Simulating Discharge Curves of an All-Aqueous TRAB to Identify Pathways for Improving System Performance

Cross, Nicholas R.; Rau, Matthew J.; Gorski, Christopher A.; Logan, Bruce E.; Hall, Derek M.

doi:10.1149/1945-7111/ad3ebb

Title: Simulating Discharge Curves of an All-Aqueous TRAB to Identify Pathways for Improving System Performance

Journal Article · 25 April 2024 · Journal of the Electrochemical Society

DOI: https://doi.org/10.1149/1945-7111/ad3ebb · OSTI ID:2341351

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Thermally regenerative ammonia batteries (TRABs) are an emerging technology that use low temperature heat (T < 150 °C) to recharge a flow battery that produces electrical power on demand. The all-aqueous copper TRAB can provide high power densities and thermal energy efficiencies relative to other devices that harvest energy from waste heat, but its performance is adversely impacted by the crossover of undesired species through the membrane and lower cell voltages compared to conventional batteries. In this work, we developed a numerical model to simulate discharge curves while accounting for crossover inefficiencies without tracking all electrolyte species through the membrane. The model was able to successfully reproduce discharge curves across a diverse range of battery conditions using a single fitting parameter to account for decay of electrode standard potential due to species crossover with minimal error (< 5%). The model was then used to simulate different design scenarios to estimate changes in energy output from alterations to the aspects of the battery electrolyte chemistry. Results from this study are used to identify pathways for improving future TRAB designs with respect to energy capacity and cost-effectiveness of the technology.

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Research Organization:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE; USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC52-07NA27344; FE0032030

OSTI ID:: 2341351

Report Number(s):: LLNL-JRNL-859138

Journal Information:: Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Journal Issue: 4 Vol. 171; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (40)

Electrochemical Methods for Exploiting Low‐Temperature Heat Sources: Challenges in Material Research Brogioli, Doriano; La Mantia, Fabio Advanced Energy Materials, Vol. 12, Issue 22 https://doi.org/10.1002/aenm.202103842	journal	April 2022
Copper(I)-Containing Ionic Liquids for High-Rate Electrodeposition Brooks, Neil R.; Schaltin, Stijn; Van Hecke, Kristof Chemistry - A European Journal, Vol. 17, Issue 18 https://doi.org/10.1002/chem.201003209	journal	March 2011
Enhancing Low-Grade Thermal Energy Recovery in a Thermally Regenerative Ammonia Battery Using Elevated Temperatures Zhang, Fang; LaBarge, Nicole; Yang, Wulin ChemSusChem, Vol. 8, Issue 6 https://doi.org/10.1002/cssc.201403290	journal	February 2015
Waste Heat to Power: Full‐Cycle Analysis of a Thermally Regenerative Flow Battery Engelpracht, Mirko; Kohrn, Markus; Tillmanns, Dominik Energy Technology, Vol. 10, Issue 8 https://doi.org/10.1002/ente.202200152	journal	June 2022
On the regeneration of thermally regenerative ammonia batteries Vicari, Fabrizio; D’Angelo, Adriana; Kouko, Yohan Journal of Applied Electrochemistry, Vol. 48, Issue 12 https://doi.org/10.1007/s10800-018-1240-0	journal	August 2018
Solubilities, densities and electrical conductivities of aqueous copper(I) and copper(II) chlorides in solutions containing other chlorides such as iron, zinc, sodium and hydrogen chlorides Berger, Jean Marc; Winand, René Hydrometallurgy, Vol. 12, Issue 1 https://doi.org/10.1016/0304-386X(84)90048-3	journal	February 1984
A spectrophotometric study of aqueous copper(I)–chloride complexes in LiCl solutions between 100 °C and 250 °C Liu, Weihua; Brugger, Joël; McPhail, D. C. Geochimica et Cosmochimica Acta, Vol. 66, Issue 20, p. 3615-3633 https://doi.org/10.1016/S0016-7037(02)00942-0	journal	October 2002
System efficiency and power assessment of the all-aqueous copper thermally regenerative ammonia battery Cross, Nicholas R.; Rau, Matthew J.; Lvov, Serguei N. Applied Energy, Vol. 339 https://doi.org/10.1016/j.apenergy.2023.120959	journal	June 2023
A techno-economic analysis of a thermally regenerative ammonia-based battery Vazquez-Sanchez, Holkan; Nagaraja, Shashank S.; Cross, Nicholas R. Applied Energy, Vol. 347 https://doi.org/10.1016/j.apenergy.2023.121501	journal	October 2023
Vapor pressure measurement of electrolyte solution and its impact on regeneration process in TRAB Luo, Jielin; Wang, Zeming; Wu, Hao Case Studies in Thermal Engineering, Vol. 36 https://doi.org/10.1016/j.csite.2022.102201	journal	August 2022
Electrochemical study of binary and ternary copper complexes in ammonia-chloride medium Vazquez-Arenas, Jorge; Lazaro, Isabel; Cruz, Roel Electrochimica Acta, Vol. 52, Issue 20 https://doi.org/10.1016/j.electacta.2007.03.062	journal	June 2007
A dynamic performance model for redox-flow batteries involving soluble species Shah, A. A.; Watt-Smith, M. J.; Walsh, F. C. Electrochimica Acta, Vol. 53, Issue 27, p. 8087-8100 https://doi.org/10.1016/j.electacta.2008.05.067	journal	November 2008
The development of an all copper hybrid redox flow battery using deep eutectic solvents Lloyd, David; Vainikka, Tuomas; Kontturi, Kyösti Electrochimica Acta, Vol. 100 https://doi.org/10.1016/j.electacta.2013.03.130	journal	June 2013
Numerical analysis of vanadium crossover effects in all-vanadium redox flow batteries Won, Seongyeon; Oh, Kyeongmin; Ju, Hyunchul Electrochimica Acta, Vol. 177 https://doi.org/10.1016/j.electacta.2015.01.166	journal	September 2015
A non-aqueous all-copper redox flow battery with highly soluble active species Li, Yun; Sniekers, Jeroen; Malaquias, João Electrochimica Acta, Vol. 236 https://doi.org/10.1016/j.electacta.2017.03.039	journal	May 2017
Temperature characteristics of a copper/zinc thermally-regenerative ammonia battery Wang, Weiguang; Huo, Dongxing; Tian, Hua Electrochimica Acta, Vol. 357 https://doi.org/10.1016/j.electacta.2020.136860	journal	October 2020
The impact of fiber arrangement and advective transport in porous electrodes for silver-based thermally regenerated batteries Cross, Nicholas R.; Hall, Derek M.; Lvov, Serguei N. Electrochimica Acta, Vol. 388 https://doi.org/10.1016/j.electacta.2021.138527	journal	August 2021
Hydrocarbon-based membranes cost-effectively manage species transport and increase performance in thermally regenerative batteries Cross, Nicholas R.; Vazquez-Sanchez, Holkan; Rau, Matthew J. Electrochimica Acta, Vol. 467 https://doi.org/10.1016/j.electacta.2023.143090	journal	November 2023
Three-dimensional, transient, nonisothermal model of all-vanadium redox flow batteries Oh, Kyeongmin; Yoo, Haneul; Ko, Johan Energy, Vol. 81 https://doi.org/10.1016/j.energy.2014.05.020	journal	March 2015
Solubility prediction of malachite in aqueous ammoniacal ammonium chloride solutions at 25 °C Wang, Xi; Chen, Qiyuan; Hu, Huiping Hydrometallurgy, Vol. 99, Issue 3-4 https://doi.org/10.1016/j.hydromet.2009.08.011	journal	November 2009
A transient electrochemical model incorporating the Donnan effect for all-vanadium redox flow batteries Lei, Y.; Zhang, B. W.; Bai, B. F. Journal of Power Sources, Vol. 299 https://doi.org/10.1016/j.jpowsour.2015.08.100	journal	December 2015
Electrical power production from low-grade waste heat using a thermally regenerative ethylenediamine battery Rahimi, Mohammad; D'Angelo, Adriana; Gorski, Christopher A. Journal of Power Sources, Vol. 351 https://doi.org/10.1016/j.jpowsour.2017.03.074	journal	May 2017
A numerical model for a thermally-regenerative ammonia-based flow battery using for low grade waste heat recovery Wang, Weiguang; Shu, Gequn; Tian, Hua Journal of Power Sources, Vol. 388 https://doi.org/10.1016/j.jpowsour.2018.03.070	journal	June 2018
Modelling of a bimetallic thermally-regenerative ammonia flow battery for conversion efficiency and performance evaluation Wang, Weiguang; Tian, Hua; Huo, Dongxing Journal of Power Sources, Vol. 499 https://doi.org/10.1016/j.jpowsour.2021.229943	journal	July 2021
Power and energy capacity tradeoffs in an all-aqueous copper thermally regenerative ammonia battery Cross, Nicholas R.; Rau, Matthew J.; Lvov, Serguei N. Journal of Power Sources, Vol. 531 https://doi.org/10.1016/j.jpowsour.2022.231339	journal	May 2022
Prospects of applying ionic liquids and deep eutectic solvents for renewable energy storage by means of redox flow batteries Chakrabarti, Mohammed Harun; Mjalli, Farouq Sabri; AlNashef, Inas Muen Renewable and Sustainable Energy Reviews, Vol. 30 https://doi.org/10.1016/j.rser.2013.10.004	journal	February 2014
Progress and prospects for low-grade heat recovery electrochemical technologies Huo, Dongxing; Tian, Hua; Shu, Gequn Sustainable Energy Technologies and Assessments, Vol. 49 https://doi.org/10.1016/j.seta.2021.101802	journal	February 2022
All-Soluble All-Iron Aqueous Redox-Flow Battery Gong, Ke; Xu, Fei; Grunewald, Jonathan B. ACS Energy Letters, Vol. 1, Issue 1 https://doi.org/10.1021/acsenergylett.6b00049	journal	May 2016
Assessment methods and performance metrics for redox flow batteries Yao, Yanxin; Lei, Jiafeng; Shi, Yang Nature Energy https://doi.org/10.1038/s41560-020-00772-8	journal	February 2021
Copper(i) speciation in mixed thiosulfate-chloride and ammonia-chloride solutions: XAS and UV-Visible spectroscopic studies Etschmann, Barbara E.; Black, Jay R.; Grundler, Pascal V. RSC Advances, Vol. 1, Issue 8 https://doi.org/10.1039/C1RA00708D	journal	January 2011
Towards an all-copper redox flow battery based on a copper-containing ionic liquid Schaltin, Stijn; Li, Yun; Brooks, Neil R. Chemical Communications, Vol. 52, Issue 2 https://doi.org/10.1039/C5CC06774J	journal	January 2016
Emerging electrochemical and membrane-based systems to convert low-grade heat to electricity Rahimi, Mohammad; Straub, Anthony P.; Zhang, Fang Energy & Environmental Science, Vol. 11, Issue 2 https://doi.org/10.1039/C7EE03026F	journal	January 2018
Thermally regenerative copper nanoslurry flow batteries for heat-to-power conversion with low-grade thermal energy Maye, Sunny; Girault, Hubert H.; Peljo, Pekka Energy & Environmental Science, Vol. 13, Issue 7 https://doi.org/10.1039/D0EE01590C	journal	January 2020
Innovative technologies for energy production from low temperature heat sources: critical literature review and thermodynamic analysis Brogioli, Doriano; La Mantia, Fabio Energy & Environmental Science, Vol. 14, Issue 3 https://doi.org/10.1039/D0EE02795B	journal	January 2021
Towards a thermally regenerative all-copper redox flow battery Peljo, Pekka; Lloyd, David; Doan, Nguyet Physical Chemistry Chemical Physics, Vol. 16, Issue 7 https://doi.org/10.1039/c3cp54585g	journal	January 2014
GEOTHERMAL ENERGY FROM THE EARTH:Its Potential Impact as an Environmentally Sustainable Resource Mock, John E.; Tester, Jefferson W.; Wright, P. Michael Annual Review of Energy and the Environment, Vol. 22, Issue 1 https://doi.org/10.1146/annurev.energy.22.1.305	journal	November 1997
The Energy Storage Density of Redox Flow Battery Chemistries: A Thermodynamic Analysis Hall, Derek M.; Grenier, Justin; Duffy, Timothy S. Journal of The Electrochemical Society, Vol. 167, Issue 11 https://doi.org/10.1149/1945-7111/aba4e2	journal	July 2020
An All-Aqueous Thermally Regenerative Ammonia Battery Chemistry Using Cu(I, II) Redox Reactions Springer, Renaldo; Cross, Nicholas R.; Lvov, Serguei N. Journal of The Electrochemical Society, Vol. 168, Issue 7 https://doi.org/10.1149/1945-7111/ac1030	journal	July 2021
A Transient Vanadium Flow Battery Model Incorporating Vanadium Crossover and Water Transport through the Membrane Knehr, K. W.; Agar, Ertan; Dennison, C. R. Journal of The Electrochemical Society, Vol. 159, Issue 9 https://doi.org/10.1149/2.017209jes	journal	January 2012
Analysis and Optimization of Thermally-Regenerative Ammonia-Based Flow Battery Based on a 3-D Model Tian, Hua; Jiang, Wei; Shu, Gequn Journal of The Electrochemical Society, Vol. 166, Issue 13 https://doi.org/10.1149/2.0711912jes	journal	January 2019

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