Bio-based lactone acrylic plastics with performance and recyclability advantages

Gilsdorf, Reid A.; Chokkapu, Eswara Rao; Athaley, Abhay; Uekert, Taylor; Gowda, Ravikumar R.; Singh, Avantika; DesVeaux, Jason S.; Beckham, Gregg T.; Chen, Eugene Y. -X.

doi:10.1016/j.xcrp.2024.101938

Title: Bio-based lactone acrylic plastics with performance and recyclability advantages

Journal Article · 30 April 2024 · Cell Reports Physical Science

DOI: https://doi.org/10.1016/j.xcrp.2024.101938 · OSTI ID:2341660

Gilsdorf, Reid A.; Chokkapu, Eswara Rao; Athaley, Abhay; Uekert, Taylor; Gowda, Ravikumar R.; Singh, Avantika; DesVeaux, Jason S.; Beckham, Gregg T.;

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Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

OSTI ID:: 2341660

Alternate ID(s):: OSTI ID: 2367308

Journal Information:: Cell Reports Physical Science, Journal Name: Cell Reports Physical Science Journal Issue: 5 Vol. 5; ISSN 2666-3864

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (44)

Conversion of Furfural to 1,5-Pentanediol: Process Synthesis and Analysis Huang, Kefeng; Brentzel, Zachary J.; Barnett, Kevin J. ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 6 https://doi.org/10.1021/acssuschemeng.7b00059	journal	May 2017
Fast Bulk Depolymerization of Polymethacrylates by ATRP De Luca Bossa, Ferdinando; Yilmaz, Gorkem; Matyjaszewski, Krzysztof ACS Macro Letters, Vol. 12, Issue 8 https://doi.org/10.1021/acsmacrolett.3c00389	journal	August 2023
Sustainable production of γ-valerolactone and δ-valerolactone through the coupling of hydrogenation and dehydrogenation Wang, Hongxing; Ding, Guoqiang; Li, Xianqing Sustainable Energy & Fuels, Vol. 5, Issue 4 https://doi.org/10.1039/D0SE01776K	journal	January 2021
Alternate Biobased Route To Produce δ-Decalactone: Elucidating the Role of Solvent and Hydrogen Evolution in Catalytic Transfer Hydrogenation Alam, Md. Imteyaz; Khan, Tuhin S.; Haider, M. Ali ACS Sustainable Chemistry & Engineering, Vol. 7, Issue 3 https://doi.org/10.1021/acssuschemeng.8b05014	journal	December 2018
Polymerization of sterically congested ?-alkylacrylates under high pressure Rzayev, Javid; Penelle, Jacques Journal of Polymer Science Part A: Polymer Chemistry, Vol. 40, Issue 7 https://doi.org/10.1002/pola.10161	journal	February 2002
Bulk depolymerization of poly(methyl methacrylate) via chain-end initiation for catalyst-free reversion to monomer Young, James B.; Hughes, Rhys W.; Tamura, Ariana M. Chem, Vol. 9, Issue 9 https://doi.org/10.1016/j.chempr.2023.07.004	journal	September 2023
Upgrading of Biobased Lactones with Dialkylcarbonates Caretto, Alessio; Noè, Marco; Selva, Maurizio ACS Sustainable Chemistry & Engineering, Vol. 2, Issue 9 https://doi.org/10.1021/sc500323a	journal	July 2014
Closed-loop recyclable plastics from poly(ethyl cyanoacrylate) Christy, Allison J.; Phillips, Scott T. Science Advances, Vol. 9, Issue 12 https://doi.org/10.1126/sciadv.adg2295	journal	March 2023
Monomer recovery by pyrolysis of poly(methyl methacrylate) (PMMA) Kaminsky, W.; Franck, J. Journal of Analytical and Applied Pyrolysis, Vol. 19 https://doi.org/10.1016/0165-2370(91)80052-A	journal	July 1991
Reversing RAFT Polymerization: Near-Quantitative Monomer Generation Via a Catalyst-Free Depolymerization Approach Wang, Hyun Suk; Truong, Nghia P.; Pei, Zhipeng Journal of the American Chemical Society, Vol. 144, Issue 10 https://doi.org/10.1021/jacs.2c00963	journal	February 2022
Growing environmental footprint of plastics driven by coal combustion Cabernard, Livia; Pfister, Stephan; Oberschelp, Christopher Nature Sustainability, Vol. 5, Issue 2 https://doi.org/10.1038/s41893-021-00807-2	journal	December 2021
The Critical Role of Process Analysis in Chemical Recycling and Upcycling of Waste Plastics Nicholson, Scott R.; Rorrer, Julie E.; Singh, Avantika Annual Review of Chemical and Biomolecular Engineering, Vol. 13, Issue 1 https://doi.org/10.1146/annurev-chembioeng-100521-085846	journal	March 2022
Plastic futures and their CO2 emissions Stegmann, Paul; Daioglou, Vassilis; Londo, Marc Nature, Vol. 612, Issue 7939 https://doi.org/10.1038/s41586-022-05422-5	journal	December 2022
Controlled radical depolymerization of chlorine-capped PMMA via reversible activation of the terminal group by ruthenium catalyst Sano, Yuki; Konishi, Takahiro; Sawamoto, Mitsuo European Polymer Journal, Vol. 120 https://doi.org/10.1016/j.eurpolymj.2019.08.008	journal	November 2019
Hybrid monomer design for unifying conflicting polymerizability, recyclability, and performance properties Shi, Changxia; Li, Zi-Chen; Caporaso, Lucia Chem, Vol. 7, Issue 3 https://doi.org/10.1016/j.chempr.2021.02.003	journal	March 2021
Hybrid Monomer Design Synergizing Property Trade‐offs in Developing Polymers for Circularity and Performance Shi, Changxia; Reilly, Liam T.; Chen, Eugene Y. ‐X. Angewandte Chemie International Edition, Vol. 62, Issue 31 https://doi.org/10.1002/anie.202301850	journal	May 2023
ReCiPe2016: a harmonised life cycle impact assessment method at midpoint and endpoint level Huijbregts, Mark A. J.; Steinmann, Zoran J. N.; Elshout, Pieter M. F. The International Journal of Life Cycle Assessment, Vol. 22, Issue 2 https://doi.org/10.1007/s11367-016-1246-y	journal	December 2016
Synthesis and homopolymerization kinetics of α-methylene-δ-valerolactone, an exo-methylene cyclic monomer with a nonplanar ring system spanning the radical center Ueda, Mitsuru; Takahashi, Masami; Imai, Yoshio Macromolecules, Vol. 16, Issue 8 https://doi.org/10.1021/ma00242a009	journal	August 1983
Quantification and evaluation of plastic waste in the United States Milbrandt, Anelia; Coney, Kamyria; Badgett, Alex Resources, Conservation and Recycling, Vol. 183 https://doi.org/10.1016/j.resconrec.2022.106363	journal	August 2022
Photoassisted Radical Depolymerization Young, James B.; Bowman, Jared I.; Eades, Cabell B. ACS Macro Letters, Vol. 11, Issue 12 https://doi.org/10.1021/acsmacrolett.2c00603	journal	December 2022
A Review of the Properties and Applications of Poly (Methyl Methacrylate) (PMMA) Ali, Umar; Karim, Khairil Juhanni Bt. Abd; Buang, Nor Aziah Polymer Reviews, Vol. 55, Issue 4 https://doi.org/10.1080/15583724.2015.1031377	journal	June 2015
Chemical and biological catalysis for plastics recycling and upcycling Ellis, Lucas D.; Rorrer, Nicholas A.; Sullivan, Kevin P. Nature Catalysis, Vol. 4, Issue 7 https://doi.org/10.1038/s41929-021-00648-4	journal	July 2021
Feedstock recycling of polymers by pyrolysis in a fluidised bed Kaminsky, W.; Predel, M.; Sadiki, A. Polymer Degradation and Stability, Vol. 85, Issue 3 https://doi.org/10.1016/j.polymdegradstab.2003.05.002	journal	September 2004
Preparation of highly dispersed Cu catalysts from hydrotalcite precursor for the dehydrogenation of 1,4-butanediol Liu, Haolan; Jiang, Yuanyuan; Zhao, Huaiyuan Journal of Industrial and Engineering Chemistry, Vol. 102 https://doi.org/10.1016/j.jiec.2021.07.008	journal	October 2021
High chemical recyclability of vinyl lactone acrylic bioplastics Gilsdorf, Reid A.; Nicki, Matthew A.; Chen, Eugene Y. -X. Polymer Chemistry, Vol. 11, Issue 30 https://doi.org/10.1039/D0PY00786B	journal	January 2020
Bio-based polymers with performance-advantaged properties Cywar, Robin M.; Rorrer, Nicholas A.; Hoyt, Caroline B. Nature Reviews Materials, Vol. 7, Issue 2 https://doi.org/10.1038/s41578-021-00363-3	journal	September 2021
Energy and Material Flows and Carbon Footprint Assessment Concerning the Production of HMF and Furfural from a Cellulosic Biomass Schöppe, Hannes; Kleine-Möllhoff, Peter; Epple, Rolf Processes, Vol. 8, Issue 1 https://doi.org/10.3390/pr8010119	journal	January 2020
Critical advances and future opportunities in upcycling commodity polymers Jehanno, Coralie; Alty, Jill W.; Roosen, Martijn Nature, Vol. 603, Issue 7903 https://doi.org/10.1038/s41586-021-04350-0	journal	March 2022
Revisiting the Anionic Polymerization of Methyl Ethacrylate Kennemur, Justin G.; Bates, Frank S.; Hillmyer, Marc A. Macromolecular Chemistry and Physics, Vol. 219, Issue 1 https://doi.org/10.1002/macp.201700282	journal	September 2017
Depolymerization of Polymethacrylates by Iron ATRP Martinez, Michael R.; Schild, Dirk; De Luca Bossa, Ferdinando Macromolecules, Vol. 55, Issue 23 https://doi.org/10.1021/acs.macromol.2c01712	journal	November 2022
Recyclable cyclic bio-based acrylic polymer via pairwise monomer enchainment by a trifunctional Lewis pair Song, Yanjiao; He, Jianghua; Zhang, Yuetao Nature Chemistry, Vol. 15, Issue 3 https://doi.org/10.1038/s41557-022-01097-7	journal	November 2022
Organocatalytic Conjugate-Addition Polymerization of Linear and Cyclic Acrylic Monomers by N-Heterocyclic Carbenes: Mechanisms of Chain Initiation, Propagation, and Termination Zhang, Yuetao; Schmitt, Meghan; Falivene, Laura Journal of the American Chemical Society, Vol. 135, Issue 47 https://doi.org/10.1021/ja4088677	journal	November 2013
Zinc-Mediated Allylation-Lactonization One-Pot Reaction to Methylene Butyrolactones: Renewable Monomers for Sustainable Acrylic Polymers with Closed-Loop Recyclability Zhang, Zhen-Hua; Wang, Xing; Weng, Biwei ACS Polymers Au, Vol. 2, Issue 4 https://doi.org/10.1021/acspolymersau.2c00001	journal	April 2022
Kinetic and thermodynamic analysis of methyl ethacrylate radical polymerization Penelle, Jacques; Collot, Joseph; Rufflard, Gladys Journal of Polymer Science Part A: Polymer Chemistry, Vol. 31, Issue 9 https://doi.org/10.1002/pola.1993.080310926	journal	August 1993
Reversed Controlled Polymerization (RCP): Depolymerization from Well-Defined Polymers to Monomers Jones, Glen R.; Wang, Hyun Suk; Parkatzidis, Kostas Journal of the American Chemical Society, Vol. 145, Issue 18 https://doi.org/10.1021/jacs.3c00589	journal	May 2023
Manufacturing energy and greenhouse gas emissions associated with plastics consumption Nicholson, Scott R.; Rorrer, Nicholas A.; Carpenter, Alberta C. Joule https://doi.org/10.1016/j.joule.2020.12.027	journal	January 2021
The characterization of recycled PMMA Popescu, Violeta; Vasile, Cornelia; Brebu, Mihai Journal of Alloys and Compounds, Vol. 483, Issue 1-2 https://doi.org/10.1016/j.jallcom.2008.08.148	journal	August 2009
Copper(II) Chloride/Tris(2-pyridylmethyl)amine-Catalyzed Depolymerization of Poly(n-butyl methacrylate) Martinez, Michael R.; De Luca Bossa, Ferdinando; Olszewski, Mateusz Macromolecules, Vol. 55, Issue 1 https://doi.org/10.1021/acs.macromol.1c02246	journal	December 2021
Recycling poly-(methyl methacrylate) by pyrolysis in a conical spouted bed reactor Lopez, Gartzen; Artetxe, Maite; Amutio, Maider Chemical Engineering and Processing: Process Intensification, Vol. 49, Issue 10 https://doi.org/10.1016/j.cep.2010.08.002	journal	October 2010
Design principles for intrinsically circular polymers with tunable properties Shi, Changxia; Reilly, Liam T.; Phani Kumar, V. Sai Chem, Vol. 7, Issue 11 https://doi.org/10.1016/j.chempr.2021.10.004	journal	November 2021
Recyclable Vinyl‐Functionalized Polyesters via Chemoselective Organopolymerization of Bifunctional α‐Methylene‐δ‐Valerolactone Xu, Tie‐Qi; Yu, Zhi‐Qi; Zhang, Xue‐Min Macromolecular Chemistry and Physics, Vol. 220, Issue 12 https://doi.org/10.1002/macp.201900150	journal	May 2019
Improving economics of lignocellulosic biofuels: An integrated strategy for coproducing 1,5-pentanediol and ethanol Huang, Kefeng; Won, Wangyun; Barnett, Kevin J. Applied Energy, Vol. 213 https://doi.org/10.1016/j.apenergy.2017.11.002	journal	March 2018
Production, use, and fate of all plastics ever made Geyer, Roland; Jambeck, Jenna R.; Law, Kara Lavender Science Advances, Vol. 3, Issue 7 https://doi.org/10.1126/sciadv.1700782	journal	July 2017
Bio-based 1,5-Pentanediol as a Replacement for Petroleum-Derived 1,6-Hexanediol for Polyester Polyols, Coatings, and Adhesives Zheng, Lei; McClelland, Daniel J.; Rehmann, Kelsi M. S. ACS Sustainable Chemistry & Engineering, Vol. 10, Issue 18 https://doi.org/10.1021/acssuschemeng.1c08198	journal	April 2022

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