Production of chitosan-based composite film reinforced with lignin-rich lignocellulose nanofibers from rice husk

Kang, Hye Jee; Lee, Yeon Ju; Lee, Jin Kyoung; Nurika, Irnia; Suhartini, Sri; Choe, Deokyeong; Kim, Dong Hyun; Choi, Hoon; Murphy, Natasha P.; Kim, Ho Yong; Jung, Young Hoon

doi:10.1016/j.jobab.2024.03.002

Title: Production of chitosan-based composite film reinforced with lignin-rich lignocellulose nanofibers from rice husk

Journal Article · 15 March 2024 · Journal of Bioresources and Bioproducts (Online)

DOI: https://doi.org/10.1016/j.jobab.2024.03.002 · OSTI ID:2344973

Kang, Hye Jee ^[1]; Lee, Yeon Ju ^[1]; Lee, Jin Kyoung ^[2]; Nurika, Irnia ^[3]; Suhartini, Sri ^[3]; Choe, Deokyeong ^[1]; Kim, Dong Hyun ^[1]; Choi, Hoon ^[4]; Murphy, Natasha P. ^[4]; Kim, Ho Yong ^[5]; Jung, Young Hoon ^[1]

Kyungpook National Univ., Daegu (Korea, Republic of)
CPR S&T Co., Ltd., Gunpo (Korea, Republic of)
Univ. Brawijaya, Malang (Indonesia)
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Korea Research Institute of Chemical Technology (KRICT), Daejeon (Korea, Republic of)

Lignocellulosic nanofibers (LCNFs), implying lignin-containing cellulose fibers, maintain the properties of both lignin and cellulose, which are hydrophobic and hydrophilic, respectively. The presence of hydrophobic lignin in LCNFs is expected to be an economical and attractive option that can improve the thermal and mechanical properties of polymers. Thus, this study was conducted to produce lignin-rich LCNFs from sugar-rich waste obtained from rice husks after acidic pretreatment. The LCNFs were produced from the lignin-rich solid fractions obtained after pretreatment and enzymatic hydrolysis, which were then incorporated as an additive into a chitosan-based film. The variations in lignin content in the range of approximately 50.6%-66.8% in differently obtained LCNFs gave significantly different optical strengths and mechanical properties. These controllable processes may allow for customized film formation. Additionally, the glucose-rich liquid fractions obtained after pretreatment and enzymatic hydrolysis were used as a substrate for ethanol fermentation to achieve total utilization of rice husk biomass waste. In conclusion, the lignin-rich biomass fraction holds promise as a suitable material for chitosan-LCNF film and has the potential to increase the economic feasibility of the biomaterial industry.

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Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE; National Research Foundation of Korea (NRF)

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 2344973

Report Number(s):: NREL/JA--2800-89759; MainId:90538; UUID:936ee365-ef3d-450f-aff7-35b671f6acfd; MainAdminId:72502

Journal Information:: Journal of Bioresources and Bioproducts (Online), Journal Name: Journal of Bioresources and Bioproducts (Online) Journal Issue: 2 Vol. 9; ISSN 2369-9698

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
60 APPLIED LIFE SCIENCES
chitosan film
lignin-based material
lignocellulose nanofiber
rice husk
upcycling

Title: Production of chitosan-based composite film reinforced with lignin-rich lignocellulose nanofibers from rice husk

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