Photolysis-driven bond activation by thorium and uranium tetraosmate polyhydride complexes

Ye, Christopher Z.; Del Rosal, Iker; Kelly, Sheridon N.; Brackbill, I. Joseph; Maron, Laurent; Camp, Clément; Arnold, John

doi:10.1039/D4SC02380C

Title: Photolysis-driven bond activation by thorium and uranium tetraosmate polyhydride complexes

Journal Article · 25 June 2024 · Chemical Science

DOI: https://doi.org/10.1039/D4SC02380C · OSTI ID:2367399

^[1];

^[2];

^[1];

^[1]; Maron, Laurent ^[2];

^[3];

^[1]

Department of Chemistry, Chemical Sciences Division, Lawrence Berkeley National Laboratory, University of California, Berkeley, California 94720, USA
LPCNO, INSA Toulouse, Université de Toulouse, 135 Avenue de Rangueil, Toulouse 31077, France
Laboratory of Catalysis, Polymerization, Processes and Materials, CP2M UMR 5128, CNRS, CPE-Lyon, Institut de Chimie de Lyon, Université Claude Bernard Lyon 1, 43 Bd du 11 Novembre 1918, 69616 Villeurbanne, France

We report the synthesis of actinide–osmium polyhydrides and demonstrate their ability to promote photo-induced intra- and intermolecular C–H activation.

View Journal Article

Cite

Export

Save

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-05CH11231; NA0003996

OSTI ID:: 2367399

Alternate ID(s):: OSTI ID: 2472434

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 25 Vol. 15; ISSN 2041-6520; ISSN CSHCBM

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (71)

Dihydrogen Complexes as Homogeneous Reduction Catalysts Esteruelas, Miguel A.; Oro, Luis A. Chemical Reviews, Vol. 98, Issue 2 https://doi.org/10.1021/cr970322u	journal	April 1998
New lanthanide–hydrogen–transition metal compounds: [{(PMe₃)₃WH₅}₂Yb·L₃] and [{(η-C₅H₅)₂NbH₂}₂Yb·L₃] where L₃=(MeOCH₂CH₂)₂O Green, Malcolm L. H.; Hughes, Andrew K.; Michaelidou, Despo M. J. Chem. Soc., Chem. Commun., Issue 7 https://doi.org/10.1039/C39930000591	journal	January 1993
Bimetallic Cleavage of Aromatic C–H Bonds by Rare-Earth-Metal Complexes Huang, Wenliang; Dulong, Florian; Khan, Saeed I. Journal of the American Chemical Society, Vol. 136, Issue 50 https://doi.org/10.1021/ja510761j	journal	December 2014
Insertion, protonolysis and photolysis reactivity of a thorium monoalkyl amidinate complex Settineri, Nicholas S.; Arnold, John Chemical Science, Vol. 9, Issue 10 https://doi.org/10.1039/C7SC05328B	journal	January 2018
Bridging phenyl ligands. Unsaturated mercury-triosmium carbonyl cluster complexes containing bridging phenyl ligands Adams, Richard D.; Luo, Zhongwen; Wong, Yuen Onn Journal of Organometallic Chemistry, Vol. 784 https://doi.org/10.1016/j.jorganchem.2014.08.009	journal	May 2015
Cooperative dihydrogen activation with unsupported uranium–metal bonds and characterization of a terminal U(iv) hydride Ward, Robert J.; Rungthanaphatsophon, Pokpong; Huang, Patrick Chemical Science, Vol. 14, Issue 43 https://doi.org/10.1039/D3SC04857H	journal	January 2023
Synthesis, structure, and reactivity of heterometallic polyhydride complexes of rhenium with yttrium and lutetium Alvarez, Daniel; Caulton, Kenneth G.; Evans, William J. Inorganic Chemistry, Vol. 31, Issue 26 https://doi.org/10.1021/ic00052a028	journal	December 1992
Photochemistry of Transition Metal Hydrides Perutz, Robin N.; Procacci, Barbara Chemical Reviews, Vol. 116, Issue 15 https://doi.org/10.1021/acs.chemrev.6b00204	journal	June 2016
Synthesis and Characterization of Osmium Polyhydrides. X-ray Crystal Structures of (C₅Me₅)OsH₅and (C₅Me₅)₂Os₂H₄ Gross, Christopher L.; Girolami, Gregory S. Organometallics, Vol. 26, Issue 1 https://doi.org/10.1021/om060920b	journal	December 2006
.sigma.-Bond metathesis for carbon-hydrogen bonds of hydrocarbons and Sc-R (R = H, alkyl, aryl) bonds of permethylscandocene derivatives. Evidence for noninvolvement of the .pi. system in electrophilic activation of aromatic and vinylic C-H bonds Thompson, Mark E.; Baxter, Steven M.; Bulls, A. Ray Journal of the American Chemical Society, Vol. 109, Issue 1 https://doi.org/10.1021/ja00235a031	journal	January 1987
Nickel Hydride Complexes Eberhardt, Nathan A.; Guan, Hairong Chemical Reviews, Vol. 116, Issue 15 https://doi.org/10.1021/acs.chemrev.6b00259	journal	June 2016
Heterometallic Polyhydride Complexes Containing Yttrium Hydrides with Different Cp Ligands: Synthesis, Structure, and Hydrogen‐Uptake/Release Properties Shima, Takanori; Hou, Zhaomin Chemistry – A European Journal, Vol. 19, Issue 10 https://doi.org/10.1002/chem.201203495	journal	January 2013
Construction of heterometallic clusters with multiple uranium–metal bonds by using dianionic nitrogen–phosphorus ligands Feng, Genfeng; McCabe, Karl N.; Wang, Shuao Chemical Science, Vol. 11, Issue 29 https://doi.org/10.1039/D0SC00389A	journal	January 2020
Homoleptic uranium and lanthanide phosphinodiboranates Blake, Anastasia V.; Fetrow, Taylor V.; Theiler, Zachary J. Chemical Communications, Vol. 54, Issue 44 https://doi.org/10.1039/C8CC02862A	journal	January 2018
Activation and Dehydrogenative Silylation of the C–H Bonds of Phosphine-coordinated Ruthenium in Lu/Ru Heteromultimetallic Hydride Complexes Shima, Takanori; Hou, Zhaomin Chemistry Letters, Vol. 37, Issue 3 https://doi.org/10.1246/cl.2008.298	journal	February 2008
Hydrogen in actinides: electronic and lattice properties Havela, Ladislav; Legut, Dominik; Kolorenč, Jindřich Reports on Progress in Physics, Vol. 86, Issue 5 https://doi.org/10.1088/1361-6633/acbe50	journal	April 2023
Organolanthanide and organoyttrium hydride chemistry. 6. Direct synthesis and proton NMR spectral analysis of the trimetallic yttrium and yttrium-zirconium tetrahydride complexes, {[(C5H5)2YH]3H}{Li(THF)4} and {[(CH3C5H4)2YH]2[(CH3C5H4)2ZrH]H} Evans, William J.; Meadows, James H.; Hanusa, Timothy P. Journal of the American Chemical Society, Vol. 106, Issue 16 https://doi.org/10.1021/ja00328a027	journal	August 1984
A novel dinuclear tetrahydride bridged ruthenium complex, (.eta.5-C5Me5)Ru(.mu.-H)4Ru(.eta.5-C5Me5) Suzuki, Hiroharu; Omori, Hideki; Lee, Dong Hwan Organometallics, Vol. 7, Issue 10 https://doi.org/10.1021/om00100a032	journal	October 1988
Multiple C−H Bond Activation of Phenyl-Substituted Pyrimidines and Triazines Promoted by an Osmium Polyhydride: Formation of Osmapolycycles with Three, Five, and Eight Fused Rings Esteruelas, Miguel A.; Fernández, Israel; Herrera, Antonio Organometallics, Vol. 29, Issue 4 https://doi.org/10.1021/om901030q	journal	January 2010
Lanthanide Terminal Hydride Complexes Bearing Two Sterically Demanding C ₅ Me ₄ SiMe ₃ Ligands. Synthesis, Structure, and Reactivity Takenaka, Yasumasa; Hou, Zhaomin Organometallics, Vol. 28, Issue 17 https://doi.org/10.1021/om900453j	journal	September 2009
Synthesis and Transformations of Triosmium Carbonyl Cluster Complexes Containing Bridging Aryl Ligands Adams, Richard D.; Rassolov, Vitaly; Zhang, Qiang Organometallics, Vol. 31, Issue 8 https://doi.org/10.1021/om300235n	journal	April 2012
Synthesis of a hydride-rich uranium-rhenium dimer: [(p-F-C6H4)3P]2ReH6U(η-C5H5)3 Baudry, Denise; Ephritikhine, Michel Journal of Organometallic Chemistry, Vol. 311, Issue 1-2 https://doi.org/10.1016/0022-328X(86)80231-5	journal	September 1986
Aromatic Diosmatricyclic Nitrogen-Containing Compounds Esteruelas, Miguel A.; Masamunt, Ana B.; Oliván, Montserrat Journal of the American Chemical Society, Vol. 130, Issue 35 https://doi.org/10.1021/ja8048892	journal	August 2008
Chemical structure and bonding in a thorium( iii )–aluminum heterobimetallic complex Altman, Alison B.; Brown, Alexandra C.; Rao, Guodong Chemical Science, Vol. 9, Issue 18 https://doi.org/10.1039/C8SC01260A	journal	January 2018
Rare Earth/d-Transition Metal Heteromultimetallic Polyhydride Complexes Based on Half-Sandwich Rare Earth Moieties Shima, Takanori; Hou, Zhaomin Organometallics, Vol. 28, Issue 7 https://doi.org/10.1021/om900024q	journal	March 2009
14-Coordinate uranium(IV). Structure of uranium borohydride by single-crystal neutron diffraction Bernstein, E. R.; Hamilton, Walter C.; Keiderling, T. A. Inorganic Chemistry, Vol. 11, Issue 12 https://doi.org/10.1021/ic50118a027	journal	December 1972
Synthesis and Properties of a Fifteen-Coordinate Complex: The Thorium Aminodiboranate [Th(H3BNMe2BH3)4] Daly, Scott R.; Piccoli, Paula M. B.; Schultz, Arthur J. Angewandte Chemie International Edition, Vol. 49, Issue 19 https://doi.org/10.1002/anie.200905797	journal	March 2010
Reduction of Transition-Metal-Coordinated Carbon Monoxide by a Rare-Earth Hydride Cluster: Isolation of Well-Defined Heteromultimetallic Oxycarbene, Oxymethyl, Carbene, and Methyl Complexes Takenaka, Yasumasa; Shima, Takanori; Baldamus, Jens Angewandte Chemie International Edition, Vol. 48, Issue 42 https://doi.org/10.1002/anie.200903660	journal	October 2009
Mononuclear Organometallic Platinum(II) Complexes and Platinum(II)−Copper(I) Mixed Complexes from Symmetrical 3,5-Bis(iminoacetyl)pyrazolate Ligands Moret, Marc-Etienne; Chen, Peter Organometallics, Vol. 27, Issue 19 https://doi.org/10.1021/om800403y	journal	September 2008
Interaction of Organoplatinum(II) Complexes with Monovalent Coinage Metal Triflates Moret, Marc-Etienne; Chen, Peter Journal of the American Chemical Society, Vol. 131, Issue 15 https://doi.org/10.1021/ja900449y	journal	April 2009
A versatile strategy for the formation of hydride-bridged actinide–iridium multimetallics Ye, Christopher Z.; Del Rosal, Iker; Boreen, Michael A. Chemical Science, Vol. 14, Issue 4 https://doi.org/10.1039/D2SC04903A	journal	January 2023
New actinide hydrogen transition metal compounds. Synthesis of [K(C ₁₂ H ₂₄ O ₆ )][(η-C ₅ Me ₅ ) ₂ (Cl)UH ₆ Re(PPh ₃ ) ₂ ] and the crystal structure of its benzene solvate Cendrowski-Guillaume, Sophie M.; Lance, Monique; Nierlich, Martine J. Chem. Soc., Chem. Commun., Issue 14 https://doi.org/10.1039/C39940001655	journal	January 1994
X-ray Crystal Structure of Thorium Tetrahydroborate, Th(BH₄)₄, and Computational Studies of An(BH₄)₄ (An = Th, U) Dunbar, Andrew C.; Wright, Joseph C.; Grant, Daniel J. Inorganic Chemistry, Vol. 60, Issue 16 https://doi.org/10.1021/acs.inorgchem.1c01710	journal	August 2021
Structural variation in copper( i ) complexes with pyridylmethylamide ligands: structural analysis with a new four-coordinate geometry index, τ ₄ Yang, Lei; Powell, Douglas R.; Houser, Robert P. Dalton Trans., Issue 9 https://doi.org/10.1039/B617136B	journal	January 2007
Coinage Metal Hydrides: Synthesis, Characterization, and Reactivity Jordan, Abraham J.; Lalic, Gojko; Sadighi, Joseph P. Chemical Reviews, Vol. 116, Issue 15 https://doi.org/10.1021/acs.chemrev.6b00366	journal	June 2016
Preparation and reactions of tetrahydrido(pentamethylcyclopentadienyl)iridium: a novel iridium(V) polyhydride Gilbert, Thomas M.; Bergman, Robert G. Organometallics, Vol. 2, Issue 10 https://doi.org/10.1021/om50004a037	journal	October 1983
Molecular heterometallic hydride clusters composed of rare-earth and d-transition metals Shima, Takanori; Luo, Yi; Stewart, Timothy Nature Chemistry, Vol. 3, Issue 10 https://doi.org/10.1038/nchem.1147	journal	September 2011
Synthesis and Characterization of (C5Me5)2Os2Br4 and the Osmium Polyhydride (C5Me5)OsH5: A New Synthetic Entry into Mono(pentamethylcyclopentadienyl)osmium Chemistry Gross, Christopher L.; Wilson, Scott R.; Girolami, Gregory S. Journal of the American Chemical Society, Vol. 116, Issue 22 https://doi.org/10.1021/ja00101a057	journal	November 1994
Photophysical and Theoretical Studies on Luminescent Tetranuclear Coinage Metal Building Blocks Fernández, Eduardo J.; Laguna, Antonio; López-de-Luzuriaga, José M. Organometallics, Vol. 25, Issue 15 https://doi.org/10.1021/om060181z	journal	June 2006
Mn-, Fe-, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins Crossley, Steven W. M.; Obradors, Carla; Martinez, Ruben M. Chemical Reviews, Vol. 116, Issue 15 https://doi.org/10.1021/acs.chemrev.6b00334	journal	June 2016
Reaction of a Heterobimetallic Polyhydrido Cluster, [CpRu(μ-H)₄OsCp] (Cp* = η⁵-C₅Me₅), with Diphenylacetylene. Regioselective C−H Bond Activation at the Osmium Center Shima, Takanori; Ichikawa, Toshiaki; Suzuki, Hiroharu Organometallics, Vol. 26, Issue 25 https://doi.org/10.1021/om700606q	journal	October 2007
Metal–Metal Bonding in Uranium–Group 10 Complexes Hlina, Johann A.; Pankhurst, James R.; Kaltsoyannis, Nikolas Journal of the American Chemical Society, Vol. 138, Issue 10 https://doi.org/10.1021/jacs.5b10698	journal	March 2016
Lanthanide–tungsten heterobimetallic complexes viaσ-bond metathesis Radu, Nora S.; Gantzel, Peter K.; Tilley, T. Don J. Chem. Soc., Chem. Commun., Vol. 0, Issue 10 https://doi.org/10.1039/C39940001175	journal	January 1994
Synthesis and reactivity of hydrogen-rich uranium–rhenium compounds; an unsuspected detrimental effect of alkali-metal halide on chemical metathesis Cendrowski-Guillaume, Sophie M.; Ephritikhine, Michel J. Chem. Soc., Dalton Trans., Issue 8 https://doi.org/10.1039/DT9960001487	journal	January 1996
Syntheses and Structures of the Crystalline, Highly Crowded 1,3-Bis(trimethylsilyl)cyclopentadienyls [MCp″ ₃ ] (M = Y, Er, Yb), [PbCp″ ₂ ], [{YCp″ ₂ (μ-OH)} ₂ ], [(ScCp″ ₂ ) ₂ (μ-η ² :η ² -C ₂ H ₄ )], [YbCp″ ₂ Cl(μ-Cl)K(18-crown-6)], and [{KCp″} _∞ ] Coles, Martyn P.; Hitchcock, Peter B.; Lappert, Michael F. Organometallics, Vol. 31, Issue 7 https://doi.org/10.1021/om2009364	journal	December 2011
Uranium azide photolysis results in C–H bond activation and provides evidence for a terminal uranium nitride Thomson, Robert K.; Cantat, Thibault; Scott, Brian L. Nature Chemistry, Vol. 2, Issue 9 https://doi.org/10.1038/nchem.705	journal	July 2010
Osmium- and Iridium-Promoted C–H Bond Activation of 2,2′-Bipyridines and Related Heterocycles: Kinetic and Thermodynamic Preferences Cancela, Lara; Esteruelas, Miguel A.; López, Ana M. Organometallics, Vol. 39, Issue 11 https://doi.org/10.1021/acs.organomet.0c00156	journal	May 2020
Unsaturated Triosmium Carbonyl Cluster Complexes with Bridging Aryl Ligands: Structures, Bonding, and Transformations Adams, Richard D.; Rassolov, Vitaly; Zhang, Qiang Organometallics, Vol. 32, Issue 21 https://doi.org/10.1021/om4007399	journal	October 2013
Photochemical Route to Actinide-Transition Metal Bonds: Synthesis, Characterization and Reactivity of a Series of Thorium and Uranium Heterobimetallic Complexes Ward, Ashleigh L.; Lukens, Wayne W.; Lu, Connie C. Journal of the American Chemical Society, Vol. 136, Issue 9 https://doi.org/10.1021/ja413192m	journal	February 2014
Cs[H ₂ NB ₂ (C ₆ F ₅ ) ₆ ] Featuring an Unequivocal 16-Coordinate Cation Pollak, David; Goddard, Richard; Pörschke, Klaus-Richard Journal of the American Chemical Society, Vol. 138, Issue 30 https://doi.org/10.1021/jacs.6b02590	journal	June 2016
Cobalt-centred boron molecular drums with the highest coordination number in the CoB16− cluster Popov, Ivan A.; Jian, Tian; Lopez, Gary V. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9654	journal	October 2015
Covalent radii revisited Cordero, Beatriz; Gómez, Verónica; Platero-Prats, Ana E. Dalton Transactions, Issue 21 https://doi.org/10.1039/b801115j	journal	January 2008
Azole Assisted C–H Bond Activation Promoted by an Osmium-Polyhydride: Discerning between N and NH Eguillor, Beatriz; Esteruelas, Miguel A.; Fernández, Israel Organometallics, Vol. 34, Issue 10 https://doi.org/10.1021/acs.organomet.5b00174	journal	May 2015
NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist Fulmer, Gregory R.; Miller, Alexander J. M.; Sherden, Nathaniel H. Organometallics, Vol. 29, Issue 9 https://doi.org/10.1021/om100106e	journal	May 2010
Osmium-Mediated Direct C–H Bond Activation at the 8-Position of Quinolines Esteruelas, Miguel A.; Larramona, Carmen; Oñate, Enrique Organometallics, Vol. 35, Issue 11 https://doi.org/10.1021/acs.organomet.6b00264	journal	May 2016
Heterometallic Hydride Complexes of Rare-Earth Metals and Ruthenium through C–H Bond Activation Sobaczynski, Adam P.; Bauer, Tobias; Kempe, Rhett Organometallics, Vol. 32, Issue 5 https://doi.org/10.1021/om301039g	journal	December 2012
Heterobimetallic Polyhydride Complex, CpRu(μ-H)₄OsCp (Cp* = η⁵-C₅Me₅). Synthesis and Reaction with Ethylene Shima, Takanori; Suzuki, Hiroharu Organometallics, Vol. 24, Issue 16 https://doi.org/10.1021/om0503996	journal	July 2005
Reversible opening and closing of hetero trimetallic units in (C5H5)2Y(THF)Re2H7(PMe2Ph)4 and (C5H5)2LuRe2H7(PMe2Ph)4 Alvarez, Daniel; Caulton, Kenneth G.; Evans, William J. Journal of the American Chemical Society, Vol. 112, Issue 14 https://doi.org/10.1021/ja00170a061	journal	July 1990
Bismetallocenes: Lanthanoid-Transition-Metal Bonds through Alkane Elimination Butovskii, M. V.; Tok, O. L.; Wagner, F. R. Angewandte Chemie International Edition, Vol. 47, Issue 34 https://doi.org/10.1002/anie.200800407	journal	August 2008
A Crystallizable f-Element Tuck-In Complex: The Tuck-in Tuck-over Uranium Metallocene [(C ₅ Me ₅ )U{μ-η ⁵ :η ¹ :η ¹ -C ₅ Me ₃ (CH ₂ ) ₂ }(μ-H) ₂ U(C ₅ Me ₅ ) ₂ ] Evans, William J.; Miller, Kevin A.; DiPasquale, Antonio G. Angewandte Chemie International Edition, Vol. 47, Issue 27 https://doi.org/10.1002/anie.200801062	journal	June 2008
Hydrogen for Fluorine Exchange in C ₆ F ₆ and C ₆ F ₅ H by Monomeric [1,3,4-(Me ₃ C) ₃ C ₅ H ₂ ] ₂ CeH: Experimental and Computational Studies Maron, Laurent; Werkema, Evan L.; Perrin, Lionel Journal of the American Chemical Society, Vol. 127, Issue 1 https://doi.org/10.1021/ja0451012	journal	January 2005
Interactions of cis-P2PtX2 Complexes (X = H, Me) with Bis(pentamethylcyclopentadienyl)ytterbium Schwartz, David J.; Ball, Graham E.; Andersen, Richard A. Journal of the American Chemical Society, Vol. 117, Issue 22 https://doi.org/10.1021/ja00127a016	journal	June 1995
A Crystallizable Dinuclear Tuck-In-Tuck-Over Tuck-Over Dialkyl Tren Uranium Complex and Double Dearylation of BPh ₄ ⁻ To Give the BPh ₂ -Functionalized Metallocycle [U{N(CH ₂ CH ₂ NSiMe ₃ ) ₂ (CH ₂ CH ₂ NSiMe ₂ CHBPh ₂ )}(THF)] Gardner, Benedict M.; McMaster, Jonathan; Lewis, William Journal of the American Chemical Society, Vol. 131, Issue 30 https://doi.org/10.1021/ja904459q	journal	August 2009
High coordination number actinide-noble gas complexes; a computational study Yang, Lin; Cooper, Sophie; Kaltsoyannis, Nikolas Physical Chemistry Chemical Physics, Vol. 23, Issue 7 https://doi.org/10.1039/D0CP06175A	journal	January 2021
Spontaneous reduction and C–H borylation of arenes mediated by uranium(III) disproportionation Arnold, Polly L.; Mansell, Stephen M.; Maron, Laurent Nature Chemistry, Vol. 4, Issue 8 https://doi.org/10.1038/nchem.1392	journal	July 2012
Isolation and characterization of a uranium(VI)–nitride triple bond King, David M.; Tuna, Floriana; McInnes, Eric J. L. Nature Chemistry, Vol. 5, Issue 6 https://doi.org/10.1038/nchem.1642	journal	May 2013
Synthesis, Structure, and Reactions of Hydride, Borohydride, and Aluminohydride Compounds of the f-Elements Ephritikhine, Michel Chemical Reviews, Vol. 97, Issue 6 https://doi.org/10.1021/cr960366n	journal	October 1997
Ab initio study on the structure and H2 dissociation reaction of a tetrahydride-bridged dinuclear Ru complex, (C5H5)Ru(μ-H)4Ru(C5H5) Koga, Nobuaki; Morokuma, Keiji Journal of Molecular Structure, Vol. 300 https://doi.org/10.1016/0022-2860(93)87016-3	journal	December 1993
Cooperative activation of carbon–hydrogen bonds by heterobimetallic systems Lachguar, Abdelhak; Pichugov, Andrey V.; Neumann, Till Dalton Transactions, Vol. 53, Issue 4 https://doi.org/10.1039/D3DT03571A	journal	January 2024
Synthesis and Characterization of Chelating Alkyl-borohydride Complexes of Thorium and Uranium: Th(CH₂NMe₂BH₃)₄ and U(CH₂NMe₂BH₃)₄ Lastowski, R. Joseph; Caroff, Christopher M.; Vogiatzis, Konstantinos D. Organometallics, Vol. 42, Issue 19 https://doi.org/10.1021/acs.organomet.3c00306	journal	September 2023
PNP-Ligated Heterometallic Rare-Earth/Ruthenium Hydride Complexes Bearing Phosphinophenyl and Phosphinomethyl Bridging Ligands O., Wylie W. N.; Kang, Xiaohui; Luo, Yi Organometallics, Vol. 33, Issue 4 https://doi.org/10.1021/om401216v	journal	February 2014

Similar Records

Investigations of thermal and photochemical arene displacement reactions from ruthenium and osmium arene complexes. 2. Photochemical carbon-hydrogen bond activation via the photolysis of iridium(III) azide and oxalate complexes

Thesis/Dissertation · 1992 · OSTI ID:5517731

Freedman, D A

Polyhydride and dihydrogen complexes: Structure and reactivity

Thesis/Dissertation · 1993 · OSTI ID:6930912

Michos, D

Synthesis and characterization of (pentamethylcyclopentadienyl)iridium polyhydride and polyphosphine complexes

Technical Report · 1985 · OSTI ID:6809018

Gilbert, T M

Title: Photolysis-driven bond activation by thorium and uranium tetraosmate polyhydride complexes

Citation Formats

References (71)

Similar Records

Related Subjects