Oversaturating Liquid Interfaces with Nanoparticle‐Surfactants

Wu, Xuefei; Xue, Han; Fink, Zachary; Helms, Brett A.; Ashby, Paul D.; Omar, Ahmad K.; Russell, Thomas P.

doi:10.1002/ange.202403790

Title: Oversaturating Liquid Interfaces with Nanoparticle‐Surfactants

Journal Article · 02 May 2024 · Angewandte Chemie

DOI: https://doi.org/10.1002/ange.202403790 · OSTI ID:2345801

^[1];

^[2];

^[3];

^[4]; Omar, Ahmad K. ^[5];

^[6]

Materials Sciences Division Lawrence Berkeley National Laboratory Berkeley CA-94720 USA
Materials Sciences Division Lawrence Berkeley National Laboratory Berkeley CA-94720 USA, Polymer Science and Engineering Department University of Massachusetts Amherst MA-01003 USA
Materials Sciences Division Lawrence Berkeley National Laboratory Berkeley CA-94720 USA, Molecular Foundry Lawrence Berkeley National Laboratory Berkeley CA-94720 USA
Molecular Foundry Lawrence Berkeley National Laboratory Berkeley CA-94720 USA
Materials Sciences Division Lawrence Berkeley National Laboratory Berkeley CA-94720 USA, Department of Materials Science and Engineering University of California, Berkeley Berkeley CA-94720 USA
Materials Sciences Division Lawrence Berkeley National Laboratory Berkeley CA-94720 USA, Polymer Science and Engineering Department University of Massachusetts Amherst MA-01003 USA, Advanced Institute for Materials Research (AIMR) Tohoku University 2-1-1 Katahira, Aoba Sendai 980-8577 Japan

Abstract Assemblies of nanoparticles at liquid interfaces hold promise as dynamic “active” systems when there are convenient methods to drive the system out of equilibrium via crowding. To this end, we show that oversaturated assemblies of charged nanoparticles can be realized and held in that state with an external electric field. Upon removal of the field, strong interparticle repulsive forces cause a high in‐plane electrostatic pressure that is released in an explosive emulsification. We quantify the packing of the assembly as it is driven into the oversaturated state under an applied electric field. Physiochemical conditions substantially affect the intensity of the induced explosive emulsification, underscoring the crucial role of interparticle electrostatic repulsion.

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 2345801

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 24 Vol. 136; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (62)

Cellular Motility Driven by Assembly and Disassembly of Actin Filaments Pollard, Thomas D.; Borisy, Gary G. Cell, Vol. 112, Issue 4 https://doi.org/10.1016/S0092-8674(03)00120-X	journal	February 2003
Binary Thiol-Capped Gold Nanoparticle Monolayer Films for Quantitative Surface-Enhanced Raman Scattering Analysis Tian, Huihui; Li, Hongbian; Fang, Ying ACS Applied Materials & Interfaces, Vol. 11, Issue 17 https://doi.org/10.1021/acsami.9b02069	journal	April 2019
Graphene–molecule–graphene single-molecule junctions to detect electronic reactions at the molecular scale Yang, Chen; Yang, Caiyao; Guo, Yilin Nature Protocols, Vol. 18, Issue 6 https://doi.org/10.1038/s41596-023-00822-x	journal	April 2023
Nanoparticles at fluid interfaces: Exploiting capping ligands to control adsorption, stability and dynamics Garbin, Valeria; Crocker, John C.; Stebe, Kathleen J. Journal of Colloid and Interface Science, Vol. 387, Issue 1 https://doi.org/10.1016/j.jcis.2012.07.047	journal	December 2012
Dynamic Reconfiguration of Compressed 2D Nanoparticle Monolayers Kim, Paul Y.; Gao, Yige; Fink, Zachary ACS Nano, Vol. 16, Issue 4 https://doi.org/10.1021/acsnano.1c09853	journal	March 2022
Why Are Hydrophobic/Water Interfaces Negatively Charged? Roger, Kevin; Cabane, Bernard Angewandte Chemie International Edition, Vol. 51, Issue 23 https://doi.org/10.1002/anie.201108228	journal	April 2012
Ballistic Ejection of Microdroplets from Overpacked Interfacial Assemblies Wu, Xuefei; Bordia, Gautam; Streubel, Robert Advanced Functional Materials, Vol. 33, Issue 20 https://doi.org/10.1002/adfm.202213844	journal	February 2023
Heavy Metal Sensing Using Self‐Assembled Nanoparticles at a Liquid–Liquid Interface Cecchini, Michael P.; Turek, Vladimir A.; Demetriadou, Angela Advanced Optical Materials, Vol. 2, Issue 10 https://doi.org/10.1002/adom.201400211	journal	July 2014
Field-Induced Assembly and Propulsion of Colloids Harraq, Ahmed Al; Choudhury, Brishty Deb; Bharti, Bhuvnesh Langmuir, Vol. 38, Issue 10 https://doi.org/10.1021/acs.langmuir.1c02581	journal	March 2022
Aggregation dynamics of active rotating particles in dense passive media Aragones, Juan L.; Steimel, Joshua P.; Alexander-Katz, Alfredo Soft Matter, Vol. 15, Issue 19 https://doi.org/10.1039/C8SM02207K	journal	January 2019
Interfacial self-assembly of nanoparticles into macroscopic, monolayered films Cheng, Qianhui; Fang, Hetong; Cao, Rui Supramolecular Materials, Vol. 1 https://doi.org/10.1016/j.supmat.2022.100021	journal	December 2022
Hybrid films of reduced graphene oxide with noble metal nanoparticles generated at a liquid/liquid interface for applications in catalysis Bramhaiah, K.; John, Neena S. RSC Advances, Vol. 3, Issue 21 https://doi.org/10.1039/c3ra23324c	journal	January 2013
In situ X-ray scattering observation of two-dimensional interfacial colloidal crystallization Wu, Longlong; Wang, Xiao; Wang, Geng Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-03767-y	journal	April 2018
Monodisperse Double Emulsions Generated from a Microcapillary Device Utada, A. S. Science, Vol. 308, Issue 5721 https://doi.org/10.1126/science.1109164	journal	April 2005
Assembly of Reconfigurable Colloidal Structures by Multidirectional Field-Induced Interactions Bharti, Bhuvnesh; Velev, Orlin D. Langmuir, Vol. 31, Issue 29 https://doi.org/10.1021/la504793y	journal	February 2015
Tunable assembly of hydrophobic protein nanoparticle at fluid interfaces with tannic acid Zou, Yuan; Wan, Zhili; Guo, Jian Food Hydrocolloids, Vol. 63 https://doi.org/10.1016/j.foodhyd.2016.09.010	journal	February 2017
Orthogonal Light-Induced Self-Assembly of Nanoparticles using Differently Substituted Azobenzenes Manna, Debasish; Udayabhaskararao, Thumu; Zhao, Hui Angewandte Chemie International Edition, Vol. 54, Issue 42 https://doi.org/10.1002/anie.201502419	journal	May 2015
Active structuring of colloidal armour on liquid drops Dommersnes, Paul; Rozynek, Zbigniew; Mikkelsen, Alexander Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3066	journal	June 2013
Electric-field-induced capillary attraction between like-charged particles at liquid interfaces Nikolaides, M. G.; Bausch, A. R.; Hsu, M. F. Nature, Vol. 420, Issue 6913 https://doi.org/10.1038/nature01113	journal	November 2002
Reconfigurable ferromagnetic liquid droplets Liu, Xubo; Kent, Noah; Ceballos, Alejandro Science, Vol. 365, Issue 6450 https://doi.org/10.1126/science.aaw8719	journal	July 2019
Reactions in Droplets in Microfluidic Channels Song, Helen; Chen, Delai L.; Ismagilov, Rustem F. Angewandte Chemie International Edition, Vol. 45, Issue 44, p. 7336-7356 https://doi.org/10.1002/anie.200601554	journal	November 2006
Plasmonic Ruler at the Liquid–Liquid Interface Turek, Vladimir A.; Cecchini, Michael P.; Paget, Jack ACS Nano, Vol. 6, Issue 9 https://doi.org/10.1021/nn302941k	journal	August 2012
Structured Liquids with pH-Triggered Reconfigurability Huang, Caili; Sun, Zhiwei; Cui, Mengmeng Advanced Materials, Vol. 28, Issue 31 https://doi.org/10.1002/adma.201600691	journal	May 2016
Self-assembled nanoparticle-coated interfaces: Capillary pressure, shell formation and buckling Liu, Q.; Sun, Z.; Santamarina, J. Carlos Journal of Colloid and Interface Science, Vol. 581 https://doi.org/10.1016/j.jcis.2020.07.110	journal	January 2021
Understanding voltage-induced localization of nanoparticles at a liquid–liquid interface Flatté, M. E.; Kornyshev, A. A.; Urbakh, M. Journal of Physics: Condensed Matter, Vol. 20, Issue 7 https://doi.org/10.1088/0953-8984/20/7/073102	journal	January 2008
Building Reconfigurable Devices Using Complex Liquid–Fluid Interfaces Forth, Joe; Kim, Paul Y.; Xie, Ganhua Advanced Materials, Vol. 31, Issue 18 https://doi.org/10.1002/adma.201806370	journal	February 2019
Electrotunable nanoplasmonic liquid mirror Montelongo, Yunuen; Sikdar, Debabrata; Ma, Ye Nature Materials, Vol. 16, Issue 11 https://doi.org/10.1038/nmat4969	journal	September 2017
Emergence of reconfigurable wires and spinners via dynamic self-assembly Kokot, Gasper; Piet, David; Whitesides, George M. Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep09528	journal	March 2015
Reconfigurable Liquids Stabilized by DNA Surfactants Qian, Bingqing; Shi, Shaowei; Wang, Haiqiao ACS Applied Materials & Interfaces, Vol. 12, Issue 11 https://doi.org/10.1021/acsami.0c01487	journal	February 2020
Interfacial Localization and Voltage-Tunable Arrays of Charged Nanoparticles Bera, Mrinal K.; Chan, Henry; Moyano, Daniel F. Nano Letters, Vol. 14, Issue 12 https://doi.org/10.1021/nl502450j	journal	November 2014
Redistribution of charged aluminum nanoparticles on oil droplets in water in response to applied electrical field Li, Mengqi; Li, Dongqing Journal of Nanoparticle Research, Vol. 18, Issue 5 https://doi.org/10.1007/s11051-016-3390-5	journal	May 2016
Ligand–Ligand-Interaction-Dominated Self-Assembly of Gold Nanoparticles at the Oil/Water Interface: An Atomic-Scale Simulation Jia, Haihong; Zhang, Yan-Fang; Zhang, Chunlei The Journal of Physical Chemistry B, Vol. 127, Issue 10 https://doi.org/10.1021/acs.jpcb.2c07937	journal	March 2023
Instant interfacial self-assembly for homogeneous nanoparticle monolayer enabled conformal “lift-on” thin film technology Song, Liping; Xu, Ben Bin; Cheng, Qian Science Advances, Vol. 7, Issue 52 https://doi.org/10.1126/sciadv.abk2852	journal	December 2021
Assessing Pair Interaction Potentials of Nanoparticles on Liquid Interfaces Kim, Paul Y.; Gao, Yige; Chai, Yu ACS Nano, Vol. 13, Issue 3 https://doi.org/10.1021/acsnano.8b08189	journal	February 2019
Dual-responsive nanoparticles that aggregate under the simultaneous action of light and CO ₂ Lee, Ji-Woong; Klajn, Rafal Chemical Communications, Vol. 51, Issue 11 https://doi.org/10.1039/C4CC08541H	journal	January 2015
Dynamic self-assembly and control of microfluidic particle crystals Lee, W.; Amini, H.; Stone, H. A. Proceedings of the National Academy of Sciences, Vol. 107, Issue 52 https://doi.org/10.1073/pnas.1010297107	journal	December 2010
Stabilizing Liquid Drops in Nonequilibrium Shapes by the Interfacial Jamming of Nanoparticles Cui, M.; Emrick, T.; Russell, T. P. Science, Vol. 342, Issue 6157, p. 460-463 https://doi.org/10.1126/science.1242852	journal	October 2013
Reversible Voltage-Induced Assembly of Au Nanoparticles at Liquid\|Liquid Interfaces Su, Bin; Abid, Jean-Pierre; Fermín, David J. Journal of the American Chemical Society, Vol. 126, Issue 3 https://doi.org/10.1021/ja0386187	journal	January 2004
Interfacial Assembly and Jamming of Polyelectrolyte Surfactants: A Simple Route To Print Liquids in Low-Viscosity Solution Xu, Ruiyan; Liu, Tan; Sun, Huilou ACS Applied Materials & Interfaces, Vol. 12, Issue 15 https://doi.org/10.1021/acsami.0c00577	journal	February 2020
Catalytically powered dynamic assembly of rod-shaped nanomotors and passive tracer particles Wang, Wei; Duan, Wentao; Sen, Ayusman Proceedings of the National Academy of Sciences, Vol. 110, Issue 44 https://doi.org/10.1073/pnas.1311543110	journal	October 2013
Predator–prey interactions between droplets driven by non-reciprocal oil exchange Meredith, Caleb H.; Moerman, Pepijn G.; Groenewold, Jan Nature Chemistry, Vol. 12, Issue 12 https://doi.org/10.1038/s41557-020-00575-0	journal	November 2020
Structure Development of the Interphase between Drying Cellulose Materials Revealed by In Situ Grazing-Incidence Small-Angle X-ray Scattering Li, Hailong; Roth, Stephan V.; Freychet, Guillaume Biomacromolecules, Vol. 22, Issue 10 https://doi.org/10.1021/acs.biomac.1c00845	journal	September 2021
Fine-Tuning Nanoparticle Packing at Water–Oil Interfaces Using Ionic Strength Chai, Yu; Lukito, Alysia; Jiang, Yufeng Nano Letters, Vol. 17, Issue 10 https://doi.org/10.1021/acs.nanolett.7b03462	journal	September 2017
Light-controlled self-assembly of reversible and irreversible nanoparticle suprastructures Klajn, R.; Bishop, K. J. M.; Grzybowski, B. A. Proceedings of the National Academy of Sciences, Vol. 104, Issue 25 https://doi.org/10.1073/pnas.0611371104	journal	June 2007
Self-Assembly at All Scales Whitesides, George M.; Grzybowski, Bartosz Science, Vol. 295, Issue 5564, p. 2418-2421 https://doi.org/10.1126/science.1070821	journal	March 2002
Magnetic manipulation of self-assembled colloidal asters Snezhko, Alexey; Aranson, Igor S. Nature Materials, Vol. 10, Issue 9 https://doi.org/10.1038/nmat3083	journal	August 2011
Small Angle X-ray Scattering for Nanoparticle Research Li, Tao; Senesi, Andrew J.; Lee, Byeongdu Chemical Reviews, Vol. 116, Issue 18 https://doi.org/10.1021/acs.chemrev.5b00690	journal	April 2016
Spatiotemporal Study of Iron Oxide Nanoparticle Monolayer Formation at Liquid/Liquid Interfaces by Using In Situ Small-Angle X-ray Scattering Hu, Jiayang; Spotte-Smith, Evan W. C.; Pan, Brady The Journal of Physical Chemistry C, Vol. 124, Issue 43 https://doi.org/10.1021/acs.jpcc.0c07024	journal	September 2020
Relaxation and Aging of Nanosphere Assemblies at a Water–Oil Interface Kim, Paul Y.; Fink, Zachary; Zhang, Qingteng ACS Nano, Vol. 16, Issue 6 https://doi.org/10.1021/acsnano.2c00020	journal	June 2022
Magnetic assembly of colloidal superstructures with multipole symmetry Erb, Randall M.; Son, Hui S.; Samanta, Bappaditya Nature, Vol. 457, Issue 7232 https://doi.org/10.1038/nature07766	journal	February 2009
Self-assembly of nanoparticles at interfaces Böker, Alexander; He, Jinbo; Emrick, Todd Soft Matter, Vol. 3, Issue 10 https://doi.org/10.1039/b706609k	journal	January 2007
On the Universal Scaling Behavior of the Distance Decay of Plasmon Coupling in Metal Nanoparticle Pairs: A Plasmon Ruler Equation Jain, Prashant K.; Huang, Wenyu; El-Sayed, Mostafa A. Nano Letters, Vol. 7, Issue 7 https://doi.org/10.1021/nl071008a	journal	July 2007
Self‐Propulsion by Directed Explosive Emulsification Wu, Xuefei; Xue, Han; Bordia, Gautam Advanced Materials https://doi.org/10.1002/adma.202310435	journal	February 2024
Motile behaviour of droplets in lipid systems Babu, Dhanya; Katsonis, Nathalie; Lancia, Federico Nature Reviews Chemistry, Vol. 6, Issue 6 https://doi.org/10.1038/s41570-022-00392-8	journal	May 2022
From dynamic self-assembly to networked chemical systems Grzybowski, Bartosz A.; Fitzner, Krzysztof; Paczesny, Jan Chemical Society Reviews, Vol. 46, Issue 18 https://doi.org/10.1039/C7CS00089H	journal	January 2017
Turkevich Method for Gold Nanoparticle Synthesis Revisited Kimling, J.; Maier, M.; Okenve, B. The Journal of Physical Chemistry B, Vol. 110, Issue 32 https://doi.org/10.1021/jp061667w	journal	August 2006
Experimental Evidence of Enhanced Adsorption Dynamics at Liquid–Liquid Interfaces under an Electric Field Mhatre, Sameer; Simon, Sébastien; Sjöblom, Johan Analytical Chemistry, Vol. 92, Issue 19 https://doi.org/10.1021/acs.analchem.0c01287	journal	September 2020
Nonequilibrium physics in biology Fang, Xiaona; Kruse, Karsten; Lu, Ting Reviews of Modern Physics, Vol. 91, Issue 4 https://doi.org/10.1103/RevModPhys.91.045004	journal	December 2019
Structural Characterization of Nanoparticle-Supported Lipid Bilayer Arrays by Grazing Incidence X-ray and Neutron Scattering Paracini, Nicolò; Gutfreund, Philipp; Welbourn, Rebecca ACS Applied Materials & Interfaces, Vol. 15, Issue 3 https://doi.org/10.1021/acsami.2c18956	journal	January 2023
An ionic surfactant-mediated Langmuir–Blodgett method to construct gold nanoparticle films for surface-enhanced Raman scattering Pienpinijtham, Prompong; Han, Xiao Xia; Ekgasit, Sanong Physical Chemistry Chemical Physics, Vol. 14, Issue 29 https://doi.org/10.1039/c2cp41419h	journal	January 2012
Interfacial liquid-state surface-enhanced Raman spectroscopy Kim, Kihoon; Han, Hye Soo; Choi, Inhee Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3182	journal	July 2013
Assembly of Highly Ordered Nanoparticle Monolayers at a Water/Hexane Interface Park, Yong-Kyun; Yoo, Sang-Hoon; Park, Sungho Langmuir, Vol. 23, Issue 21 https://doi.org/10.1021/la701445a	journal	October 2007

Similar Records

Oversaturating Liquid Interfaces with Nanoparticle-Surfactants

Journal Article · 2024 · Angewandte Chemie (International Edition) · OSTI ID:2429602

Wu, Xuefei; Xue, Han; Fink, Zachary; +4 more

The Assembly and Jamming of Nanoparticle Surfactants at Liquid–Liquid Interfaces

Journal Article · 2022 · Angewandte Chemie (International Edition) · OSTI ID:1841787

Wang, Beibei; Yin, Bangqi; Zhang, Zhao; +5 more

The Assembly and Jamming of Nanoparticle Surfactants at Liquid–Liquid Interfaces

Journal Article · 2022 · Angewandte Chemie · OSTI ID:1842904

Wang, Beibei; Yin, Bangqi; Zhang, Zhao; +5 more

Title: Oversaturating Liquid Interfaces with Nanoparticle‐Surfactants

Citation Formats

References (62)

Similar Records

Related Subjects