Relaxation and diffusion of an ionic plasticizer in amorphous poly(vinylpyrrolidone)

Röwekamp, Lara; Moch, Kevin; Seren, Merve; Münzner, Philipp; Böhmer, Roland; Gainaru, Catalin

doi:10.1039/D4CP01001A

Title: Relaxation and diffusion of an ionic plasticizer in amorphous poly(vinylpyrrolidone)

Journal Article · 01 May 2024 · Physical Chemistry Chemical Physics. PCCP

DOI: https://doi.org/10.1039/D4CP01001A · OSTI ID:2338222

Röwekamp, Lara ^[1];

^[1]; Seren, Merve ^[1];

^[1];

^[2]

Fakultät Physik, Technische Universität Dortmund, D-44221 Dortmund, Germany
Fakultät Physik, Technische Universität Dortmund, D-44221 Dortmund, Germany, Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA

The present work focuses on the dynamics of the ionic constituents of 1-propyl-3-methyl-imidazolium-bis-(trifluormethylsulfonyl)-imide (PMIM-TFSI), a paradigmatic ionic liquid, as an additive in poly(vinylpyrrolidone) (PVP).

View Journal Article

Cite

Export

Save

Sponsoring Organization:: USDOE

OSTI ID:: 2338222

Journal Information:: Physical Chemistry Chemical Physics. PCCP, Journal Name: Physical Chemistry Chemical Physics. PCCP Vol. 26 Journal Issue: 17; ISSN 1463-9076

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (81)

Modified Free Volume Theory for Self-Diffusion of Small Molecules in Amorphous Polymers Mansuri, Ali; Völkel, Milan; Feuerbach, Tim Macromolecules, Vol. 56, Issue 8 https://doi.org/10.1021/acs.macromol.2c02451	journal	April 2023
Translational and Rotational Motion of Probes in Supercooled 1,3,5-Tris(naphthyl)benzene Blackburn, F. R.; Wang, Chia-Ying; Ediger, M. D. The Journal of Physical Chemistry, Vol. 100, Issue 46 https://doi.org/10.1021/jp9622041	journal	January 1996
Broadband dielectric investigation on poly(vinyl pyrrolidone) and its water mixtures Cerveny, Silvina; Alegría, Ángel; Colmenero, Juan The Journal of Chemical Physics, Vol. 128, Issue 4 https://doi.org/10.1063/1.2822332	journal	January 2008
Structure and dynamics of short-chain polymerized ionic liquids Wieland, F.; Bocharova, V.; Münzner, P. The Journal of Chemical Physics, Vol. 151, Issue 3 https://doi.org/10.1063/1.5109228	journal	July 2019
Alternative Explanation of the Difference between Translational Diffusion and Rotational Diffusion in Supercooled Liquids Ngai, K. L. The Journal of Physical Chemistry B, Vol. 103, Issue 48 https://doi.org/10.1021/jp990554s	journal	November 1999
Comparative Study of DSC-Based Protocols for API–Polymer Solubility Determination Mathers, Alex; Hassouna, Fatima; Klajmon, Martin Molecular Pharmaceutics, Vol. 18, Issue 4 https://doi.org/10.1021/acs.molpharmaceut.0c01232	journal	March 2021
On Enhanced Translational Diffusion or the Fractional Stokes−Einstein Relation Observed in a Supercooled Ionic Liquid Ngai, K. L. The Journal of Physical Chemistry B, Vol. 110, Issue 51 https://doi.org/10.1021/jp065601c	journal	December 2006
Charge transport and mass transport in imidazolium-based ionic liquids Sangoro, J. R.; Serghei, A.; Naumov, S. Physical Review E, Vol. 77, Issue 5 https://doi.org/10.1103/PhysRevE.77.051202	journal	May 2008
Thermal and electrochemical stability of cathode materials in solid polymer electrolyte Xia, Yongyao; Fujieda, Takuya; Tatsumi, Kuniaki Journal of Power Sources, Vol. 92, Issue 1-2 https://doi.org/10.1016/S0378-7753(00)00533-4	journal	January 2001
Dynamic processes in ionic glasses Angell, C. Austin Chemical Reviews, Vol. 90, Issue 3 https://doi.org/10.1021/cr00101a006	journal	May 1990
Importance of liquid fragility for energy applications of ionic liquids Sippel, P.; Lunkenheimer, P.; Krohns, S. Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep13922	journal	September 2015
Temperature dependent Broadband dielectric relaxation study of Aqueous Polyvinylpyrrolidone (PVP K-15, K-30 & K-90) using a TDR Ingole, Shital A.; Kumbharkhane, Ashok Physics and Chemistry of Liquids, Vol. 59, Issue 5 https://doi.org/10.1080/00319104.2020.1836641	journal	October 2020
Communication: Correlation of terminal relaxation rate and viscosity enhancement in supramolecular small-molecule liquids Bierwirth, S. P.; Gainaru, C.; Böhmer, R. The Journal of Chemical Physics, Vol. 148, Issue 22 https://doi.org/10.1063/1.5037803	journal	June 2018
Enhanced translation of probe molecules in supercooled o ‐terphenyl: Signature of spatially heterogeneous dynamics? Cicerone, Marcus T.; Ediger, M. D. The Journal of Chemical Physics, Vol. 104, Issue 18 https://doi.org/10.1063/1.471433	journal	May 1996
The Role of Ionic Liquids in the Pharmaceutical Field: An Overview of Relevant Applications Pedro, Sónia N.; R. Freire, Carmen S.; Silvestre, Armando J. D. International Journal of Molecular Sciences, Vol. 21, Issue 21 https://doi.org/10.3390/ijms21218298	journal	November 2020
Application of free-volume theory to self diffusion of solvents in polymers below the glass transition temperature: A review Ramesh, N.; Davis, P. K.; Zielinski, J. M. Journal of Polymer Science Part B: Polymer Physics, Vol. 49, Issue 23 https://doi.org/10.1002/polb.22366	journal	September 2011
Molecular Mobility as an Effective Predictor of the Physical Stability of Amorphous Trehalose Bhardwaj, Sunny P.; Suryanarayanan, Raj Molecular Pharmaceutics, Vol. 9, Issue 11 https://doi.org/10.1021/mp300302g	journal	October 2012
Heterogeneity at the Glass Transition: Translational and Rotational Self-Diffusion Chang, Inyong; Sillescu, Hans The Journal of Physical Chemistry B, Vol. 101, Issue 43 https://doi.org/10.1021/jp9640989	journal	October 1997
Dielectric studies of molecular motions in the glassy states of pure and aqueous poly(vinylpyrrolidone) Jain, S. K.; Johari, G. P. The Journal of Physical Chemistry, Vol. 92, Issue 20 https://doi.org/10.1021/j100331a061	journal	October 1988
Polymers: Opening Doors to Future Batteries Muldoon, John; Bucur, Claudiu B.; Boaretto, Nicola Polymer Reviews, Vol. 55, Issue 2 https://doi.org/10.1080/15583724.2015.1011966	journal	April 2015
Structural and dynamical characterisation of intermediate water interacting polyvinyl pyrrolidone Nakada, Masaru; Ishida, Hiroyuki; Furushima, Yoshitomo Materialia, Vol. 12 https://doi.org/10.1016/j.mtla.2020.100743	journal	August 2020
Solubilities of Crystalline Drugs in Polymers: An Improved Analytical Method and Comparison of Solubilities of Indomethacin and Nifedipine in PVP, PVP/VA, and PVAc Sun, Ye; Tao, Jing; Zhang, Geoff G. Z. Journal of Pharmaceutical Sciences, Vol. 99, Issue 9 https://doi.org/10.1002/jps.22251	journal	September 2010
The relationship between charge and molecular dynamics in viscous acid hydrates Ahlmann, S.; Münzner, P.; Moch, K. The Journal of Chemical Physics, Vol. 155, Issue 1 https://doi.org/10.1063/5.0055179	journal	July 2021
Communication: Fast dynamics perspective on the breakdown of the Stokes-Einstein law in fragile glassformers Puosi, F.; Pasturel, A.; Jakse, N. The Journal of Chemical Physics, Vol. 148, Issue 13 https://doi.org/10.1063/1.5025614	journal	April 2018
Ideal Copolymers and the Second-Order Transitions of Synthetic Rubbers. I. Noncrystalline Copolymers Gordon, Manfred; Taylor, James S. Rubber Chemistry and Technology, Vol. 26, Issue 2 https://doi.org/10.5254/1.3539818	journal	June 1953
Coupling and Decoupling of Rotational and Translational Diffusion of Proteins under Crowding Conditions Roos, Matthias; Ott, Maria; Hofmann, Marius Journal of the American Chemical Society, Vol. 138, Issue 32 https://doi.org/10.1021/jacs.6b06615	journal	August 2016
Rotational correlation functions and apparently enhanced translational diffusion in a free-energy landscape model for the α relaxation in glass-forming liquids Diezemann, Gregor; Sillescu, Hans; Hinze, Gerald Physical Review E, Vol. 57, Issue 4 https://doi.org/10.1103/PhysRevE.57.4398	journal	April 1998
Influence of Polymer Molecular Weight on Drug–polymer Solubility: A Comparison between Experimentally Determined Solubility in PVP and Prediction Derived from Solubility in Monomer Knopp, Matthias Manne; Olesen, Niels Erik; Holm, Per Journal of Pharmaceutical Sciences, Vol. 104, Issue 9 https://doi.org/10.1002/jps.24410	journal	September 2015
Molecular Dynamics and Diffusion in Amorphous Solid Dispersions Containing Imidacloprid Mansuri, Ali; Münzner, Philipp; Heermant, Anrika Molecular Pharmaceutics, Vol. 20, Issue 4 https://doi.org/10.1021/acs.molpharmaceut.2c01042	journal	March 2023
Rheology based estimates of self- and collective diffusivities in viscous liquids Gainaru, C.; Ahlmann, S.; Röwekamp, L. S. The Journal of Chemical Physics, Vol. 155, Issue 1 https://doi.org/10.1063/5.0055811	journal	July 2021
Transport Properties of the Solid Polymer Electrolyte System P(EO) _n LiTFSI Edman, Ludvig; Doeff, Marca M.; Ferry, Anders The Journal of Physical Chemistry B, Vol. 104, Issue 15 https://doi.org/10.1021/jp993897z	journal	April 2000
Fundamental questions relating to ion conduction in disordered solids Dyre, Jeppe C.; Maass, Philipp; Roling, Bernhard Reports on Progress in Physics, Vol. 72, Issue 4 https://doi.org/10.1088/0034-4885/72/4/046501	journal	March 2009
Hydrogen Bonding Interactions in Amorphous Indomethacin and Its Amorphous Solid Dispersions with Poly(vinylpyrrolidone) and Poly(vinylpyrrolidone- co -vinyl acetate) Studied Using ¹³ C Solid-State NMR Yuan, Xiaoda; Xiang, Tian-Xiang; Anderson, Bradley D. Molecular Pharmaceutics, Vol. 12, Issue 12 https://doi.org/10.1021/acs.molpharmaceut.5b00705	journal	November 2015
An explanation of the differences in diffusivity of the components of the metallic glass Pd43Cu27Ni10P20 Ngai, K. L.; Capaccioli, S. The Journal of Chemical Physics, Vol. 138, Issue 9 https://doi.org/10.1063/1.4793597	journal	March 2013
Dielectric relaxation strength and magnitude of dipole moment of poly(vinyl pyrrolidone)in polar solutions Shinyashiki, Naoki; Miyara, Masahiko; Nakano, Shinya Journal of Molecular Liquids, Vol. 181 https://doi.org/10.1016/j.molliq.2013.02.020	journal	May 2013
Ionic Liquid–Polymer Composites: A New Platform for Multifunctional Applications Correia, Daniela Maria; Fernandes, Liliana Correia; Martins, Pedro Manuel Advanced Functional Materials, Vol. 30, Issue 24 https://doi.org/10.1002/adfm.201909736	journal	April 2020
Equilibrium and Non-Equilibrium Type β-Relaxations: d -Sorbitol versus o -Terphenyl Wagner, Hermann; Richert, Ranko The Journal of Physical Chemistry B, Vol. 103, Issue 20 https://doi.org/10.1021/jp9838947	journal	May 1999
Nonexponential relaxations in strong and fragile glass formers Böhmer, R.; Ngai, K. L.; Angell, C. A. The Journal of Chemical Physics, Vol. 99, Issue 5 https://doi.org/10.1063/1.466117	journal	September 1993
Enhanced translational diffusion of rubrene in sucrose benzoate Rajesh Rajian, Justin; Huang, Wei; Richert, Ranko The Journal of Chemical Physics, Vol. 124, Issue 1 https://doi.org/10.1063/1.2151898	journal	January 2006
Status and prospects of polymer electrolytes for solid-state Li–O ₂ (air) batteries Yi, Jin; Guo, Shaohua; He, Ping Energy & Environmental Science, Vol. 10, Issue 4 https://doi.org/10.1039/C6EE03499C	journal	January 2017
Breakdown of the Stokes–Einstein relation in supercooled liquids Tarjus, Gilles; Kivelson, Daniel The Journal of Chemical Physics, Vol. 103, Issue 8 https://doi.org/10.1063/1.470495	journal	August 1995
Coexistence of two structural relaxation processes in monohydroxy alcohol–alkyl halogen mixtures: Dielectric and rheological studies Bierwirth, S. Peter; Gainaru, Catalin; Böhmer, Roland The Journal of Chemical Physics, Vol. 149, Issue 4 https://doi.org/10.1063/1.5037037	journal	July 2018
Ionic-Liquid-Based Polymer Electrolytes for Battery Applications Osada, Irene; de Vries, Henrik; Scrosati, Bruno Angewandte Chemie International Edition, Vol. 55, Issue 2 https://doi.org/10.1002/anie.201504971	journal	November 2015
Electrode polarization effects in broadband dielectric spectroscopy Emmert, S.; Wolf, M.; Gulich, R. The European Physical Journal B, Vol. 83, Issue 2 https://doi.org/10.1140/epjb/e2011-20439-8	journal	September 2011
The Haven ratio in glasses Isard, J. O. Journal of Non-Crystalline Solids, Vol. 246, Issue 1-2 https://doi.org/10.1016/S0022-3093(99)00036-8	journal	April 1999
Effect of Polymer Molecular Weight on the Crystallization Behavior of Indomethacin Amorphous Solid Dispersions Mohapatra, Sarat; Samanta, Subarna; Kothari, Khushboo Crystal Growth & Design, Vol. 17, Issue 6 https://doi.org/10.1021/acs.cgd.7b00096	journal	May 2017
Static and Dynamic Structure Analysis of Intermediate Water on Polyvinyl Pyrrolidone Using Neutron Scattering Nakada, Masaru; Yamada, Takeshi; Ikeda, Kazutaka Proceedings of the 3rd J-PARC Symposium (J-PARC2019) https://doi.org/10.7566/JPSCP.33.011080	conference	March 2021
Mechanism of Conductivity Relaxation in Liquid and Polymeric Electrolytes: Direct Link between Conductivity and Diffusivity Gainaru, C.; Stacy, E. W.; Bocharova, V. The Journal of Physical Chemistry B, Vol. 120, Issue 42 https://doi.org/10.1021/acs.jpcb.6b08567	journal	October 2016
Broadband Dielectric Spectroscopy Kremer, Friedrich; Schönhals, Andreas https://doi.org/10.1007/978-3-642-56120-7	book	January 2003
Aggregation Behavior in the Semidilute Poly( N -vinyl-2-pyrrolidone)/Water System Sun, Thomas; King, H. E. Macromolecules, Vol. 29, Issue 9 https://doi.org/10.1021/ma951734c	journal	January 1996
Polymer and Dye Probe Diffusion in Poly(methyl methacrylate) below the Glass Transition Studied by Forced Rayleigh Scattering Veniaminov, Andrey V.; Sillescu, Hans Macromolecules, Vol. 32, Issue 6 https://doi.org/10.1021/ma981312d	journal	March 1999
Investigating Miscibility and Molecular Mobility of Nifedipine-PVP Amorphous Solid Dispersions Using Solid-State NMR Spectroscopy Yuan, Xiaoda; Sperger, Diana; Munson, Eric J. Molecular Pharmaceutics, Vol. 11, Issue 1 https://doi.org/10.1021/mp400498n	journal	November 2013
A review of materials used as carrier agents in pesticide formulations Yusoff, S. N. M.; Kamari, A.; Aljafree, N. F. A. International Journal of Environmental Science and Technology, Vol. 13, Issue 12 https://doi.org/10.1007/s13762-016-1096-y	journal	September 2016
Large angle jumps of small molecules in amorphous matrices analyzed by 2D exchange NMR Medick, P.; Vogel, M.; Rössler, E. Journal of Magnetic Resonance, Vol. 159, Issue 2 https://doi.org/10.1016/S1090-7807(02)00100-3	journal	December 2002
Component dynamics in polyvinylpyrrolidone concentrated aqueous solutions Busselez, Rémi; Arbe, Arantxa; Cerveny, Silvina The Journal of Chemical Physics, Vol. 137, Issue 8 https://doi.org/10.1063/1.4746020	journal	August 2012
Indications for a change of diffusion mechanism in supercooled liquids Rössler, Ernst Physical Review Letters, Vol. 65, Issue 13 https://doi.org/10.1103/PhysRevLett.65.1595	journal	September 1990
Anomalous Diffusion of Probe Molecules in Polystyrene: Evidence for Spatially Heterogeneous Segmental Dynamics Cicerone, Marcus T.; Blackburn, F. R.; Ediger, M. D. Macromolecules, Vol. 28, Issue 24 https://doi.org/10.1021/ma00128a036	journal	November 1995
Perspectives for Polymer Electrolytes: A View from Fundamentals of Ionic Conductivity Bocharova, V.; Sokolov, A. P. Macromolecules, Vol. 53, Issue 11 https://doi.org/10.1021/acs.macromol.9b02742	journal	April 2020
Electrode polarization in dielectric measurements: a review Ishai, Paul Ben; Talary, Mark S.; Caduff, Andreas Measurement Science and Technology, Vol. 24, Issue 10 https://doi.org/10.1088/0957-0233/24/10/102001	journal	August 2013
Analysis of complex dielectric spectra. I. One-dimensional derivative techniques and three-dimensional modelling Wübbenhorst, Michael; van Turnhout, Jan Journal of Non-Crystalline Solids, Vol. 305, Issue 1-3 https://doi.org/10.1016/S0022-3093(02)01086-4	journal	July 2002
Enhanced translational diffusion of rubrene and tetracene in polysulfone Hwang, Y.; Ediger, M. D. Journal of Polymer Science Part B: Polymer Physics, Vol. 34, Issue 17 https://doi.org/10.1002/polb.1996.952	journal	December 1996
Biodegradable blends based on polyvinyl pyrrolidone for insulation purposes El‐Houssiny, A. S.; Ward, A. A. M.; Mansour, S. H. Journal of Applied Polymer Science, Vol. 124, Issue 5 https://doi.org/10.1002/app.35483	journal	November 2011
Enthalpy relaxation and recovery in amorphous materials Hodge, I. M. Journal of Non-Crystalline Solids, Vol. 169, Issue 3 https://doi.org/10.1016/0022-3093(94)90321-2	journal	April 1994
Heat capacities at 298.15K of the extended [CnC1im][Ntf2] ionic liquid series Rocha, Marisa A. A.; Bastos, Margarida; Coutinho, João A. P. The Journal of Chemical Thermodynamics, Vol. 53 https://doi.org/10.1016/j.jct.2012.04.025	journal	October 2012
Mechanisms Controlling the Energy Barrier for Ion Hopping in Polymer Electrolytes Gainaru, Catalin; Kumar, Rajeev; Popov, Ivan Macromolecules, Vol. 56, Issue 15 https://doi.org/10.1021/acs.macromol.3c00879	journal	July 2023
Generalization of Kramers-Kronig transforms and some approximations of relations between viscoelastic quantities Booij, H. C.; Thoone, G. P. J. M. Rheologica Acta, Vol. 21, Issue 1 https://doi.org/10.1007/BF01520701	journal	January 1982
Breakdown of the Stokes–Einstein relation in supercooled water: the jump-diffusion perspective Dubey, Vikas; Dueby, Shivam; Daschakraborty, Snehasis Physical Chemistry Chemical Physics, Vol. 23, Issue 36 https://doi.org/10.1039/D1CP02202D	journal	January 2021
Deeply supercooled aqueous LiCl solution studied by frequency-resolved shear rheology Münzner, Philipp; Hoffmann, Lars; Böhmer, Roland The Journal of Chemical Physics, Vol. 150, Issue 23 https://doi.org/10.1063/1.5100600	journal	June 2019
Mechanism of ion transport in PEO/LiTFSI complexes: Effect of temperature, molecular weight and end groups Devaux, D.; Bouchet, R.; Glé, D. Solid State Ionics, Vol. 227 https://doi.org/10.1016/j.ssi.2012.09.020	journal	October 2012
Single molecule demonstration of Debye–Stokes–Einstein breakdown in polystyrene near the glass transition temperature Mandel, Nicole L.; Lee, Soohyun; Kim, Kimyung Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-31318-z	journal	June 2022
Small-Angle X-Ray Scattering Study of Porous Polysulfone and Poly(Vinyl Pyrrolidone)/Polysulfone Blend Membranes Sen, Debasis; Mazumder, S.; Sengupta, P. Journal of Macromolecular Science, Part B, Vol. 39, Issue 2 https://doi.org/10.1081/MB-100100382	journal	March 2000
Relating the dynamics of hydrated poly(vinyl pyrrolidone) to the dynamics of highly asymmetric mixtures and polymer blends Sasaki, Kaito; Takatsuka, Masanobu; Shinyashiki, Naoki Journal of Molecular Liquids, Vol. 333 https://doi.org/10.1016/j.molliq.2021.115907	journal	July 2021
Probe translational and rotational diffusion in polymers near Tg: roles of probe size, shape, and secondary bonding in deviations from Debye–Stokes–Einstein scaling Hall, David B.; Deppe, Denise D.; Hamilton, Kenneth E. Journal of Non-Crystalline Solids, Vol. 235-237 https://doi.org/10.1016/S0022-3093(98)00642-5	journal	August 1998
Mobile ion concentrations in solid electrolytes from an analysis of a.c. conductivity Almond, D.; West, A. Solid State Ionics, Vol. 9-10 https://doi.org/10.1016/0167-2738(83)90247-3	journal	December 1983
Translational Diffusion on Heterogeneous Lattices: A Model for Dynamics in Glass Forming Materials Cicerone, Marcus T.; Wagner, Paul A.; Ediger, M. D. The Journal of Physical Chemistry B, Vol. 101, Issue 43 https://doi.org/10.1021/jp970595t	journal	October 1997
Translation-rotation paradox for diffusion in fragile glass-forming liquids Stillinger, Frank H.; Hodgdon, Jennifer A. Physical Review E, Vol. 50, Issue 3 https://doi.org/10.1103/PhysRevE.50.2064	journal	September 1994
Dynamics of Glassy, Crystalline and Liquid Ionic Conductors: Experiments, Theories, Simulations Habasaki, Junko; Leon, Carlos; Ngai, K. L. Topics in Applied Physics https://doi.org/10.1007/978-3-319-42391-3	book	January 2017
The Role of Polymer Concentration on the Molecular Mobility and Physical Stability of Nifedipine Solid Dispersions Kothari, Khushboo; Ragoonanan, Vishard; Suryanarayanan, Raj Molecular Pharmaceutics, Vol. 12, Issue 5 https://doi.org/10.1021/mp500800c	journal	April 2015
Decoupling of rotational and translational diffusion in supercooled colloidal fluids Edmond, Kazem V.; Elsesser, Mark T.; Hunter, Gary L. Proceedings of the National Academy of Sciences, Vol. 109, Issue 44 https://doi.org/10.1073/pnas.1203328109	journal	October 2012
Tuning the dynamics of imidazolium-based ionic liquids via hydrogen bonding. I. The viscous regime Thomann, C. A.; Münzner, P.; Moch, K. The Journal of Chemical Physics, Vol. 153, Issue 19 https://doi.org/10.1063/5.0026144	journal	November 2020
Tracer diffusion at the glass transition Ehlich, Dietmar; Sillescu, Hans Macromolecules, Vol. 23, Issue 6 https://doi.org/10.1021/ma00208a008	journal	March 1990

Similar Records

Tuning the dynamics of imidazolium-based ionic liquids via hydrogen bonding. I. The viscous regime

Journal Article · 2020 · Journal of Chemical Physics · OSTI ID:1767846

Thomann, C. A.; Münzner, P.; Moch, K.; +5 more

Poly(methyl methacrylate)-block-poly(n-butyl methacrylate) Diblock Copolymer Micelles in an Ionic Liquid: Scaling of Core and Corona Size with Core Block Length

Journal Article · 2016 · Macromolecules · OSTI ID:1256360

Ma, Yuanchi; Lodge, Timothy P.

Ion Dynamics in Ionic-Liquid-Based Li-Ion Electrolytes Investigated by Neutron Scattering and Dielectric Spectroscopy

Journal Article · 2018 · ChemSusChem · OSTI ID:1479749

Jafta, Charl J.; Bridges, Craig; Haupt, Leon; +10 more

Title: Relaxation and diffusion of an ionic plasticizer in amorphous poly(vinylpyrrolidone)

Citation Formats

References (81)

Similar Records

Related Subjects