Extraction of 88Y, 152Eu, 228Ac, 241Am, and 244Cm with 2-thenoyltrifluoroacetone (TTA) resin

Kmak, Kelly N.; Despotopulos, John D.; Kerlin, William

doi:10.1007/s10967-024-09448-z

Title: Extraction of ⁸⁸Y, ¹⁵²Eu, ²²⁸Ac, ²⁴¹Am, and ²⁴⁴Cm with 2-thenoyltrifluoroacetone (TTA) resin

Journal Article · 20 March 2024 · Journal of Radioanalytical and Nuclear Chemistry

DOI: https://doi.org/10.1007/s10967-024-09448-z · OSTI ID:2338048

^[1]; Despotopulos, John D. ^[1]; Kerlin, William ^[1]

Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States). Nuclear and Chemical Sciences Division

In this report the behavior of ⁸⁸Y, ¹⁵²Eu, ²²⁸Ac, ²⁴¹Am, and ²⁴⁴Cm was studied with 2-thenoyltrifluoroacetone resin with batch uptake, kinetics and column studies. Studies were performed in acetate buffer solutions (pH ~ 2 to ~ 6) and there was high uptake of all isotopes, except ²²⁸Ac, at pH > 4.5. The kinetics of uptake were reasonable, although slower for the actinides, and sufficient for column studies. The retention of ⁸⁸Y, ¹⁵²Eu, and ²⁴¹Am on the resin in column studies was demonstrated as well as a reasonable separation of these isotopes from ²²⁸Ac.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC52-07NA27344

OSTI ID:: 2338048

Report Number(s):: LLNL-JRNL-858107; 1088197

Journal Information:: Journal of Radioanalytical and Nuclear Chemistry, Journal Name: Journal of Radioanalytical and Nuclear Chemistry Journal Issue: 4 Vol. 333; ISSN 0236-5731

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

References (31)

Synergistic extraction of rare earth elements, actinium, americium, and barium with TTA and Pb resin from acetate buffer solutions Kmak, Kelly N.; Despotopulos, John D. Journal of Radioanalytical and Nuclear Chemistry, Vol. 332, Issue 8 https://doi.org/10.1007/s10967-023-09027-8	journal	July 2023
A REVIEW OF THE BASIC CHEMISTRY AND RECENT DEVELOPMENTS IN TRIVALENT f-ELEMENTS SEPARATIONS Nash, Kenneth L. Solvent Extraction and Ion Exchange, Vol. 11, Issue 4 https://doi.org/10.1080/07366299308918184	journal	May 1993
Instruments for Radiation Measurement in Life Sciences (4) . VI. Use of Accelerator Mass Spectrometry in Studies on Drug Metabolism and Pharmacokinetics Ikeda, Toshihiko RADIOISOTOPES, Vol. 54, Issue 1 https://doi.org/10.3769/radioisotopes.54.15	journal	January 2005
Separation and preconcentration of uranium from acidic media by extraction chromatography Horwitz, E. Philip; Dietz, Mark L.; Chiarizia, Renato Analytica Chimica Acta, Vol. 266, Issue 1 https://doi.org/10.1016/0003-2670(92)85276-C	journal	August 1992
Solvent Effect on Synergistic Extraction of Americium(III)/ 2 -Thenoyltrifluoroacetone /Crown Ether Meguro, Yoshihiro; Muto, Hiroshi; Yoshida, Zenko Analytical Sciences, Vol. 7, Issue S1 https://doi.org/10.2116/analsci.7.Supple_51	journal	February 1991
The hydrolysis of actinium Zielińska, B.; Bilewicz, A. Journal of Radioanalytical and Nuclear Chemistry, Vol. 261, Issue 1 https://doi.org/10.1023/B:JRNC.0000030956.61947.c5	journal	January 2004
Rapid Separation of Radioactive Strontium by Solvent Extraction with TTA-Hexone Kiba, Toshiyasu; Mizukami, Shigeru Bulletin of the Chemical Society of Japan, Vol. 31, Issue 9 https://doi.org/10.1246/bcsj.31.1007	journal	September 1958
Studies of Actinium(III) in Various Solutions. II. Distribution Behavior of Lanthanum(III) and Actinium(III) in Some Chelate Extraction Systems Sekine, Tatsuya; Koike, Yasuaki; Hasegawa, Yuko Bulletin of the Chemical Society of Japan, Vol. 42, Issue 2 https://doi.org/10.1246/bcsj.42.432	journal	February 1969
Synergistic solvent extraction of rare-earth metal ions with thenoyltrifluoroacetone admixed with tributylphosphate Farbu, L.; Alstad, J.; Augustson, J. H. Journal of Inorganic and Nuclear Chemistry, Vol. 36, Issue 9 https://doi.org/10.1016/0022-1902(74)80730-X	journal	September 1974
A Study of Hydrolysis Reaction of Curium(III) by Time Resolved Laser Fluorescence Spectroscopy Wimmer, H.; Klenze, R.; Kim, J. I. ract, Vol. 56, Issue 2 https://doi.org/10.1524/ract.1992.56.2.79	journal	February 1992
Extraction of radium and actinium with dibenzo-21-crown-7 resin and Rose Bengal Kmak, Kelly N.; Despotopulos, John D. Journal of Radioanalytical and Nuclear Chemistry, Vol. 331, Issue 7 https://doi.org/10.1007/s10967-022-08368-0	journal	June 2022
The Isolation of Actinium ¹ Hagemann, French Journal of the American Chemical Society, Vol. 72, Issue 2 https://doi.org/10.1021/ja01158a033	journal	February 1950
Solvent extraction of rare-earth metal ions with thenoyltrifluoroacetone in carbon tetrachloride Alstad, J.; Augustson, J. H.; Farbu, L. Journal of Inorganic and Nuclear Chemistry, Vol. 36, Issue 4 https://doi.org/10.1016/0022-1902(74)80832-8	journal	April 1974
New separation method for americium based on liquid-liquid extraction behavior of americium(V) Stokely, James R.; Moore, Fletcher Langley. Analytical Chemistry, Vol. 39, Issue 8 https://doi.org/10.1021/ac60252a027	journal	July 1967
Steric Effects in the Synergic Extraction of the Lanthanides, Yttrium, and Scandium Manning, P. G. Canadian Journal of Chemistry, Vol. 41, Issue 3 https://doi.org/10.1139/v63-093	journal	March 1963
Synergistic Extraction of Trivalent Actinides and Lanthanides Using Htta and an Aza-Crown Ether Ensor, Dale D.; Nicks, Margo; Pruett, David J. Separation Science and Technology, Vol. 23, Issue 12-13 https://doi.org/10.1080/01496398808075634	journal	October 1988
Synergistic extraction of trivalent Am, Cm, Bk and Cf with HTTA+TBP in xylene Khopkar, P. K.; Mathur, J. N. Journal of Radioanalytical Chemistry, Vol. 60, Issue 1 https://doi.org/10.1007/BF02518290	journal	March 1980
Crown Ethers as Synergistic Agents in the Solvent Extraction of Trivalent Lanthanoids with Thenoyltrifluoroacetone Atanassova, M.; Dukov, I. L. Separation Science and Technology, Vol. 40, Issue 5 https://doi.org/10.1081/SS-200049855	journal	April 2005
Overview of the Actinide and Lanthanide (the f ) Elements Seaborg, Glenn T. Radiochimica Acta, Vol. 61, Issue 3-4 https://doi.org/10.1524/ract.1993.61.34.115	journal	January 1993
Comparative hydrolysis behavior of the rare earths and yttrium: the influence of temperature and ionic strength Klungness, Greta D.; Byrne, Robert H. Polyhedron, Vol. 19, Issue 1 https://doi.org/10.1016/S0277-5387(99)00332-0	journal	January 2000
Extraction of some Lanthanides and Actinides by 15-Crown-5 Thenoyltrifluoroacetone Mixture in Chloroform Aly, H. F.; Khalifa, S. M.; Navratil, J. D. Solvent Extraction and Ion Exchange, Vol. 3, Issue 5 https://doi.org/10.1080/07366298508918531	journal	October 1985
Metals Analysis with Thenoyltrifluoroacetone Moore, F. L. Symposium on Solvent Extraction in The Analysis of Metals https://doi.org/10.1520/STP39522S	book	January 1958
Distribution studies between thenoyltrifluoroacetone (TTA) in methyl isobutyl ketone (MIBK) and aqueous solutions using radiotracers of Group II and Group III elements Jackson, W. Morrison.; Gleason, Geoffrey I.; Hammons, Percy J. Analytical Chemistry, Vol. 42, Issue 11 https://doi.org/10.1021/ac60293a004	journal	September 1970
A summary of TTA extraction coefficients Poskanzer, A. M.; Foreman, B. M. Journal of Inorganic and Nuclear Chemistry, Vol. 16, Issue 3-4 https://doi.org/10.1016/0022-1902(61)80507-1	journal	February 1961
A tetrad effect in the liquid-liquid extraction ordering of lanthanides(III) Peppard, D. F.; Mason, G. W.; Lewey, S. Journal of Inorganic and Nuclear Chemistry, Vol. 31, Issue 7 https://doi.org/10.1016/0022-1902(69)90044-X	journal	July 1969
The Chemistry of Americium. I. A Study of the Preparation of Am (V) and Its Behavior by Means of TTA Extraction Hara, Mitsuo Bulletin of the Chemical Society of Japan, Vol. 43, Issue 1 https://doi.org/10.1246/bcsj.43.89	journal	January 1970
Solvent Extraction Separation of Trivalent Americium from Curium and the Lanthanides Jensen, Mark P.; Chiarizia, Renato; Ulicki, Joseph S. Solvent Extraction and Ion Exchange, Vol. 33, Issue 4 https://doi.org/10.1080/07366299.2015.1046292	journal	February 2015
Extraction Behavior of Americium and Curium on Selected Extraction Chromatography Resins from Pure Acidic Matrices Gharibyan, Narek; Dailey, Ashlee; McLain, Derek R. Solvent Extraction and Ion Exchange, Vol. 32, Issue 4 https://doi.org/10.1080/07366299.2014.884888	journal	May 2014
A Novel Strontium-Selective Extraction Chromatographic Resin* Philip Horwitz, E.; Chiarizia, Renato; Dietz, Mark L. Solvent Extraction and Ion Exchange, Vol. 10, Issue 2 https://doi.org/10.1080/07366299208918107	journal	April 1992
Separation of oxidised americium from trivalent transplutonium elements and lanthanides by solvent extraction Fardy, J. J.; Buchanan, J. M. Journal of Inorganic and Nuclear Chemistry, Vol. 38, Issue 1 https://doi.org/10.1016/0022-1902(76)80068-1	journal	January 1976
Synergistic Extraction of Trivalent Actinides by Mixtures of Thenoyltrifluoroacetone and Neutral Oxo Donors Khopkar, P. K.; Mathur, Jagdish N. Separation Science and Technology, Vol. 16, Issue 8 https://doi.org/10.1080/01496398108058139	journal	September 1981

Similar Records

Synergistic extraction of rare earth elements, actinium, americium, and barium with TTA and Pb resin from acetate buffer solutions

Journal Article · 2023 · Journal of Radioanalytical and Nuclear Chemistry · OSTI ID:1996098

Kmak, Kelly N.; Despotopulos, John D.

Rapid Method for Ra-226 and Ra-228 in Water Samples

Journal Article · 2006 · OSTI ID:881497

Coprecipitation of {sup 152}Eu with Iron(III) hydroxide formed upon reduction of sodium ferrate(VI) in aqueous medium

Journal Article · 1995 · Radiochemistry · OSTI ID:160278

Stupin, D Yu; Ozernoi, M I

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
extraction chromatography
rare earth elements
americium
actinium
curium

Title: Extraction of 88Y, 152Eu, 228Ac, 241Am, and 244Cm with 2-thenoyltrifluoroacetone (TTA) resin

Citation Formats

References (31)

Similar Records

Related Subjects

Title: Extraction of ⁸⁸Y, ¹⁵²Eu, ²²⁸Ac, ²⁴¹Am, and ²⁴⁴Cm with 2-thenoyltrifluoroacetone (TTA) resin