Finite Element Modeling of the Phase Change in Thermally-Grown SiO2 in SiC Systems for Gas Turbines

Aguirre, Trevor G.; Lin, Lianshan; Ridley, Mackenzie J.; Kane, Kenneth A.; Pint, Bruce A.

doi:10.1007/s11837-024-06507-4

Title: Finite Element Modeling of the Phase Change in Thermally-Grown SiO₂ in SiC Systems for Gas Turbines

Journal Article · 22 April 2024 · JOM. Journal of the Minerals, Metals & Materials Society

DOI: https://doi.org/10.1007/s11837-024-06507-4 · OSTI ID:2345340

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^[1]; Kane, Kenneth A. ^[2];

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Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Johns Hopkins Univ., Laurel, MD (United States)

The operating lifetimes of SiC-based components in combustion environments are directly linked to the adhesion of the protective environmental barrier coating (EBC) layer. One of the major known failure modes for EBCs is the formation of a thick SiO₂ thermally grown oxide (TGO), which decreases coating adhesion and encourages eventual coating spallation. The effect of the TGO thickness under Yb₂Si₂O₇ EBCs on silicon carbide was investigated using finite element models (FEMs) with various interfacial architectures and SiO₂ TGO thicknesses. Further, the FEMs incorporated a user-defined material to simulate the volume contraction of the TGO during the silica phase transformation from β-cristobalite to α-cristobalite upon cooling from the stress-free state at 1350°C to room temperature. Systems with and without a silicon bond coating intermediary layer were assessed. It was shown that the TGO phase transformation stress (1.6–1.7 GPa) dominated the increase in stress in the TGO and EBC layers. Furthermore, it was found that stress increase in the TGO was independent of TGO thickness and interface geometry. These results indicate that stabilization of the TGO to mitigate the phase transformation could dramatically improve the performance of SiC-base components with EBCs.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 2345340

Journal Information:: JOM. Journal of the Minerals, Metals & Materials Society, Vol. 76; ISSN 1047-4838

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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