Realizing synergy between Cu, Ga, and Zr for selective CO2 hydrogenation to methanol

Al Abdulghani, Abdullah J.; Turizo-Pinilla, Edgar E.; Fabregas-Angulo, Maria J.; Hagmann, Ryan H.; Ibrahim, Faysal; Jansen, Jacob H.; Agbi, Theodore O.; Bhat, Samiha; Sepúlveda-Pagán, Miguel; Kraimer, Morgan O.; Queen, Collin M.; Sun, Zhuoran; Nikolla, Eranda; Pagán-Torres, Yomaira J.; Hermans, Ive

doi:10.1016/j.apcatb.2024.124198

Title: Realizing synergy between Cu, Ga, and Zr for selective CO2 hydrogenation to methanol

Journal Article · 30 September 2024 · Applied Catalysis. B, Environmental

DOI: https://doi.org/10.1016/j.apcatb.2024.124198 · OSTI ID:2352366

Al Abdulghani, Abdullah J.; Turizo-Pinilla, Edgar E.; Fabregas-Angulo, Maria J.; Hagmann, Ryan H.;

; Jansen, Jacob H.; Agbi, Theodore O.;

; Sepúlveda-Pagán, Miguel; Kraimer, Morgan O.; Queen, Collin M.; Sun, Zhuoran;

; Pagán-Torres, Yomaira J.;

Not Available

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE

OSTI ID:: 2352366

Journal Information:: Applied Catalysis. B, Environmental, Journal Name: Applied Catalysis. B, Environmental Journal Issue: C Vol. 355; ISSN 0926-3373

Publisher:: ElsevierCopyright Statement

Country of Publication:: Netherlands

Language:: English

References (71)

Lewis Acid Strength of Interfacial Metal Sites Drives CH ₃ OH Selectivity and Formation Rates on Cu‐Based CO ₂ Hydrogenation Catalysts Noh, Gina; Lam, Erwin; Bregante, Daniel T. Angewandte Chemie International Edition, Vol. 60, Issue 17 https://doi.org/10.1002/anie.202100672	journal	March 2021
Mapping Support Interactions in Copper Catalysts Chatterjee, Rishika; Kuld, Sebastian; van den Berg, Roy Topics in Catalysis, Vol. 62, Issue 7-11 https://doi.org/10.1007/s11244-019-01150-9	journal	February 2019
Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Sc, Ti, V, Cu and Zn Biesinger, Mark C.; Lau, Leo W. M.; Gerson, Andrea R. Applied Surface Science, Vol. 257, Issue 3 https://doi.org/10.1016/j.apsusc.2010.07.086	journal	November 2010
Recent advancements and perspectives of the CO2 hydrogenation reaction Wang, Wenhang; Zeng, Chunyang; Tsubaki, Noritatsu Green Carbon, Vol. 1, Issue 2 https://doi.org/10.1016/j.greenca.2023.10.003	journal	December 2023
Interaction of Gallium with a Copper Surface: Surface Alloying and Formation of Ordered Structures Lee, Si Woo; Subramanian, Arravind; Zamudio, Fernando Buendia The Journal of Physical Chemistry C, Vol. 127, Issue 42 https://doi.org/10.1021/acs.jpcc.3c05711	journal	October 2023
Ultraviolet-induced Ostwald ripening strategy towards a mesoporous Ga₂O₃/GaOOH heterojunction composite with a controllable structure for enhanced photocatalytic hydrogen evolution Zheng, Yuenan; Fan, Meihong; Li, Kaiqian Catalysis Science & Technology, Vol. 10, Issue 9 https://doi.org/10.1039/D0CY00303D	journal	January 2020
Active sites for CO ₂ hydrogenation to methanol on Cu/ZnO catalysts Kattel, Shyam; Ramírez, Pedro J.; Chen, Jingguang G. Science, Vol. 355, Issue 6331 https://doi.org/10.1126/science.aal3573	journal	March 2017
Zr(IV) surface sites determine CH3OH formation rate on Cu/ZrO2/SiO2 - CO2 hydrogenation catalysts Lam, Erwin; Larmier, Kim; Tada, Shohei Chinese Journal of Catalysis, Vol. 40, Issue 11 https://doi.org/10.1016/S1872-2067(19)63348-6	journal	November 2019
CO2 hydrogenation to methanol over Cu/ZnO/ZrO2 catalysts prepared by precipitation-reduction method Dong, Xiaosu; Li, Feng; Zhao, Ning Applied Catalysis B: Environmental, Vol. 191 https://doi.org/10.1016/j.apcatb.2016.03.014	journal	August 2016
Impact of hybrid CO2-CO feeds on methanol synthesis over In2O3-based catalysts Araújo, Thaylan P.; Shah, Arjun; Mondelli, Cecilia Applied Catalysis B: Environmental, Vol. 285 https://doi.org/10.1016/j.apcatb.2021.119878	journal	May 2021
Copper/zirconia catalysts for the synthesis of methanol from carbon dioxide Koeppel, R. A.; Baiker, A.; Wokaun, A. Applied Catalysis A: General, Vol. 84, Issue 1 https://doi.org/10.1016/0926-860X(92)80340-I	journal	May 1992
Effect of metal oxide additives on the activity and stability of Cu/ZnO/ZrO2 catalysts in the synthesis of methanol from CO2 and H2 Sloczynski, J.; Grabowski, R.; Olszewski, P. Applied Catalysis A: General, Vol. 310 https://doi.org/10.1016/j.apcata.2006.05.035	journal	August 2006
Methanol synthesis from CO2 + H2 II. Copper-based binary and ternary catalysts Amenomiya, Y. Applied Catalysis, Vol. 30, Issue 1 https://doi.org/10.1016/S0166-9834(00)81011-8	journal	March 1987
Towards Oil Independence Through Renewable Methanol Chemistry Olah, George A. Angewandte Chemie International Edition, Vol. 52, Issue 1 https://doi.org/10.1002/anie.201204995	journal	December 2012
Towards reliable X-ray photoelectron spectroscopy: Sputter-damage effects in transition metal borides, carbides, nitrides, and oxides Greczynski, G.; Hultman, L. Applied Surface Science, Vol. 542 https://doi.org/10.1016/j.apsusc.2020.148599	journal	March 2021
Analysis of mineral surface chemistry in flotation separation using imaging XPS Biesinger, Mark C.; Hart, Brian R.; Polack, Russell Minerals Engineering, Vol. 20, Issue 2 https://doi.org/10.1016/j.mineng.2006.08.006	journal	February 2007
Performance of ternary Cu–Ga2O3–ZrO2 catalysts in the synthesis of methanol using CO2-rich gas mixtures Fornero, Esteban L.; Sanguineti, Pamela B.; Chiavassa, Dante L. Catalysis Today, Vol. 213 https://doi.org/10.1016/j.cattod.2013.03.012	journal	September 2013
Supported Copper Catalysts Prepared from Copper(II) Formate Denise, B.; Cherifi, O.; Bettahar, M. M. Applied Catalysis, Vol. 48, Issue 2 https://doi.org/10.1016/S0166-9834(00)82805-5	journal	March 1989
Oxide transformation and break-up of liquid metal in boiling solutions Yang, LiXiang; Zhao, Xi; Xu, Shuo Science China Technological Sciences, Vol. 63, Issue 2 https://doi.org/10.1007/s11431-018-9444-5	journal	March 2019
Insights into the Selectivity Determinant and Rate-Determining Step of CO₂ Hydrogenation to Methanol Tang, Chizhou; Tang, Shan; Sha, Feng The Journal of Physical Chemistry C, Vol. 126, Issue 25 https://doi.org/10.1021/acs.jpcc.2c02995	journal	June 2022
CO ₂ -to-Methanol Hydrogenation on Zirconia-Supported Copper Nanoparticles: Reaction Intermediates and the Role of the Metal-Support Interface Larmier, Kim; Liao, Wei-Chih; Tada, Shohei Angewandte Chemie International Edition, Vol. 56, Issue 9 https://doi.org/10.1002/anie.201610166	journal	January 2017
Role of Zirconia in Indium Oxide-Catalyzed CO ₂ Hydrogenation to Methanol Frei, Matthias S.; Mondelli, Cecilia; Cesarini, Alessia ACS Catalysis, Vol. 10, Issue 2 https://doi.org/10.1021/acscatal.9b03305	journal	December 2019
Dispersion and surface states of copper catalysts by temperature-programmed-reduction of oxidized surfaces (s-TPR) Gervasini, Antonella; Bennici, Simona Applied Catalysis A: General, Vol. 281, Issue 1-2 https://doi.org/10.1016/j.apcata.2004.11.030	journal	March 2005
DRIFTS-SSITKA-MS investigations on the mechanism of plasmon preferentially enhanced CO2 hydrogenation over Au/γ-Al2O3 Wang, Ke; Shao, Shibo; Liu, Yanrong Applied Catalysis B: Environmental, Vol. 328 https://doi.org/10.1016/j.apcatb.2023.122531	journal	July 2023
Catalytic valorization of CO2 via methanol synthesis with Ga-promoted Cu–ZnO–ZrO2 catalysts Ladera, Rosa; Pérez-Alonso, Francisco J.; González-Carballo, Juan M. Applied Catalysis B: Environmental, Vol. 142-143 https://doi.org/10.1016/j.apcatb.2013.05.019	journal	October 2013
Cu Species Incorporated into Amorphous ZrO ₂ with High Activity and Selectivity in CO ₂ -to-Methanol Hydrogenation Tada, Shohei; Katagiri, Ayaka; Kiyota, Keiko The Journal of Physical Chemistry C, Vol. 122, Issue 10 https://doi.org/10.1021/acs.jpcc.7b11284	journal	February 2018
Turning a Methanation Co Catalyst into an In–Co Methanol Producer Bavykina, Anastasiya; Yarulina, Irina; Al Abdulghani, Abdullah J. ACS Catalysis, Vol. 9, Issue 8 https://doi.org/10.1021/acscatal.9b01638	journal	June 2019
Prospects for the production of green hydrogen: Review of countries with high potential Panchenko, V. A.; Daus, Yu. V.; Kovalev, A. A. International Journal of Hydrogen Energy, Vol. 48, Issue 12 https://doi.org/10.1016/j.ijhydene.2022.10.084	journal	February 2023
Preparation and Activity of Copper–Gallium Nanocomposite Catalysts for Carbon Dioxide Hydrogenation to Methanol Hengne, Amol M.; Yuan, Ding Jier; Date, Nandan S. Industrial & Engineering Chemistry Research, Vol. 58, Issue 47 https://doi.org/10.1021/acs.iecr.9b04083	journal	October 2019
Methanol synthesis from CO2: A mechanistic overview Azhari, Noerma J.; Erika, Denanti; Mardiana, St Results in Engineering, Vol. 16 https://doi.org/10.1016/j.rineng.2022.100711	journal	December 2022
Enhancing methanol selectivity of commercial Cu/ZnO/Al2O3 catalyst in CO2 hydrogenation by surface silylation Cui, Xiaojing; Liu, Yequn; Yan, Wenjun Applied Catalysis B: Environmental, Vol. 339 https://doi.org/10.1016/j.apcatb.2023.123099	journal	December 2023
An ESCA study of the termination of the passivation of elemental metals Barr, Tery L. The Journal of Physical Chemistry, Vol. 82, Issue 16 https://doi.org/10.1021/j100505a006	journal	August 1978
An Insight into Synergistic Metal-Oxide Interaction in CO2 Hydrogenation to Methanol over Cu/ZnO/ZrO2 Chang, Xiao; Zi, Xiaohui; Li, Jing Catalysts, Vol. 13, Issue 10 https://doi.org/10.3390/catal13101337	journal	September 2023
Auger and direct electron spectra in X-ray photoelectron studies of zinc, zinc oxide, gallium and gallium oxide Schön, Gunnar Journal of Electron Spectroscopy and Related Phenomena, Vol. 2, Issue 1 https://doi.org/10.1016/0368-2048(73)80049-0	journal	January 1973
Tuning the CO2 hydrogenation path by moderately phosphating the Co-Al catalyst toward methanol synthesis Zhang, Heng; Mao, Donglei; Zhang, Jinxin Applied Catalysis B: Environmental, Vol. 340 https://doi.org/10.1016/j.apcatb.2023.123257	journal	January 2024
Isotopic study of the rates of hydrogen provision vs. methanol synthesis from CO2 over Cu–Ga–Zr catalysts Fornero, Esteban L.; Bonivardi, Adrian L.; Baltanás, Miguel A. Journal of Catalysis, Vol. 330 https://doi.org/10.1016/j.jcat.2015.07.025	journal	October 2015
Following the structure of copper-zinc-alumina across the pressure gap in carbon dioxide hydrogenation Beck, Arik; Zabilskiy, Maxim; Newton, Mark A. Nature Catalysis, Vol. 4, Issue 6 https://doi.org/10.1038/s41929-021-00625-x	journal	June 2021
Structural Evolution of Ga–Cu Model Catalysts for CO₂ Hydrogenation Reactions Zhong, Jian-Qiang; Shaikhutdinov, Shamil; Roldan Cuenya, Beatriz The Journal of Physical Chemistry C, Vol. 125, Issue 2 https://doi.org/10.1021/acs.jpcc.0c09382	journal	January 2021
Chemisorption of N2O and H2 for the Surface Determination of Copper Catalysts Hinrichsen, O.; Genger, T.; Muhler, M. Chemical Engineering & Technology, Vol. 23, Issue 11 https://doi.org/10.1002/1521-4125(200011)23:11<956::AID-CEAT956>3.0.CO;2-L	journal	November 2000
Renewable energy-to-green hydrogen: A review of main resources routes, processes and evaluation Hassan, Qusay; Abdulateef, Ammar M.; Hafedh, Saadoon Abdul International Journal of Hydrogen Energy, Vol. 48, Issue 46 https://doi.org/10.1016/j.ijhydene.2023.01.175	journal	May 2023
Unravelling the role of metal-metal oxide interfaces of Cu/ZnO/ZrO2/Al2O3 catalyst for methanol synthesis from CO2: Insights from experiments and DFT-based microkinetic modeling Dharmalingam, Balaji C.; Koushik V., Ajay; Mureddu, Mauro Applied Catalysis B: Environmental, Vol. 332 https://doi.org/10.1016/j.apcatb.2023.122743	journal	September 2023
Promoting Strong Metal Support Interaction: Doping ZnO for Enhanced Activity of Cu/ZnO:M (M = Al, Ga, Mg) Catalysts Schumann, Julia; Eichelbaum, Maik; Lunkenbein, Thomas ACS Catalysis, Vol. 5, Issue 6 https://doi.org/10.1021/acscatal.5b00188	journal	April 2015
Isolated Zr Surface Sites on Silica Promote Hydrogenation of CO ₂ to CH ₃ OH in Supported Cu Catalysts Lam, Erwin; Larmier, Kim; Wolf, Patrick Journal of the American Chemical Society, Vol. 140, Issue 33 https://doi.org/10.1021/jacs.8b05595	journal	July 2018
Surface Sites in Cu-Nanoparticles: Chemical Reactivity or Microscopy? Larmier, Kim; Tada, Shohei; Comas-Vives, Aleix The Journal of Physical Chemistry Letters, Vol. 7, Issue 16 https://doi.org/10.1021/acs.jpclett.6b01328	journal	August 2016
Detection of Ga suboxides and their impact on III-V passivation and Fermi-level pinning Hinkle, C. L.; Milojevic, M.; Brennan, B. Applied Physics Letters, Vol. 94, Issue 16 https://doi.org/10.1063/1.3120546	journal	April 2009
The measurement of copper surface areas by reactive frontal chromatography*1 Chinchen, G. Journal of Catalysis, Vol. 103, Issue 1 https://doi.org/10.1016/0021-9517(87)90094-7	journal	January 1987
An insight of CO ₂ hydrogenation to methanol synthesis: Thermodynamics, catalysts, operating parameters, and reaction mechanism Kanuri, Suresh; Roy, Sounak; Chakraborty, Chanchal International Journal of Energy Research, Vol. 46, Issue 5 https://doi.org/10.1002/er.7562	journal	December 2021
Recent Advances in Carbon Dioxide Hydrogenation to Methanol via Heterogeneous Catalysis Jiang, Xiao; Nie, Xiaowa; Guo, Xinwen Chemical Reviews, Vol. 120, Issue 15 https://doi.org/10.1021/acs.chemrev.9b00723	journal	February 2020
The Equilibrium Between the Three Hydrogens Rittenberg, D.; Bleakney, Walker; Urey, Harold C. The Journal of Chemical Physics, Vol. 2, Issue 1 https://doi.org/10.1063/1.1749360	journal	January 1934
CO ₂ Hydrogenation to Methanol over ZrO ₂ -Containing Catalysts: Insights into ZrO ₂ Induced Synergy Li, Kongzhai; Chen, Jingguang G. ACS Catalysis, Vol. 9, Issue 9 https://doi.org/10.1021/acscatal.9b01943	journal	July 2019
Enhanced CH₃OH selectivity in CO₂ hydrogenation using Cu-based catalysts generated via SOMC from Ga^III single-sites Lam, Erwin; Noh, Gina; Chan, Ka Wing Chemical Science, Vol. 11, Issue 29 https://doi.org/10.1039/D0SC00465K	journal	January 2020
Global hydrogen development - A technological and geopolitical overview Lebrouhi, B. E.; Djoupo, J. J.; Lamrani, B. International Journal of Hydrogen Energy, Vol. 47, Issue 11 https://doi.org/10.1016/j.ijhydene.2021.12.076	journal	February 2022
Tuning Selectivity of CO ₂ Hydrogenation Reactions at the Metal/Oxide Interface Kattel, Shyam; Liu, Ping; Chen, Jingguang G. Journal of the American Chemical Society, Vol. 139, Issue 29 https://doi.org/10.1021/jacs.7b05362	journal	July 2017
Copper–gallia interaction in Cu–Ga2O3–ZrO2 catalysts for methanol production from carbon oxide(s) hydrogenation Sanguineti, Pamela B.; Baltanás, Miguel A.; Bonivardi, Adrian L. Applied Catalysis A: General, Vol. 504 https://doi.org/10.1016/j.apcata.2014.11.021	journal	September 2015
The unique interplay between copper and zinc during catalytic carbon dioxide hydrogenation to methanol Zabilskiy, Maxim; Sushkevich, Vitaly L.; Palagin, Dennis Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-16342-1	journal	May 2020
Distinction between Surface and Bulk Oxidation of Cu through N2O Decomposition Sato, Satoshi; Takahashi, Ryoji; Sodesawa, Toshiaki Journal of Catalysis, Vol. 196, Issue 1 https://doi.org/10.1006/jcat.2000.3028	journal	November 2000
Insights into Bimetallic Oxide Synergy during Carbon Dioxide Hydrogenation to Methanol and Dimethyl Ether over GaZrO_x Oxide Catalysts Feng, Wen-Hua; Yu, Ming-Ming; Wang, Li-Jun ACS Catalysis, Vol. 11, Issue 8 https://doi.org/10.1021/acscatal.0c05410	journal	April 2021
Plant-to-planet analysis of CO ₂ -based methanol processes González-Garay, Andrés; Frei, Matthias S.; Al-Qahtani, Amjad Energy & Environmental Science, Vol. 12, Issue 12 https://doi.org/10.1039/C9EE01673B	journal	January 2019
Unraveling the regulation of Mn in Cu-ZnOx formation during methanol synthesis from syngas over Cu/ZnO/Al2O3-Mn catalysts Zhang, Zhenzhou; Cheng, Sifan; Liu, Wenqi Applied Catalysis B: Environmental, Vol. 338 https://doi.org/10.1016/j.apcatb.2023.122985	journal	December 2023
An improved N2O-method for measuring Cu-dispersion Jensen, J. R.; Johannessen, T.; Livbjerg, H. Applied Catalysis A: General, Vol. 266, Issue 1 https://doi.org/10.1016/j.apcata.2004.02.009	journal	July 2004
Role of Lattice Strain and Defects in Copper Particles on the Activity of Cu/ZnO/Al2O3 Catalysts for Methanol Synthesis Kasatkin, Igor; Kurr, Patrick; Kniep, Benjamin Angewandte Chemie International Edition, Vol. 46, Issue 38 https://doi.org/10.1002/anie.200702600	journal	September 2007
Differences in bifunctionality of ZnO and ZrO2 in Cu/ZnO/ZrO2/Al2O3 catalysts in hydrogenation of carbon oxides for methanol synthesis Abbas, Imran; Kim, Honggon; Shin, Chae-Ho Applied Catalysis B: Environmental, Vol. 258 https://doi.org/10.1016/j.apcatb.2019.117971	journal	December 2019
The changing nature of the active site of Cu-Zn-Zr catalysts for the CO2 hydrogenation reaction to methanol Bonura, G.; Cordaro, M.; Cannilla, C. Applied Catalysis B: Environmental, Vol. 152-153 https://doi.org/10.1016/j.apcatb.2014.01.035	journal	June 2014
CO2 hydrogenation to high-value products via heterogeneous catalysis Ye, Run-Ping; Ding, Jie; Gong, Weibo Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-13638-9	journal	December 2019
Exploiting oriented attachment in stabilizing La³⁺-doped gallium oxide nano-spindles Dar, M. Ibrahim; Sampath, S.; Shivashankar, S. A. RSC Adv., Vol. 4, Issue 90 https://doi.org/10.1039/C4RA07089E	journal	January 2014
Determination of the Dispersion and Surface Oxidation States of Supported Cu Catalysts Dandekar, A.; Vannice, M. A. Journal of Catalysis, Vol. 178, Issue 2 https://doi.org/10.1006/jcat.1998.2190	journal	September 1998
State of the art and perspectives in heterogeneous catalysis of CO ₂ hydrogenation to methanol Zhong, Jiawei; Yang, Xiaofeng; Wu, Zhilian Chemical Society Reviews, Vol. 49, Issue 5 https://doi.org/10.1039/C9CS00614A	journal	January 2020
CO2 hydrogenation to methanol on Ga2O3-Pd/SiO2 catalysts: Dual oxide-metal sites or (bi)metallic surface sites? Collins, Sebastián E.; Baltanás, Miguel A.; Delgado, Juan José Catalysis Today, Vol. 381 https://doi.org/10.1016/j.cattod.2020.07.048	journal	December 2021
CO2 Hydrogenation to Methanol Over Cu/ZnO/Al2O3 Catalyst: Kinetic Modeling Based on Either Single- or Dual-Active Site Mechanism Li, Hou-Xing; Yang, Liu-Qing-Qing; Chi, Zi-Yi Catalysis Letters, Vol. 152, Issue 10 https://doi.org/10.1007/s10562-021-03913-0	journal	January 2022
Advanced analysis of copper X-ray photoelectron spectra: Advanced analysis of copper X-ray photoelectron spectra Biesinger, Mark C. Surface and Interface Analysis, Vol. 49, Issue 13 https://doi.org/10.1002/sia.6239	journal	May 2017
Binding and Exchange Reactions of Hydrogen Isotopes on Surfaces of Dispersed Pt Nanoparticles Leung, Samuel L.; Hibbitts, David; Gárcia-Diéguez, Mónica The Journal of Physical Chemistry C, Vol. 126, Issue 8 https://doi.org/10.1021/acs.jpcc.1c09131	journal	February 2022

Similar Records

Highly active and selective Cu-ZnO based catalyst for methanol and dimethyl ether synthesis via CO2 hydrogenation

Journal Article · 2019 · Fuel · OSTI ID:1613729

Ren, Shoujie; Shoemaker, Weston R.; Wang, Xiaofeng; +7 more

Fundamental Studies of Methanol Synthesis from CO2 Hydrogenation on Cu(111), Cu Clusters, and Cu/ZnO(000ī)

Journal Article · 2010 · Physical Chemistry Chemical Physics · OSTI ID:1004644

Liu, P; Yang, Y; Evans, J; +2 more

Hydrogenation of CO2 to methanol and CO on Cu/ZnO/Al2O3: Is there a common intermediate or not?

Journal Article · 2015 · Journal of Catalysis · OSTI ID:1255093

Kunkes, Edward L.; Studt, Felix; Abild-Pedersen, Frank; +2 more

Title: Realizing synergy between Cu, Ga, and Zr for selective CO2 hydrogenation to methanol

Citation Formats

References (71)

Similar Records

Related Subjects