DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Effects of silanol defects and Ti site location within Ti-MWW on alkene epoxidation with aqueous hydrogen peroxide

Journal Article · · Applied Catalysis. B, Environmental

Not Available

Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0020224
OSTI ID:
2345274
Journal Information:
Applied Catalysis. B, Environmental, Journal Name: Applied Catalysis. B, Environmental Journal Issue: C Vol. 354; ISSN 0926-3373
Publisher:
ElsevierCopyright Statement
Country of Publication:
Netherlands
Language:
English

References (52)

The Yin and Yang in the Development of Catalytic Processes: Catalysis Research and Reaction Engineering journal February 2015
Solvent Effects during the Oxidation of Olefins and Alcohols with Hydrogen Peroxide on Ti-Beta Catalyst: The Influence of the Hydrophilicity–Hydrophobicity of the Zeolite journal June 1996
A Novel Titanosilicate with MWW Structure: II. Catalytic Properties in the Selective Oxidation of Alkenes journal September 2001
A Fourier-transform infrared spectral study of H-ZSM-5 surface sites and reactivity sequences in methanol conversion journal July 1984
Synthesis of propylene oxide from propylene and hydrogen peroxide catalyzed by titanium silicalite journal May 1991
Catalytic properties of crystalline titanium silicalites III. Ammoximation of cyclohexanone journal October 1991
Characteristics of the poisoning effect of nickel deposited on USY zeolite journal November 1992
Characterization and catalytic activity of titanium containing SSZ-33 and aluminum-free zeolite beta journal August 1996
A novel titanosilicate with MWW structure III. Highly efficient and selective production of glycidol through epoxidation of allyl alcohol with H2O2 journal March 2003
Hydrothermal synthesis of boron-free Ti-MWW with dual structure-directing agents
  • Liu, Na; Liu, Yueming; Xie, Wei
  • From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference, Proceedings of the 15th International Zeolite Conference https://doi.org/10.1016/S0167-2991(07)80877-9
book October 2007
Highly efficient epoxidation of propylene over a novel Ti-MWW catalyst
  • Song, Fen; Liu, Yueming; Wang, Lingling
  • From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference, Proceedings of the 15th International Zeolite Conference https://doi.org/10.1016/S0167-2991(07)80983-9
book October 2007
Pathways of phenol and benzene photooxidation using TiO2 supported on a zeolite journal May 2002
Hydrophobicity enhancement of Ti-MWW catalyst and its improvement in oxidation activity journal August 2015
Enhanced catalytic oxidation performance of F-Ti-MWW through the synergistic effect of anion and cation journal June 2017
Green and efficient epoxidation of propylene with hydrogen peroxide (HPPO process) catalyzed by hollow TS-1 zeolite: A 1.0 kt/a pilot-scale study journal July 2016
In-depth understanding of acid catalysis of solvolysis of propene oxide over titanosilicates and titanosilicate/H2O2 systems journal May 2016
Selective synthesis of propylene oxide through liquid-phase epoxidation of propylene with H2O2 over formed Ti-MWW catalyst journal October 2016
Kinetic and spectroscopic evidence for reaction pathways and intermediates for olefin epoxidation on Nb in *BEA journal April 2017
Transition state stabilization depends on solvent identity, pore size, and hydrophilicity for epoxidations in zeolites journal January 2022
Density functional theory investigations into the structure and spectroscopic properties of the Ti4+ species in Ti-MWW zeolite journal September 2014
Enhanced catalytic performance of trimethylsilylated Ti-MWW zeolites for the liquid-phase epoxidation of propylene with H2O2 journal December 2021
Effect of P modification on the structure and catalytic performance of Ti-MWW zeolite journal May 2022
Effects of Hydrofluoric Acid Concentration on the Density of Silanol Groups and Water Adsorption in Hydrothermally Synthesized Transition-Metal-Substituted Silicalite-1 journal August 2020
Catalytic Consequences of Oxidant, Alkene, and Pore Structures on Alkene Epoxidations within Titanium Silicates journal August 2020
Alkene Epoxidations with H 2 O 2 over Groups 4–6 Metal-Substituted BEA Zeolites: Reactive Intermediates, Reaction Pathways, and Linear Free-Energy Relationships journal December 2020
MWW and MFI Frameworks as Model Layered Zeolites: Structures, Transformations, Properties, and Activity journal February 2021
Effect of Interactions between Alkyl Chains and Solvent Structures on Lewis Acid Catalyzed Epoxidations journal October 2022
Effects of Solvent–Pore Interaction on Rates and Barriers for Vapor Phase Alkene Epoxidation with Gaseous H2O2 in Ti-BEA Catalysts journal April 2023
Solvent Mediated Interactions on Alkene Epoxidations in Ti-MFI: Effects of Solvent Identity and Silanol Density journal June 2023
Consequences of Confinement for Alkene Epoxidation with Hydrogen Peroxide on Highly Dispersed Group 4 and 5 Metal Oxide Catalysts journal February 2018
Synthesis of Expanded Titanosilicate MWW-Related Materials from a Pure Silica Precursor journal November 2012
Chemical and Technical Aspects of Propene Oxide Production via Hydrogen Peroxide (HPPO Process) journal January 2013
Ordered Hydrogen-Bonded Alcohol Networks Confined in Lewis Acid Zeolites Accelerate Transfer Hydrogenation Turnover Rates journal October 2020
Dominant Role of Entropy in Stabilizing Sugar Isomerization Transition States within Hydrophobic Zeolite Pores journal September 2018
Cooperative Effects between Hydrophilic Pores and Solvents: Catalytic Consequences of Hydrogen Bonding on Alkene Epoxidation in Zeolites journal January 2019
Dynamic Reorganization and Confinement of Ti IV Active Sites Controls Olefin Epoxidation Catalysis on Two-Dimensional Zeotypes journal April 2019
A Novel Titanosilicate with MWW Structure. I. Hydrothermal Synthesis, Elimination of Extraframework Titanium, and Characterizations journal April 2001
Improving the Hydrophobicity and Oxidation Activity of Ti−MWW by Reversible Structural Rearrangement journal March 2008
Direct Synthesis and Characterization of Hydrophobic Aluminum-Free Ti−Beta Zeolite journal January 1998
Two new three-dimensional twelve-ring zeolite frameworks of which zeolite beta is a disordered intergrowth journal March 1988
Efficient epoxidation over dinuclear sites in titanium silicalite-1 journal October 2020
The shape of water in zeolites and its impact on epoxidation catalysis journal September 2021
Novel surfactant-free route to delaminated all-silica and titanosilicate zeolites derived from a layered borosilicate MWW precursor journal January 2014
Heteroatom substituted zeolite FAU with ultralow Al contents for liquid-phase oxidation catalysis journal January 2020
Highly selective 1-pentene epoxidation over Ti-MWW with modified microenvironment of Ti active sites journal January 2020
Influence of solvent structure and hydrogen bonding on catalysis at solid–liquid interfaces journal January 2021
Engineering intraporous solvent environments: effects of aqueous-organic solvent mixtures on competition between zeolite-catalyzed epoxidation and H2O2 decomposition pathways journal January 2023
Computational characterization of zeolite porous networks: an automated approach journal January 2011
Fluorine-planted titanosilicate with enhanced catalytic activity in alkene epoxidation with hydrogen peroxide journal January 2012
Post-synthesis, characterization and catalytic properties of fluorine-planted MWW-type titanosilicate journal January 2013
Post-synthetic preparation of Sn-, Ti- and Zr-beta: a facile route to water tolerant, highly active Lewis acidic zeolites journal January 2014
Evaluation of Ti Distribution in Zeolite Framework Based on the Catalytic Activity for Alkene Epoxidation journal September 2019