High-Spin and Reactive Fe13 Cluster with Exposed Metal Sites

Scott, Anna G.; Alves Galico, Diogo; Bogacz, Isabel; Oyala, Paul H.; Yano, Junko; Suturina, Elizaveta A.; Murugesu, Muralee; Agapie, Theodor

doi:10.1002/anie.202313880

Title: High-Spin and Reactive Fe₁₃ Cluster with Exposed Metal Sites

Journal Article · 23 October 2023 · Angewandte Chemie (International Edition)

DOI: https://doi.org/10.1002/anie.202313880 · OSTI ID:2367197

Scott, Anna G. ^[1]; Alves Galico, Diogo ^[2];

^[3]; Oyala, Paul H. ^[1];

^[3];

^[4]; Murugesu, Muralee ^[2];

^[1]

California Institute of Technology (CalTech), Pasadena, CA (United States)
University of Ottawa, ON (Canada)
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Molecular Biophysics and Integrated Bioimaging Division
University of Bath (United Kingdom)

We report atomically defined large metal clusters have applications in new reaction development and preparation of materials with tailored properties. Expanding the synthetic toolbox for reactive high nuclearity metal complexes, we report a new class of Fe clusters, Tp*₄W₄Fe₁₃S₁₂, displaying a Fe₁₃ core with M-M bonds that has precedent only in main group and late metal chemistry. M₁₃ clusters with closed shell electron configurations can show significant stability and have been classified as superatoms. In contrast, Tp*₄W₄Fe₁₃S₁₂ displays a large spin ground state of S=13. This compound performs small molecule activations involving the transfer of up to 12 electrons resulting in significant cluster rearrangements.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Institutes of Health (NIH); National Science Foundation (NSF)

Grant/Contract Number:: AC02-05CH11231; AC02-76SF00515

OSTI ID:: 2367197

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 49 Vol. 62; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (69)

New Intermediate Steps in the Synthesis of Larger Nickel Clusters Fenske, Dieter; Krautscheid, Harald; Müller, Michael Angewandte Chemie International Edition in English, Vol. 31, Issue 3 https://doi.org/10.1002/anie.199203211	journal	March 1992
[(Ph₃PAu)₆(dppeAu₂)(AuCl)₄Pd], an Icosahedral Au₁₂ Cluster with a Central Pd Atom Laupp, Martin; Strähle, Joachim Angewandte Chemie International Edition in English, Vol. 33, Issue 2 https://doi.org/10.1002/anie.199402071	journal	February 1994
A Ferromagnetically Coupled Mn19 Aggregate with a RecordS=83/2 Ground Spin State Ako, Ayuk M.; Hewitt, Ian J.; Mereacre, Valeriu Angewandte Chemie International Edition, Vol. 45, Issue 30 https://doi.org/10.1002/anie.200601467	journal	July 2006
Diselenophosphate-Induced Conversion of an Achiral [Cu ₂₀ H ₁₁ {S ₂ P(O i Pr) ₂ } ₉ ] into a Chiral [Cu ₂₀ H ₁₁ {Se ₂ P(O i Pr) ₂ } ₉ ] Polyhydrido Nanocluster Dhayal, Rajendra S.; Liao, Jian-Hong; Wang, Xiaoping Angewandte Chemie International Edition, Vol. 54, Issue 46 https://doi.org/10.1002/anie.201506736	journal	September 2015
Magnetic “Molecular Oligomers” Based on Decametallic Supertetrahedra: A Giant Mn ₄₉ Cuboctahedron and its Mn ₂₅ Na ₄ Fragment Manoli, Maria; Alexandrou, Sofia; Pham, Linh Angewandte Chemie International Edition, Vol. 55, Issue 2 https://doi.org/10.1002/anie.201509461	journal	November 2015
[Cu ₁₃ {S ₂ CN ⁿ Bu ₂ } ₆ (acetylide) ₄ ] ⁺ : A Two-Electron Superatom Chakrahari, Kiran Kumarvarma; Liao, Jian-Hong; Kahlal, Samia Angewandte Chemie International Edition, Vol. 55, Issue 47 https://doi.org/10.1002/anie.201608609	journal	October 2016
Ligand‐Based Control of Single‐Site vs. Multi‐Site Reactivity by a Trichromium Cluster Bartholomew, Amymarie K.; Juda, Cristin E.; Nessralla, Jonathon N. Angewandte Chemie International Edition, Vol. 58, Issue 17 https://doi.org/10.1002/anie.201901599	journal	March 2019
Controlled Incorporation of Nitrides into W-Fe-S Clusters Xu, Gan; Zhou, Jie; Wang, Zheng Angewandte Chemie International Edition, Vol. 58, Issue 46 https://doi.org/10.1002/anie.201908968	journal	September 2019
Controlled Dimerization and Bonding Scheme of Icosahedral M@Au ₁₂ (M=Pd, Pt) Superatoms Ito, Emi; Takano, Shinjiro; Nakamura, Toshikazu Angewandte Chemie International Edition, Vol. 60, Issue 2 https://doi.org/10.1002/anie.202010342	journal	November 2020
PHI: A powerful new program for the analysis of anisotropic monomeric and exchange-coupled polynuclear d - and f -block complexes Chilton, Nicholas F.; Anderson, Russell P.; Turner, Lincoln D. Journal of Computational Chemistry, Vol. 34, Issue 13 https://doi.org/10.1002/jcc.23234	journal	February 2013
Low valent transition metal clusters containing nitrene/imido ligands Li, Y. Coordination Chemistry Reviews, Vol. 243, Issue 1-2 https://doi.org/10.1016/S0010-8545(03)00082-1	journal	August 2003
Reactions of Ru3(CO)12 with nitrobenzene and aniline Sappa, E.; Milone, L. Journal of Organometallic Chemistry, Vol. 61 https://doi.org/10.1016/S0022-328X(00)86569-9	journal	November 1973
Large metal carbonyl clusters (LMCC) Chini, P. Journal of Organometallic Chemistry, Vol. 200, Issue 1 https://doi.org/10.1016/S0022-328X(00)88636-2	journal	November 1980
Understanding active species in catalytic transformations: From molecular catalysis to nanoparticles, leaching, “Cocktails” of catalysts and dynamic systems Eremin, Dmitry B.; Ananikov, Valentine P. Coordination Chemistry Reviews, Vol. 346 https://doi.org/10.1016/j.ccr.2016.12.021	journal	September 2017
Ubiquity of cubanes in bioinorganic relevant compounds Bigness, Alec; Vaddypally, Shivaiah; Zdilla, Michael J. Coordination Chemistry Reviews, Vol. 450 https://doi.org/10.1016/j.ccr.2021.214168	journal	January 2022
Heterometal cubane-type WFe3S4 and related clusters trigonally symmetrized with hydrotris(3,5-dimethylpyrazolyl)borate Hong, Daewon; Zhang, Yugen; Holm, R. H. Inorganica Chimica Acta, Vol. 358, Issue 7 https://doi.org/10.1016/j.ica.2004.11.051	journal	April 2005
A giant spin molecule with ninety-six parallel unpaired electrons Qin, Lei; Zhang, Hao-Lan; Zhai, Yuan-Qi iScience, Vol. 24, Issue 4 https://doi.org/10.1016/j.isci.2021.102350	journal	April 2021
Superatoms: Electronic and Geometric Effects on Reactivity Reber, Arthur C.; Khanna, Shiv N. Accounts of Chemical Research, Vol. 50, Issue 2 https://doi.org/10.1021/acs.accounts.6b00464	journal	January 2017
Ligand-Exchange-Induced Growth of an Atomically Precise Cu ₂₉ Nanocluster from a Smaller Cluster Nguyen, Thuy-Ai D.; Jones, Zachary R.; Leto, Domenick F. Chemistry of Materials, Vol. 28, Issue 22 https://doi.org/10.1021/acs.chemmater.6b03879	journal	November 2016
Growing Nanoscale Model Surfaces to Enable Correlation of Catalytic Behavior Across Dissimilar Reaction Environments Robertson, Daniel D.; Personick, Michelle L. Chemistry of Materials, Vol. 31, Issue 4 https://doi.org/10.1021/acs.chemmater.8b04595	journal	January 2019
Toward Active-Site Tailoring in Heterogeneous Catalysis by Atomically Precise Metal Nanoclusters with Crystallographic Structures Jin, Rongchao; Li, Gao; Sharma, Sachil Chemical Reviews https://doi.org/10.1021/acs.chemrev.0c00495	journal	September 2020
Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles Liu, Lichen; Corma, Avelino Chemical Reviews, Vol. 118, Issue 10 https://doi.org/10.1021/acs.chemrev.7b00776	journal	April 2018
Atomically Precise Noble Metal Nanoclusters as Efficient Catalysts: A Bridge between Structure and Properties Du, Yuanxin; Sheng, Hongting; Astruc, Didier Chemical Reviews, Vol. 120, Issue 2 https://doi.org/10.1021/acs.chemrev.8b00726	journal	March 2019
Paramagnetic Metal–Metal Bonded Heterometallic Complexes Chipman, Jill A.; Berry, John F. Chemical Reviews, Vol. 120, Issue 5 https://doi.org/10.1021/acs.chemrev.9b00540	journal	February 2020
Insights into Molecular Magnetism in Metal–Metal Bonded Systems as Revealed by a Spectroscopic and Computational Analysis of Diiron Complexes Greer, Samuel M.; Gramigna, Kathryn M.; Thomas, Christine M. Inorganic Chemistry, Vol. 59, Issue 24 https://doi.org/10.1021/acs.inorgchem.0c02605	journal	November 2020
Spectroscopic Investigation of a Metal–Metal-Bonded Fe ₆ Single-Molecule Magnet with an Isolated S = ¹⁹ / ₂ Giant-Spin Ground State Nehrkorn, Joscha; Greer, Samuel M.; Malbrecht, Brian J. Inorganic Chemistry, Vol. 60, Issue 7 https://doi.org/10.1021/acs.inorgchem.0c03595	journal	March 2021
[Ni₂₃Se₁₂(PEt₃)₁₃] Revisited: Isolation and Characterization of [Ni₂₃Se₁₂Cl₃(PEt₃)₁₀] Touchton, Alexander J.; Wu, Guang; Hayton, Trevor W. Inorganic Chemistry, Vol. 60, Issue 23 https://doi.org/10.1021/acs.inorgchem.1c02184	journal	November 2021
Nitride-Bridged Triiron Complex and Its Relevance to Dinitrogen Activation Ermert, David M.; Gordon, Jesse B.; Abboud, Khalil A. Inorganic Chemistry, Vol. 54, Issue 19 https://doi.org/10.1021/acs.inorgchem.5b00825	journal	June 2015
X-ray Absorption and Emission Spectroscopic Studies of [L ₂ Fe ₂ S ₂ ] ⁿ Model Complexes: Implications for the Experimental Evaluation of Redox States in Iron–Sulfur Clusters Kowalska, Joanna K.; Hahn, Anselm W.; Albers, Antonia Inorganic Chemistry, Vol. 55, Issue 9 https://doi.org/10.1021/acs.inorgchem.6b00295	journal	April 2016
The 4-Electron Cleavage of a N═N Double Bond by a Trimetallic TiNi ₂ Complex Dunn, Peter L.; Chatterjee, Sudipta; MacMillan, Samantha N. Inorganic Chemistry, Vol. 58, Issue 17 https://doi.org/10.1021/acs.inorgchem.9b01805	journal	August 2019
Toward Controlled Syntheses of Diphosphine-Protected Homochiral Gold Nanoclusters through Precursor Engineering Si, Wei-Dan; Li, Ying-Zhou; Zhang, Shan-Shan ACS Nano, Vol. 15, Issue 10 https://doi.org/10.1021/acsnano.1c04421	journal	September 2021
Atomically Precise, Thiolated Copper–Hydride Nanoclusters as Single-Site Hydrogenation Catalysts for Ketones in Mild Conditions Sun, Cunfa; Mammen, Nisha; Kaappa, Sami ACS Nano, Vol. 13, Issue 5 https://doi.org/10.1021/acsnano.9b02052	journal	May 2019
Quantum Sized Gold Nanoclusters with Atomic Precision Qian, Huifeng; Zhu, Manzhou; Wu, Zhikun Accounts of Chemical Research, Vol. 45, Issue 9 https://doi.org/10.1021/ar200331z	journal	June 2012
Developments in the Biomimetic Chemistry of Cubane-Type and Higher Nuclearity Iron–Sulfur Clusters Lee, Sonny C.; Lo, Wayne; Holm, R. H. Chemical Reviews, Vol. 114, Issue 7 https://doi.org/10.1021/cr4004067	journal	January 2014
Intramolecular conversion of an azoalkane ligand to two nitrene ligands on a triiron cluster Wucherer, Edward J.; Tasi, Miklos; Hansert, Bernhard Inorganic Chemistry, Vol. 28, Issue 18 https://doi.org/10.1021/ic00317a034	journal	September 1989
Single- and Double-Cubane Clusters in the Multiple Oxidation States [VFe₃S₄]^3+,2+,1+ Hauser, Christina; Bill, Eckhard; Holm, R. H. Inorganic Chemistry, Vol. 41, Issue 6 https://doi.org/10.1021/ic011011b	journal	February 2002
Specific Incorporation of Chalcogenide Bridge Atoms in Molybdenum/Tungsten-Iron-Sulfur Single Cubane Clusters Majumdar, Amit; Holm, R. H. Inorganic Chemistry, Vol. 50, Issue 21 https://doi.org/10.1021/ic2018117	journal	October 2011
X-ray Absorption Spectroscopy Systematics at the Tungsten L-Edge Jayarathne, Upul; Chandrasekaran, Perumalreddy; Greene, Angelique F. Inorganic Chemistry, Vol. 53, Issue 16 https://doi.org/10.1021/ic500256a	journal	July 2014
Reactions of a Tungsten Trisulfido Complex of Hydridotris(3,5-dimethylpyrazol-1-yl)borate (Tp) [Et₄N][TpWS₃] with CuX (X = Cl, NCS, or CN): Isolation, Structures, and Third-Order NLO Properties Wang, Jing; Sun, Zhen-Rong; Deng, Li Inorganic Chemistry, Vol. 46, Issue 26 https://doi.org/10.1021/ic701641h	journal	November 2007
Nickel-selenium-triethylphosphine (Ni23Se12(PEt3)13), an intramolecular intergrowth of nickel selenide (NiSe) and nickel Brennan, J. G.; Siegrist, T.; Kwon, Y. U. Journal of the American Chemical Society, Vol. 114, Issue 26 https://doi.org/10.1021/ja00052a034	journal	December 1992
Kinetically Controlled, High-Yield Synthesis of Au ₂₅ Clusters Zhu, Manzhou; Lanni, Eric; Garg, Niti Journal of the American Chemical Society, Vol. 130, Issue 4 https://doi.org/10.1021/ja0782448	journal	January 2008
Selenium as a Structural Surrogate of Sulfur: Template-Assisted Assembly of Five Types of Tungsten–Iron–Sulfur/Selenium Clusters and the Structural Fate of Chalcogenide Reactants Zheng, Bo; Chen, Xu-Dong; Zheng, Shao-Liang Journal of the American Chemical Society, Vol. 134, Issue 14 https://doi.org/10.1021/ja3010539	journal	April 2012
Ligand-Stabilized Au ₁₃ Cu _x ( x = 2, 4, 8) Bimetallic Nanoclusters: Ligand Engineering to Control the Exposure of Metal Sites Yang, Huayan; Wang, Yu; Lei, Jing Journal of the American Chemical Society, Vol. 135, Issue 26 https://doi.org/10.1021/ja402249s	journal	June 2013
Testing the Polynuclear Hypothesis: Multielectron Reduction of Small Molecules by Triiron Reaction Sites Powers, Tamara M.; Betley, Theodore A. Journal of the American Chemical Society, Vol. 135, Issue 33 https://doi.org/10.1021/ja405057n	journal	August 2013
Chemically Modified Gold/Silver Superatoms as Artificial Elements at Nanoscale: Design Principles and Synthesis Challenges Takano, Shinjiro; Tsukuda, Tatsuya Journal of the American Chemical Society, Vol. 143, Issue 4 https://doi.org/10.1021/jacs.0c11465	journal	January 2021
A Cu ₂₅ Nanocluster with Partial Cu(0) Character Nguyen, Thuy-Ai D.; Jones, Zachary R.; Goldsmith, Bryan R. Journal of the American Chemical Society, Vol. 137, Issue 41 https://doi.org/10.1021/jacs.5b07574	journal	October 2015
Meta-Atom Behavior in Clusters Revealing Large Spin Ground States Hernández Sánchez, Raúl; Betley, Theodore A. Journal of the American Chemical Society, Vol. 137, Issue 43 https://doi.org/10.1021/jacs.5b08962	journal	October 2015
Isolation and Structural Characterization of a Mackay 55-Metal-Atom Two-Shell Icosahedron of Pseudo-I_h Symmetry, Pd₅₅L₁₂(μ₃-CO)₂₀ (L = PR₃, R = Isopropyl): Comparative Analysis with Interior Two-Shell Icosahedral Geometries in Capped Three-Shell Pd₁₄₅, Pt-Centered Four-Shell Pd–Pt M₁₆₅, and Four-Shell Au₁₃₃ Nanoclusters Erickson, Jeremiah D.; Mednikov, Evgueni G.; Ivanov, Sergei A. Journal of the American Chemical Society, Vol. 138, Issue 5 https://doi.org/10.1021/jacs.5b13076	journal	January 2016
Reaction Mechanism and Kinetics for Ammonia Synthesis on the Fe(111) Surface Qian, Jin; An, Qi; Fortunelli, Alessandro Journal of the American Chemical Society, Vol. 140, Issue 20 https://doi.org/10.1021/jacs.7b13409	journal	April 2018
Thermally Persistent High-Spin Ground States in Octahedral Iron Clusters Sánchez, Raúl Hernández; Betley, Theodore A. Journal of the American Chemical Society, Vol. 140, Issue 48 https://doi.org/10.1021/jacs.8b10181	journal	November 2018
Structure and Properties of Fe _n , Fe _n ^– , and Fe _n ⁺ Clusters, n = 7–20 Gutsev, G. L.; Weatherford, C. A.; Jena, P. The Journal of Physical Chemistry A, Vol. 116, Issue 41 https://doi.org/10.1021/jp307284v	journal	October 2012
Cluster-Assembled Materials Claridge, Shelley A.; Castleman, A. W.; Khanna, Shiv N. ACS Nano, Vol. 3, Issue 2 https://doi.org/10.1021/nn800820e	journal	January 2009
Ultrastable silver nanoparticles Desireddy, Anil; Conn, Brian E.; Guo, Jingshu Nature, Vol. 501, Issue 7467 https://doi.org/10.1038/nature12523	journal	September 2013
A ferromagnetically coupled Fe42 cyanide-bridged nanocage Kang, Soonchul; Zheng, Hui; Liu, Tao Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms6955	journal	January 2015
Applications beyond data storage Reiss, Günter; Hütten, Andreas Nature Materials, Vol. 4, Issue 10 https://doi.org/10.1038/nmat1494	journal	October 2005
Superatoms in materials science Doud, Evan A.; Voevodin, Anastasia; Hochuli, Taylor J. Nature Reviews Materials, Vol. 5, Issue 5 https://doi.org/10.1038/s41578-019-0175-3	journal	February 2020
Identification of a spin-coupled Mo( iii ) in the nitrogenase iron–molybdenum cofactor Bjornsson, Ragnar; Lima, Frederico A.; Spatzal, Thomas Chem. Sci., Vol. 5, Issue 8 https://doi.org/10.1039/C4SC00337C	journal	January 2014
Cluster–π electronic interaction in a superatomic Au ₁₃ cluster bearing σ-bonded acetylide ligands Sugiuchi, Mizuho; Shichibu, Yukatsu; Nakanishi, Takayuki Chemical Communications, Vol. 51, Issue 70 https://doi.org/10.1039/C5CC04312C	journal	January 2015
Superatom chemistry: promising properties of near-spherical noble metal clusters Roduner, Emil Physical Chemistry Chemical Physics, Vol. 20, Issue 37 https://doi.org/10.1039/C8CP04651D	journal	January 2018
Reaction mechanism and kinetics for ammonia synthesis on the Fe(211) reconstructed surface Fuller, Jon; Fortunelli, Alessandro; Goddard III, William A. Physical Chemistry Chemical Physics, Vol. 21, Issue 21 https://doi.org/10.1039/C9CP01611B	journal	January 2019
Dimerization of pentanuclear clusters [Fe3Q(AsMe)(CO)9] (Q = Se, Te) as a conversion pathway to novel cubane-like aggregates Pushkarevsky, Nikolay A.; Konchenko, Sergey N.; Zabel, Manfred Dalton Transactions, Vol. 40, Issue 9 https://doi.org/10.1039/c0dt01587c	journal	January 2011
Nanometallic chemistry: deciphering nanoparticle catalysis from the perspective of organometallic chemistry and homogeneous catalysis Yan, Ning; Yuan, Yuan; Dyson, Paul J. Dalton Transactions, Vol. 42, Issue 37 https://doi.org/10.1039/c3dt51180d	journal	January 2013
Stabilizing subnanometer Ag(0) nanoclusters by thiolate and diphosphine ligands and their crystal structures Yang, Huayan; Wang, Yu; Zheng, Nanfeng Nanoscale, Vol. 5, Issue 7 https://doi.org/10.1039/c3nr34328f	journal	January 2013
Dalton communications. The first undecaruthenium hydrido carbonyl anion; synthesis and structural characterisation of [Ru11H(CO)27]3? Bailey, Philip J.; Beswick, Michael A.; Johnson, Brian F. G. Journal of the Chemical Society, Dalton Transactions, Issue 21 https://doi.org/10.1039/dt9920003159	journal	January 1992
Synthesis and structural characterisation of the osmium cluster dianions [Os17(CO)36]2? and [Os20(CO)40]2? Gade, Lutz H.; Johnson, Brian F. G.; Lewis, Jack Journal of the Chemical Society, Dalton Transactions, Issue 4 https://doi.org/10.1039/dt9940000521	journal	January 1994
A unified view of ligand-protected gold clusters as superatom complexes Walter, M.; Akola, J.; Lopez-Acevedo, O. Proceedings of the National Academy of Sciences, Vol. 105, Issue 27 https://doi.org/10.1073/pnas.0801001105	journal	July 2008
Ligand metathesis as rational strategy for the synthesis of cubane-type heteroleptic iron–sulfur clusters relevant to the FeMo cofactor Xu, Gan; Wang, Zheng; Ling, Rong Proceedings of the National Academy of Sciences, Vol. 115, Issue 20 https://doi.org/10.1073/pnas.1801025115	journal	April 2018
Partial synthetic models of FeMoco with sulfide and carbyne ligands: Effect of interstitial atom in nitrogenase active site Le, Linh N. V.; Bailey, Gwendolyn A.; Scott, Anna G. Proceedings of the National Academy of Sciences, Vol. 118, Issue 49 https://doi.org/10.1073/pnas.2109241118	journal	December 2021
Density functional theory investigation of 3 d , 4 d , and 5 d 13-atom metal clusters Piotrowski, Maurício J.; Piquini, Paulo; Da Silva, Juarez L. F. Physical Review B, Vol. 81, Issue 15 https://doi.org/10.1103/PhysRevB.81.155446	journal	April 2010

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
high-spin
iron-sulfur clusters
magnetic properties
metal-metal interactions
small molecule activation

CCDC 2128364: Experimental Crystal Structure Determination G., Scott, Anna; Alves, Galico, Diogo; Isabel, Bogacz, https://doi.org/10.5517/ccdc.csd.cc29fqxd The current record is supplemented by this dataset	dataset	January 2023
CCDC 2128365: Experimental Crystal Structure Determination G., Scott, Anna; Alves, Galico, Diogo; Isabel, Bogacz, https://doi.org/10.5517/ccdc.csd.cc29fqyf The current record is supplemented by this dataset	dataset	January 2023
CCDC 2128366: Experimental Crystal Structure Determination G., Scott, Anna; Alves, Galico, Diogo; Isabel, Bogacz, https://doi.org/10.5517/ccdc.csd.cc29fqzg The current record is supplemented by this dataset	dataset	January 2023
CCDC 2128367: Experimental Crystal Structure Determination G., Scott, Anna; Alves, Galico, Diogo; Isabel, Bogacz, https://doi.org/10.5517/ccdc.csd.cc29fr0j The current record is supplemented by this dataset	dataset	January 2023

Title: High-Spin and Reactive Fe13 Cluster with Exposed Metal Sites

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Title: High-Spin and Reactive Fe₁₃ Cluster with Exposed Metal Sites