Archeological wood conservation with selected organosilicon compounds studied by XFM and nanoindentation

Broda, Magdalena; Jakes, Joseph E.; Li, Luxi; Antipova, Olga A.

doi:10.1007/s00226-023-01503-4

Title: Archeological wood conservation with selected organosilicon compounds studied by XFM and nanoindentation

Journal Article · 10 October 2023 · Wood Science and Technology

DOI: https://doi.org/10.1007/s00226-023-01503-4 · OSTI ID:2342078

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Poznan University of Life Sciences (Poland)
USDA Forest Service, Madison, WI (United States). Forest Products Laboratory
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Waterlogged wood conservation is a complex and challenging task. Detailed knowledge about the interactions between the applied chemicals and wood is necessary to ensure the effective and safe conservation of wooden artifacts. The present research aims to determine the mechanism of dimensional stabilization of archeological wood by organosilicon compounds using the combination of synchrotron-based X-ray fluorescence microscopy (XFM) and nanoindentation. Archeological oak wood was treated with methyltrimethoxysilane, (3-mercaptopropyl)trimethoxysilane, or 1,3-bis-[(diethylamino)-3-(propoxy)propan-2-ol]-1,1,3,3-tetramethyldisiloxane, which in previous studies were found to be more effective than other organosilicons in stabilizing wood dimensions. The XFM and nanoindentation results showed that all three organosilicons infiltrated wood cell walls and enhanced their mechanical properties. The XFM also showed that part of the chemicals filled some void spaces like cell lumina. Based on the results obtained here and in our previous research, it is determined that the mechanism of archeological wood dimensional stabilization by organosilicon treatment is complex and likely involves both filling cell lumina and infiltration into cell walls where organosilicons interact with wood polymers.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 2342078

Journal Information:: Wood Science and Technology, Journal Name: Wood Science and Technology Journal Issue: 6 Vol. 57; ISSN 0043-7719

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

References (74)

Longitudinal hardness and Young's modulus of spruce tracheid secondary walls using nanoindentation technique Wimmer, R.; Lucas, B. N.; Oliver, W. C. Wood Science and Technology, Vol. 31, Issue 2 https://doi.org/10.1007/BF00705928	journal	April 1997
Improvement of wood material properties via in situ polymerization of styrene into tosylated cell walls Ermeydan, Mahmut A.; Cabane, Etienne; Gierlinger, Notburga RSC Advances, Vol. 4, Issue 25 https://doi.org/10.1039/C4RA00741G	journal	January 2014
Study on the impregnation of archaeological waterlogged wood with consolidation treatments using synchrotron radiation microtomography Bugani, S.; Modugno, F.; Łucejko, J. J. Analytical and Bioanalytical Chemistry, Vol. 395, Issue 7 https://doi.org/10.1007/s00216-009-3101-5	journal	September 2009
X-Ray Interactions: Photoabsorption, Scattering, Transmission, and Reflection at E = 50-30,000 eV, Z = 1-92 Henke, B. L.; Gullikson, E. M.; Davis, J. C. Atomic Data and Nuclear Data Tables, Vol. 54, Issue 2, p. 181-342 https://doi.org/10.1006/adnd.1993.1013	journal	July 1993
Measurement of moisture-dependent ion diffusion constants in wood cell wall layers using time-lapse micro X-ray fluorescence microscopy Jakes, Joseph E.; Zelinka, Samuel L.; Hunt, Christopher G. Scientific Reports, Vol. 10, Issue 1 https://doi.org/10.1038/s41598-020-66916-8	journal	June 2020
Evaluation of chemical treatments on dimensional stabilization of archeological waterlogged hardwoods obtained from the Thang Long Imperial Citadel site, Vietnam Nguyen, Thanh Duc; Kohdzuma, Yohsei; Endo, Rie Journal of Wood Science, Vol. 64, Issue 4 https://doi.org/10.1007/s10086-018-1719-7	journal	April 2018
In situ polymerisation of isoeugenol as a green consolidation method for waterlogged archaeological wood McHale, Emily; Steindal, Calin C.; Kutzke, Hartmut Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/srep46481	journal	April 2017
Dimensional stabilization of flakeboard by chemical modification Rowell, R. M.; Tillman, A. -M.; Zhengtian, Liu Wood Science and Technology, Vol. 20, Issue 1 https://doi.org/10.1007/BF00350696	journal	January 1986
Best Practices for Quasistatic Berkovich Nanoindentation of Wood Cell Walls Jakes, Joseph E.; Stone, Donald S. Forests, Vol. 12, Issue 12 https://doi.org/10.3390/f12121696	journal	December 2021
Bio-based consolidants for waterlogged archaeological wood: Assessment of the performance and optimization of the diagnostic protocol Papacchini, Alessandra; Dominici, Simona; Di Giulio, Giuseppina Journal of Cultural Heritage, Vol. 40 https://doi.org/10.1016/j.culher.2019.05.009	journal	November 2019
The Bremen Cog of 1380 – An electron microscopic study of its degraded wood before and after stabilization with PEG Hoffmann, P.; Singh, A.; Kim, Y. S. Holzforschung, Vol. 58, Issue 3 https://doi.org/10.1515/HF.2004.033	journal	May 2004
Study of Fe(II) sulphides in waterlogged archaeological wood Rémazeilles, Céline; Tran, Khoi; Guilminot, Elodie Studies in Conservation, Vol. 58, Issue 4 https://doi.org/10.1179/2047058412Y.0000000071	journal	October 2013
Dynamic mechanical analysis (DMA) of waterlogged archaeological wood at room temperature Pizzo, Benedetto; Pecoraro, Elisa; Lazzeri, Simona Holzforschung, Vol. 72, Issue 5 https://doi.org/10.1515/hf-2017-0114	journal	April 2018
Comparison of Contemporary Elm (Ulmus spp.) and Degraded Archaeological Elm: The Use of Dynamic Mechanical Analysis Under Ambient Moisture Conditions Spear, Morwenna J.; Broda, Magdalena Materials, Vol. 13, Issue 21 https://doi.org/10.3390/ma13215026	journal	November 2020
Scanning Electron Microscopy Protocol for Studying Anatomy of Highly Degraded Waterlogged Archaeological Wood Balzano, Angela; Merela, Maks; Čufar, Katarina Forests, Vol. 13, Issue 2 https://doi.org/10.3390/f13020161	journal	January 2022
Determination of the content of selected elements in medieval waterlogged oak wood from the Lednica Lake—a case study Broda, Magdalena; Frankowski, Marcin Environmental Science and Pollution Research, Vol. 24, Issue 29 https://doi.org/10.1007/s11356-017-9972-7	journal	August 2017
Sulfur and iron speciation in recently recovered timbers of the Mary Rose revealed via X-ray absorption spectroscopy Wetherall, K. M.; Moss, R. M.; Jones, A. M. Journal of Archaeological Science, Vol. 35, Issue 5 https://doi.org/10.1016/j.jas.2007.09.007	journal	May 2008
Characterization of model samples simulating degradation processes induced by iron and sulfur species on waterlogged wood Monachon, Mathilde; Albelda-Berenguer, Magdalena; Pelé, Charlène Microchemical Journal, Vol. 155 https://doi.org/10.1016/j.microc.2020.104756	journal	June 2020
Conservation process of archaeological waterlogged wood studied by spectroscopy and gradient NMR methods Kowalczuk, Joanna; Rachocki, Adam; Broda, Magdalena Wood Science and Technology, Vol. 53, Issue 6 https://doi.org/10.1007/s00226-019-01129-5	journal	October 2019
Durability of model degraded wood treated with organosilicon compounds against fungal decay Broda, Magdalena; Plaza, Nayomi Z. International Biodeterioration & Biodegradation, Vol. 178 https://doi.org/10.1016/j.ibiod.2022.105562	journal	March 2023
Polysaccharide degradation in waterlogged oak wood from the ancient warship Vasa Lindfors, Eva-Lisa; Lindström, Mikael; Iversen, Tommy Holzforschung, Vol. 62, Issue 1 https://doi.org/10.1515/HF.2008.008	journal	January 2008
MAPS : A set of software tools for analysis and visualization of 3D X-ray fluorescence data sets Vogt, S. Journal de Physique IV (Proceedings), Vol. 104 https://doi.org/10.1051/jp4:20030160	journal	March 2003
X-ray methods to observe and quantify adhesive penetration into wood Jakes, Joseph E.; Frihart, Charles R.; Hunt, Christopher G. Journal of Materials Science, Vol. 54, Issue 1 https://doi.org/10.1007/s10853-018-2783-5	journal	August 2018
Organosilicon compounds with various active groups as consolidants for the preservation of waterlogged archaeological wood Broda, Magdalena; Mazela, Bartłomiej; Dutkiewicz, Agnieszka Journal of Cultural Heritage, Vol. 35 https://doi.org/10.1016/j.culher.2018.06.006	journal	January 2019
Kinetics of the hydrolysis and condensation of organofunctional alkoxysilanes: a review Osterholtz, F. D.; Pohl, E. R. Journal of Adhesion Science and Technology, Vol. 6, Issue 1 https://doi.org/10.1163/156856192X00106	journal	January 1992
X-ray fluorescence microprobe imaging in biology and medicine Paunesku, Tatjana; Vogt, Stefan; Maser, Jörg Journal of Cellular Biochemistry, Vol. 99, Issue 6 https://doi.org/10.1002/jcb.21047	journal	January 2006
Synthesis and characterisation of lignin-like oligomers as a bio-inspired consolidant for waterlogged archaeological wood McHale, Emily; Braovac, Susan; Steindal, Calin C. Pure and Applied Chemistry, Vol. 88, Issue 10-11 https://doi.org/10.1515/pac-2016-0814	journal	November 2016
The removal of iron from waterlogged archaeological wood: efficacy and effects on the room temperature wood properties Pecoraro, Elisa; Pelé-Meziani, Charlène; Macchioni, Nicola Wood Material Science & Engineering, Vol. 18, Issue 2 https://doi.org/10.1080/17480272.2022.2061870	journal	April 2022
Methyltrimethoxysilane as a stabilising agent for archaeological waterlogged wood differing in the degree of degradation Broda, Magdalena; Mazela, Bartłomiej; Radka, Krzysztof Journal of Cultural Heritage, Vol. 35 https://doi.org/10.1016/j.culher.2018.06.004	journal	January 2019
Fiji: an open-source platform for biological-image analysis Schindelin, Johannes; Arganda-Carreras, Ignacio; Frise, Erwin Nature Methods, Vol. 9, Issue 7 https://doi.org/10.1038/nmeth.2019	journal	June 2012
The sorption of water vapour by anhydride modified softwood Papadopoulos, A. N.; Hill, C. A. S. Wood Science and Technology, Vol. 37, Issue 3-4 https://doi.org/10.1007/s00226-003-0192-6	journal	December 2003
The Viscoelastic Behaviour of Waterlogged Archaeological Wood Treated with Methyltrimethoxysilane Broda, Magdalena; Spear, Morwenna J.; Curling, Simon F. Materials, Vol. 14, Issue 18 https://doi.org/10.3390/ma14185150	journal	September 2021
Thermoporometry of waterlogged archaeological wood: Insights into the change of pore traits after the water-removal by supercritical drying Guo, Juan; Chen, Jiabao; Li, Ren Thermochimica Acta, Vol. 715 https://doi.org/10.1016/j.tca.2022.179297	journal	September 2022
Deterioration of the cell wall in waterlogged wooden archeological artifacts, 2400 years old Guo, Juan; Xiao, Lin; Han, Liuyang IAWA Journal, Vol. 40, Issue 4 https://doi.org/10.1163/22941932-40190241	journal	November 2019
Relations of density, polyethylene glycol treatment and moisture content with stiffness properties of Vasa oak samples Vorobyev, Alexey; Almkvist, Gunnar; van Dijk, Nico P. Holzforschung, Vol. 71, Issue 4 https://doi.org/10.1515/hf-2016-0202	journal	February 2017
Improved methods for nanoindentation Berkovich probe calibrations using fused silica Jakes, Joseph E. Journal of Materials Science, Vol. 53, Issue 7 https://doi.org/10.1007/s10853-017-1922-8	journal	December 2017
Even Visually Intact Cell Walls in Waterlogged Archaeological Wood Are Chemically Deteriorated and Mechanically Fragile: A Case of a 170 Year-Old Shipwreck Han, Liuyang; Tian, Xingling; Keplinger, Tobias Molecules, Vol. 25, Issue 5 https://doi.org/10.3390/molecules25051113	journal	March 2020
Biological effectiveness of archaeological oak wood treated with methyltrimethoxysilane and PEG against Brown-rot fungi and moulds Broda, Magdalena International Biodeterioration & Biodegradation, Vol. 134 https://doi.org/10.1016/j.ibiod.2018.09.001	journal	October 2018
The modification of wood by treatment with low molecular weight phenol-formaldehyde resin: a properties enhancement with neutralized phenolic-resin and resin penetration into wood cell walls Kajita, H.; Furuno, T.; Imamura, Y. Wood Science and Technology, Vol. 37, Issue 5 https://doi.org/10.1007/s00226-003-0176-6	journal	March 2004
Raman Spectroscopic Investigation of Iron-Tannin Precipitates in Waterlogged Archaeological Oak Henrik-Klemens, Åke; Bengtsson, Felicia; Björdal, Charlotte G. Studies in Conservation, Vol. 67, Issue 4 https://doi.org/10.1080/00393630.2020.1864895	journal	January 2021
Sulfur and iron accumulation in three marine-archaeological shipwrecks in the Baltic Sea: The Ghost, the Crown and the Sword Fors, Yvonne; Grudd, Håkan; Rindby, Anders Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep04222	journal	February 2014
Cellulose and Lignin Nano-Scale Consolidants for Waterlogged Archaeological Wood Antonelli, Federica; Galotta, Giulia; Sidoti, Giancarlo Frontiers in Chemistry, Vol. 8 https://doi.org/10.3389/fchem.2020.00032	journal	January 2020
Flavonoid Insertion into Cell Walls Improves Wood Properties Ermeydan, Mahmut A.; Cabane, Etienne; Masic, Admir ACS Applied Materials & Interfaces, Vol. 4, Issue 11 https://doi.org/10.1021/am301266k	journal	October 2012
Pickering Emulsions Based on Wax and Halloysite Nanotubes: An Ecofriendly Protocol for the Treatment of Archeological Woods Lisuzzo, Lorenzo; Hueckel, Theodore; Cavallaro, Giuseppe ACS Applied Materials & Interfaces, Vol. 13, Issue 1 https://doi.org/10.1021/acsami.0c20443	journal	December 2020
Sulphur in the environment: A review Brown, Keith A. Environmental Pollution Series B, Chemical and Physical, Vol. 3, Issue 1 https://doi.org/10.1016/0143-148X(82)90042-8	journal	January 1982
The ecology and biotechnology of sulphate-reducing bacteria Muyzer, Gerard; Stams, Alfons J. M. Nature Reviews Microbiology, Vol. 6, Issue 6 https://doi.org/10.1038/nrmicro1892	journal	May 2008
Hardness and elastic modulus of TiN based on continuous indentation technique and new correlation Stone, D. S.; Yoder, K. B.; Sproul, W. D. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 9, Issue 4 https://doi.org/10.1116/1.577270	journal	July 1991
Organosilicons of different molecular size and chemical structure as consolidants for waterlogged archaeological wood – a new reversible and retreatable method Broda, Magdalena; Dąbek, Izabela; Dutkiewicz, Agnieszka Scientific Reports, Vol. 10, Issue 1 https://doi.org/10.1038/s41598-020-59240-8	journal	February 2020
Morphological Study of Bio-Based Polymers in the Consolidation of Waterlogged Wooden Objects Walsh-Korb, Zarah; Stelzner, Ingrid; dos Santos Gabriel, Juliana Materials, Vol. 15, Issue 2 https://doi.org/10.3390/ma15020681	journal	January 2022
A versatile strategy for grafting polymers to wood cell walls Keplinger, T.; Cabane, E.; Chanana, M. Acta Biomaterialia, Vol. 11 https://doi.org/10.1016/j.actbio.2014.09.016	journal	January 2015
Treatment of Waterlogged Archaeological wood Using Chitosan- and Modified Chitosan Solutions. part 1: Chemical Compatibility and Microstructure Christensen, Mikkel; Larnøy, Erik; Kutzke, Hartmut Journal of the American Institute for Conservation, Vol. 54, Issue 1 https://doi.org/10.1179/1945233014Y.0000000034	journal	February 2015
Effects of Biological and Chemical Degradation on the Properties of Scots Pine—Part II: Wood-Moisture Relations and Viscoelastic Behaviour Broda, Magdalena; Spear, Morwenna J.; Curling, Simon F. Forests, Vol. 13, Issue 9 https://doi.org/10.3390/f13091390	journal	August 2022
Effect of methyltrimethoxysilane impregnation on the cell wall porosity and water vapour sorption of archaeological waterlogged oak Broda, Magdalena; Curling, Simon F.; Spear, Morwenna J. Wood Science and Technology, Vol. 53, Issue 3 https://doi.org/10.1007/s00226-019-01095-y	journal	May 2019
Interactions between Different Organosilicons and Archaeological Waterlogged Wood Evaluated by Infrared Spectroscopy Popescu, Carmen-Mihaela; Broda, Magdalena Forests, Vol. 12, Issue 3 https://doi.org/10.3390/f12030268	journal	February 2021
Conservation of Waterlogged Wood—Past, Present and Future Perspectives Broda, Magdalena; Hill, Callum A. S. Forests, Vol. 12, Issue 9 https://doi.org/10.3390/f12091193	journal	September 2021
High retreatability and dimensional stability of polymer grafted waterlogged archaeological wood achieved by ARGET ATRP Zhou, Yihang; Wang, Kai; Hu, Dongbo Scientific Reports, Vol. 9, Issue 1 https://doi.org/10.1038/s41598-019-46366-7	journal	July 2019
Halloysite nanotubes/pluronic nanocomposites for waterlogged archeological wood: thermal stability and X-ray microtomography Parisi, Filippo; Bernardini, Federico; Cavallaro, Giuseppe Journal of Thermal Analysis and Calorimetry, Vol. 141, Issue 3 https://doi.org/10.1007/s10973-020-09637-4	journal	April 2020
Conservation of waterlogged archaeological wood Kaye, Barry Chemical Society Reviews, Vol. 24, Issue 1 https://doi.org/10.1039/CS9952400035	journal	January 1995
Correlation between sulfur accumulation and microbial wood degradation on shipwreck timbers Björdal, Charlotte Gjelstrup; Fors, Yvonne International Biodeterioration & Biodegradation, Vol. 140 https://doi.org/10.1016/j.ibiod.2019.03.010	journal	May 2019
Multi-analysis of chemical transformations of lignin macromolecules from waterlogged archaeological wood Xia, Yan; Chen, Tian-Ying; Wen, Jia-Long International Journal of Biological Macromolecules, Vol. 109 https://doi.org/10.1016/j.ijbiomac.2017.12.114	journal	April 2018
New trials in the consolidation of waterlogged archaeological wood with different acetone-carried products Giachi, Gianna; Capretti, Chiara; Donato, Ines D. Journal of Archaeological Science, Vol. 38, Issue 11 https://doi.org/10.1016/j.jas.2011.06.012	journal	November 2011
Structure of oak wood from the Swedish warship Vasa revealed by X-ray scattering and microtomography Svedström, Kirsi; Bjurhager, Ingela; Kallonen, Aki Holzforschung, Vol. 66, Issue 3 https://doi.org/10.1515/hf.2011.157	journal	March 2012
Reactivity of Waterlogged Archeological Elm Wood with Organosilicon Compounds Applied as Wood Consolidants: 2D 1H–13C Solution-State NMR Studies Broda, Magdalena; Yelle, Daniel J. Molecules, Vol. 27, Issue 11 https://doi.org/10.3390/molecules27113407	journal	May 2022
Aminoethyl substitution enhances the self-assembly properties of an aminocellulose as a potential archaeological wood consolidant Wakefield, Jennifer M. K.; Hampe, Robert; Gillis, Richard B. European Biophysics Journal, Vol. 49, Issue 8 https://doi.org/10.1007/s00249-020-01451-y	journal	August 2020
Nanoindentation near the edge Jakes, J. E.; Frihart, C. R.; Beecher, J. F. Journal of Materials Research, Vol. 24, Issue 3 https://doi.org/10.1557/jmr.2009.0076	journal	March 2009
Long-term alteration processes of iron fasteners extracted from archaeological shipwrecks aged in biologically active waterlogged media Rémazeilles, Céline; Lévêque, François; Conforto, Egle Corrosion Science, Vol. 181 https://doi.org/10.1016/j.corsci.2020.109231	journal	April 2021
Natural decay of archaeological oak wood versus artificial degradation processes — An FT-IR spectroscopy and X-ray diffraction study Broda, Magdalena; Popescu, Carmen-Mihaela Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 209 https://doi.org/10.1016/j.saa.2018.10.057	journal	February 2019
Fossilization, permineralization, coalification, carbonization and wet wood conservation Schweingruber, Fritz H.; Börner, Annett The Plant Stem https://doi.org/10.1007/978-3-319-73524-5_13	book	January 2018
Contribution of magnetic measurement methods to the analysis of iron sulfides in archaeological waterlogged wood‑iron assemblies Rémazeilles, Céline; Lévêque, François; Conforto, Egle Microchemical Journal, Vol. 148 https://doi.org/10.1016/j.microc.2019.04.062	journal	July 2019
Synchrotron-based X-ray Fluorescence Microscopy in Conjunction with Nanoindentation to Study Molecular-Scale Interactions of Phenol–Formaldehyde in Wood Cell Walls Jakes, Joseph E.; Hunt, Christopher G.; Yelle, Daniel J. ACS Applied Materials & Interfaces, Vol. 7, Issue 12 https://doi.org/10.1021/am5087598	journal	March 2015
Nanocomposites based on esterified colophony and halloysite clay nanotubes as consolidants for waterlogged archaeological woods Cavallaro, Giuseppe; Lazzara, Giuseppe; Milioto, Stefana Cellulose, Vol. 24, Issue 8 https://doi.org/10.1007/s10570-017-1369-8	journal	June 2017
Experimental method to account for structural compliance in nanoindentation measurements Jakes, J. E.; Frihart, C. R.; Beecher, J. F. Journal of Materials Research, Vol. 23, Issue 4 https://doi.org/10.1557/jmr.2008.0131	journal	April 2008
Sulfur and iron in shipwrecks cause conservation concerns Fors, Yvonne; Sandström, Magnus Chemical Society Reviews, Vol. 35, Issue 5 https://doi.org/10.1039/B507010B	journal	January 2006
Synchrotron-based X-ray fluorescence microscopy enables multiscale spatial visualization of ions involved in fungal lignocellulose deconstruction Kirker, Grant; Zelinka, Sam; Gleber, Sophie-Charlotte Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/srep41798	journal	January 2017

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