N-Heterocyclic Carbene to Actinide d-Based π-bonding Correlates with Observed Metal–Carbene Bond Length Shortening Versus Lanthanide Congeners

Goodwin, Conrad A. P.; Adams, Ralph W.; Gaunt, Andrew J.; Hanson, Susan K.; Janicke, Michael T.; Kaltsoyannis, Nikolas; Liddle, Stephen T.; May, Iain; Miller, Jeffrey L.; Scott, Brian L.; Seed, John A.; Whitehead, George F. S.

doi:10.1021/jacs.3c12721

Title: N-Heterocyclic Carbene to Actinide d-Based π-bonding Correlates with Observed Metal–Carbene Bond Length Shortening Versus Lanthanide Congeners

Journal Article · 03 April 2024 · Journal of the American Chemical Society

DOI: https://doi.org/10.1021/jacs.3c12721 · OSTI ID:2339659

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^[3]; Janicke, Michael T. ^[3];

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^[4]; May, Iain ^[3]; Miller, Jeffrey L. ^[3]; Scott, Brian L. ^[5];

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Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, United States, Centre for Radiochemistry Research, The University of Manchester, Oxford Road, Manchester M13 9PL, U.K., Department of Chemistry, The University of Manchester, Oxford Road, Manchester M13 9PL, U.K.
Department of Chemistry, The University of Manchester, Oxford Road, Manchester M13 9PL, U.K.
Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, United States
Centre for Radiochemistry Research, The University of Manchester, Oxford Road, Manchester M13 9PL, U.K., Department of Chemistry, The University of Manchester, Oxford Road, Manchester M13 9PL, U.K.
Materials Physics & Applications Division, Los Alamos National Laboratory, Los Alamos, New Mexico, 87545, United States

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Sponsoring Organization:: USDOE

OSTI ID:: 2339659

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 15 Vol. 146; ISSN 0002-7863

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Electronic Energy Levels of the Lighter Actinides: U ³⁺ , Np ³⁺ , Pu ³⁺ , Am ³⁺ , and Cm ³⁺ Carnall, W. T.; Wybourne, B. G. The Journal of Chemical Physics, Vol. 40, Issue 11 https://doi.org/10.1063/1.1725018	journal	June 1964
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