Charge Transfer Mechanism on a Cobalt-Polyoxometalate-TiO 2 Photoanode for Water Oxidation in Acid

Zhao, Fengyi; Cheng, Ting; Lu, Xinlin; Ghorai, Nandan; Yang, Yiwei; Geletii, Yurii V.; Musaev, Djamaladdin G.; Hill, Craig L.; Lian, Tianquan

doi:10.1021/jacs.4c01441

Title: Charge Transfer Mechanism on a Cobalt-Polyoxometalate-TiO ₂ Photoanode for Water Oxidation in Acid

Journal Article · 14 May 2024 · Journal of the American Chemical Society

DOI: https://doi.org/10.1021/jacs.4c01441 · OSTI ID:2350855

^[1]; Cheng, Ting ^[1]; Lu, Xinlin ^[1];

^[1]; Yang, Yiwei ^[1];

^[1];

^[2];

^[1];

^[1]

Department of Chemistry, Emory University, Atlanta, Georgia 30322, United States
Department of Chemistry, Emory University, Atlanta, Georgia 30322, United States, Cherry L. Emerson Centre for Scientific Computation, Emory University, 1515 Dickey Drive, Atlanta, Georgia 30322, United States

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Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-07ER15906

OSTI ID:: 2350855

Alternate ID(s):: OSTI ID: 2368754

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society; ISSN 0002-7863

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (78)

Efficient BiVO ₄ Thin Film Photoanodes Modified with Cobalt Phosphate Catalyst and W-doping Abdi, Fatwa F.; Firet, Nienke; van de Krol, Roel ChemCatChem, Vol. 5, Issue 2 https://doi.org/10.1002/cctc.201200472	journal	November 2012
Electron Accumulation Induces Efficiency Bottleneck for Hydrogen Production in Carbon Nitride Photocatalysts Yang, Wenxing; Godin, Robert; Kasap, Hatice Journal of the American Chemical Society, Vol. 141, Issue 28 https://doi.org/10.1021/jacs.9b04556	journal	June 2019
Electron Transfer Dynamics in Semiconductor–Chromophore–Polyoxometalate Catalyst Photoanodes Xiang, Xu; Fielden, John; Rodríguez-Córdoba, William The Journal of Physical Chemistry C, Vol. 117, Issue 2 https://doi.org/10.1021/jp312092u	journal	January 2013
Carbon quantum dots as a visible light sensitizer to significantly increase the solar water splitting performance of bismuth vanadate photoanodes Ye, Kai-Hang; Wang, Zilong; Gu, Jiuwang Energy & Environmental Science, Vol. 10, Issue 3 https://doi.org/10.1039/C6EE03442J	journal	January 2017
Visible-light-absorbing semiconductor/molecular catalyst hybrid photoelectrodes for H ₂ or O ₂ evolution: recent advances and challenges Wang, Mei; Yang, Yong; Shen, Junyu Sustainable Energy & Fuels, Vol. 1, Issue 8 https://doi.org/10.1039/C7SE00222J	journal	January 2017
The Role of Cobalt Phosphate in Enhancing the Photocatalytic Activity of α-Fe ₂ O ₃ toward Water Oxidation Barroso, Monica; Cowan, Alexander J.; Pendlebury, Stephanie R. Journal of the American Chemical Society, Vol. 133, Issue 38 https://doi.org/10.1021/ja205325v	journal	September 2011
Photoelectrochemical and Impedance Spectroscopic Investigation of Water Oxidation with “Co–Pi”-Coated Hematite Electrodes Klahr, Benjamin; Gimenez, Sixto; Fabregat-Santiago, Francisco Journal of the American Chemical Society, Vol. 134, Issue 40 https://doi.org/10.1021/ja306427f	journal	September 2012
Water Splitting by Nanocrystalline TiO ₂ in a Complete Photoelectrochemical Cell Exhibits Efficiencies Limited by Charge Recombination Cowan, Alexander J.; Tang, Junwang; Leng, Wenhua The Journal of Physical Chemistry C, Vol. 114, Issue 9 https://doi.org/10.1021/jp909993w	journal	February 2010
La- and Mn-doped cobalt spinel oxygen evolution catalyst for proton exchange membrane electrolysis Chong, Lina; Gao, Guoping; Wen, Jianguo Science, Vol. 380, Issue 6645 https://doi.org/10.1126/science.ade1499	journal	May 2023
Nature of Activated Manganese Oxide for Oxygen Evolution Huynh, Michael; Shi, Chenyang; Billinge, Simon J. L. Journal of the American Chemical Society, Vol. 137, Issue 47 https://doi.org/10.1021/jacs.5b06382	journal	November 2015
A Functionally Stable Manganese Oxide Oxygen Evolution Catalyst in Acid Huynh, Michael; Bediako, D. Kwabena; Nocera, Daniel G. Journal of the American Chemical Society, Vol. 136, Issue 16 https://doi.org/10.1021/ja413147e	journal	April 2014
Single-Atom Iridium on Hematite Photoanodes for Solar Water Splitting: Catalyst or Spectator? Guo, Qian; Zhao, Qi; Crespo-Otero, Rachel Journal of the American Chemical Society, Vol. 145, Issue 3 https://doi.org/10.1021/jacs.2c09974	journal	January 2023
Solar-to-hydrogen efficiency of more than 9% in photocatalytic water splitting Zhou, Peng; Navid, Ishtiaque Ahmed; Ma, Yongjin Nature, Vol. 613, Issue 7942 https://doi.org/10.1038/s41586-022-05399-1	journal	January 2023
Photocatalytic water splitting with a quantum efficiency of almost unity Takata, Tsuyoshi; Jiang, Junzhe; Sakata, Yoshihisa Nature, Vol. 581, Issue 7809 https://doi.org/10.1038/s41586-020-2278-9	journal	May 2020
FeO_x Derived from an Iron-Containing Polyoxometalate Boosting the Photocatalytic Water Oxidation Activity of Ti³⁺-Doped TiO₂ Wang, Yifan; Cao, Xiaohu; Hu, Qiyu ACS Applied Materials & Interfaces, Vol. 11, Issue 26 https://doi.org/10.1021/acsami.9b03714	journal	June 2019
Random walk models of charge transfer and transport in dye sensitized systems Nelson, Jenny; Chandler, Rosemary E. Coordination Chemistry Reviews, Vol. 248, Issue 13-14 https://doi.org/10.1016/j.ccr.2004.04.001	journal	July 2004
Electrochemically Driven Water-Oxidation Catalysis Beginning with Six Exemplary Cobalt Polyoxometalates: Is It Molecular, Homogeneous Catalysis or Electrode-Bound, Heterogeneous CoO _x Catalysis? Folkman, Scott J.; Soriano-Lopez, Joaquin; Galán-Mascarós, José Ramón Journal of the American Chemical Society, Vol. 140, Issue 38 https://doi.org/10.1021/jacs.8b06303	journal	September 2018
Batch Experiments for the Determination of the Ti(IV,III) Couple Formal Potential in 1 mol⋅dm−3 HCl, 2 mol⋅dm−3 NaCl Medium at 25 °C Amorello, Diana; Ledda, Fabrizio; Romano, Vincenzo Journal of Solution Chemistry, Vol. 38, Issue 2 https://doi.org/10.1007/s10953-008-9359-y	journal	November 2008
Adaptive semiconductor/electrocatalyst junctions in water-splitting photoanodes Lin, Fuding; Boettcher, Shannon W. Nature Materials, Vol. 13, Issue 1 https://doi.org/10.1038/nmat3811	journal	December 2013
Electrochemistry of Polyoxometalates: From Fundamental Aspects to Applications Ueda, Tadaharu ChemElectroChem, Vol. 5, Issue 6 https://doi.org/10.1002/celc.201701170	journal	February 2018
The Electronic Origin of the Visible-Light Absorption Properties of C-, N- and S-Doped TiO ₂ Nanomaterials Chen, Xiaobo; Burda, Clemens Journal of the American Chemical Society, Vol. 130, Issue 15 https://doi.org/10.1021/ja711023z	journal	April 2008
Water- and Oxygen-Induced Decay Kinetics of Photogenerated Electrons in TiO₂ and Pt/TiO₂: A Time-Resolved Infrared Absorption Study Yamakata, Akira; Ishibashi, Taka-aki; Onishi, Hiroshi The Journal of Physical Chemistry B, Vol. 105, Issue 30 https://doi.org/10.1021/jp010802w	journal	July 2001
Transition-Metal (Co, Ni, and Fe)-Based Electrocatalysts for the Water Oxidation Reaction Han, Lei; Dong, Shaojun; Wang, Erkang Advanced Materials, Vol. 28, Issue 42 https://doi.org/10.1002/adma.201602270	journal	August 2016
Electrolysis of water at strontium titanate (SrTiO3) photoelectrodes: distinguishing between the statistical and stochastic formalisms for electron-transfer processes in fuel-forming photoelectrochemical systems Kumar, Amit; Santangelo, Patrick G.; Lewis, Nathan S. The Journal of Physical Chemistry, Vol. 96, Issue 2 https://doi.org/10.1021/j100181a057	journal	January 1992
Polyoxometalate electrocatalysts based on earth-abundant metals for efficient water oxidation in acidic media Blasco-Ahicart, Marta; Soriano-López, Joaquín; Carbó, Jorge J. Nature Chemistry, Vol. 10, Issue 1 https://doi.org/10.1038/nchem.2874	journal	October 2017
Evaluation of Surface State Mediated Charge Recombination in Anatase and Rutile TiO ₂ Sachs, Michael; Pastor, Ernest; Kafizas, Andreas The Journal of Physical Chemistry Letters, Vol. 7, Issue 19 https://doi.org/10.1021/acs.jpclett.6b01501	journal	September 2016
Simultaneously Solving the Photovoltage and Photocurrent at Semiconductor–Liquid Interfaces Iqbal, Asif; Bevan, Kirk H. The Journal of Physical Chemistry C, Vol. 122, Issue 1 https://doi.org/10.1021/acs.jpcc.7b08517	journal	December 2017
Highly Efficient Plasmon Induced Hot-Electron Transfer at Ag/TiO₂ Interface Song, Jia; Long, Jinlin; Liu, Yawei ACS Photonics, Vol. 8, Issue 5 https://doi.org/10.1021/acsphotonics.1c00321	journal	April 2021
Identification of a Nonanuclear {Co ^II ₉ } Polyoxometalate Cluster as a Homogeneous Catalyst for Water Oxidation Goberna-Ferrón, Sara; Vigara, Laura; Soriano-López, Joaquín Inorganic Chemistry, Vol. 51, Issue 21 https://doi.org/10.1021/ic301618h	journal	October 2012
Design of template-stabilized active and earth-abundant oxygen evolution catalysts in acid Huynh, Michael; Ozel, Tuncay; Liu, Chong Chemical Science, Vol. 8, Issue 7 https://doi.org/10.1039/C7SC01239J	journal	January 2017
The role of ultra-thin MnO_x co-catalysts on the photoelectrochemical properties of BiVO₄ photoanodes Irani, Rowshanak; Plate, Paul; Höhn, Christian Journal of Materials Chemistry A, Vol. 8, Issue 11 https://doi.org/10.1039/D0TA00939C	journal	January 2020
Understanding the origin of photoelectrode performance enhancement by probing surface kinetics Thorne, James E.; Jang, Ji-Wook; Liu, Erik Y. Chemical Science, Vol. 7, Issue 5 https://doi.org/10.1039/C5SC04519C	journal	January 2016
A Fully Noble Metal-Free Photosystem Based on Cobalt-Polyoxometalates Immobilized in a Porphyrinic Metal–Organic Framework for Water Oxidation Paille, Grégoire; Gomez-Mingot, Maria; Roch-Marchal, Catherine Journal of the American Chemical Society, Vol. 140, Issue 10 https://doi.org/10.1021/jacs.7b11788	journal	February 2018
Potential-sensing electrochemical atomic force microscopy for in operando analysis of water-splitting catalysts and interfaces Nellist, Michael R.; Laskowski, Forrest A. L.; Qiu, Jingjing Nature Energy, Vol. 3, Issue 1 https://doi.org/10.1038/s41560-017-0048-1	journal	December 2017
Identification of Reactive Species in Photoexcited Nanocrystalline TiO ₂ Films by Wide-Wavelength-Range (400−2500 nm) Transient Absorption Spectroscopy Yoshihara, Toshitada; Katoh, Ryuzi; Furube, Akihiro The Journal of Physical Chemistry B, Vol. 108, Issue 12 https://doi.org/10.1021/jp031305d	journal	March 2004
Nanoporous BiVO₄ Photoanodes with Dual-Layer Oxygen Evolution Catalysts for Solar Water Splitting Kim, Tae Woo; Choi, Kyoung-Shin Science, Vol. 343, Issue 6174, p. 990-994 https://doi.org/10.1126/science.1246913	journal	February 2014
A stable iron-containing polyoxometalate coupled with semiconductor for efficient photocatalytic water oxidation under acidic condition Hu, Qiyu; Meng, Xiangyu; Dong, Yinjuan Chemical Communications, Vol. 55, Issue 78 https://doi.org/10.1039/C9CC05726A	journal	January 2019
Photochemical Route for Accessing Amorphous Metal Oxide Materials for Water Oxidation Catalysis Smith, Rodney D. L.; Prévot, Mathieu S.; Fagan, Randal D. Science, Vol. 340, Issue 6128 https://doi.org/10.1126/science.1233638	journal	March 2013
Interface engineering for light-driven water oxidation: unravelling the passivating and catalytic mechanism in BiVO ₄ overlayers Liu, Guiji; Eichhorn, Johanna; Jiang, Chang-Ming Sustainable Energy & Fuels, Vol. 3, Issue 1 https://doi.org/10.1039/C8SE00473K	journal	January 2019
Cobalt–Iron (Oxy)hydroxide Oxygen Evolution Electrocatalysts: The Role of Structure and Composition on Activity, Stability, and Mechanism Burke, Michaela S.; Kast, Matthew G.; Trotochaud, Lena Journal of the American Chemical Society, Vol. 137, Issue 10 https://doi.org/10.1021/jacs.5b00281	journal	March 2015
Time-resolved infrared absorption spectroscopy of photogenerated electrons in platinized TiO2 particles Yamakata, Akira; Ishibashi, Taka-aki; Onishi, Hiroshi Chemical Physics Letters, Vol. 333, Issue 3-4 https://doi.org/10.1016/S0009-2614(00)01374-9	journal	January 2001
Heterogenization of Molecular Water Oxidation Catalysts in Electrodes for (Photo)Electrochemical Water Oxidation Casadevall, Carla Water, Vol. 14, Issue 3 https://doi.org/10.3390/w14030371	journal	January 2022
Redox tuning the Weakley-type polyoxometalate archetype for the oxygen evolution reaction Martin-Sabi, Mercè; Soriano-López, Joaquín; Winter, Ross S. Nature Catalysis, Vol. 1, Issue 3 https://doi.org/10.1038/s41929-018-0037-1	journal	March 2018
Water oxidation electrocatalysis in acidic media with Co-containing polyoxometalates Arens, J. T.; Blasco-Ahicart, M.; Azmani, K. Journal of Catalysis, Vol. 389 https://doi.org/10.1016/j.jcat.2020.06.006	journal	September 2020
Near-Complete Suppression of Surface Recombination in Solar Photoelectrolysis by “Co-Pi” Catalyst-Modified W:BiVO ₄ Zhong, Diane K.; Choi, Sujung; Gamelin, Daniel R. Journal of the American Chemical Society, Vol. 133, Issue 45 https://doi.org/10.1021/ja207348x	journal	November 2011
Recent advances in semiconductors for photocatalytic and photoelectrochemical water splitting Hisatomi, Takashi; Kubota, Jun; Domen, Kazunari Chem. Soc. Rev., Vol. 43, Issue 22 https://doi.org/10.1039/C3CS60378D	journal	January 2014
A review on fundamentals for designing oxygen evolution electrocatalysts Song, Jiajia; Wei, Chao; Huang, Zhen-Feng Chemical Society Reviews, Vol. 49, Issue 7 https://doi.org/10.1039/C9CS00607A	journal	January 2020
Dynamics of photogenerated charges in the phosphate modified TiO2 and the enhanced activity for photoelectrochemical water splitting Jing, Liqiang; Zhou, Jia; Durrant, James R. Energy & Environmental Science, Vol. 5, Issue 4 https://doi.org/10.1039/c2ee03383f	journal	January 2012
Anatase TiO2 nanoparticles for lithium-ion batteries El-Deen, S. S.; Hashem, A. M.; Abdel Ghany, A. E. Ionics, Vol. 24, Issue 10 https://doi.org/10.1007/s11581-017-2425-y	journal	January 2018
Differentiating Homogeneous and Heterogeneous Water Oxidation Catalysis: Confirmation that [Co₄(H₂O)₂(α-PW₉O₃₄)₂]^10– Is a Molecular Water Oxidation Catalyst Vickers, James W.; Lv, Hongjin; Sumliner, Jordan M. Journal of the American Chemical Society, Vol. 135, Issue 38, p. 14110-14118 https://doi.org/10.1021/ja4024868	journal	September 2013
Time-Resolved Spectroscopic Investigation of Charge Trapping in Carbon Nitrides Photocatalysts for Hydrogen Generation Godin, Robert; Wang, Yiou; Zwijnenburg, Martijn A. Journal of the American Chemical Society, Vol. 139, Issue 14 https://doi.org/10.1021/jacs.7b01547	journal	March 2017
Low Catalyst Loading Enhances Charge Accumulation for Photoelectrochemical Water Splitting Liu, Tianying; Li, Wei; Wang, David Z. Angewandte Chemie, Vol. 135, Issue 34 https://doi.org/10.1002/ange.202307909	journal	July 2023
Photoinduced Absorption Spectroscopy of CoPi on BiVO ₄ : The Function of CoPi during Water Oxidation Ma, Yimeng; Kafizas, Andreas; Pendlebury, Stephanie R. Advanced Functional Materials, Vol. 26, Issue 27 https://doi.org/10.1002/adfm.201600711	journal	May 2016
Sustainable oxygen evolution electrocatalysis in aqueous 1 M H2SO4 with earth abundant nanostructured Co3O4 Yu, Jiahao; Garcés-Pineda, Felipe A.; González-Cobos, Jesús Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-32024-6	journal	July 2022
A Fast Soluble Carbon-Free Molecular Water Oxidation Catalyst Based on Abundant Metals Yin, Q.; Tan, J. M.; Besson, C. Science, Vol. 328, Issue 5976, p. 342-345 https://doi.org/10.1126/science.1185372	journal	March 2010
Where Do Photogenerated Holes Go in Anatase:Rutile TiO ₂ ? A Transient Absorption Spectroscopy Study of Charge Transfer and Lifetime Kafizas, Andreas; Wang, Xiuli; Pendlebury, Stephanie R. The Journal of Physical Chemistry A, Vol. 120, Issue 5 https://doi.org/10.1021/acs.jpca.5b11567	journal	December 2015
Electrocatalysis for the oxygen evolution reaction: recent development and future perspectives Suen, Nian-Tzu; Hung, Sung-Fu; Quan, Quan Chemical Society Reviews, Vol. 46, Issue 2 https://doi.org/10.1039/C6CS00328A	journal	January 2017
One-step synthesis of cobalt-doped MoS ₂ nanosheets as bifunctional electrocatalysts for overall water splitting under both acidic and alkaline conditions Xiong, Qizhong; Zhang, Xian; Wang, Haojie Chemical Communications, Vol. 54, Issue 31 https://doi.org/10.1039/C8CC00766G	journal	January 2018
Energy and fuels from electrochemical interfaces Stamenkovic, Vojislav R.; Strmcnik, Dusan; Lopes, Pietro P. Nature Materials, Vol. 16, Issue 1 https://doi.org/10.1038/nmat4738	journal	December 2016
Nature and Light Dependence of Bulk Recombination in Co-Pi-Catalyzed BiVO ₄ Photoanodes Abdi, Fatwa F.; van de Krol, Roel The Journal of Physical Chemistry C, Vol. 116, Issue 17 https://doi.org/10.1021/jp3007552	journal	April 2012
An Exceptionally Fast Homogeneous Carbon-Free Cobalt-Based Water Oxidation Catalyst Lv, Hongjin; Song, Jie; Geletii, Yurii V. Journal of the American Chemical Society, Vol. 136, Issue 26 https://doi.org/10.1021/ja5045488	journal	June 2014
Stabilization of Polyoxometalate Water Oxidation Catalysts on Hematite by Atomic Layer Deposition Lauinger, Sarah M.; Piercy, Brandon D.; Li, Wei ACS Applied Materials & Interfaces, Vol. 9, Issue 40 https://doi.org/10.1021/acsami.7b12168	journal	September 2017
High Stability of Immobilized Polyoxometalates on TiO ₂ Nanoparticles and Nanoporous Films for Robust, Light-Induced Water Oxidation Lauinger, Sarah M.; Sumliner, Jordan M.; Yin, Qiushi Chemistry of Materials, Vol. 27, Issue 17 https://doi.org/10.1021/acs.chemmater.5b01248	journal	August 2015
Non-iridium-based electrocatalyst for durable acidic oxygen evolution reaction in proton exchange membrane water electrolysis Wu, Zhen-Yu; Chen, Feng-Yang; Li, Boyang Nature Materials, Vol. 22, Issue 1 https://doi.org/10.1038/s41563-022-01380-5	journal	October 2022
Enabling unassisted solar water splitting by iron oxide and silicon Jang, Ji-Wook; Du, Chun; Ye, Yifan Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8447	journal	June 2015
Speciation and Dynamics in the [Co ₄ V ₂ W ₁₈ O ₆₈ ] ^10– /Co(II) _aq /CoO _x Catalytic Water Oxidation System Sullivan, Kevin P.; Wieliczko, Marika; Kim, Mooeung ACS Catalysis, Vol. 8, Issue 12 https://doi.org/10.1021/acscatal.7b01030	journal	November 2018
Powering the planet: Chemical challenges in solar energy utilization Lewis, N. S.; Nocera, D. G. Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735 https://doi.org/10.1073/pnas.0603395103	journal	October 2006
Boosting photocatalytic water oxidation achieved by BiVO4 coupled with iron-containing polyoxometalate: Analysis the true catalyst Zheng, Min; Cao, Xiaohu; Ding, Yong Journal of Catalysis, Vol. 363 https://doi.org/10.1016/j.jcat.2018.04.022	journal	July 2018
Structure sensitive photocatalytic reduction of nitroarenes over TiO 2 Challagulla, Swapna; Tarafder, Kartick; Ganesan, Ramakrishnan Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-08599-2	journal	August 2017
Adsorption of 3-mercaptopropyltrimethoxysilane and 3-aminopropyltrimethoxysilane at platinum electrodes Brito, Rosa; Rodrı́guez, V. A.; Figueroa, Janet Journal of Electroanalytical Chemistry, Vol. 520, Issue 1-2 https://doi.org/10.1016/S0022-0728(01)00718-5	journal	February 2002
Interpretation of photocurrent transients at semiconductor electrodes: Effects of band-edge unpinning Peter, Laurence M.; Walker, Alison B.; Bein, Thomas Journal of Electroanalytical Chemistry, Vol. 872 https://doi.org/10.1016/j.jelechem.2020.114234	journal	September 2020
Low-bias photoelectrochemical water splitting via mediating trap states and small polaron hopping Wu, Hao; Zhang, Lei; Du, Aijun Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-33905-6	journal	October 2022
Efficient suppression of back electron/hole recombination in cobalt phosphate surface-modified undoped bismuth vanadate photoanodes Ma, Yimeng; Le Formal, Florian; Kafizas, Andreas Journal of Materials Chemistry A, Vol. 3, Issue 41 https://doi.org/10.1039/C5TA05826K	journal	January 2015
Efficient Light-Driven Carbon-Free Cobalt-Based Molecular Catalyst for Water Oxidation Huang, Zhuangqun; Luo, Zhen; Geletii, Yurii V. Journal of the American Chemical Society, Vol. 133, Issue 7, p. 2068-2071 https://doi.org/10.1021/ja109681d	journal	February 2011
Light-Induced Water Splitting with Hematite: Improved Nanostructure and Iridium Oxide Catalysis Tilley, S. David; Cornuz, Maurin; Sivula, Kevin Angewandte Chemie International Edition, Vol. 49, Issue 36 https://doi.org/10.1002/anie.201003110	journal	July 2010
Iridium Single Atoms Coupling with Oxygen Vacancies Boosts Oxygen Evolution Reaction in Acid Media Yin, Jie; Jin, Jing; Lu, Min Journal of the American Chemical Society, Vol. 142, Issue 43 https://doi.org/10.1021/jacs.0c05050	journal	September 2020
A Keggin Polyoxometalate Shows Water Oxidation Activity at Neutral pH: POM@ZIF-8, an Efficient and Robust Electrocatalyst Mukhopadhyay, Subhabrata; Debgupta, Joyashish; Singh, Chandani Angewandte Chemie International Edition, Vol. 57, Issue 7 https://doi.org/10.1002/anie.201711920	journal	January 2018
Hole diffusion length in n ‐TiO ₂ single crystals and sintered electrodes: Photoelectrochemical determination and comparative analysis Salvador, P. Journal of Applied Physics, Vol. 55, Issue 8 https://doi.org/10.1063/1.333358	journal	April 1984

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Title: Charge Transfer Mechanism on a Cobalt-Polyoxometalate-TiO ₂ Photoanode for Water Oxidation in Acid