Phase Morphology Dependence of Ionic Conductivity and Oxidative Stability in Fluorinated Ether Solid-State Electrolytes

Doyle, Emily S.; Mirmira, Priyadarshini; Ma, Peiyuan; Vu, Minh Canh; Hixson-Wells, Trinity; Kumar, Ritesh; Amanchukwu, Chibueze V.

doi:10.1021/acs.chemmater.4c00199

Title: Phase Morphology Dependence of Ionic Conductivity and Oxidative Stability in Fluorinated Ether Solid-State Electrolytes

Journal Article · 08 May 2024 · Chemistry of Materials

DOI: https://doi.org/10.1021/acs.chemmater.4c00199 · OSTI ID:2349143

Doyle, Emily S. ^[1];

^[1]; Ma, Peiyuan ^[1]; Vu, Minh Canh ^[1]; Hixson-Wells, Trinity ^[1]; Kumar, Ritesh ^[1];

^[1]

Pritzker School of Molecular Engineering, University of Chicago, Chicago, Illinois 60637, United States

Not Available

View Journal Article

Cite

Export

Save

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 2349143

Alternate ID(s):: OSTI ID: 2367461

Journal Information:: Chemistry of Materials, Journal Name: Chemistry of Materials Journal Issue: 10 Vol. 36; ISSN 0897-4756

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (67)

Effect of Building Block Connectivity and Ion Solvation on Electrochemical Stability and Ionic Conductivity in Novel Fluoroether Electrolytes Ma, Peiyuan; Mirmira, Priyadarshini; Amanchukwu, Chibueze V. ACS Central Science, Vol. 7, Issue 7 https://doi.org/10.1021/acscentsci.1c00503	journal	July 2021
Quantum Calculation of Molecular Energies and Energy Gradients in Solution by a Conductor Solvent Model Barone, Vincenzo; Cossi, Maurizio The Journal of Physical Chemistry A, Vol. 102, Issue 11 https://doi.org/10.1021/jp9716997	journal	March 1998
Role of solvent-anion charge transfer in oxidative degradation of battery electrolytes Fadel, Eric R.; Faglioni, Francesco; Samsonidze, Georgy Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-11317-3	journal	July 2019
A Strategy to Make High Voltage LiCoO ₂ Compatible with Polyethylene Oxide Electrolyte in All-Solid-State Lithium Ion Batteries Ma, Jun; Liu, Zhaolin; Chen, Bingbing Journal of The Electrochemical Society, Vol. 164, Issue 14 https://doi.org/10.1149/2.0221714jes	journal	January 2017
Crosslinked perfluoropolyether solid electrolytes for lithium ion transport Devaux, Didier; Villaluenga, Irune; Bhatt, Mahesh Solid State Ionics, Vol. 310 https://doi.org/10.1016/j.ssi.2017.08.007	journal	November 2017
A monofluoride ether-based electrolyte solution for fast-charging and low-temperature non-aqueous lithium metal batteries Zhang, Guangzhao; Chang, Jian; Wang, Liguang Nature Communications, Vol. 14, Issue 1 https://doi.org/10.1038/s41467-023-36793-6	journal	February 2023
Correlating the NMR self-diffusion and relaxation measurements with ionic conductivity in polymer electrolytes composed of cross-linked poly(ethylene oxide-propylene oxide) doped with LiN(SO2CF3)2 Hayamizu, Kikuko; Aihara, Yuichi; Price, William S. The Journal of Chemical Physics, Vol. 113, Issue 11 https://doi.org/10.1063/1.1288801	journal	September 2000
Dead lithium: mass transport effects on voltage, capacity, and failure of lithium metal anodes Chen, Kuan-Hung; Wood, Kevin N.; Kazyak, Eric Journal of Materials Chemistry A, Vol. 5, Issue 23 https://doi.org/10.1039/C7TA00371D	journal	January 2017
Optimizing Ion Transport in Polyether-Based Electrolytes for Lithium Batteries Zheng, Qi; Pesko, Danielle M.; Savoie, Brett M. Macromolecules, Vol. 51, Issue 8 https://doi.org/10.1021/acs.macromol.7b02706	journal	April 2018
Fluorine–Fluorine Interactions in the Solid State: An Experimental and Theoretical Study Baker, Robert J.; Colavita, Paula E.; Murphy, Deirdre M. The Journal of Physical Chemistry A, Vol. 116, Issue 5 https://doi.org/10.1021/jp2099976	journal	December 2011
Ion-conductive polymer electrolytes based on poly(ethylene carbonate) and its derivatives Tominaga, Yoichi Polymer Journal, Vol. 49, Issue 3 https://doi.org/10.1038/pj.2016.115	journal	December 2016
The intrinsic behavior of lithium fluoride in solid electrolyte interphases on lithium He, Mingfu; Guo, Rui; Hobold, Gustavo M. Proceedings of the National Academy of Sciences, Vol. 117, Issue 1 https://doi.org/10.1073/pnas.1911017116	journal	December 2019
Phase Behavior and Electrochemical Characterization of Blends of Perfluoropolyether, Poly(ethylene glycol), and a Lithium Salt Wong, Dominica H. C.; Vitale, Alessandra; Devaux, Didier Chemistry of Materials, Vol. 27, Issue 2 https://doi.org/10.1021/cm504228a	journal	January 2015
Determining the Absolute Anodic Stability Threshold of Polymer Electrolytes: A Capacity-Based Electrochemical Method Li, Zhuo; Zhao, Yineng; Tenhaeff, Wyatt E. Chemistry of Materials, Vol. 33, Issue 6 https://doi.org/10.1021/acs.chemmater.0c04248	journal	March 2021
Hyperbranched PEO-Based Hyperstar Solid Polymer Electrolytes with Simultaneous Improvement of Ion Transport and Mechanical Strength Chen, Yang; Shi, Yi; Liang, Yanliang ACS Applied Energy Materials, Vol. 2, Issue 3 https://doi.org/10.1021/acsaem.8b02188	journal	February 2019
Ultra-stable all-solid-state sodium metal batteries enabled by perfluoropolyether-based electrolytes Wang, Xiaoen; Zhang, Cheng; Sawczyk, Michal Nature Materials, Vol. 21, Issue 9 https://doi.org/10.1038/s41563-022-01296-0	journal	July 2022
Intrinsic Ion Transport Properties of Block Copolymer Electrolytes Sharon, Daniel; Bennington, Peter; Dolejsi, Moshe ACS Nano, Vol. 14, Issue 7 https://doi.org/10.1021/acsnano.0c03713	journal	June 2020
Investigating the Effect of Added Salt on the Chain Dimensions of Poly(ethylene oxide) through Small-Angle Neutron Scattering Loo, Whitney S.; Mongcopa, Katrina I.; Gribble, Daniel A. Macromolecules, Vol. 52, Issue 22 https://doi.org/10.1021/acs.macromol.9b01509	journal	November 2019
Stable cycling of high-voltage lithium metal batteries in ether electrolytes Jiao, Shuhong; Ren, Xiaodi; Cao, Ruiguo Nature Energy, Vol. 3, Issue 9 https://doi.org/10.1038/s41560-018-0199-8	journal	July 2018
A New Class of Ionically Conducting Fluorinated Ether Electrolytes with High Electrochemical Stability Amanchukwu, Chibueze V.; Yu, Zhiao; Kong, Xian Journal of the American Chemical Society, Vol. 142, Issue 16 https://doi.org/10.1021/jacs.9b11056	journal	April 2020
Factors affecting cyclic durability of all-solid-state lithium polymer batteries using poly(ethylene oxide)-based solid polymer electrolytes Nakayama, Masanobu; Wada, Shinta; Kuroki, Shigeki Energy & Environmental Science, Vol. 3, Issue 12 https://doi.org/10.1039/c0ee00266f	journal	January 2010
Designing polymers for advanced battery chemistries Lopez, Jeffrey; Mackanic, David G.; Cui, Yi Nature Reviews Materials, Vol. 4, Issue 5 https://doi.org/10.1038/s41578-019-0103-6	journal	April 2019
A Cation-Tethered Flowable Polymeric Interface for Enabling Stable Deposition of Metallic Lithium Huang, Zhuojun; Choudhury, Snehashis; Gong, Huaxin Journal of the American Chemical Society, Vol. 142, Issue 51 https://doi.org/10.1021/jacs.0c09649	journal	December 2020
A review of composite polymer-ceramic electrolytes for lithium batteries Yu, Xingwen; Manthiram, Arumugam Energy Storage Materials, Vol. 34 https://doi.org/10.1016/j.ensm.2020.10.006	journal	January 2021
Poly(2-aminoazulene) Filler–Improved PEO-Based Electrolyte for Highly Stable Solid-State Li-Metal Batteries Wen, Jia; Chen, Zhenying; Han, Sheng Journal of The Electrochemical Society, Vol. 168, Issue 9 https://doi.org/10.1149/1945-7111/ac2685	journal	September 2021
Fluorine-containing triblock copolymers as solid-state polymer electrolytes for lithium metal batteries Sun, Yuxue; Zhang, Xiaorong; Ma, Chunhui Journal of Power Sources, Vol. 516 https://doi.org/10.1016/j.jpowsour.2021.230686	journal	December 2021
Use of Solid-State NMR Spectroscopy for the Characterization of Molecular Structure and Dynamics in Solid Polymer and Hybrid Electrolytes Foran, Gabrielle; Verdier, Nina; Lepage, David Polymers, Vol. 13, Issue 8 https://doi.org/10.3390/polym13081207	journal	April 2021
A Superior Polymer Electrolyte with Rigid Cyclic Carbonate Backbone for Rechargeable Lithium Ion Batteries Chai, Jingchao; Liu, Zhihong; Zhang, Jianjun ACS Applied Materials & Interfaces, Vol. 9, Issue 21 https://doi.org/10.1021/acsami.7b02844	journal	May 2017
Synthesis of Li[sup +] Ion Conductive PEO-PSt Block Copolymer Electrolyte with Microphase Separation Structure Niitani, Takeshi; Shimada, Mikiya; Kawamura, Kiyoshi Electrochemical and Solid-State Letters, Vol. 8, Issue 8 https://doi.org/10.1149/1.1940491	journal	January 2005
Incipient microphase separation in short chain perfluoropolyether-block-poly(ethylene oxide) copolymers Chintapalli, Mahati; Timachova, Ksenia; Olson, Kevin R. Soft Matter, Vol. 13, Issue 22 https://doi.org/10.1039/C7SM00738H	journal	January 2017
Optically Transparent, Amphiphilic Networks Based on Blends of Perfluoropolyethers and Poly(ethylene glycol) Hu, Zhaokang; Chen, Liang; Betts, Douglas E. Journal of the American Chemical Society, Vol. 130, Issue 43 https://doi.org/10.1021/ja803991n	journal	October 2008
Nanostructured Block Polymer Electrolytes: Tailoring Self-Assembly to Unlock the Potential in Lithium-Ion Batteries Ketkar, Priyanka M.; Epps, Thomas H. Accounts of Chemical Research, Vol. 54, Issue 23 https://doi.org/10.1021/acs.accounts.1c00468	journal	November 2021
Designing an asymmetric ether-like lithium salt to enable fast-cycling high-energy lithium metal batteries Xia, Yingchun; Zhou, Pan; Kong, Xian Nature Energy, Vol. 8, Issue 9 https://doi.org/10.1038/s41560-023-01282-z	journal	June 2023
Designing Weakly Solvating Solid Main-Chain Fluoropolymer Electrolytes: Synergistically Enhancing Stability toward Li Anodes and High-Voltage Cathodes Ma, Mingyu; Shao, Fei; Wen, Peng ACS Energy Letters, Vol. 6, Issue 12 https://doi.org/10.1021/acsenergylett.1c02036	journal	November 2021
Understanding Lithium-Ion Dynamics in Single-Ion and Salt-in-Polymer Perfluoropolyethers and Polyethyleneglycol Electrolytes Using Solid-State NMR Amanchukwu, Chibueze V.; Gunnarsdóttir, Anna B.; Choudhury, Snehashis Macromolecules, Vol. 56, Issue 10 https://doi.org/10.1021/acs.macromol.2c02160	journal	April 2023
Nonflammable perfluoropolyether-based electrolytes for lithium batteries Wong, Dominica H. C.; Thelen, Jacob L.; Fu, Yanbao Proceedings of the National Academy of Sciences, Vol. 111, Issue 9 https://doi.org/10.1073/pnas.1314615111	journal	February 2014
PEO-based solid-state electrolyte modified by cationic covalent organic frameworks enabling high-performance all-solid-state Li metal and graphite anode batteries Chen, Jing; Han, Sheng Chemical Engineering Journal, Vol. 470 https://doi.org/10.1016/j.cej.2023.144150	journal	August 2023
Mapping a stable solvent structure landscape for aprotic Li–air battery organic electrolytes Feng, Shuting; Chen, Mao; Giordano, Livia Journal of Materials Chemistry A, Vol. 5, Issue 45 https://doi.org/10.1039/C7TA08321A	journal	January 2017
Poly(Ethylene Oxide)-based Electrolyte for Solid-State-Lithium-Batteries with High Voltage Positive Electrodes: Evaluating the Role of Electrolyte Oxidation in Rapid Cell Failure Homann, Gerrit; Stolz, Lukas; Nair, Jijeesh Scientific Reports, Vol. 10, Issue 1 https://doi.org/10.1038/s41598-020-61373-9	journal	March 2020
Room‐Temperature Solid‐State Polymer Electrolyte in Li‐LiFePO₄, Li‐S and Li‐O₂ Batteries Marangon, Vittorio; Minnetti, Luca; Barcaro, Edoardo Chemistry – A European Journal, Vol. 29, Issue 45 https://doi.org/10.1002/chem.202301345	journal	July 2023
A Cross-Linked Poly(Ethylene Oxide)-Based Electrolyte for All-Solid-State Lithium Metal Batteries With Long Cycling Stability Xin, Chengzhou; Wen, Kaihua; Guan, Shundong Frontiers in Materials, Vol. 9 https://doi.org/10.3389/fmats.2022.864478	journal	April 2022
Enhanced Conductivity via Homopolymer-Rich Pathways in Block Polymer-Blended Electrolytes Morris, Melody A.; Sung, Seung Hyun; Ketkar, Priyanka M. Macromolecules, Vol. 52, Issue 24 https://doi.org/10.1021/acs.macromol.9b01879	journal	December 2019
Relationship between Conductivity, Ion Diffusion, and Transference Number in Perfluoropolyether Electrolytes Chintapalli, Mahati; Timachova, Ksenia; Olson, Kevin R. Macromolecules, Vol. 49, Issue 9 https://doi.org/10.1021/acs.macromol.6b00412	journal	April 2016
Challenges for Rechargeable Li Batteries Goodenough, John B.; Kim, Youngsik Chemistry of Materials, Vol. 22, Issue 3, p. 587-603 https://doi.org/10.1021/cm901452z	journal	February 2010
Experimental Studies of Salt Concentration in Electrolyte on the Performance of Li-O₂Batteries at Various Current Densities Mohazabrad, Farhad; Wang, Fangzhou; Li, Xianglin Journal of The Electrochemical Society, Vol. 163, Issue 13 https://doi.org/10.1149/2.0711613jes	journal	January 2016
Molecular Level Differences in Ionic Solvation and Transport Behavior in Ethylene Oxide-Based Homopolymer and Block Copolymer Electrolytes Sharon, Daniel; Bennington, Peter; Webb, Michael A. Journal of the American Chemical Society, Vol. 143, Issue 8 https://doi.org/10.1021/jacs.0c12538	journal	February 2021
Polymer Electrolytes Hallinan, Daniel T.; Balsara, Nitash P. Annual Review of Materials Research, Vol. 43, Issue 1 https://doi.org/10.1146/annurev-matsci-071312-121705	journal	July 2013
The absolute electrode potential: an explanatory note (Recommendations 1986) Trasatti, S. Pure and Applied Chemistry, Vol. 58, Issue 7 https://doi.org/10.1351/pac198658070955	journal	January 1986
Enabling High-Voltage Lithium-Metal Batteries under Practical Conditions Ren, Xiaodi; Zou, Lianfeng; Cao, Xia Joule, Vol. 3, Issue 7 https://doi.org/10.1016/j.joule.2019.05.006	journal	July 2019
Molecular design for electrolyte solvents enabling energy-dense and long-cycling lithium metal batteries Yu, Zhiao; Wang, Hansen; Kong, Xian Nature Energy, Vol. 5, Issue 7 https://doi.org/10.1038/s41560-020-0634-5	journal	June 2020
Role of solvation site segmental dynamics on ion transport in ethylene-oxide based side-chain polymer electrolytes Bennington, Peter; Deng, Chuting; Sharon, Daniel Journal of Materials Chemistry A, Vol. 9, Issue 15 https://doi.org/10.1039/d1ta00899d	journal	January 2021
VMD: Visual molecular dynamics Humphrey, William; Dalke, Andrew; Schulten, Klaus Journal of Molecular Graphics, Vol. 14, Issue 1 https://doi.org/10.1016/0263-7855(96)00018-5	journal	February 1996
Miscible Polyether/Poly(ether–acetal) Electrolyte Blends Gao, Kevin W.; Loo, Whitney S.; Snyder, Rachel L. Macromolecules, Vol. 53, Issue 14 https://doi.org/10.1021/acs.macromol.0c00747	journal	July 2020
A Critical Review for an Accurate Electrochemical Stability Window Measurement of Solid Polymer and Composite Electrolytes Méry, Adrien; Rousselot, Steeve; Lepage, David Materials, Vol. 14, Issue 14 https://doi.org/10.3390/ma14143840	journal	July 2021
Modelling lithium ion transport in helical PEO by ab initio calculations Johansson, Patrik; Tegenfeldt, Jörgen; Lindgren, Jan Polymer, Vol. 42, Issue 15 https://doi.org/10.1016/S0032-3861(01)00101-X	journal	July 2001
Monolithic solid–electrolyte interphases formed in fluorinated orthoformate-based electrolytes minimize Li depletion and pulverization Cao, Xia; Ren, Xiaodi; Zou, Lianfeng Nature Energy, Vol. 4, Issue 9 https://doi.org/10.1038/s41560-019-0464-5	journal	September 2019
Infrared and Raman study of the PEO-LiTFSI polymer electrolyte Rey, I.; Lassègues, J. C.; Grondin, J. Electrochimica Acta, Vol. 43, Issue 10-11 https://doi.org/10.1016/s0013-4686(97)10092-5	journal	April 1998
Thermodynamics of Ion-Containing Polymer Blends and Block Copolymers Nakamura, Issei; Balsara, Nitash P.; Wang, Zhen-Gang Physical Review Letters, Vol. 107, Issue 19 https://doi.org/10.1103/PhysRevLett.107.198301	journal	November 2011
Overcoming the Challenges of 5 V Spinel LiNi _0.5 Mn _1.5 O ₄ Cathodes with Solid Polymer Electrolytes Xu, Hantao; Zhang, Huanrui; Ma, Jun ACS Energy Letters, Vol. 4, Issue 12 https://doi.org/10.1021/acsenergylett.9b01871	journal	October 2019
Interface chemistry of an amide electrolyte for highly reversible lithium metal batteries Wang, Qidi; Yao, Zhenpeng; Zhao, Chenglong Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-17976-x	journal	August 2020
Perfluoropolyether-based block copolymer electrolytes enabling high-temperature-resistant solid-state lithium metal batteries Sun, Yuxue; Zhang, Xiaorong; Xu, Pingbo Journal of Power Sources, Vol. 561 https://doi.org/10.1016/j.jpowsour.2023.232751	journal	March 2023
Suppression of Lithium Dendrite Growth Using Cross-Linked Polyethylene/Poly(ethylene oxide) Electrolytes: A New Approach for Practical Lithium-Metal Polymer Batteries Khurana, Rachna; Schaefer, Jennifer L.; Archer, Lynden A. Journal of the American Chemical Society, Vol. 136, Issue 20 https://doi.org/10.1021/ja502133j	journal	May 2014
Mechanistic insight into the improved Li ion conductivity of solid polymer electrolytes Patra, Sudeshna; Thakur, Pallavi; Soman, Bhaskar RSC Advances, Vol. 9, Issue 66 https://doi.org/10.1039/C9RA08003A	journal	January 2019
100th Anniversary of Macromolecular Science Viewpoint: Solid Polymer Electrolytes in Cathode Electrodes for Lithium Batteries. Current Challenges and Future Opportunities Patel, Shrayesh N. ACS Macro Letters, Vol. 10, Issue 1 https://doi.org/10.1021/acsmacrolett.0c00724	journal	January 2021
Role of solvation site segmental dynamics on ion transport in ethylene-oxide based side-chain polymer electrolytes Bennington, Peter; Deng, Chuting; Sharon, Daniel Journal of Materials Chemistry A, Vol. 9, Issue 15 https://doi.org/10.1039/D1TA00899D	journal	January 2021
Fluorinated ether electrolyte with controlled solvation structure for high voltage lithium metal batteries Zhao, Yan; Zhou, Tianhong; Ashirov, Timur Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-29199-3	journal	May 2022
Origin of the Immiscibility of Alkanes and Perfluoroalkanes Pollice, Robert; Chen, Peter Journal of the American Chemical Society, Vol. 141, Issue 8 https://doi.org/10.1021/jacs.8b10745	journal	January 2019

Similar Records

Non-Conductive Polymers Enable Higher Ionic Conductivities and Suppress Reactivity in Hybrid Sulfide-Polymer Solid State Electrolytes

Journal Article · 2022 · ACS Applied Energy Materials · OSTI ID:1910051

Mirmira, Priyadarshini; Fuschi, Claire; Gillett, Walker; +4 more

Yttrium–Sodium Halides as Promising Solid-State Electrolytes with High Ionic Conductivity and Stability for Na-Ion Batteries

Journal Article · 2020 · Journal of Physical Chemistry Letters · OSTI ID:1800861

Qie, Yu; Wang, Shuo; Fu, Sijie; +3 more

Ionic Conduction Mechanism and Design of Metal–Organic Framework Based Quasi-Solid-State Electrolytes

Journal Article · 2022 · Journal of the American Chemical Society · OSTI ID:1872477

Hou, Tingzheng; Xu, Wentao; Pei, Xiaokun; +3 more

Title: Phase Morphology Dependence of Ionic Conductivity and Oxidative Stability in Fluorinated Ether Solid-State Electrolytes

Citation Formats

References (67)

Similar Records

Related Subjects