ARJUNA: An Electrochemical Interface Mapping Probe for Solid-State Batteries

Dixit, Marm; Kwok, Chen Yuen; Amin, Ruhul; Polizos, Georgios; Balasubramanian, Mahalingam; Belharouak, Ilias

doi:10.1149/1945-7111/ad3f53

Title: ARJUNA: An Electrochemical Interface Mapping Probe for Solid-State Batteries

Journal Article · 24 April 2024 · Journal of the Electrochemical Society

DOI: https://doi.org/10.1149/1945-7111/ad3f53 · OSTI ID:2340967

; Kwok, Chen Yuen; Amin, Ruhul; Polizos, Georgios;

; Belharouak, Ilias

Solid-state batteries (SSBs) are promising candidates for next-generation energy storage, although their performance can be compromised by interfacial heterogeneity within the electrolyte. Furthermore, ensuring the quality of large form-factors electrolyte film is crucial for establishing a robust manufacturing platform for solid-state batteries. Herein, we report on the use of ARJUNA, an electrochemical interface mapping system, to characterize heterogeneities at solid electrolyte interfaces and to serve as a quality control system for SSB manufacturing. In addition to spatial mapping, the proposed system can also probe the interface behavior as a function of pressure and temperature. We present the operating principle, design, instrumentation, and evaluation of the system alongside a typical hybrid solid electrolyte produced using two common manufacturing processes. This report showcases the capability of ARJUNA to probe the heterogeneity and quality of processed solid electrolyte films.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE; USDOE Laboratory Directed Research and Development (LDRD) Program; USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 2340967

Journal Information:: Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Journal Issue: 4 Vol. 171; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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25 ENERGY STORAGE
batteries
interface
mapping
quality control
solid electrolyte

Title: ARJUNA: An Electrochemical Interface Mapping Probe for Solid-State Batteries

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