Tuning lithium–yttrium chloride local structure through coordination control and mixing during synthesis

Brahmbhatt, Teerth; Li, Cheng; Garaga, Mounesha N.; Tsai, Wan-Yu; Greenbaum, Steve G.; Nanda, Jagjit; Sacci, Robert L.

doi:10.1039/D4QI00559G

Title: Tuning lithium–yttrium chloride local structure through coordination control and mixing during synthesis

Journal Article · 13 May 2024 · Inorganic Chemistry Frontiers (Online)

DOI: https://doi.org/10.1039/D4QI00559G · OSTI ID:2339914

Brahmbhatt, Teerth ^[1]; Li, Cheng ^[2];

^[3];

^[4];

^[3]; Nanda, Jagjit ^[5];

^[4]

Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37830, USA, Bredesen Center for Interdisciplinary Research and Education, University of Tennessee, Knoxville, TN 37996, USA
Neutron Scattering Division, Oak Ridge National Laboratory, Oak Ridge, TN 37830, USA
Department of Physics and Astronomy, Hunter College, City University of New York, New York, NY 10065, USA
Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37830, USA
Applied Energy Division, SLAC National Laboratory, Menlo Park, CA 94025, USA, Materials Science and Engineering, Stanford University, Stanford, CA 94035, USA

Synthesis of Li ₃ YCl ₆ is facilitated by the addition of NH ₄ Cl. Synthesis method affects local ordering and Li ⁺ dynamics as determined by neutron diffraction, impedance and NMR spectroscopy.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 2339914

Alternate ID(s):: OSTI ID: 2403632

Journal Information:: Inorganic Chemistry Frontiers (Online), Journal Name: Inorganic Chemistry Frontiers (Online) Journal Issue: 10 Vol. 11; ISSN 2052-1553; ISSN ICFNAW

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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