Mesophase pitch-based high performance carbon fiber production using coal extracts from mild direct coal liquefaction

Thompson, Christina; Frank, George; Edwards, Vivian; Martinelli, Michela; Vego, Asmund; Vautard, Frederic; Cakmak, Ercan; Craddock, John; Meier, Mark; Andrews, Rodney; Weisenberger, Matthew

doi:10.1016/j.carbon.2024.119212

Title: Mesophase pitch-based high performance carbon fiber production using coal extracts from mild direct coal liquefaction

Journal Article · 03 May 2024 · Carbon

DOI: https://doi.org/10.1016/j.carbon.2024.119212 · OSTI ID:2351011

^[1]; Frank, George ^[1];

^[1]; Martinelli, Michela ^[1];

^[1]; Vautard, Frederic ^[2];

^[2];

^[1];

^[1]; Andrews, Rodney ^[1]; Weisenberger, Matthew ^[1]

University of Kentucky, Lexington, KY (United States)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Mild direct coal liquefaction (autogenous pressure, no catalyst, no H2 gas) of Springfield coal in fluid catalytic cracking decant oil is shown to effectively produce coal extract precursors to spinnable mesophase pitch. Here this work demonstrates that the coal extract can be thermally treated to obtain mesophase pitch in a facile one-step process, bypassing the production of an intermediate isotropic pitch. Furthermore, the presence of 25 wt.% coal in the initial slurry can increase the yield to mesophase pitch nearly twofold and yield to carbon fiber by approximately 70%. The coal extract-derived mesophase pitch was melt-spun and heat treated to produce carbon fiber with graphitic texture, high modulus (>400 GPa) and tensile strength up to 943 MPa. Overall, this work demonstrates that coal can be effectively utilized to markedly amplify the mesophase pitch and carbon fiber yield from fluid catalytic cracking decant oil by relatively simple processing, while conserving utility as a precursor to high performance carbon fiber and potentially other high value graphitic products.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 2351011

Journal Information:: Carbon, Journal Name: Carbon Journal Issue: N/A Vol. 226; ISSN 0008-6223

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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36 MATERIALS SCIENCE
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Title: Mesophase pitch-based high performance carbon fiber production using coal extracts from mild direct coal liquefaction

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References (55)

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