.1016/j.mattod.2014.10.040	journal	June 2015
Butyronitrile-Based Electrolytes for Fast Charging of Lithium-Ion Batteries Hilbig, Peter; Ibing, Lukas; Winter, Martin Energies, Vol. 12, Issue 15 https://doi.org/10.3390/en12152869	journal	July 2019
Structural Interactions within Lithium Salt Solvates: Cyclic Carbonates and Esters Seo, Daniel M.; Afroz, Taliman; Allen, Joshua L. The Journal of Physical Chemistry C, Vol. 118, Issue 45 https://doi.org/10.1021/jp5079168	journal	November 2014

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