New Platinum Complexes from Salen- and Hydroxy-Substituted Salpn-Naphthalene Ligands with CO2 Reduction Activity

Rivera-Reyes, Javier O.; Soto-Pérez, Joesene; Sepulveda-Pagán, Miguel; Lu, Linguo; Borrero-Negrón, Justin; Luna-Ramírez, Alanys V.; Trinidad-Pérez, Pedro; Pagán-Torres, Yomaira; Chen, Zhongfang; Cabrera, Carlos R.; West, William C.; Jones, John-Paul; Piñero Cruz, Dalice M.

doi:10.3390/catal13050911

Title: New Platinum Complexes from Salen- and Hydroxy-Substituted Salpn-Naphthalene Ligands with CO₂ Reduction Activity

Journal Article · 21 May 2023 · Catalysts

DOI: https://doi.org/10.3390/catal13050911 · OSTI ID:2346222

Rivera-Reyes, Javier O. ^[1];

^[2]; Sepulveda-Pagán, Miguel ^[3]; Lu, Linguo ^[2]; Borrero-Negrón, Justin ^[3]; Luna-Ramírez, Alanys V. ^[3];

^[3];

^[3]; Chen, Zhongfang ^[2]; Cabrera, Carlos R. ^[4]; West, William C. ^[5]; Jones, John-Paul ^[5];

^[2]

Univ. of Puerto Rico, San Juan, PR (United States); University of Puerto Rico, Rio Piedras Campus
Univ. of Puerto Rico, San Juan, PR (United States)
Univ. of Puerto Rico, Mayaguez, PR (United States)
Univ. of Texas at El Paso, TX (United States)
California Institute of Technology (CalTech), Pasadena, CA (United States). Jet Propulsion Lab. (JPL)

The electrocatalytic reduction of carbon dioxide (CO₂) into added-value products is a promising alternative to completing the cycle of atmospheric CO₂. We report two new platinum complexes—a salen-like naphthalene (PtL1) and a hydroxy-substituted salpn naphthalene (PtL2)—that are capable of activating CO₂ to produce carbon monoxide (CO). The predominant keto tautomer of the non-innocent ligands was determined using DFT calculations and UV-Vis spectroscopy. The PtL2 complex has a CO Faradaic efficiency >40% in the presence of water as a sacrificial proton source at -2.5 V vs. Fc/Fc⁺. The addition of the hydroxy group in combination with water as a proton source decreased the reduction potential and increased the CO formation tenfold when compared to PtL1.

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Research Organization:: Univ. of Puerto Rico, Mayaguez (Puerto Rico)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Aeronautics and Space Administration (NASA); National Science Foundation (NSF)

Contributing Organization:: University of Texas, El Paso; California Institute of Technology (CalTech). Jet Propulsion Lab. (JPL)

Grant/Contract Number:: SC0023418

OSTI ID:: 2346222

Journal Information:: Catalysts, Journal Name: Catalysts Journal Issue: 5 Vol. 13; ISSN 2073-4344

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

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electrocatalysis
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CCDC 2129562: Experimental Crystal Structure Determination O., Rivera-Reyes, Javier; Joesene, Soto-Pérez,; Miguel, Sepulveda-Pagán, https://doi.org/10.5517/ccdc.csd.cc29gzkb The current record is supplemented by this dataset	dataset	January 2023
CCDC 2128738: Experimental Crystal Structure Determination O., Rivera-Reyes, Javier; Joesene, Soto-Pérez,; Miguel, Sepulveda-Pagán, https://doi.org/10.5517/ccdc.csd.cc29g3zw The current record is supplemented by this dataset	dataset	January 2023

Title: New Platinum Complexes from Salen- and Hydroxy-Substituted Salpn-Naphthalene Ligands with CO2 Reduction Activity

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Title: New Platinum Complexes from Salen- and Hydroxy-Substituted Salpn-Naphthalene Ligands with CO₂ Reduction Activity