Understanding High-Voltage Behavior of Sodium-Ion Battery Cathode Materials Using Synchrotron X-ray and Neutron Techniques: A Review

Shipitsyn, Vadim; Jayakumar, Rishivandhiga; Zuo, Wenhua; Sun, Bing; Ma, Lin

doi:10.3390/batteries9090461

Title: Understanding High-Voltage Behavior of Sodium-Ion Battery Cathode Materials Using Synchrotron X-ray and Neutron Techniques: A Review

Journal Article · 11 September 2023 · Batteries

DOI: https://doi.org/10.3390/batteries9090461 · OSTI ID:2350935

^[1]; Jayakumar, Rishivandhiga ^[1]; Zuo, Wenhua ^[2]; Sun, Bing ^[3];

^[1]

University of North Carolina, Charlotte, NC (United States)
Argonne National Laboratory (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
University of Technology Sydney, Ultimo (Australia)

Despite substantial research efforts in developing high-voltage sodium-ion batteries (SIBs) as high-energy-density alternatives to complement lithium-ion-based energy storage technologies, the lifetime of high-voltage SIBs is still associated with many fundamental scientific questions. In particular, the structure phase transition, oxygen loss, and cathode–electrolyte interphase (CEI) decay are intensely discussed in the field. Synchrotron X-ray and neutron scattering characterization techniques offer unique capabilities for investigating the complex structure and dynamics of high-voltage cathode behavior. In this review, to accelerate the development of stable high-voltage SIBs, we provide a comprehensive and thorough overview of the use of synchrotron X-ray and neutron scattering in studying SIB cathode materials with an emphasis on high-voltage layered transition metal oxide cathodes. We then discuss these characterizations in relation to polyanion-type cathodes, Prussian blue analogues, and organic cathode materials. Finally, future directions of these techniques in high-voltage SIB research are proposed, including CEI studies for polyanion-type cathodes and the extension of neutron scattering techniques, as well as the integration of morphology and phase characterizations.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE; National Science Foundation (NSF)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 2350935

Journal Information:: Batteries, Journal Name: Batteries Journal Issue: 9 Vol. 9; ISSN 2313-0105

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

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